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General Definitions:
Acid: a substance which when added to water produces hydrogen ions
[H+].
Base: a substance which when added to water produces hydroxide ions
[OH-].
2. Properties:
Acids:
Bases:
Remember: the smaller the negative exponent, the larger the number is.
Therefore:
Example 2: What is the [H+] of human saliva if its [OH-] is 4 x 10-8 M? Is human saliva
acidic, basic, or neutral?
4. pH
relationship between [H+] and pH
pH = -log10[H+]
if pH is 8.5, then the antilog of -8.5 is 3.2 x 10-9. Thus the [H+] is 3.2 x 10-
9
M
Now you try a few by yourself. You can then check your answers using the Java applet
that follows, but remember, you won't learn how to do them if you don't try by yourself
first.
Practice #1. What is the pH of a solution of NaOH that has a [OH-] of 3.5 x 10-3 M?
Acids
1. Strong Acids:
completely dissociate in water, forming H+ and an anion.
The reaction is
A 0.01 M solution of nitric acid contains 0.01 M of H+ and 0.01 M N03- ions
and almost no HN03 molecules. The pH of the solution would be 2.0.
There are only 6 strong acids: You must learn them. The
remainder of the acids therefore are considered weak
acids.
o HCl
o H2SO4
o HNO3
o HClO4
o HBr
o HI
2. Note: when a strong acid dissociates only one H+ ion is removed. H2S04
dissociates giving H+ and HS04- ions.
H2SO4 → H+ + HSO41-
A 0.01 M solution of sulfuric acid would contain 0.01 M H+ and 0.01 M
HSO41- (bisulfate or hydrogen sulfate ion).
2. Weak acids:
a weak acid only partially dissociates in water to give H+ and the anion
Note the use of the double arrow with the weak acid. That is because an
equilibrium exists between the dissociated ions and the undissociated
molecule. In the case of a strong acid dissociating, only one arrow ( → )
is required since the reaction goes virtually to completion.
An equilibrium expression can be written for this system:
Ka = [ H+][F-] / [HF]
Which are the weak acids? Anything that dissociates in water to produce H+
and is not one of the 6 strong acids.
o Molecules containing an ionizable proton. (If the formula starts with H then
it is a prime candidate for being an acid.) Also: organic acids have at least
one carboxyl group, -COOH, with the H being ionizable.
o Anions that contain an ionizable proton. ( HSO41- → H+ + SO42- )
o Cations: (transition metal cations and heavy metal cations with high
charge)
Bases
1. Strong Bases:
They dissociate 100% into the cation and OH- (hydroxide ion).
a. 0.010 M NaOH solution will contain 0.010 M OH- ions (as well as 0.010 M Na+
ions) and have a pH of 12.
Note: the hydroxides of Group II metals produce 2 mol of OH- ions for every
mole of base that dissociates. These hydroxides are not very soluble, but what
amount that does dissolve completely dissociates into ions.
2. Weak Bases:
What compounds are considered to be weak bases?
3. When a weak base reacts with water the OH- comes from the water and the
remaining H+ attaches itsef to the weak base, giving a weak acid as one of the
products. You may think of it as a two-step reaction similar to the hydrolysis of
water by cations to give acid solutions.
examples:
Examples: determine if the following solutions are acidic, basic, or neutral Click
on each one to find out the answer.
KC2H3O2 NaHPO4
Cu(NO3)2 LiHS
KClO4 NH4Cl
6. Acid-Base Reactions:
Strong acid + strong base: HCl + NaOH → NaCl + H2O
net ionic reaction: H+ + OH- → H2O
Strong acid + weak base:
example: write the net ionic equation for the reaction between hydrochloric acid, HCl,
and aqueous ammonia, NH3. What is the pH of the resulting solution?
example: write the net ionic equation for the reaction between citric acid (H 3C6H507)
and sodium hydroxide. What is the pH of the resulting solution?
7. Titrations
1. Nomenclature: these are terms that are used when talking about
titrating one substance with another. You need to learn these definitions
well enough to explain them to someone else.
titration
titrant
indicator
equivalence point
end point
titration cuve
titration curve
pH at equivalence point
species present
appropriate indicators
titration curve
pH at end point
species present
appropriate indicators
example: titration
curve for the titration
of vinegar with NaOH
pH at end point-
approximately 8.5
appropiate indicator-
phenolphthalein
b. What is the solubility of the calcium hydroxide in water at 30 oC? Express your answer
in grams of Ca(OH)2 / 100 mL water?