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1)c Cleansing agents are chemical substances used to remove greasa and dirt.
2)c There are two types of cleansing agents:
a)c Soaps
b)c Detergents
3)c Soaps are sodium or potassium salt of fatty acids that contains 12 to 18 carbon atoms per
molecule.
4)c Soaps are cleansing agents made from animal fats or vegetable oil by saponification.
History of Soap Manufacturing:
1)c Soaps have been used for more than 3000 years.It was recorded that the Babylonians
and potassium carbonate.The ashes were boiled with lime (calcium oxide) to produce
caustic potash (potassium hydroxide).Caustic potash is then boiled with animal fats to
produces soap.
boiled
a)c Ash + Lime Caustic Potash
boiled
3)c In 1816,the French chemist Michel Chevreul (1786-1889) discovered that animal fats are
composed of fatty acids and glycerol.This discovery contributed to the rapid development
of the soap and candle industry.
4)c In 1816,the Belgian chemist Ernest Solvay (1838-1922) discovered the process to make
soda (sodium carbonate) from common salt (sodium chloride) and calcium
carbonate.This process is known as the Solvay Process which produces sodium carbonate
which is used for making glass,soaps and detergent.
Preparation of Soap by Saponification:
(heating
CH2COOC17H35 3C17H35COONa +
CH2OH
Glyceryl tristearate Sodium stearate (soap) Glycerol
1.c When soap is dissolved in water, it will dissociate and produce sodium ions
and carboxylate ions (RCOO-). For example, sodium stearate dissolves in
water to form sodium ions and stearate ions.
C17H35COONa (s) + water C17H35COO- (aq) + Na+ (aq)
sodium stearate stearate ions
2 . The active substance in soap is the carboxylate ion, for example, stearate
ion. The stearate ion consist of two parts : the µhead¶ and the µtail¶. The
µhead¶ id negatively charged and the µtail¶ is a long hydrocarbon chain
3. The µhead¶ contains the -C-O- ions which dissolves readily in water
(hydrophilic) but does not dissolve in oil. Conversely, the µtail¶ contains a long hydrocarbon
chain which is insoluble in water (hydrophobic) but dissolves readily in oil.
5. The figure 5.3 9a) shows the molecular model of palmitate ion and
Figure 5.3 (b) shows the simple representation of the structure of the palmitate ion.
a) The molecular model of the palmitate ion.
1.Detergents are synthetic cleansing agents made from hydrocarbons obtained from petroleum fractions. Thus,
detergents are petrochemicals.
2. Detergents can be classified into three main types, depending on the charge
on the detergent ion.
a) Anionic detergents where the head of the detergent particle contains a
negatively charged ion.
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Example : R ± O ± SO3-Na+ (Sodium alkyl sulphate)
c
Example : R ± O ± CH2CH2OH
c
Where R represents a long hydrocarbon chain. We can represent the detergent ion, alkylbenzene sulphonate ion,more
simply as
Preparation of detergents
1.c The detergent,sodium alkyl sulphate can be prepared from alcohols with chain lengths of
12 to 18 carbon atoms in two steps.
STEP 1: Reaction with concentrated sulphuric acid.
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The Effectiveness of Soap and Detergent as Cleansing Agents.
1.Soaps are effective cleansing agents in soft water, that is water does not contain Mg2+ and
Ca2+
ions.
2.Soaps do not cause pollution problems to the environment. This is because soaps are made
from
chemical found in animals and plants. This means that soaps are biodegradable, that is they can
be composed by the action of bacteria.
1. Soaps are ineffective in hard water, that is, water that contains magnesium and calcium salts.
2.In hard water, soaps will react with Mg2+ and thus, soaps do not lather in hard water.
3.Scum is grey solid that is insoluble in water. It consists of magnesium stearate and calcium
stearate.
4.Soaps are not also effective in acidic water, for example rainwater containing dissolves acids.
H+
ions from acids will react with soap ions to produce carboxylic acids molecular size that are
insoluble in water.
5. Stearic acids and other carboxylic acids do not act as cleansing agents because they exist
mainly
as molecules and do not anionic hydrophilic ends (¶head¶) that dissolves in water.
1.Detergents are cleansing agents that are effective in soft water as well as hard water. This is
because detergents do not form scum with Mg+ and Ca2+ ions found in hard water.
2.The detergents ions (R ±O ± SO3- and R ± SO3- )react with Mg+ and Ca2+ ions in hard water.
However, the magnesium salts and calcium salts which are formed are soluble in water. Hence,
the scum is not formed and the detergents are still active in hard water and lathers easily.
