sustancia pm P

metanol 1 32.04 g/mol 0.792 g/cm3 Vt=50

acetona 2 58.08 g/mol 0.784 g/m³

Tabla de datos experimentales

x1 x2 nliq T© nvap=cond
0 1 1.3578 51 1.3578
0.1 0.9 1.3572 49.5 1.3563
0.2 0.8 1.3559 50 1.3549
0.3 0.7 1.3545 49 1.3542
0.4 0.6 1.3523 50 1.3531
0.5 0.5 1.3499 51 1.3529
0.6 0.4 1.3471 51.5 1.3509
0.7 0.3 1.344 54 1.3495
0.8 0.2 1.34 55 1.3452
0.9 0.1 1.3348 57 1.3393
1 0 1.3286 60 1.3286

punto 4

Y1 VS X1
1.2

0.8

0.6

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1
 0 0 74.08163265306 74.0816327 3704.08163
202.272727273 4.0454545454546 66.67346938776 70.7189239 3333.67347
404.545454545 8.0909090909091 59.26530612245 67.3562152 2963.26531
606.818181818 12.136363636364 51.85714285714 63.9935065 2592.85714
809.090909091 16.181818181818 44.44897959184 60.6307978 2222.44898
1011.36363636 20.227272727273 37.04081632653 57.2680891 1852.04082
1213.63636364 24.272727272727 29.63265306122 53.9053803 1481.63265
1415.90909091 28.318181818182 22.22448979592 50.5426716 1111.22449
1618.18181818 32.363636363636 14.81632653061 47.1799629 740.816327
1820.45454545 36.409090909091 7.408163265306 43.8172542 370.408163
2022.72727273 40.454545454546 0 40.4545455 0
202.27272727273 4.045454545455 66.6734694
404.54545454546 8.090909090909 59.2653061 67.3562152
606.81818181818 12.13636363636 51.8571429 63.9935065
809.09090909091 16.18181818182 44.4489796 60.6307978
1011.3636363636 20.22727272727 37.0408163 57.2680891
1213.6363636364 24.27272727273 29.6326531 53.9053803
1415.9090909091 28.31818181818 22.2244898 50.5426716
1618.1818181818 32.36363636364 14.8163265 47.1799629
1820.4545454546 36.40909090909 7.40816327 43.8172542
2022.7272727273 40.45454545455 0 40.4545455

1.820454545455 0.03640909 16.0241611 16.0605702

1.618181818182 0.03236364 16.0241611 16.0565247
1.415909090909 0.02831818 32.0483221 32.0766403
1.213636363636 0.02427273 32.0483221 32.0725949
1.011363636364 0.02022727 48.0724832 48.0927105
0.809090909091 0.01618182 48.0724832 48.088665
0.606818181818 0.01213636 64.0966443 64.1087807
0.404545454545 0.00809091 64.0966443 64.1047352
0.202272727273 0.00404545 80.1208054 80.1248508
0 0 80.1208054 80.1208054
801.2080536913 16.0241611 0.03236364 16.0565247
1201.812080537 24.0362416 0.02831818 24.0645598
1602.416107383 32.0483221 0.02427273 32.0725949
2003.020134228 40.0604027 0.02022727 40.08063
2403.624161074 48.0724832 0.01618182 48.088665
2804.228187919 56.0845638 0.01213636 56.0967001
3204.832214765 64.0966443 0.00809091 64.1047352
3605.436241611 72.1087248 0.00404545 72.1127703
4006.040268456 80.1208054 0 80.1208054
 curva de calibracion

nliq vs x1
v1 v2 Y1 Y2 1.365
0 50 0 1 1.36
2.8602348 47.1397652 0.19279 0.80721 1.355 f(x) = − 0.027097902097903 x² − 0.001038461538461 x + 1.3574671
6.00605977 43.9939402 0.29184 0.70816 1.35
9.48249619 40.5175038 0.33099 0.66901 1.345
13.3445532 36.6554468 0.38491 0.61509 1.34
17.6601604 32.3398396 0.39396 0.60604 1.335
22.5141972 27.4858028 0.47539 0.52461 1.33
28.0141323 21.9858677 0.52519 0.47481 1.325
34.2980731 15.7019269 0.6555 0.3445 1.32
41.5465227 8.45347729 0.80126 0.19874 1.315
50 0 1 0 1.31
0 0.2 0.4 0.6 0.8

