Chemical Feed & Disinfection

Siemens Water Technologies
Strantrol®
Control Systems
Chemical Feed & Disinfection – Municipal
For internal use only / Copyright © Siemens

Protection
AG 2006.
noticeAll
/ Copyright
rights reserved.
notice
Page 1 Strantrol_2008.ppt Water Technologies
Overview of Contents
Today, disinfection and

dechlorination in water can be Contents
precisely controlled by High
Resolution Redox® (HRR) § Introduction 3
a result of Siemens’ research. § Technical Overview 5
§ Product Portfolio 26
In applications worldwide, HRR®
§ Municipal Applications 34
sensing is used to control the
addition of chlorine, bromine, § Implementation 38
ozone, sulfur dioxide, sodium § Service Capabilities 50
metabisulfite and sodium
§ References 53
bisulfite.
Protection notice / Copyright notice

Siemens – Innovation to Change
Energy
From the invention of the dynamo – to the world's most efficient gas turbines
Industry
From the first electronic controls – to fully automated factories
Healthcare
From the first views inside the body – to full-body 3D scans

Siemens Water Technologies
Chemical Feed & Disinfection (CF&D) Group
§ Comprised of Wallace & Tiernan® and Stranco® products
§ In 2006, acquired ALTIVIA chlorine dioxide and Sunlight UV
CF&D Global Headquarters – Vineland, New Jersey

Technical Overview
A FEW ADDITIONAL FACTORS TO

CONSIDER ABOUT DISINFECTION:
Successful Disinfection:
§ What is Required for Compliance?
§ ORP vs. PPM
Sufficient Quantity = Residual § Basic Process Chemistry
§ Work Value Relationship of Your
+ Oxidant
§ Benefits of the DOCS Hybrid Control
Sufficient Time = Contact Time Technology
Strantrol®
Control Systems

Technical Overview
Residual Control
§ All the measurements for residual only give the quantitative

picture.
§ Typically measure chlorine residual in ppm.
EPA Observations
“Chick’s Law does not accurately predict coliform numbers as
a function of dose in the real-world, continuous flow
systems….The observation has frequently been made that
inactivation of organisms in batch experiments, even when the
disinfectant is kept constant, does not follow the exponential
decay pattern predicted”

Technical Overview
ORP Free Residual

2 2
1.8 1.8
1.6 1.6
1.4 1.4
1.2 1.2
1 1
0.8 0.8
0.6 0.6
0.4 0.4
0.2 0.2
0 0
1 2 3 4 5 6 7 8 9 10 1 2 3 4 5 6 7 8 9 10
Time
Technical Overview
Disinfection Performance
fecal coliform fecal coliform

chlorine residual
chlorine residual
time time
Technical Overview
+ 50% Correlation to kill

+ + +
Free Cl2 ( 0 - 3 ppm )
+
+ + + +
+ +
+ + +
+
+ +
Time ( 4 hours )
Technical Overview
+ 97% Correlation to kill

+
ORP ( 200 - 800 mV )
+ +
+ +
+ + + +
+ +
Time
Technical Overview
Basic Chlorine Chemistry

Cl2 + H2O HCl + HOCl
(Strong Acid + Weak Acid)
HOCl H+ + OCl-
(Weak Acid Dissociates)
NaOCl + H2O NaOH + HOCl

(Strong Base + Weak Acid)
HOCl H+ + OCl-
(Weak Acid Dissociates)
Technical Overview
Typical pH Values
6.5 7.0 7.5
92% 78% 50%
HOCl OCl-
Free Residual measurement remains constant
Technical Overview
Typical pH Values
6.5 7.0 7.5
92% 78% 50%
HOCl OCl-
ORP Value Decreases
Technical Overview
Work Value of Chlorine Species
8 0
HOCl 7 0
Dichloramine 6 0
Monochloramine
5 0
4 0
Trichloramine 3 0
OCl 2 0
1 0
Organochloramine 0

