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MEETING REPORT
MEETING REPORT
Molecular interactions*
Although a bond between two atoms in a discussion meeting on ‘molecular inter- similar structures. Moreover, molecular
molecule is fairly well-understood, inter- actions’ was organized with the support beam electric resonance spectroscopy
molecular interactions remain at the of the Indian Academy of Sciences, Ban- showed that the complex formed between
heart of chemistry and biology. Hydro- galore. The meeting attracted scientists HF and ClF had a structure HF⋅⋅⋅ClF,
gen bonding is the most important of working in diverse fields. rather than the expected hydrogen bonded
intermolecular interactions, as it controls The meeting started with a brief intro- ClF⋅⋅⋅HF. Though it was originally called
the properties of the molecules of life, duction by E. Arunan (Indian Institute of ‘anti-hydrogen bond’, it is now well-
water and DNA. While the importance of Science (IISc), Bangalore), convener of recognized as a halogen-bonded com-
these strong O–H⋅⋅⋅O and N–H⋅⋅⋅N the meeting. He pointed out that there plex. The International Union of Pure
hydrogen bonds in life has been well- have been several key advances over the and Applied Chemistry (IUPAC) recog-
recognized for long, some recent studies last decade that challenged the conven- nized the importance of these phenomena
reveal that weak hydrogen bonds may tional wisdom about hydrogen bonding. and formed task groups to summarize our
play a crucial role in anesthesia. Ad- The stunning difference between the understanding of these phenomena and
vances in various experimental and theo- crystal structure close to the freezing define hydrogen bonding and halogen
retical techniques are contributing to point at ambient conditions, for ice bonding.
shaping and enhancing our understanding (H2O) at 0°C and H2S at –60°C has led to The meeting had 16 invited lectures
of all these molecular interactions. A the common perception of ‘hydrogen and there were discussions during and
bonding’ and ‘van der Waals interaction’ after the talks. The topics ranged from
*A report on the Discussion Meeting on as two distinguishable physical forces the interaction between two rare gas atoms
Molecular Interactions held at Orange County, among chemists. The advent of molecular such as argon and neon to the interaction
Coorg, during 28 November–1 December beam spectroscopy and scattering studies between the domains in multi-domain
2010. have showed that (H2O)2 and (H2S)2 have and multifunctional proteins. The first