3.Detergents are synthetic cleansing agents. This means that the structure of the hydrocarbon
chain
can be modified to produce detergents with specific properties. Nowadays, different types of
detergents have been synthesised for specific uses such as shampoos and dish cleaner.
4.Furthermore, detergents are also effective in acidic water because H+ ion is acidic water do not
combined with detergents ions.
1. Most detergents have branched hydrocarbon chains and are non-biodegradable, that is, they
cannot decomposed by bacteria. As a result, non-biodegradable detergents cause water pollution.
2.Phosphates in detergents act as fertilizers and promote the growth of water plants and algae.
When the plants die and decay, they will used up the oxygen dissolves in water. This will
decrease the oxygen content in water and kill fishes and other aquatic lives.
3.Detergents produce a lot of foam in water. The layer of foam that covers the water surface will
prevents oxygen from dissolving in water. This condition will cause fish and other aquatic life ti
die from oxygen starvation.
4.Additives such as sodium hydrochlorite (bleaching agents) releases chlorine gas in water that is
acidic. Chlorine gas is highly toxic and kills aquatic life.
Additives of Detergent.
1. Modern detergents used for washing clothes usually contains a few types of additives to :
b)The whitening (bleaching) agents commonly used in detergent are sodium perborate
(NaH2BO43H2O). Sodium perborate decomposes in hot water to release oxygen (an
oxidising agent) which is responsible for the whitening (bleaching) action.
c) Unlike chlorine, oxygen does not bleach the colour of dyes are not damaging to fabrics. When
properly used, the perborate bleaches make fabrics whiter than chlorine bleaches and the
colourful dyes of the fabrics do not fade when dirty stains are removed.
d) Besides sodium perborate, sodium hypochlorite, (NaCIO) can also be used as bleaches in
detergents. The IUPAC name of sodium hypochlorite is sodium chlorate (I).
e)Sodium hypochlorite releases chlorine that bleaches with dirty stains. However, high
concentrations of chlorine can be quite damaging to fabrics. These bleaches do not work well on
synthetic fabrics (polyster fabrics), often causing a yellowing rather than the desire whitening.
Also chlorine causes the dyes on fabrics to fade.
a) Protein stains such blood, milk, and tomato sauce cannot be removed by the ordinary
detergents because these types of stains are insoluble in water.
b) Biological enzymes in detergents can break down fat and protein molecules in food stains.
The fatty acids, glycerol and amino acids produced are soluble in water and are removed during
washing.
6. Brighteners
a) Figure below shows the action of brighteners. The brighteners absorb the invisible ultra-
violet and re-radiate it as blue light.
USES OF FOOD
ADDITIVES
Types of additives and examples
1.c Food preservative have been used since ancient times. Ancient civilization used
salt to preserve meat and fish, herbs and spices to improve the flavor of food.
2. Food additives are chemicals that are added to food in small quantities for specific
purposes such as protection against bacterial attack or restoring the colour of
food destroyed during food processing.
c) To add colouring to food so that the food looks fresher, more interesting
or more appealing.
4. There are two main groups of food additives :
a) Preservatives and antioxidants to protect food from being spoiled by
bacterial attact or atmospheric oxidation. In this way, the food can be kept
longer.
b) Flavouring agents, stabilizers, thickening agents (thickeners), and dyes
(colouring agents) to enhance the taste, smell and appearance of the food.
5. Table below show a list of different types of food additives, their functions and
examples of each types.
Preservatives
1. Preservatives are chemicals that are added to food to retard or to prevent the
growth of microorganism such as bacteria, mould or fungus, so that the food can
be stored for a long time.
2. In ancient times, food additives from natural sources such as salt, sugar and
vinegar were used to preserve food and to make the food taste better.
3. Nowadays, synthetic preservatives are used, table below shows the types of
preservatives commonly used. Many of the preservatives are organic acids and
salts of organic acids.
1.c Antioxidants are chemicals that are added to foods to prevent the oxidation of fats
and oils by oxygen in the air.
2.c Foods containing fats or oils are oxidized and become rancid when exposed to air.
3. When the fats and oils are oxidized, rancid product are formed. This makes the
food unpalatable. The rancid product are volatile organic compound with foul
odours (for example , butanoic acid, C3H7COOH).
4. Antioxidants are added to fats, oils, cakes, sausages, biscuits and fried foods to
slow down the oxidation process so that these foods do not become rancid.
Flavouring agents
1. There are two types of flavouring agents : artificial flavours and flavour enhancer.
They are added to foods to make them taste better.
2. Flavour enhancer have little or no taste of their own. They are chemicals that are
added to food to bring out the flavours or to enhance the taste of food.
