Technical Information

TI 375C/07/en/06.03 pH Electrodes
51513127
OrbiPore CPS 91

pH electrodes with open aperture for heavily soiled

media, with optional built-in temperature sensor

Application
• Chemical processes
• Heavily soiled media:
– Solids
– Emulsions
– Precipitation

 With ATEX and FM approval for

application in hazardous areas

Your benefits
• Low maintenance due to gel filling
• Open aperture for application in heavily
soiled media
• Built-in temperature sensor for effective
temperature compensation (optional)
• Long service life due to new stabilised
gel
• Extremely insensitive to pressure and
temperature variation
• Short response time
• Double junction reference system
protecting from electrode poisoning

Quality made by
Endress+Hauser

ISO 9001
 OrbiPore CPS 91

Function and system design

Measuring principle pH measurement
The pH value is used as a unit of measurement for the acidity or alkalinity of a liquid medium. The
membrane glass of the electrode supplies an electrochemical potential which is dependent upon
the pH value of the medium. This potential is generated by the selective penetration of H+ ions
through the outer layer of the membrane. An electrochemical boundary layer with an electric
potential forms at this point. An integrated Ag/AgCl reference system serves as reference
electrode.
The transmitter converts the measured voltage into the corresponding pH value using the Nernst
equation.

Important properties • Open aperture

Due to its open aperture, the CPS 91 electrode can be applied in heavily soiled media.
• Temperature compensation
Depending on the ordered version, a Pt 100 or Pt 1000 temperature sensor is integrated in the
electrode to measure the medium temperature.
• Easy connection
The electrode is connected via a GSA plug-in head or via the water-proof TOP 68 plug-in
system (IP 68).
• Durability
The electrode is pressure-proof up to 13 bar / 188.5 psi and can be applied with temperatures
of up to 110 °C / 230 °F.

Measuring system A complete measuring system comprises:

• CPS 91 pH electrode
• Transmitter, e.g. Liquisys M CPM 223/253
• Special measuring cable, e.g. CPK 9
• Immersion, flow or retractable assembly, e.g. CleanFit P CPA 472

ENDRESS+HAUSER
LIQUISYS

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OrbiPore CPS 91

Input
Measured variables pH value
Temperature


Measuring range 0 ... 14 pH
0 ... 110 °C / 32 ... 230 °F
Caution!
Please note the process operating conditions.

Installation

Installation instructions Do not install the electrode overhead. The angle of inclination must be at least 15° from the
horizontal. A smaller installation angle is not allowed since such an angle results in air cushion
forming in the glass sphere. This may impair full wetting of the pH membrane with the inner
electrolyte.

permissible installation angle

not permissible! not permissible!

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Make sure to follow the installation instructions in the operating instructions for the used assembly.

Environment


Ambient temperature
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Do not operate the sensor at temperatures below –15 °C / 5 °F.

Storage temperature 0 ... 50 °C / 32 ... 122 °F

Ingress protection IP 67 with GSA plug-in head

IP 68 with TOP 68 plug-in head (1 m / 3.28 ft water column, 50 °C / 122 °F, 168 h)

Endress+Hauser 3
 OrbiPore CPS 91

Process

Process temperature 0 ... 110 °C / 32 ... 230 °F

Process pressure 0 ... 13 bar / 188.5 psi

Pressure-temperature load
curve T [°F]
32 68 104 140 176 230

14
13 188.5
12 174
10 145
p [bar]

p [psi]
8 116
6 Application range CPS 91 87
4 58
2 29
0
0 20 40 60 80 110
T [°C]
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Conductivity min. 10 µS/cm


pH range 0 ... 14 pH
Caution!
Danger of damage to the electrode
Do not operate the electrode in applications outside the given specifications!

4 Endress+Hauser
OrbiPore CPS 91

Mechanical construction
Design, dimensions
mm / inch

mm / inch

1 1

2 2

4.72, 8.86, 14.17, 16.73

4.72, 8.86, 14.17, 16.73

120, 225, 360, 425 /

3
120, 225, 360, 425 /

4 4

5 5

6 6

7
8 7
Ø 12 / Ø 12 /
Ø 0.47 Ø 0.47
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Weight approx. 0.1 kg / 0.2 lb.

Material Electrode shaft glass, suitable for processes

pH membrane glass type B
Metal lead Ag/AgCl
Diaphragm open aperture

Process connection Pg 13.5

Temperature sensor Pt 100, Pt 1000

Plug-in heads ESA plug-in head Pg 13.5, TOP 68 for electrodes with or without temperature sensor,
16 bar / 232 psi, Ex
GSA plug-in head Pg 13.5 for electrodes without temperature sensor

Electrolyte Reference electrolyte with a polymer concentration ≤ 9.8 %

Cationic cross-linked and stabilised gel

Endress+Hauser 5
 OrbiPore CPS 91

Certificates and approvals

Ex approval CPS 91 (ESA) • ATEX II 1G EEX ia IIC T4/T6
• FM Class I Div. 2, in combination with the MyPro CPM 431 and Mycom S CPM 153 transmitters

TÜV certificate TOP 68 Pressure resistance 16 bar, min. triple safety overpressure
plug-in head

