Beruflich Dokumente
Kultur Dokumente
Paolo Perona
*Email: perona@ihw.baug.ethz.ch
Fax: x41.44.6321061
Abstract:
The correlation between the Bostwick degree and the static rheological properties of yield stress food fuids is
first revisited and then reformulated in this work. The role of the yield stress in the free surface flow of the Bost-
wick test is studied using dimensional analysis. Results from experiments on 48 different samples of yield stress
fluids are considered and included to check the adequacy of the proposed correlation. Asymptotic dynamic beha-
viour is also presented and discussed as a mechanism of complete self similarity with respect of the dimen-
sionless time. This approach would seem to support the opinions in favor of the yield stress as a key parameter,
and thus offers an interesting new viewpoint useful to both future experiments on the Bostwick test and stu-
dies of 'dam-break' like dynamics.
Zusammenfassung:
In dieser Arbeit wird die Wechselbeziehung zwischen dem Bostwick-Grad und den statischen rheologischen
Eigenschaften von flüssigen Nahrungsmitteln behandelt und neu formuliert. Die Rolle der Fliessspannung im
freien Oberflächenfluss des Bostwick-Tests wurde mit Hilfe der Dimensionsanalyse untersucht. Resultate von
Experimenten mit 48 verschiedenen Proben von Flüssigkeiten mit einer Fliessspannung wurden in diese Studie
einbezogen, um die Richtigkeit der vorgeschlagenen Wechselbeziehung zu überprüfen. Zusätzlich wird eine
Analyse des asymptotischen dynamischen Verhaltens vorgestellt und diskutiert. Dieser Ansatz scheint die The-
orie der Fliessspannung als Hauptparameter zu unterstützen, und bietet folglich eine neue und interessante
Sichtweise, welche sowohl für zukünftige Experimente mit dem Bostwick-Test als auch für Untersuchungen von
"dammbrechungsähnlicher" Dynamik nützlich ist.
Résumé:
Dans ce travail la corrélation entre le degré Bostwick et les propriétés rhéologiques statiques des fluides ali-
mentaires avec contrainte seuil est d'abord revisitée et ensuite reformulée. Le rôle de la contrainte seuil dans
l'écoulement de Bostwick est étudié en utilisant l'analyse dimensionnelle. Les résultats des expériences entre-
prises sur 48 échantillons différents de fluides avec contrainte seuil sont aussi considérés et inclus pour vérifier
l'adéquation de la corrélation proposée. Une analyse du comportement dynamique asymptotique est également
présentée et discutée. Cette approche semblerait soutenir les avis en faveur de la contrainte seuil comme para-
mètre principal, et offre ainsi un nouveau point de vue, intéressant et utile aux futures expériences sur l'essai
de Bostwick de même que sur les études sur la dynamique de rupture.
Key words: Bostwick consistometer, yield stress, viscoplastic fluids, food rheology, dimensional analysis, fruit
purees
Applied Rheology
218 Volume 15 · Issue 4
Applied_Rheology_Vol_15_4.qxd 04.09.2005 17:55 Uhr Seite 219
Applied Rheology
Volume 15 · Issue 4 219
Applied_Rheology_Vol_15_4.qxd 04.09.2005 17:55 Uhr Seite 220
and can be assumed as being smooth. Its length imputable to the apparent viscosity and not to the
can range up from 0.24 to 0.50 m, depending on yield stress property of the fluid. However, as also
the consistency of the products being tested. pointed out by the authors themselves, the weak
A conceptually similar to dam-break flow point of the analysis was the estimate of the yield
occurs as soon as the sluice gate is released and stress with an empirical model instead of mea-
the material filling the reservoir starts to flow suring it. After such first debates, other authors
along the aisle. The reading (in centimeters) of came up to either coherent or contrasting con-
the distance covered after a conventional time clusions, thus resetting the problem to a sort of
(usually 30 s for pureed products or 10 s for toma- basic starting point. For instance, Vercruysse and
to sauces) and averaged over three consecutive Steffe [9] accurately analyzed baby food products
tests is the Bostwick consistency, hereby referred and found a poor correlation between Bostwick
to as B30. and apparent viscosity. Singh et al. [10] suggest-
ed the use of the Brix degree (i.e. the sugar con-
2.2 WHAT IS KNOWN FROM THE PAST tent) for in-line continuous measurements. Bar-
ringer et al. [11] studied the correlation of
The experiment with the Bostwick consistometer Bostwick data with measured differential pres-
is empirically funded. The distance covered by the sure in pipe flow; Trifiro et al. [12] used an oscilla-
sample within the established time interval gives tory viscosimeter and Alamprese et al. [13] corre-
a rough idea of the mean resistance (perhaps an lated the Bostwick with the parameters of an
equivalent mean viscosity) that the fluid experi- Ostwald-de Waele rheological model.