5. Both aspartame and saccharin can be used as a substitute for sugar to enhance the
sweetness in food and drink. However, the used of saccharin is banned in many
countries because it is carcinogenic. Aspartame has largely replaced saccharin as
the artificial sweetener or choice.
6. Many esters have fruity odours and tastes and are used as artificial flavours. Table
below shows some examples of esters that are used in making drinks.
1.c Stabilisers and thickening agents improve the texture and the blending of foods.
2.c Stabilisers are chemicals that are used to enable oil and water in the food to mix
together properly in order to form an emulsion of oil and water. Examples of
stabilizers are gelatin and acacia gum.
3.c Stabilisers are added to improve the texture of foods. For examples, stabilisers are
added to ice-cream and peanut butter to keep them smooth and creamy.
4.c In the presence of stabilisers, the emulsion of oil does not separate from water.
This means that the stabilisers improves the stability of some foods such as ice-
cream and salad dressings (mayonnaise).
5.c Without stabilisers, ice crystals would form in ice-cream, particles of chocolate
would settle out of chocolate milk, oil and vinegar in salad dressing will separate
as soon as mixing is stopped.
6.c Thickening agents are chemicals that are added to foods to thicken the liquid and
to prevent the foods from becoming liquid. Thickening agents (also called
thickeners) absorb water and thicken the liquid in foods to produce a jelly-like
structure.
7.c Most thickening agents are natural carbohydrates. Gelatin and pectin are added to
help jams and jellies to set.
Dyes
1.c Dyes (colouring agents) are chemicals that are added to foods to give them colour
so as to improve their appearance.
2.c Some foods are naturally coloured, but the colour is lost during food processing.
3.c Some dyes are naturally plant pigments while others are synthetically prepared.
The synthetic colours used in foods are azo and triphenyl compounds. Both these
compounds are organic compounds.
4.c The synthetic dyes , brilliant blue, is an example of triphenyl compound. The
synthetic dye, tartrazine and sunset yellow are examples of azo compounds.
5.c Azo compounds are organic compounds containing the diazo group, - N = N -, and
are usually yellow , red, brown, black in colour. Triphenyl compounds are organic compounds
containing three phenyl groups, -C6H5, and are usually green. Blue or purple in colour.
4. Allergy
a)Food additives such as sodium sulphite (preservative),
BHA and BHT (antioxidants), MSG (flavouring) and some
food colours (e.g, Yellow No. 5) can cause allergic
reactions in some people.
6. Brain damage
Excessive intake of nitrites for a prolonged period of time can cause brain damage. In this
condition, the supply of oxygen to the brain is disrupted and this cause brain damage.
7. Hyperactivity
a)Food additives such as tartrazine can cause
hyperactivity.
b)Children who are hyperactivity become very active, find
it difficult to relax or sleep and are very restless.
The rationale for using food additives
Advantages
~
a)Oxidation and microorganism (bacteria, fungi) are the
main causes in the decomposition of food. In hot climate,
meat and fish rot easily. The use of preservatives is an
effective way to prevent food spoilage and to ensure that
foods can be supplied throughout the year.
b) Artificial sweeteners give the sweet taste but without adding calories to the food. Thus, they
can be used to reduce obesity.
Disadvantages
2.c Some food additives are used to make foods look more
appealing. These additives have little nutritional value. Eating
such foods increases the risk of health hazard.
Modern medicines
1.c Before the 20th century, most medicines were extracted from plants (herbal medicines). Since
1900. Thousands of modern drugs have been synthesised from organic compound.
2.c Modern medicines can be classified as follows based on their
effects on the human body.
3. Some examples of modern medicines are analgesics, antibiotics, psychotherapeutic drugs.
infectious microorganism.
3.Stimulants
4.Antidepressants
5.Antipsychotic medicines
Hear voice and see things that are not really there
(hallucinations)
Have belief that are not based on reality (delusions)
b)In psychiatry, there are a number of disorders that are
classified under µ psuchosis¶, such as schizophrenias
(madness), psychotic depression, mania and so on.
1. Self-medication
Do not prescribe medicines for yourself (self-medication) or for
other people. Discuss with your doctor and listen to him
concerning the medicine to be taken.
4. Side effects
Visit the doctor immediately if there are symptoms of
allergy
or other effects of the drugs.
5. Expiry date
Like foods, medicines also have expiry date. Do not take
medicines after their expiry dates.
Photos of traditional medicines:
commonly use drugs
: Marjiuana,cocaine,opium,heroin,LSD
- Easy to find
- Family and relationship issues
- peer pressure
- media influence
Side effect
- heart-attack
- depression
- death and coma
- repiratory failure
immpact on soceity
ÃLASS:5 ADIODA