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128 Z. Anal. Chem.

, Band 265, tteft 2 (1973)

r i c h t i g e r A n s w e r t u n g usw. k 6 n n e n m i t d e n F o r t - Literatur
s c h r i t t e n der R c c h n e r a u s w e r t u n g a u f Gr6Benord- 1. Gebauhr, W., Martin, J.: diese Z. 200, 266 (1964).
n u n g e n r e d u z i e r t werden, in d e n e n sic fiir die der- 2. Haan, E. F., van der Drift, A., Schampers, P. P. M. :
zeitigen A n f o r d e r u n g e n a n die S p u r e n a n a l y s e n Philips Techn. Rdsch. 25, 251 (1964).
3. Irving, B. A.: The electrochemistry of semiconductors,
k a u m n o c h ins G e w i c h t fallen. p. 256, hrsg. yon P . J . Holmes. London-l~ew York:
Z u s a m m e n f a s s e n d k a n n gesagt werden, d a b ver- Acad. Press 1962.
gleiehsweise n u r wenige Schwierigkeiten aus der Teeh- 4. Kern, W. : RCA Review 81, 207, 234 (1970) ; 82, 64 (1971).
n i k d e r A k t i v i e r u n g s a n a l y s e entstehen. Die wesent- 5. Marth, W. : Bestrahlungstechnik an Forschungsreaktoren,
S. 39. Thiemig-Taschenbficher, Band 13, 1969.
lichen P r o b l e m e d e r A n a l y s e hochreiner M a t e r i a l i e n
6. 1V[artin,J. : Semiconductor silicon, S. 547; hrsg. vonR. R.
liegen i m E r k c n n e n u n d B e h e r r s c h e n des b e s o n d e r e n Haberecht u. E . L . Kern. I~ew York: The Electro-
chemisehen a n d p h y s i k a l i s c h e n V e r h a l t e n s kleiner chemical Society, Inc. 1969.
E l e m e n t m e n g e n in u n d a u f d e n h o c h r e i n e n P r o b e n . 7. YYeeb,K . H . , Franke, R., Iqeidl, H.: diese Z. 247, 225
Zweifellos b i e t e t die A k t i v i c r u n g s a n a l y s e d u r c h ihre (1969).
8. Niese, S.: Kernenergie 7, 105 (1964).
h o h e n N a c h w e i s e m p f i n d l i c h k e i t e n , d u r c h die M6g- 9. Seith, W., ~Ieumann, Th. : Diffusion in Metallen, S. 185.
lichkeiten d e r a u t o r a d i o g r a p h i s c h e n O r t u n g u n d der Berlin-G6ttingen-Heidelberg: Springer 1955.
b l i n d w e r t f r e i e n B e a r b e i t u n g der P r o b e n n a c h d e r
J. A. Martin
A k t i v i e r u n g , n o c h a m ehesten die V o r a u s s e t z u n g e n Radiochemisches Laboratorium der Siemens AG
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empfindlichen R e i n s t s t o f f a n a l y s e n . Bundesrepublik Deutschland

Kurze Mitteilungen

Homogeneous Precipitation To a solution containing 5--100 mg lead taken in a 100 ml


beaker, 10 ml each of 5 % EDTA and 0.1 M ammonium
of Lead Sulphate from Lead(II)-EDTA sulphate are added in the same order and the pH adjusted to
1.0 in the case of copper(II) or 2.0 in the case of nickel(IX).
Complex by Displacement The solution is diluted to 50 ml and 8 ml of 0.2 M copper or
with Copper(II) and Nickel(II) nickel nitrate solutions are added. The contents of the beaker
are heated on a water bath until the volume is about 15 ml
(90 min). After cooling for 30 rain, the precipitate is filtered
Fi~llung yon Bleisulfat aus homogener LSsung
through a sintered glass crucible (porosity 4) and washed
aus dem Blei(II)-Ji__DTA-Komplex durch Verdr~ngung
first with l~ sulphurie acid and then with 500/0 ethanol
mit Kupfer(II) oder :Nickel(IX)
until free from sulphate. The precipitate is dried at 120~
for 1 h and weighed as PbSO a.
Best. yon Blei als Bleisulfat; Gravimetrie; homogene LSsung
T h e m e t h o d yields v e r y a c c u r a t e results a n d h a s
J. Rajagopala Rao, A. Suryanarayana, and B.R. Sang
also been a p p l i e d for t h e analysis of t y p e m e t a l .
Regional Research Laboratory, Bhubaneswar, Orissa, India AI(III), Fe(III), Zn(II), Mn(II), Sn(II), and Sb(III)
Received October 10, 1972; revised March 12, 1973 do n o t interfere i n t h e e s t i m a t i o n
Grateful thanks of the authors are due to Prof. P. K. Jena,
Director, Regional Research Laboratory, Bhubaneswar, for
I n a n earlier c o m m u n i c a t i o n [1], a m e t h o d for t h e facilities and interest in the work.
h o m o g e n e o u s p r e c i p i t a t i o n of l e a d s u l p h a t e t h r o u g h
c a t i o n release w i t h i r o n ( I I I ) o b t a i n e d b y t h e slow Re/erence
o x i d a t i o n o f i r o n ( I I ) was described. T h e m e t a l - E D T A 1. Suryanarayana, A., Rajagopala Rao, J., Sant, B.R. : Anal.
s t a b i h t y c o n s t a n t values for copper a n d nickel are Chim. Acta 59, 481 (1972).
o n l y slightly higher t h a n t h a t of lead. A g r a v i m e t r i c
Dr. B. R. Sang
m e t h o d for t h e d e t e r m i n a t i o n of l e a d b y c a t i o n dis- Regional Research Laboratory
p l a c e m e n t w i t h e o p p e r ( I I ) or nickel(H) h a s n o w been Bhubancswar-4
w o r k e d out. Orissa, India

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