Beruflich Dokumente
Kultur Dokumente
Submitted to
Xanthe Farnworth
for
English 316
Brigham Young University
Provo, UT
12 June 2009
by
Darrell Skousen
David Smyth
Nick Andersen
June 12, 2009
Xanthe Farnworth
We are submitting this technical report to you in order to demonstrate our ability
to work as a group, research a topic, organize information, create and revise a technical
document, and present a professional report. In our report, we discuss four applications
of carbon nanotubes.
Carbon nanotubes are a relatively new technology with many unique properties.
Since we don’t expect you or any of our readers to be experts, the report presents a large
We have attempted to follow models given in the class packet and from the
Lannon textbook. Along with all required sections of the report, we have included a
glossary for technical terms. We use AIP format, which calls specifically for references,
We expect that you will find this report interesting and easy to read. If you have
any further questions regarding the report please contact us. Thank you.
Sincerely,
Table of Contents
Abstract iv
Introduction 1
Research Information 2
Materials Science
2
Carbon Nanotubes
4
Incorporating Carbon Nanotubes
4
Focus Applications
5
Standards of Judgment
6
Product Comparison 7
Paper Batteries
7
Composite Materials
9
Displays
11
Computing
13
Results
17
Conclusion 20
References 21
List of Figures 22
List of Tables 22
Glossary of Terms
23
iv
Abstract
and has ordered a preliminary report regarding the most profitable nanotube applica-
tion. Four potential applications, paper batteries, composite materials, displays, and
soon the product can be marketed), cost (how much money will be invested in research
and production), and consumer demand (the size of the potential consumer base). Re-
sults show displays being the most profitable application with a high demand, while
composite materials are a profitable application with low demand. Current research
shows that paper batteries and nanocomputers are too far from production to be profit-
able in the near future. This report concludes that CNI should invest in production of
Introduction
Carbon nanotubes (CNTs) are a remarkable new technology with very unique
properties, making them applicable in nearly every field from consumer electronics to
medical equipment and even to clothing. The purpose of this technical report is to com-
pare four popular, near-future applications of carbon nanotubes, paper batteries, com-
Information has been researched and gathered entirely from external sources,
including scientific journals, company websites, and newspaper articles. Therefore, re-
sults are generally based on implications of expert findings and are often estimated for
purposes of comparison. The individual sections for each application include back-
ground information and a detailed analysis of profitability based on the three standards
materials science and CNTs, and it discusses how they can be incorporated into future
applications, with a specific focus on paper batteries, composite materials, displays, and
nanocomputers. Next, there is a section discussing the standards of judgment and crite-
ria used in the comparison of the four focus applications. The paper continues with a
*Descriptions of bold terms can be found in the glossary at the end of the report.
2
section designed for a more technical audience; it includes a detailed analysis of each
application, comparing each using the three standards of judgment. Finally, the results
are presented followed by a conclusion that discusses the recommendation of which ap-
plication will be the most profitable. The document concludes with a references page, a
Research Information
Materials Science
focuses on the fundamental properties and characteristics of materials and their appli-
cation in various products. Material properties often include tensile strength*, heat
material’s application, are either desired or avoided. For instance, the copper wiring on
the inside of a power cord has a high electrical conductivity, while the rubber insulation
on the outside of the same cord is not electrically conductive at all. Engineers study
materials science in order to improve and perfect the products they design and manu-
facture.
3
• When two or more material properties are desired, but cannot readily be found
Allotropes. When a material is broken into its constituent parts, scientists can
study the basic elements that it is made of and modify those elements to change the
physical and chemical properties of the material. One modification can be made by us-
ing a given element’s allotrope (the same element in a different form or structure) in
that element’s place in the material. Different allotropes of the same material often have
unexpectedly different properties that scientists can take advantage of by using them in
Graphite Diamond
Carbon is a unique element with many different allotropes, the most common be-
ing graphite and diamond. Graphite, formed from parallel layers of carbon atoms in a
common products such as pencils. Diamond, an extremely rare allotrope formed from
4
carbon atoms in a crystal lattice, is the hardest known mineral and is not electrically
conductive at all.
Carbon Nanotubes
50,000 times thinner than a human hair, they are formed from
A computer model of a
a single, atom-thick layer of carbon curled into a cylindrical carbon nanotube.
