bapp03.

indd 672
TABLE C.7 Values for log [!(0)]

672
Pr
Tr 0.01 0.025 0.05 0.075 0.1 0.25 0.5 0.6 0.7 0.8 0.9 1 1.1
0.3 23.708 24.104 24.402 24.575 24.697 25.076 25.346 25.412 25.467 25.512 25.551 25.584 25.613
0.35 22.472 22.868 23.166 23.339 23.461 23.842 24.115 24.183 24.239 24.285 24.325 24.359 24.390
0.4 21.566 21.962 22.261 22.434 22.557 22.939 23.214 23.283 23.340 23.387 23.428 23.464 23.495
0.45 20.879 21.276 21.574 21.748 21.871 22.254 22.531 22.601 22.658 22.707 22.748 22.784 22.816
0.5 20.344 20.741 21.040 21.214 21.336 21.721 21.999 22.070 22.128 22.177 22.219 22.256 22.288
0.55 20.008 20.315 20.614 20.788 20.911 21.296 21.576 21.647 21.705 21.755 21.798 21.835 21.868
0.6 20.007 20.016 20.269 20.443 20.566 20.952 21.233 21.304 21.363 21.413 21.456 21.494 21.527
0.65 20.005 20.013 20.026 20.160 20.283 20.670 20.951 21.023 21.082 21.132 21.176 21.214 21.248
0.7 20.004 20.010 20.021 20.032 20.043 20.435 20.717 20.789 20.848 20.899 20.942 20.981 21.015
0.75 20.003 20.009 20.017 20.026 20.035 20.237 20.520 20.592 20.652 20.703 20.746 20.785 20.819
0.8 20.003 20.007 20.014 20.021 20.029 20.076 20.354 20.426 20.486 20.537 20.581 20.619 20.654
0.85 20.002 20.006 20.012 20.018 20.024 20.062 20.213 20.285 20.345 20.396 20.440 20.479 20.513
0.9 20.002 20.005 20.010 20.015 20.020 20.052 20.111 20.166 20.225 20.276 20.320 20.359 20.393
0.93 20.002 20.005 20.009 20.014 20.018 20.047 20.099 20.122 20.163 20.214 20.258 20.296 20.330
0.95 20.002 20.004 20.008 20.013 20.017 20.044 20.092 20.113 20.136 20.176 20.220 20.258 20.292
0.97 20.002 20.004 20.008 20.012 20.016 20.041 20.086 20.105 20.126 20.148 20.185 20.223 20.256
0.98 20.002 20.004 20.008 20.012 20.016 20.040 20.083 20.101 20.121 20.142 20.168 20.206 20.240
0.99 20.001 20.004 20.007 20.011 20.015 20.038 20.080 20.098 20.117 20.137 20.159 20.191 20.224
1 20.001 20.004 20.007 20.011 20.015 20.037 20.077 20.095 20.113 20.132 20.152 20.176 20.209
1.01 20.001 20.004 20.007 20.011 20.014 20.036 20.075 20.091 20.109 20.127 20.146 20.168 20.195
1.02 20.001 20.003 20.007 20.010 20.014 20.035 20.073 20.088 20.105 20.122 20.141 20.161 20.184
1.03 20.001 20.003 20.007 20.010 20.013 20.034 20.070 20.086 20.101 20.118 20.136 20.154 20.175
1.05 20.001 20.003 20.006 20.009 20.013 20.032 20.066 20.080 20.095 20.110 20.126 20.143 20.161
1.1 20.001 20.003 20.005 20.008 20.011 20.028 20.057 20.069 20.081 20.093 20.106 20.120 20.133
1.15 20.001 20.002 20.005 20.007 20.009 20.024 20.049 20.059 20.069 20.080 20.091 20.102 20.113
1.2 20.001 20.002 20.004 20.006 20.008 20.021 20.042 20.051 20.060 20.069 20.078 20.088 20.097
1.3 20.001 20.002 20.003 20.005 20.006 20.016 20.033 20.039 20.046 20.052 20.059 20.066 20.073
1.4 20.001 20.001 20.003 20.004 20.005 20.013 20.025 20.030 20.035 20.040 20.046 20.051 20.056
1.5 0.000 20.001 20.002 20.003 20.004 20.010 20.020 20.024 20.028 20.032 20.035 20.039 20.043
1.6 0.000 20.001 20.002 20.002 20.003 20.008 20.016 20.019 20.022 20.025 20.028 20.031 20.034
1.7 0.000 20.001 20.001 20.002 20.002 20.006 20.012 20.015 20.017 20.020 20.022 20.024 20.027
1.8 0.000 0.000 20.001 20.001 20.002 20.005 20.010 20.012 20.014 20.015 20.017 20.019 20.021
1.9 0.000 0.000 20.001 20.001 20.002 20.004 20.008 20.009 20.011 20.012 20.014 20.015 20.016
2 0.000 0.000 20.001 20.001 20.001 20.003 20.006 20.007 20.008 20.009 20.011 20.012 20.013
2.25 0.000 0.000 0.000 0.000 20.001 20.002 20.003 20.004 20.004 20.005 20.005 20.006 20.006
2.5 0.000 0.000 0.000 0.000 0.000 20.001 20.001 20.001 20.002 20.002 20.002 20.002 20.002
2.75 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001
3 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.001 0.001 0.002 0.002 0.002 0.002
3.5 0.000 0.000 0.000 0.000 0.000 0.001 0.002 0.002 0.003 0.003 0.003 0.004 0.004
4 0.000 0.000 0.000 0.000 0.000 0.001 0.002 0.003 0.003 0.004 0.004 0.005 0.005
5 0.000 0.000 0.000 0.000 0.001 0.001 0.003 0.003 0.004 0.004 0.005 0.005 0.006