Technical Overview
Wastewater Chlorination Chemistry
Inorganic Nitrogen
§ Ammonia
§ Nitrites
§ Nitrates
Organic Nitrogen
§ Amino Acids
§ Proteins

Technical Overview
Relationship Between Ammonia and Free Chlorine Residual

Technical Overview
Chloramines Exhibit Lower ORP Values

Technical Overview
Wastewater Chlorination Chemistry

§ Oxygen
§ Alkalinity Cause
§ Temperature Nitrification/Denitrification
§ pH Episodes
§ Time
§ Loading
Nitrification:
Oxidation of ammonium ion or ammonia to nitrite or nitrate
ion. How ammonia affects the water chemistry and the
disinfection process

Technical Overview
Sensor Reads Both Sides of Zero
§ Overfeed looks at sulfite residual

§ Notice what’s going on near 0 mg/L
All the measurements for ORP give

the qualitative picture; i.e. the
relative strength of disinfectant for
bug kill.

Technical Overview
Breakpoint Chlorination
NH3-N Conc.
Ammonia-N Conc. ppm

Chlorine Conc. ppm
Total Chlorine Hump
Applied
Measured
Chlorine
Residual Breakpoint
5 7.6
Cl2 to NH3-N Ratio
Technical Overview
Oxidative Disinfection
§ All oxidative disinfection can be measured and controlled by its

Oxidation Reduction Potential.
§ Track & maintain the effectiveness of the disinfection program
to ensure desired results.
§ Track & maintain the dechlorination process to maintain tight
discharge limits.
Hypochlorite, gas chlorine, chlorine dioxide & ozone.

Implementing Strantrol®
Typical Installation – Strantrol® 960

Technical Overview
Strantrol® 960 Design Philosophy
§ A new level of process and disinfection control

§ Smooth transition through process changes
§ Integrated software and control functions
§ New Slo-logic
§ Window to upstream processes
Combine quantitative value of residual (PPM) with qualitative

value of ORP (HRR)

Technical Overview
Strantrol® 960 Design Philosophy

§ Any parameter change requires an offsetting change of another
parameter
§ Integrated software to evaluate and make required changes
based on actual conditions
Sufficient Quantity = Residual

+
Sufficient Quality = ORP
+
Sufficient Time = Contact Time

Technical Overview
Strantrol® 960 Control Capabilities
Fixed Rate
ORP
Output
Flow Pace
Residual

Strantrol® Controllers
Portfolio
§ High Resolution Redox® (HRR)
§ Submersible Sensors
§ Strantrol 880
§ Strantrol 890
§ Strantrol 960 (DOCS®)
§ Strantrol FVC

High Resolution Redox® (HRR)
§ High purity platinum tip

§ Porous Teflon® liquid junction
§ Fouling resistant electrolyte gel
§ Measures oxidant/reductant activity
§ Precise disinfection control

Strantrol® Submersible Sensors

Strantrol® 880 Transmitter
§ Signal transmitter
§ Stand-alone monitor
§ RS-232 / RS-485 communication
§ ORP or pH input
§ 4-20 mA output

Strantrol® 890 Controller
§ Single channel controller

§ ORP or pH
§ 5 control modes
§ 4 line / 20 character display
§ Data logging
§ Optional modem
§ Open channel or closed loop
applications


Chemical Feed &amp; Disinfection

Hochgeladen von

Dokumentinformationen

Copyright

Verfügbare Formate

Dieses Dokument teilen

Dokument teilen oder einbetten

Freigabeoptionen

Stufen Sie dieses Dokument als nützlich ein?

Sind diese Inhalte unangemessen?

Copyright:

Verfügbare Formate

Chemical Feed &amp; Disinfection

Hochgeladen von

Copyright:

Verfügbare Formate

Siemens Water Technologies

For internal use only / Copyright © Siemens

Today, disinfection and

Protection notice / Copyright notice

From the first electronic controls – to fully automated factories

From the first views inside the body – to full-body 3D scans