(tube) shape. Although their small diameter initially seems like it could be a limiting fac-
tor, they have a higher tensile strength than steel and they retain their strength at
lengths millions of times larger than their diameter. For instance, if a carbon nanotube
had the diameter of a human hair, it could be longer than a football field and it would
While CNTs are very impressive by themselves, the possibilities of how they can
effect other products are endless. The two most desirable properties of CNTs—namely
new products to be designed. CNTs add their own strength to structural supports, cables
5
are stronger, batteries conduct power more efficiently, and satellite housings conduct
heat better. This allows for smaller structures and more efficient designs. Their variably
their heat conduction can prevent heat buildup in a system's critical components. These
properties can be utilized in such a wide variety of applications that only a few have been
Focus Applications
Since there are limitless applications of CNTs, many applications cannot be con-
sidered because of prohibitive startup costs due to years of research that still needs to be
done before production. Four applications of CNT technology will be compared to de-
termine which is most suitable for production: paper batteries, composite materials,
Paper batteries. Paper batteries hold charge in packages more compact than cur-
batteries can be formed into any shape and made paper thin so they can fit into compact
spaces, wrap around a product, or cover any surface. Paper batteries would allow more
desired properties from each material. These composite materials often contain numer-
6
ous individual materials in varying amounts to achieve the desired property combina-
tion. CNT technology can be used as part of a composite material in many products such
as body armor to provide a lighter, stronger protection for military use. Some CNTs can
also be used in clothing to detect the presence of blood and indicate wounds. Composite
materials also allow for adjustable electrical conductivity to match the desired qualities
screen picture that combines the size and brightness of flat panel televisions with the
be ideal in computing applications, introducing high quality parts to the system that will
allow a computer to work faster and with lower power requirements, thus increasing ef-
ficiency.
Standards of Judgment
Schedule. This section estimates how long it will take for each application to be-
came a marketable product, based on research and expert opinions. It discusses whether
quantity. For example, nanocomputers are still in the experimental stage and are not
Cost. This section estimates how much research and manufacturing will cost. It
discusses research, material, machinery and other costs. Prices are dropping quickly in
7
many applications so future costs are also estimated. In this section we compare costs of
Consumer Demand. This section discusses the marketability and current demand
for each application, focusing on potential for product sales to consumers including pri-
vate companies, government and military organizations, and the general public. It also
discusses current revenues and where demand is for the chosen application. For in-
Product Comparison
Paper Batteries
Batteries are common devices used in almost all modern electronic technology to
store chemical energy for use over a period of time. Like batteries, supercapacitors
store energy, but unlike batteries, no chemical change takes place, allowing energy to be
quickly stored or released. Supercapacitors can be cycled, used, and recharged many
times more than a battery; however, they do not store nearly as much energy as
batteries. By incorporating carbon nanotubes into battery and capacitor technology, sci-
entists can make thin, flexible, and safe batteries, supercapacitors, and dual-storage
both the high storage capacity of batteries and the quick release of energy of superca-
pacitors. A flashlight with this CNT battery supercapacitor could be dimly lit for hours
Paper batteries are made of three materials: cellulose, CNTs, and electrolytes.
Cellulose, the same material that paper is made of, makes up over 90% of the battery,
making it cheap, environmentally friendly, and easy to manufacture. CNTs are grown,
embedded in dissolved cellulose, and then dried. The main components of these
units can be cut into any size and can be used in smart cards,
Paper batteries can be
displays, or implantable medical devices. Carbon nanotube bent, twisted, or rolled.
Paper batteries do not contain any water, so they can operate at a temperature
range of 195-423 K (approx. -108°F to 300°F), a much greater range than commercial
Paper batteries also are unique since they can be activated by body fluid electrolytes
such as blood, sweat, and urine, giving them a demand in various medical fields.2
MIT estimate that it will be five to ten years before CNT batteries will be commercially
be mass produced, including the time it takes to integrate these batteries into current
electronic applications.
Cost. The processes for making paper batteries are fairly simple; however, both
research costs and machinery costs will be high. Carbon nanotube material will be the
9
most expensive part of the production since CNT prices are still $50/g or more—that
material is 100 to 1000 times more expensive than what is currently being used.3 In the
future, prices are expected to decrease rapidly, making CNT batteries a more reasonable
option.
that several billion batteries are sold each year. There is always an increasing need for
smaller, lighter, and more powerful batteries to meet the requirements of today’s tech-
nology, including the rise of hybrid and electric cars as well as specialized medical
applications.2 Since paper batteries will reduce much of the weight in cell phones and
Composite Materials
properties, but make one structure. Composites have been used for ages. One of the ear-
liest examples of a composite material is the mixture of straw with mud to make bricks.
The straw creates a structure that strengthens the mud that holds it together. A more
recent and comparable composite is fiberglass, in which strands of glass in resin in-
Composite materials are engineered to have as many benefits and as few disad-
vantages as possible. Carbon nanotubes can be incorporated into many existing prod-
ucts with unique and interesting results. Polystyrene, a specific type of plastic that in-
corporates CNTs, has been seen to change from electrically nonconducting to conduct-
ing while doubling its tensile strength. This means that the new composite material can
10
take twice the load before stretching the same amount as the original material. This re-
sult was accomplished with only 0.05% to 2.5% of nanotubes by volume in the
composite.4
Composite materials are mainly used where performance is a key issue. The aero-
space industry was one of the first to turn to composites as they needed strong and light
materials. Today, the aerospace industry accounts for only a small fraction of the com-
posite materials market while the transportation industry accounts for a significant
portion.5
product designs can be produced immediately. Since current maximum CNT lengths
limit the extent to which the composite is strengthened, further research will focus on
increasing tube length and overall quality. Although CNT manufacturers are discovering
ways to make them longer, current lengths are sufficient to begin composite material
production.
