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In the industrialized countries, it is largely the demand for chlorine for the
synthesis of various organo-chloro compounds which has stimulated growth and
expansion of the chloro-alkali industry. For every tonne of chlorine made, 1.1
tonnes of caustic soda (100%) and 0.03 tonnes of hydrogen are produced.
In the diaphragm cell process, the anolyte is separated from the catholoyte by
asbestos diaphragm to prevent contact between chlorine produced at the anode
and the caustic soda and hydrogen at the cathode. In the membrane cell process,
cat-ion exchange membranes are used to separate the anode and cathode
compartment of the electrolytic cell. At the anode, chlorine ions discharge with
evolution of chlorine gas. At the cathode, hydrogen is evolved and caustic soda
is formed. The cat-ion exchange is impermeable to the chloride ions and
therefore the caustic soda produced contains only trace levels of sodium
chloride. In mercury cell process, the liquid mercury cathode forms amalgam
with sodium. The amalgam is removed from the cell and reacted with water in
denuders to give caustic soda and hydrogen. Chlorine is liberated at the anode.
Each of these processes utilizes NaCl salt as the primary raw material. The salt
is electrolytically split using direct current (DC) electricity, resulting in Chlorine
and an available sodium ion (Na+) that is reacted with water in the cell to make
Caustic Soda and by-product Hydrogen. The hydrogen by-product produced is
used as a fuel source, sold to hydrogen customers, or to produce high purity
(burner grade) Hydrochloric Acid.
the particulate filter housing, for a period of time. The strip then is
sent to a laboratory for analysis. As corrosive gases react with the
base metal of an air compressor component, a chemical product in
the form of a film will build up on the surface of the base metal.
Specially prepared copper and silver strips are usually exposed for
a time period varying from 30 to 90 days. Analysis of the test strip
will reveal the average film thickness built up during the test
period.
a. The positive displacement action of the pump lifts the raw sewage
from the sump into the cutting chamber of the macerator. The
sewage and any textile and fibrous matter is macerated and then
pumped away to the main gravity sewer. When the pumping cycle
ends, un-macerated material falls back into the sump, clearing the
suction pipe for the next duty run. Low suction velocities ensure
foreign object damage is eliminated, unlike pumping stations with
submersible pumps. Any large objects remain in the sump for
periodic removal, avoiding any pump damage.
control and make the same subject to audit and statutory compliances.
UNITS 2002-03 2003-04 2004-05
Annual Production MT 65842 77274 80209
Total Energy per Annum KWH (lakhs) 1815.87 2111.78 2214.18
Total Thermal Energy Million K cal 55901.82 56842.29 44474.07
Total Annual sales turnover Cost Rs. Lakhs 5578.7 6769.2 17688
Total Energy Cost Rs. Lakhs 5631.45 6699.62 7070.58
Energy Cost as % of Production Cost % 55.4 55.4 64
DC Electrolysis Power Consumption KWH/MT 2639 2346 2402
AC Rectification Power Consumption KWH/MT 2340 2406 2464
AC Power Consumption with Aux. KWH/MT 2726 2682 2725
Auxiliary Power Consumption KWH/MT 296 275 261
Steam Consumption Mkcal/MT 0.85 0.73 0.55
5. Coal-fired power plants can add PVC scrap to their coal and make
byproduct hydrochloric acid. The result would be elimination of mercury
both from coal-fired stacks as well as from the obsolesced chlorine
manufacturing facilities. There would also be greenhouse gas benefits
and elimination of the environmental problems associated with disposing
of millions of tons of waste PVC.
The Energy Policy in our industry is always part of our ESOH policy for ISO
14000 and OHSAS 18000 standards and it is shown as under.
Suggestions for effective implementation of EC Act in Chloro Alkali sector.
Apart from the conventional practice of involving people as a participation
systems, which is always mandatory and to be encouraged, technological
improvements are essential in making continuous improvements. And for
this mediocrity needs sharpening and encouragements to technical inputs is
paramount.
• Encourage and provide incentive to adopt membrane technology in
next 5 years. Stop manufacturing by other harmful processes using
asbestos or mercury after following first step.
• EC Act to be made a part of Pollution Control Board’s area of control.
Consents must encompass Energy standards also.
• Pursue EC Act among municipalities. This will create awareness
among masses. In a market driven economy, this industry must have
ways to efficiently manufacture a lower capacities also. Else
discourage to operate and will ensure better capacity utilization in
efficient processes.
• Chlorine is never used independently. It is mostly a feed stock for
other processes. Decentralization of Chlorine manufacturing at the
point of use will reduce many handling and storage systems of
Chlorine gas. This is being practiced but need to be speeded up.
• Renewable sources of energy are on the look out across the globe.
How about renewable sources of Chlorine? This organo-chloro
chemistry needs further research and promotion.