06/11/12 6:28 PM
bapp03.indd 673
TABLE C.7 Continued
Pr
Tr 1.2 1.3 1.4 1.5 1.75 2 2.5 3 4 5 7.5 10
0.3 25.638 25.660 25.680 25.697 25.733 25.759 25.793 25.810 25.810 25.782 25.647 25.462
0.35 24.416 24.440 24.460 24.479 24.518 24.548 24.588 24.611 24.623 24.608 24.505 24.352
0.4 23.522 23.546 23.568 23.588 23.629 23.661 23.707 23.735 23.757 23.752 23.673 23.545
0.45 22.845 22.870 22.892 22.913 22.956 22.990 23.039 23.071 23.101 23.104 23.046 22.938
0.5 22.317 22.343 22.366 22.387 22.432 22.468 22.520 22.555 22.592 22.601 22.559 22.468
0.55 21.897 21.924 21.947 21.969 22.015 22.052 22.107 22.145 22.187 22.201 22.173 22.095
0.6 21.557 21.584 21.608 21.630 21.677 21.715 21.773 21.812 21.859 21.878 21.861 21.795
0.65 21.278 21.305 21.329 21.352 21.400 21.439 21.498 21.539 21.589 21.612 21.604 21.549
0.7 21.045 21.073 21.097 21.120 21.169 21.208 21.269 21.312 21.365 21.391 21.391 21.344
0.75 20.850 20.877 20.902 20.925 20.974 21.015 21.076 21.121 21.176 21.204 21.212 21.172
0.8 20.684 20.712 20.737 20.760 20.810 20.851 20.913 20.958 21.016 21.046 21.060 21.026
0.85 20.544 20.572 20.597 20.620 20.670 20.711 20.774 20.820 20.879 20.911 20.929 20.901
0.9 20.424 20.452 20.477 20.500 20.550 20.591 20.654 20.700 20.761 20.794 20.817 20.793
0.93 20.361 20.389 20.414 20.437 20.486 20.527 20.591 20.637 20.698 20.732 20.756 20.735
0.95 20.322 20.350 20.375 20.398 20.447 20.488 20.552 20.598 20.659 20.693 20.719 20.699
0.97 20.287 20.314 20.339 20.362 20.411 20.452 20.515 20.561 20.622 20.657 20.683 20.665
0.98 20.270 20.297 20.322 20.344 20.393 20.434 20.497 20.543 20.604 20.639 20.666 20.649
0.99 20.254 20.281 20.305 20.328 20.377 20.417 20.480 20.526 20.587 20.622 20.650 20.633
1 20.238 20.265 20.289 20.312 20.360 20.401 20.463 20.509 20.570 20.605 20.634 20.617
1.01 20.224 20.250 20.274 20.297 20.345 20.385 20.447 20.493 20.554 20.589 20.618 20.602
1.02 20.210 20.236 20.260 20.282 20.330 20.370 20.432 20.477 20.538 20.573 20.603 20.588
1.03 20.199 20.223 20.246 20.268 20.315 20.355 20.417 20.462 20.523 20.558 20.588 20.573
1.05 20.180 20.201 20.222 20.242 20.288 20.327 20.388 20.433 20.493 20.529 20.559 20.546
1.1 20.148 20.163 20.178 20.193 20.232 20.267 20.324 20.368 20.427 20.462 20.493 20.482
1.15 20.125 20.136 20.148 20.160 20.191 20.220 20.272 20.312 20.369 20.403 20.435 20.426
1.2 20.106 20.116 20.126 20.135 20.160 20.184 20.229 20.266 20.319 20.352 20.384 20.377
1.3 20.080 20.086 20.093 20.100 20.117 20.134 20.167 20.195 20.239 20.269 20.299 20.293
1.4 20.061 20.066 20.071 20.076 20.089 20.101 20.125 20.146 20.181 20.205 20.231 20.226
1.5 20.047 20.051 20.055 20.059 20.068 20.077 20.095 20.111 20.138 20.157 20.178 20.173
1.6 20.037 20.040 20.043 20.046 20.053 20.060 20.073 20.085 20.105 20.120 20.136 20.129
1.7 20.029 20.031 20.033 20.036 20.041 20.046 20.056 20.065 20.081 20.092 20.102 20.094
1.8 20.023 20.024 20.026 20.028 20.032 20.036 20.044 20.050 20.061 20.069 20.075 20.066
1.9 20.018 20.019 20.020 20.022 20.025 20.028 20.033 20.038 20.046 20.052 20.054 20.043
2 20.014 20.015 20.016 20.017 20.019 20.021 20.025 20.029 20.034 20.037 20.036 20.024
2.25 20.007 20.007 20.008 20.008 20.009 20.010 20.011 20.012 20.013 20.013 20.005 0.010
2.5 20.002 20.002 20.002 20.002 20.003 20.003 20.003 20.002 0.000 0.003 0.014 0.031
2.75 0.001 0.001 0.001 0.001 0.001 0.002 0.003 0.004 0.008 0.012 0.026 0.044
3 0.003 0.003 0.003 0.003 0.004 0.005 0.007 0.009 0.013 0.018 0.034 0.053
3.5 0.005 0.005 0.006 0.006 0.007 0.008 0.011 0.013 0.019 0.025 0.042 0.061
4 0.006 0.006 0.007 0.007 0.009 0.010 0.013 0.016 0.022 0.028 0.045 0.064
5 0.006 0.007 0.007 0.008 0.009 0.011 0.014 0.016 0.022 0.029 0.045 0.062