ences against deformation in this particular type Not surprisingly all such results showed
of gravity-driven flow. Thanks to its simplicity, the both agreement and discrepancies among each
Bostwick device is often used to check and accord- other, thus exactly reflecting the deep meaning
ingly adjust the consistency of manufacturing of Eolkin's paradox. In other words, the fact that
products via a feedback. For this reason, the pos- fluids show an internal structure responsible for
sibility of implementing such a technique direct- the yield stress or, more generally for an appar-
ly in or on-line has long been studied. The first ent viscosity, cannot be distinguished by the
interesting device was proposed by D. Eolkin in Bostwick measure. This major concern proves
1958 [7] as a continuous recording consistometer that such a measure does not have a true physi-
that he himself called the plastometer. Apposite- cal meaning and does not allows for a univocal
ly designed for non-Newtonian fluids, such an identification of the rheological properties of the
instrument was able to correlate the Bostwick fluid being tested. However, whether a first gen-
consistency versus the apparent viscosity. The eral classification of the fluid can be made (e.g.
reason for this good correlation, as pointed out by with or without yield), then some better infor-
Eolkin himself, was the ability of the plastometer mation can be obtained even using such a sim-
to catch the role of the structural component (i.e. ple instrument. To this end, by an undoubtedly
something responsible for the yield stress and, in different direction moved McKarthy and Sey-
turn for the apparent viscosity) and to relating it mour [14, 15]. They approached the problem from
to the Bostwick measure. The ability of the plas- an analytical point of view conscious of the rhe-
tometer was then proved with the paradoxical ological nature of the fluid being modelled.
case of a sufficiently concentrated sugar syrup In their approach, the phenomenon was
(which still shows a Newtonian viscosity) and a simplified to a one-dimensional gravity current
yield stress puree. As expected, the Bostwick con- which can be described analytically and allowed
sistometer and the plastometer came up to two to obtain an elegant solution that is valid for both
completely different conclusions [7]: the first Newtonian [14] and non-Newtonian [15] fluids of
apparatus stated that these products were exact- the Ostwald-deWaele type. In particular, the lin-
ly the same, while the plastometer actually cap- earized form of de Saint Venant equations was
tured the difference. Twenty years later, Rao and corrected in the resistive term in order to account
Bourne [8] revisited the plastometer to investi- for the non-Newtonian effects. The solution was
gate in more detail the reason for the excellent then obtained by means of a similar solution
correlation that it showed with the Bostwick technique (see, for example the book by Baren-
reading. They suggested that this fact was more blatt [16]), and the corresponding results allowed
Applied Rheology
220 Volume 15 · Issue 4
Applied_Rheology_Vol_15_4.qxd 04.09.2005 17:55 Uhr Seite 221
to show the physics underlying the correlation finite volume V = M/r of fluid. This choice comes
between Bostwick degree, fluid density and from the need of describing the motion of a finite
apparent viscosity. Such rather interesting con- amount of product and not the evolution of a
clusions, although are still not able to take the continuously feeded stream. Both the informa-
effects of the yield stress into account, suggest tion can be taken thus into account within a
the need of this further step. unique quantity while maintaining in the rela-
tionship the characteristic dimension H of the
3 DIMENSIONAL ANALYSIS OF THE device. The Buckingham or P-theorem [16] states
BOSTWICK TEST that Eq. 1 can be rewritten in dimensionless form
provided that a representative set of dimension-
ally independent quantities is considered. For
3.1 FORMULATION FOR YIELD STRESS FLUIDS example, the triplet M, g, H is adequate and can
The longitudinal displacement of the front at be adopted to make Eq. 1 dimensionless
several time intervals can be related to the rheo-
logical properties of viscoplastic fluids (such
structured food fluids, for instance) by means of (2)
dimensional analysis. The fluid is assumed to
behave as a purely viscous time independent where the dimensionless groups are
Herschel-Bulkley material, which constitutive