VS X1 constantes antonio
A B C
Metanol (1) 8.0724 1574.99 238.87
acetona (2) 7.6313 1566.69 273.419

calcula las presiones de saturacion

x1 Texp ( C ) log(P1) log(P2)
0 51 2.63896432 2.80208223
0.1 49.5 2.61070149 2.7796499
0.2 50 2.62015505 2.78715046
0.6 0.8 1 1.2 0.3 49 2.60121509 2.77212607
0.4 50 2.62015505 2.78715046
0.5 51 2.63896432 2.80208223
0.6 51.5 2.64832038 2.80951365
0.7 54 2.69462146 2.84633028
0.8 55 2.71292132 2.86089999
0.9 57 2.74914992 2.88977485
1 60 2.80258369 2.93243761
constantes de margules
comp 1 comp 2 A12 A21
acetona metanol 0.579 0.618

constantes de van laar

comp 1 comp 2 A12 A21
acetona metanol 0.58 0..56

Presiones de vapor
x1 P1 Sat
0 870.902474
0.1 844.141386
0.2 816.943551
0.3 789.32646
0.4 761.286679
 0.5 732.834579
0.6 703.994117
0.7 674.761976
0.8 645.167517
0.9 615.238502
1 584.993069

74.0816327 0 74.0816327
66.6734694 4.04545455 70.7189239
59.2653061 8.09090909 67.3562152
51.8571429 12.1363636 63.9935065
44.4489796 16.1818182 60.6307978
37.0408163 20.2272727 57.2680891
29.6326531 24.2727273 53.9053803
22.2244898 28.3181818 50.5426716
14.8163265 32.3636364 47.1799629
7.40816327 36.4090909 43.8172542
0 40.4545455 40.4545455
 8.09090909
51.8571429 12.1363636 9.482496194825 #DIV/0!
44.4489796 16.1818182 13.344553243574 #DIV/0!
37.0408163 20.2272727 17.660160362841 #DIV/0!
29.6326531 24.2727273 22.514197212184 #DIV/0!
22.2244898 28.3181818 50.5426716 28.014132329999 0
14.8163265 32.3636364 47.1799629 34.298073141958 0
7.40816327 36.4090909 43.8172542 41.546522705621 0
0 40.4545455 40.4545455 50 0

0 0 40.4545454545 40.4545455
400.604027 8.0120805369128 36.4090909091 44.4211714 0
801.208054 16.024161073826 32.3636363636 48.3877974 9.01831298
1201.81208 24.036241610738 28.3181818182 52.3544234 16.55806
1602.41611 32.048322147651 24.2727272727 56.3210494 22.9553112
2003.02013 40.060402684564 20.2272727273 60.2876754 28.4514604
2403.62416 48.072483221477 16.1818181818 64.2543014 33.2243717
2804.22819 56.084563758389 12.1363636364 68.2209274 37.4079884
3204.83221 64.096644295302 8.09090909091 72.1875534 41.1051021
0 50 3605.43624 72.108724832215 4.04545454545 76.1541794 44.3959113
#REF! 0.11334931 4006.04027 80.120805369128 0 80.1208054 47.3439051
49.8992197 0.10078033 50
49.9411621 0.04414144
49.9621597 0.03784029
49.9747668 0.02102946
 49.983175 0.01682498
49.9891826 0.00946545 2022.72727 40.454545454546 0 40.4545455
49.9936893 0.0063107 1820.45455 36.409090909091 8.01208053691 44.4211714
49.997195 0.00252447 1618.18182 32.363636363636 16.0241610738 48.3877974
50 0 1415.90909 28.318181818182 24.0362416107 52.3544234
1213.63636 24.272727272727 32.0483221477 56.3210494
1011.36364 20.227272727273 40.0604026846 60.2876754
809.090909 16.181818181818 48.0724832215 64.2543014
606.818182 12.136363636364 56.0845637584 68.2209274
404.545455 8.0909090909091 64.0966442953 72.1875534
202.272727 4.0454545454546 72.1087248322 76.1541794
0 0 80.1208053691 80.1208054
urva de calibracion punto 3
temperatur exp vs v,y
nliq vs x1
T (C) Vs X1Y1
70