673

06/11/12 6:29 PM
bapp03.indd 674
TABLE C.8 Values for log [!(1)]*

674
Pr
Tr 0.01 0.025 0.05 0.075 0.1 0.25 0.5 0.6 0.7 0.8 0.9 1 1.1
0.3 28.779 28.779 28.780 28.781 28.782 28.787 28.796 28.799 28.803 28.806 28.810 28.813 28.817
0.35 26.526 26.527 26.528 26.529 26.530 26.536 26.546 26.550 26.554 26.558 26.562 26.566 26.570
0.4 24.912 24.913 24.914 24.915 24.916 24.922 24.932 24.936 24.941 24.945 24.949 24.953 24.957
0.45 23.726 23.726 23.727 23.728 23.729 23.736 23.746 23.750 23.754 23.758 23.762 23.766 23.770
0.5 22.838 22.838 22.839 22.840 22.841 22.847 22.857 22.861 22.865 22.868 22.872 22.876 22.880
0.55 20.013 22.163 22.164 22.165 22.166 22.171 22.181 22.184 22.188 22.192 22.196 22.199 22.203
0.6 20.009 20.023 21.644 21.645 21.646 21.651 21.660 21.664 21.667 21.671 21.674 21.678 21.681
0.65 20.006 20.015 20.031 21.241 21.241 21.247 21.255 21.258 21.262 21.265 21.268 21.272 21.275
0.7 20.004 20.010 20.021 20.032 20.044 20.929 20.937 20.940 20.943 20.946 20.949 20.952 20.955
0.75 20.003 20.007 20.014 20.022 20.030 20.677 20.685 20.688 20.691 20.694 20.697 20.700 20.703
0.8 20.002 20.005 20.010 20.015 20.020 20.056 20.484 20.487 20.490 20.493 20.496 20.498 20.501
0.85 20.001 20.003 20.006 20.010 20.013 20.036 20.324 20.327 20.330 20.332 20.335 20.338 20.341
0.9 20.001 20.002 20.004 20.006 20.009 20.023 20.053 20.199 20.202 20.204 20.207 20.210 20.212
0.93 20.001 20.002 20.003 20.005 20.007 20.017 20.037 20.048 20.138 20.141 20.143 20.146 20.149
0.95 20.001 20.001 20.003 20.004 20.005 20.014 20.030 20.037 20.046 20.103 20.106 20.108 20.111
0.97 0.000 20.001 20.002 20.003 20.004 20.011 20.023 20.029 20.034 20.042 20.072 20.075 20.077
0.98 0.000 20.001 20.002 20.003 20.004 20.010 20.020 20.025 20.030 20.035 20.056 20.059 20.062
0.99 0.000 20.001 20.002 20.003 20.003 20.009 20.018 20.021 20.025 20.030 20.034 20.044 20.047
1 0.000 20.001 20.001 20.002 20.003 20.008 20.015 20.018 20.022 20.025 20.028 20.031 20.034