Ordering information
Product structure CPS 91 Electrode type
1 without temperature sensor
2 with built-in Pt 100 (not available with GSA plug-in head)
3 with built-in Pt 1000 (not available with GSA plug-in head)

Application range
BO pH = 0 ... 14, T = 0 ... 110 °C / 32 ... 230 °F

Shaft length
2 120 mm / 4.72"
4 225 mm / 8.86"
5 360 mm / 14.17"
6 425 mm / 16.73"

Plug-in head
ESA Plug-in head Pg 13.5, TOP 68, 16 bar / 232 psi, Ex
GSA Plug-in head Pg 13.5, DIN coax, non Ex
SIX Plug-in head, Pg 13.5, Sixplug, non Ex

CPS 91- complete order code

6 Endress+Hauser
OrbiPore CPS 91

Accessories
Assemblies ❑ CleanFit W CPA 450
Manually operated retractable assembly for pH electrodes, for the installation of 120 mm
electrodes in tanks and pipes,
Ordering acc. to product structure, see Technical Information (TI 183C/07/en)
❑ CleanFit P CPA 471
Compact retractable stainless steel assembly, for the installation in tanks and pipes, manual or
pneumatic operation;
Ordering acc. to product structure, see Technical Information (TI 217C/07/en)
❑ CleanFit P CPA 472
Compact retractable plastic assembly, for the installation in tanks and pipes, manual or
pneumatic operation;
Ordering acc. to product structure, see Technical Information (TI 223C/07/en)
❑ CleanFit P CPA 473
Retractable stainless steel process assembly, with ball valve for a particularly safe and reliable
separation of the medium from the environment;
Ordering acc. to product structure, see Technical Information (TI 344C/07/en)
❑ CleanFit P CPA 474
Retractable plastic process assembly, with ball valve for a particularly safe and reliable
separation of the medium from the environment;
Ordering acc. to product structure, see Technical Information (TI 345C/07/en)

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 OrbiPore CPS 91

❑ DipFit W CPA 111

Plastic immersion and installation assembly, for open and closed tanks;
Ordering acc. to product structure, see Technical Information (TI 112C/07/en)
❑ FlowFit W CPA 250
Flow assembly for pH and ORP measurement
Ordering acc. to product structure, see Technical Information (TI 041C/07/en)

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Buffer solutions Technical buffer solutions, accuracy 0.02 pH, acc. to NIST/DIN
❑ pH 4.0 red, 100 ml (0.026 US gal.), order no. CPY 2-0
❑ pH 4.0 red, 1000 ml (0.264 US gal.), order no. CPY 2-1
❑ pH 7.0 green, 100 ml (0.026 US gal.), order no. CPY 2-2
❑ pH 7.0 green, 1000 ml (0.264 US gal.), order no. CPY 2-3
Technical buffer solutions for single use, accuracy 0.02 pH, acc. to NIST/DIN
❑ pH 4.0 20 x 20 ml (0.005 US gal.), order no. CPY 2-D
❑ pH 7.0 20 x 20 ml (0.005 US gal.), order no. CPY 2-E

Measuring cables ❑ CPK 9 special measuring cable

For pH-/redox electrodes with TOP 68 plug-in head
Ordering acc. to product structure, see Technical Information (TI 118C/07/en)
❑ CPK 1 special measuring cable
For pH-/redox electrodes with GSA plug-in head
Ordering acc. to product structure, see Technical Information (TI 118C/07/en)
❑ CPK 12 special measuring cable
For pH-/redox glass electrodes and ISFET sensors,
Ordering acc. to product structure, see Technical Information (TI 118C/07/en)

8 Endress+Hauser
OrbiPore CPS 91

Documentation
Transmitters ❑ Liquisys M CPM 223/253, Technical Information TI 194C/07/en; order no. 51500277
❑ Mycom S CPM 153, Technical Information TI 233C/07/en; order no. 51503788
❑ MyPro CPM 431, Technical Information TI 173C/07/en; order no. 50088309

Assemblies ❑ CleanFit P CPA 450, Technical Information TI 183C/07/en; order no. 50090677
❑ CleanFit P CPA 471, Technical Information TI 217C/07/en; order no. 51502596
❑ CleanFit P CPA 472, Technical Information TI 223C/07/en; order no. 51502645
❑ CleanFit P CPA 473, Technical Information TI 344C/07/en; order no. 51510923
❑ CleanFit P CPA 474, Technical Information TI 345C/07/en; order no. 51510925
❑ DipFit W CPA 111, Technical Information TI 112C/07/en; order no. 50066450
❑ FlowFit W CPA 250, Technical Information TI 041C/07/en; order no. 50036058

Measuring cables ❑ CPK 1-12, Technical Information TI 118C/07/en; order no. 50068526

Endress+Hauser 9
 OrbiPore CPS 91

10 Endress+Hauser
OrbiPore CPS 91

Endress+Hauser 11
 Endress+Hauser GmbH+Co. KG
Instruments International
P.O. Box 2222
D-79574 Weil am Rhein
Germany

Tel. (07621) 975-02

Tx 773926
Fax (07621) 975 345
e-mail: info@ii.endress.com

Internet:
http://www.endress.com

11.01

TI 375C/07/en/06.03
51513127
Printed in Germany / FM+SGML 6.0 / DT