903 x² − 0.001038461538461 x + 1.35746713286713 60

50

40

30

20

10

0.4 0.6 0.8 1 1.2 0

0 0.2 0.4 0.6 0.8 1

P= 585

calcula los coeficientes de actividad experimentales

P1 sat P2 sat x1 y1 y2
435.476097 633.989739 0 #DIV/0! 0.922727867
408.038824 602.074032 0.1 2.76400537 0.87146509
417.018235 612.562576 0.2 2.04698963 0.84536996
399.222574 591.733379 0.3 1.61671845 0.944853264
417.018235 612.562576 0.4 1.34989511 0.979022836
435.476097 633.989739 0.5 1.05845809 1.118419993
444.959391 644.931586 0.6 1.04167989 1.189648859
495.018538 701.98896 0.7 0.88665121 1.318937408
516.322819 725.938772 0.8 0.92836179 1.388081941
561.24169 775.844786 0.9 0.92797632 1.498532982
634.722205 855.928737 1 0.92166304 #DIV/0!

Ecuacion de Margules
Chart Title
0.7

0.6 f(x) = 0.657 x² − 0.044616 x + 0.002808

x1 x2 ln y1 ln y2 Chart Title
0 1 0.579 0
0.7
0.1 0.9 0.475308 0.005478
0.2 0.8 0.380544 0.022224 0.6
f(x) = 0.657 x² − 0.044616 x + 0.002808
0.3 0.7 0.295176 0.050706 f(x)
R² ==0.999916402430258
0.54 x² − 1.124616 x + 0.581808
0.5 R² = 0.999906275433211
0.4 0.6 0.219672 0.091392
0.5 0.5 0.1545 0.14475 0.4
0.6 0.4 0.100128 0.211248
0.3
0.7 0.3 0.057024 0.291354
0.8 0.2 0.025656 0.385536 0.2
0.9 0.1 0.006492 0.494262
1 0 0 0.618 0.1

0
0 0.2 0.4 0.6 0.8 1

ln y1 y=0.54(0)-1.1246(0)+0.5818
A12 0.5818

ln y2 y=0.675(1)-0.0446(1)+0.0028
A21 0.6152

x1 x2 y1 y2 Temperaturas de ebullicion
0 1 0.5818 0 x1 x2 Tsup1
0.1 0.9 0.4766688 0.0055508 0 1 969.99
0.2 0.8 0.3809024 0.0224704 0.1 0.9 941.707
0.3 0.7 0.2949016 0.0511596 0.2 0.8 913.424
0.4 0.6 0.2190672 0.0920192 0.3 0.7 885.141
0.5 0.5 0.1538 0.14545 0.4 0.6 856.858
0.6 0.4 0.0995008 0.2118528 0.5 0.5 828.575
0.7 0.3 0.0565704 0.2916284 0.6 0.4 800.292
0.8 0.2 0.0254096 0.3851776 0.7 0.3 772.009
0.9 0.1 0.0064192 0.4929012 0.8 0.2 743.726
1 0 0 0.6152 0.9 0.1 715.443
1 0 687.16

T1 687.16
T2 969.99
Fraccion mol
P2 Sat x1 x2 y1 y2 Suma
584.817598 0 1 0 1.08374314 1.08374314
567.91968 0.1 0.9 0.01344715 0.74769258 0.76113973
550.732935 0.2 0.8 0.04160773 0.59322026 0.63482799
533.27114 0.3 0.7 0.06776343 0.47369724 0.54146066
515.527166 0.4 0.6 0.1097535 0.38644217 0.49619567
497.507186 0.5 0.5 0.14663262 0.32839585 0.47502847
479.220104 0.6 0.4 0.21695307 0.23134192 0.44829499
460.673708 0.7 0.3 0.31108573 0.17092891 0.48201464
441.871891 0.8 0.2 0.46283707 0.08549946 0.54833653
422.825684 0.9 0.1 0.69184695 0.0263575 0.71820445
403.553876 1 0 1.08499522 0 1.08499522
 50
40.981687
33.44194
27.0446888
21.5485396
16.7756283
12.5920116
8.89489787
5.60408873
2.6560949
0
X1Y1

0.8 1 1.2

tividad experimentales

hart Title

808
hart Title

808
08

0.6 0.8 1 1.2

6(0)+0.5818

46(1)+0.0028