1.01 0.000 20.001 20.001 20.002 20.003 20.007 20.013 20.016 20.018 20.021 20.023 20.024 20.023
1.02 0.000 20.001 20.001 20.002 20.002 20.006 20.011 20.013 20.015 20.017 20.018 20.019 20.018
1.03 0.000 0.000 20.001 20.001 20.002 20.005 20.009 20.011 20.012 20.013 20.014 20.014 20.013
1.05 0.000 0.000 20.001 20.001 20.001 20.003 20.006 20.006 20.007 20.007 20.007 20.007 20.005
1.1 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.002 0.003 0.004 0.005 0.007 0.009
1.15 0.000 0.000 0.000 0.001 0.001 0.003 0.006 0.008 0.009 0.011 0.014 0.016 0.019
1.2 0.000 0.000 0.001 0.001 0.002 0.004 0.009 0.012 0.014 0.017 0.020 0.023 0.026
1.3 0.000 0.001 0.001 0.002 0.003 0.007 0.014 0.017 0.020 0.023 0.027 0.030 0.034
1.4 0.000 0.001 0.002 0.002 0.003 0.008 0.016 0.020 0.023 0.027 0.030 0.034 0.038
1.5 0.000 0.001 0.002 0.003 0.003 0.008 0.017 0.021 0.024 0.028 0.032 0.036 0.039
1.6 0.000 0.001 0.002 0.003 0.003 0.009 0.018 0.021 0.025 0.029 0.032 0.036 0.040
1.7 0.000 0.001 0.002 0.003 0.004 0.009 0.018 0.021 0.025 0.029 0.032 0.036 0.039
1.8 0.000 0.001 0.002 0.003 0.003 0.009 0.018 0.021 0.025 0.028 0.032 0.035 0.039
1.9 0.000 0.001 0.002 0.003 0.003 0.009 0.017 0.021 0.024 0.028 0.031 0.034 0.038
2 0.000 0.001 0.002 0.003 0.003 0.008 0.017 0.020 0.024 0.027 0.030 0.034 0.037
2.25 0.000 0.001 0.002 0.002 0.003 0.008 0.016 0.019 0.022 0.025 0.028 0.031 0.034
2.5 0.000 0.001 0.001 0.002 0.003 0.007 0.015 0.018 0.020 0.023 0.026 0.029 0.032
2.75 0.000 0.001 0.001 0.002 0.003 0.007 0.014 0.016 0.019 0.022 0.024 0.027 0.030
3 0.000 0.001 0.001 0.002 0.003 0.006 0.013 0.015 0.018 0.020 0.023 0.025 0.028
3.5 0.000 0.001 0.001 0.002 0.002 0.006 0.011 0.013 0.016 0.018 0.020 0.022 0.024
4 0.000 0.001 0.001 0.001 0.002 0.005 0.010 0.012 0.014 0.016 0.018 0.020 0.022
5 0.000 0.000 0.001 0.001 0.002 0.004 0.008 0.010 0.011 0.013 0.015 0.016 0.018
*Many of these values have a different last decimal place from those published by Lee–Kesler.

