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CHEMICAL BONDS
L s 2
p 6 8
M s 2
p 6
d 10 18
N s 2
p 6
d 10
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f 14
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- Dr. Binu 32
Ionization energy
ALLOYING ????
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C.Yeldose
THE PERIODIC TABLE
• Columns: Similar Valence Structure
inert gases
give up 1e
give up 2e
accept 2e
accept 1e
give up 3e
Metal
Nonmetal
H He
Li Intermediate Ne
Be O F
Na Mg S Cl Ar
K Ca Sc Se Br Kr
Rb Sr Y Te I Xe
Cs Ba Po At Rn
Fr Ra
Adapted
from Fig. 2.6,
Callister 6e.
Electropositive elements: Electronegative elements:
Readily give up electrons Mar Athanasius College of Readily acquire electrons 8
6
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to become - ions.
to become + ions.
C.Yeldose
Ionization energy vs. atomic number
2500 He
Ionization energy (kJ/mol)
Ne
2000
F Ar
1500
N
H O Cl
1000 Be C P S
B Mg Si
Al Ca
500
Li Na K
0
0 2 4 6 8 10 12 14 16 18 20
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Element
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C.Yeldose
Atomic radius vs. atomic number
250
K
Atom ic Radius (pm )
200
Na Ca
150 Li Mg
Al Si
100 Be P S Cl
B C N
O F Ar
50 Ne
H He
0
0 2 4 6 8 10 12 14 16 18 20
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Element
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Atomic Radius
ro
charge A X charge B
electrostatic energy α
distance
Presence of Imperfections
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Cohesive strength
Liquid Gas
E0
ro
Forming
of a bond
The
is like
breaking
marriage
of a bond
•More stable/ relates to
a divorce.
equilibrium
•exothermic
Divorce
•Less stable/
want of electrons to
fill outer shell
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•Endothermic
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Types of Chemical Bonding
• Crystalline structure.
• A regular repeating arrangement of ions in
the solid.
• Ions are strongly bonded.
• Structure is rigid.
• High melting points- because of strong
forces between ions.
H2 O
column IVA
H2 F2
C(diamond)
H He
2.1
Si C - Cl 2
Li Be C O F Ne
1.0 1.5 2.5 2.0 4.0 -
Na Mg Si Cl Ar
0.9 1.2 1.8 3.0 -
K Ca Ti Cr Fe Ni Zn Ga Ge As Br Kr
0.8 1.0 1.5 1.6 1.8 1.8 1.8 1.6 1.8 2.0 2.8 -
Rb Sr Sn I Xe
0.8 1.0 1.8 2.5 -
Cs Ba Pb At Rn
0.7 0.9 1.8 2.2 -
Fr Ra
0.7 0.9
Adapted from Fig. 2.7, Callister 6e. (Fig. 2.7 is GaAs
adapted from Linus Pauling, The Nature of the Chemical Bond, 3rd edition, Copyright 1939 and
1940, 3rd edition. Copyright 1960 by Cornell University.
Density???????????- low-
covalent bond
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Metallic Bonding
+ + + +
+ + + +
+ + + +
r4
r0 Deep well
r5
Bond energy
r4
r0
Deep well
NH3 35 0.36 - 78
Hydrogen
H2O 51 0.52 0
• Double bond: two pairs of electrons are shared between two atoms
• Triple bond: three pairs of electrons are shared between two atoms
Bond energy: the amount of energy required to break a bond holding two atoms
together.
HO
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Water
HO
H
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Hydrogen Bonding
Tetrahedron
H2O molecule
Hydrogen bonding
O
Ice structure
Atomic Number of
Symbol Element Mass percent
weight atoms
Nondirectional (ceramics)
Ionic Large!
Variable Directional
(semiconductors,
Covalent large-Diamond ceramics, polymer chains)
small-Bismuth
Variable
large-Tungsten Nondirectional
Metallic
small-Mercury (metals)
Directional
Secondary smallest
inter-chain (polymer),
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Strong forces within molecules and weak
forces between them.
Strong covalent bonding forces within molecules
C.Yeldose
Elastic properties determined by binding between
atoms. HOW?
Binding of atoms
TRUE STRESS