equation in the limits of a one dimensional
approximation is t = t0 + Kg· n · t0 is the yield
(3)
stress, while K and n are the ‘consistency’ and
flow indexes, respectively (see, for example [3]
for a general overview). Some consideration is
further made to keep the number of variables
affordable from a practical point of view. Surface
(4)
tension for example will not be considered here
accordingly to other authors [17 - 20], albeit its
importance in the asymptotic flow should be bet- Notice that by choosing these quantities the plot
ter investigated. Elastic and time dependent of the curves at parameter P3 = cost is thus sim-
effects are also neglected assuming that the plified. The dimensionless group P1 represents a
products show neither pronounced elastic com- simple scaling of the travelled distance, whereas
ponents, nor relevant structure degradation the meaning of P2 is more deeper. Once this
under shears of limited duration and intensity group is rewritten by explicitly using the fluid
[5]. Finally, as already said, the lane slope is also density r and the volume of the sample V = b2H,
negligible i.e. the Bostwick apparatus is assumed
as horizontal [14, 15].
Assuming the length L covered by the front one gets .
along the centreline is the governed quantity, Apart from the constant a, which depends on the
then the governing variables can be reasonably device geometry, such a quantity is the Bingham
identified with the mass of the sample M, gravi- number. This number compares the yield stress
ty g, rheological parameters (t0, K, n), initial magnitude with the initial hydrostatic pressure
height of the fluid at rest H and the time t. The level created by gravity. Although a similar quan-
physical link can therefore be stated as tity was already found to be useful in other pre-
vious works [17, 20, 21], the one introduced here
also accounts for the amount of material (i.e. the
(1) mass M) that is involved in the process. To this
regards, some recent works have proved the
where the flow index n appears as a simple para- importance of the total fluid mass [17, 19], the ini-
meter being itself dimensionless. Notice that the tial shape of the pile and the channel geometry
mass M instead of the fluid density r has been [19] in determining the stoppage of the flow (see,
voluntarily chosen to describe the motion of a [2] for a general overview).
Applied Rheology
Volume 15 · Issue 4 221
Applied_Rheology_Vol_15_4.qxd 04.09.2005 17:55 Uhr Seite 222
(5) (8)
The less pseudoplastic the fluid, the higher the This condition is consistent with the ones already
contribute given by the yield stress is when com- found in literature [17, 19, 22]. In particular, it
pared with that of the consistency index at low shows the existence of a complete self similarity
shear rates. In particular, such a condition means [16] for the variable P3 in the dynamics, and
that hK,n << ht0, i.e. in dimensional form this allows to reduce the link between the active vari-
occurs when ables to only two groups.
4 EXPERIMENTAL VERIFICATION
(6)
Applied Rheology
222 Volume 15 · Issue 4
Applied_Rheology_Vol_15_4.qxd 04.09.2005 17:55 Uhr Seite 223
Table 1:
Rheological and physical
data of the raw and diluted
products at the temperature
of 25°C.
Applied Rheology
Volume 15 · Issue 4 223
Applied_Rheology_Vol_15_4.qxd 04.09.2005 17:55 Uhr Seite 224
Applied Rheology
224 Volume 15 · Issue 4
Applied_Rheology_Vol_15_4.qxd 04.09.2005 17:55 Uhr Seite 225
Figure 7:
a) Scaling of the data at
P3 = 470, i.e. t = 30 s and
related approximating loga-
rithmic and power laws;
b) Scaling of the data at the
condition of complete self
similarity;
c and d) Behaviour of the
coefficient of the power law
as a function of the para-
meter P3 and related
approximating power law
curve.
a) b)
c) d)
er WIKA with a scale range 0 ÷ 0.1 bar at one end, Bostwick and rheology
while the other end was kept at atmospheric Although the standard Bostwick test B30 requires
pressure. Under incipient motion conditions and that the position of the front is read at 30 s, here
in the absence of wall slip effects a simple bal- it was sampled at different time instants, i.e. 5,
ance of forces suggests the following link 15, 30 and 60 s. An average of the value from three
between the wall shear stress tw and the yield consecutive identical experiments was then per-
value t0 formed to obtain the representative Bostwick
value. Data of the fluid front evolution at the dif-
ferent time intervals and for all the samples are
summarized in Table I and shown in Fig. 4.