05/11/12 6:18 PM
bapp03.indd 675
Pr
Tr 1.2 1.3 1.4 1.5 1.75 2 2.5 3 4 5 7.5 10
0.3 28.820 28.824 28.827 28.831 28.840 28.848 28.866 28.883 28.918 28.953 29.039 29.126
0.35 26.574 26.578 26.582 26.586 26.596 26.606 26.625 26.645 26.685 26.724 26.822 26.919
0.4 24.961 24.965 24.969 24.973 24.984 24.994 25.014 25.034 25.075 25.115 25.214 25.312
0.45 23.774 23.778 23.782 23.786 23.796 23.806 23.826 23.846 23.885 23.924 24.020 24.115
0.5 22.884 22.888 22.892 22.896 22.905 22.915 22.934 22.953 22.990 23.027 23.119 23.208
0.55 22.207 22.210 22.214 22.218 22.227 22.236 22.254 22.272 22.307 22.342 22.427 22.510
0.6 21.685 21.688 21.692 21.695 21.704 21.712 21.729 21.746 21.779 21.812 21.891 21.967
0.65 21.278 21.281 21.285 21.288 21.296 21.304 21.320 21.336 21.367 21.397 21.470 21.540
0.7 20.959 20.962 20.965 20.968 20.975 20.983 20.998 21.013 21.041 21.069 21.137 21.201
0.75 20.705 20.708 20.711 20.714 20.721 20.728 20.742 20.756 20.783 20.809 20.870 20.929
0.8 20.504 20.507 20.510 20.512 20.519 20.526 20.539 20.551 20.576 20.600 20.656 20.709
0.85 20.343 20.346 20.348 20.351 20.357 20.364 20.376 20.388 20.410 20.432 20.483 20.530
0.9 20.215 20.217 20.220 20.222 20.228 20.234 20.245 20.256 20.277 20.296 20.342 20.384
0.93 20.151 20.154 20.156 20.158 20.164 20.170 20.180 20.191 20.210 20.228 20.270 20.310
0.95 20.114 20.116 20.118 20.121 20.126 20.132 20.142 20.151 20.170 20.187 20.227 20.265
0.97 20.080 20.082 20.084 20.087 20.092 20.097 20.107 20.116 20.133 20.150 20.188 20.223
0.98 20.064 20.067 20.069 20.071 20.076 20.081 20.090 20.099 20.116 20.132 20.169 20.203
0.99 20.050 20.052 20.054 20.056 20.061 20.066 20.075 20.084 20.100 20.115 20.151 20.184
1 20.036 20.038 20.040 20.042 20.047 20.052 20.060 20.069 20.084 20.099 20.134 20.166
1.01 20.024 20.026 20.028 20.030 20.034 20.038 20.047 20.054 20.069 20.084 20.117 20.149
1.02 20.015 20.015 20.016 20.018 20.022 20.026 20.033 20.041 20.055 20.069 20.102 20.132
1.03 20.010 20.007 20.007 20.008 20.011 20.014 20.021 20.028 20.042 20.055 20.086 20.116
1.05 20.002 0.002 0.006 0.008 0.009 0.007 0.001 20.005 20.017 20.029 20.058 20.085
1.1 0.012 0.016 0.020 0.025 0.035 0.041 0.044 0.042 0.035 0.026 0.004 20.019
1.15 0.022 0.026 0.030 0.034 0.046 0.056 0.069 0.074 0.074 0.069 0.054 0.036
1.2 0.029 0.033 0.037 0.041 0.052 0.064 0.082 0.093 0.101 0.102 0.093 0.081
1.3 0.038 0.041 0.045 0.049 0.060 0.071 0.091 0.109 0.131 0.142 0.150 0.148
1.4 0.041 0.045 0.049 0.053 0.063 0.074 0.094 0.112 0.141 0.161 0.183 0.191
1.5 0.043 0.047 0.051 0.055 0.064 0.074 0.094 0.112 0.143 0.167 0.202 0.218
1.6 0.043 0.047 0.051 0.055 0.064 0.074 0.092 0.110 0.142 0.167 0.210 0.234
1.7 0.043 0.047 0.050 0.054 0.063 0.072 0.090 0.107 0.138 0.165 0.213 0.242
1.8 0.042 0.046 0.049 0.053 0.062 0.070 0.087 0.104 0.134 0.161 0.212 0.246
1.9 0.041 0.045 0.048 0.052 0.060 0.068 0.085 0.101 0.130 0.157 0.209 0.246
2 0.040 0.044 0.047 0.050 0.058 0.066 0.082 0.097 0.126 0.152 0.205 0.244
2.25 0.037 0.040 0.043 0.046 0.054 0.061 0.076 0.090 0.116 0.141 0.193 0.234
2.5 0.035 0.037 0.040 0.043 0.050 0.057 0.070 0.083 0.108 0.130 0.181 0.222
2.75 0.032 0.035 0.037 0.040 0.046 0.053 0.065 0.077 0.100 0.121 0.169 0.210
3 0.030 0.032 0.035 0.037 0.043 0.049 0.061 0.072 0.093 0.114 0.159 0.199
3.5 0.026 0.028 0.031 0.033 0.038 0.043 0.053 0.063 0.082 0.101 0.142 0.179
4 0.023 0.025 0.027 0.029 0.034 0.038 0.048 0.057 0.074 0.090 0.128 0.163
5 0.019 0.021 0.022 0.024 0.028 0.032 0.039 0.047 0.061 0.075 0.108 0.138

675

05/11/12 6:18 PM
 7.3 Fugacity in the Vapor Phase ◄ 401

0.1
4

0 3

2
−0.1
1.7

−0.2 1.5
log[ ](0)

−0.3 1.3

−0.4 1.2

−0.5 1.1
1.05
1.0
−0.6
Tr = 0.5 0.6 0.7 0.8 0.9

−0.7
0.01 0.1 1 10
Pr

Figure 7.1 Corresponding states correlation for the fugacity coefficient in reduced coordinates—
simple fluid term. Based on the Lee–Kesler equation of state.

2
1.5
0.2 3
4
1.3
0.1
1.2

0
1.1
1.05
log[ ](1)

−0.1
1.0

−0.2
0.9

−0.3

0.7 0.8
−0.4
Tr = 0.6

−0.5
0.01 0.1 1 10
Pr

Figure 7.2 Corresponding states correlation for the fugacity coefficient in reduced coordinates—
correction term. Based on the Lee–Kesler equation of state.

c07.indd 401 05/11/12 7:10 PM