(9) The rheological characterization was done
by using an experimental setup based on a tem-
where g is gravity and r the fluid density. perature controlled rectilinear pipe viscosimeter
(Fig. 3), which technical details and performances
Applied Rheology
Volume 15 · Issue 4 225
Applied_Rheology_Vol_15_4.qxd 04.09.2005 17:56 Uhr Seite 226
Table 2:
Values of the constants of
the power laws and relative
correlation coefficient.
(10)
Applied Rheology
226 Volume 15 · Issue 4
Applied_Rheology_Vol_15_4.qxd 04.09.2005 17:56 Uhr Seite 227
consequence it allows to estimate the Bostwick were therefore not included in the analysis. Figure 8 (left):
consistency B30 starting from the knowledge of Examples are the width of the flowing lane and Global scaling. Predicted vs.
measured data.
the yield stress t0 and the fluid density r only. the role of the roughness of the flow lane. While
The step back, i.e. to assess the yield stress from the effects due to the first variable could be eas- Figure 9 (right):
the consistency B30, in principle should be also ily explored, for the second one the point is much Scaling of the data in the new
possible by averaging the results coming from more delicate. In facts, as far as B30 is concerned, system of variables.
different measures of front evolutions. A final the difference using a rough plane can be as
comment is now reserved in order to show how much as 20 - 30% of the measure obtained with
the dimensionless groups introduced here can be a smooth one (Private communication by a Com-
used to transforming and making thus useful the pany producing Bostwick consistometers, name
diagram of Fig. 4. To this end, a new plot can be omitted). In particular, these errors would seem
obtained after a convenient change of variables to be due to the separation of the solid (fibers and
is introduced. By defining, for example other solid components) and liquid (i.e. the
serum) phases of the product. In turn this would
give rise to density variation and reduction of the
internal lubrication. As a consequence, an
(15) increasing of the yield stress can be expected,
eventually influencing the apparent viscosity at
low shear rates.
(16)
In order to proceed toward a better stan-
(17) dardization of the Bostwick test, which would
simplify the comparison of a wider source of
the quantities t0 and t are introduced into the data, the above mentioned effects should be first
of all better investigated or at least better docu-
dimensionless variables P1 and P2. The major
mented. Thus, users could perhaps be provided
effect of such a transformation of coordinates is of an official library of correcting factors. Doing
to distorting the curve on the cartesian plane (P1, such a step, however, requires greater efforts
P2), but still preserving the possibility of para- from both the experimental and analytical view-
meterizing all the curves at P3* = cost. The relat- points. Theoretical and experimental approach-
ed effect on data is that now they scale as shown es are therefore welcome, especially if based on
in Fig. 9, and such curves can potentially be used physically consistent assumptions that could
from a graphics point of view. improve the knowledge significantly beyond
avoiding confusion. For instance, the rheological
nature of the fluid being tested should be con-
5 DISCUSSION AND CONCLUSIONS sidered since the beginning. This first step miss-
The results of this work are of course subjected ing would bring inexorably to the aforemen-
to measurement errors and simplifications, tioned Eolkin's paradox. Aiming at the use of the
which all contributed to give the discrepancies Bostwick measure in a more wider sense there-
that are still evident in the proposed correlations. fore implies the necessity of taking the physics
In particular, there are effects which were either that lies behind the phenomenon under more
too complex or very difficult to describe that consideration (for instance following [14, 15]).
Applied Rheology
Volume 15 · Issue 4 227
Applied_Rheology_Vol_15_4.qxd 04.09.2005 17:56 Uhr Seite 228
Applied Rheology
228 Volume 15 · Issue 4
Applied_Rheology_Vol_15_4.qxd 04.09.2005 17:56 Uhr Seite 229
Applied Rheology
Volume 15 · Issue 4 229