Cost. Composite material costs are limited. Startup costs are limited to purchas-
ing equipment that produces composite material. Manufacturing methods are already
commonly established. Cost of the CNTs within the composites would be the highest;
however, as the CNTs are readily available, their cost is not a serious issue. Researching
costs are minimal since most research is already done regarding composite materials
Consumer Demand. Composite materials are often used when both weight and
strength are essential elements in a design. This limits the consumer base for such
Displays
Today, most electronic devices use some sort of display to interact with their us-
ers. These displays are designed and manufactured in a variety of ways, each employing
different materials and taking advantage of different physical properties in order to pro-
projection, and liquid crystal display (LCD), which have become standard tech-
nologies because of their application in smaller devices such as handhelds, cell phones,
etc. and their reduced footprint (how much room they take
tages, although for the average consumer, advantages of CNTs even find application
in televisions.
the newer technologies outweigh the disadvantages.
Field-Emission Displays and Carbon Nanotubes. For the last 25 years or so, en-
gineers have experimented with a new display technology called field-emission dis-
12
play, or FED, which combines the older CRT technology with the newer flat screen
technologies to create a product that shares all of the benefits of both technologies,
while virtually eliminating their detriments. An FED is a flat panel display that consists
of millions of tiny cathode ray tubes, each dedicated to a red, green, or blue pixel,
which, when used together can display any desired color. Until very recently, FED tech-
nology has only been theorized because of heat and electrical conductivity problems, but
with the discovery and implementation of CNTs, these field emission displays have be-
come a reality. The unique properties of CNTs effectively eliminate issues with heat re-
sistance and electrical conductivity while including other features such as pixel size (a
CNT display can have 40% better resolution than a plasma screen of comparable size).
In addition, a small display screen made from carbon nanotubes would be 250 times
stronger than its LCD counterpart, while remaining 10 times lighter.6 A field-emission
display that employs CNT technology would be as thin as (if not thinner than) a current
flat-panel display while having increased viewing angle, color fidelity, and contrast, and
Schedule. Since field-emission display technology has already been designed, im-
plementing carbon nanotubes in their production is not the dream of a distant future,
but a reality of today. In 2003, Samsung demonstrated a full-color 38-inch FED that
was comparable to other consumer displays in its video capabilities. Other companies
such as Motorola and Sony are also pursuing CNT field-emission displays, testing them
in applications such as handheld devices, cell phones, laptops, and other small
products.7 An efficient cinema-style screen is currently further from our grasp as con-
13
sumers because of obvious size limitations when dealing with billions of nanometer-
thick tubes.
Cost. For displays utilizing billions of CNTs each, cost will be the biggest limita-
tion. Currently, cost range from $100-$500 per gram—10 to 50 times as much as gold—
for single-wall carbon nanotubes, the CNTs necessary for effective FED
manufacturing.7 Although the display is usually the most expensive component in a de-
vice, the increase in price would clearly be a limitation for most consumers, causing CNT
over 31 million flat-panel televisions. This figure does not include any small handheld
devices or laptops, which combined would yield a similar projection. Clearly, consumers
in the United States have a high demand for flat-panel displays, making CNT field-
Computing
The electronics industry is always working toward making smaller, more power-
ful, less expensive devices. Over the last several decades, there has been large growth
kinds electronic hardware. Computing power follows Moore’s Law, doubling every two
years or so, while the size of computer chips decreases by half the size. However, due to
fundamental physical limitations (one can only fit so many electronics onto one chip), it
14
is doubtful that this growth and improvement will continue at the same rate using cur-
Moore’s Law
2,000,000,000
Moore’s Law states that
computing power will
double every two years. Transistor Count
Recent history has shown
this law to be true. 1,000,000 50,000,000
2,000 50,000
Carbon nanotubes offer an excellent solution for making smaller, more efficient
open the door to extra-fast electronics that will exponentially increase computing power.
chips. The more transistors that can be fit into a chip, the more powerful it will be. Intel
uses 42 million transistors in the Pentium 4 chip; using CNTs instead, the number could
be increased to billions.9 Results show that nanotube transistors perform better and de-
liver more than twice the electric current than other cutting edge transistors, allowing
engineers to design chips that use less electricity and saving energy for consumers who
tronic memory that allows computers to run programs and operating systems. However,
DRAM, unlike a hard drive, stores information only when the computer is turned on.
CNTs can be used to make nonvolatile DRAM, a type of DRAM which stores information
even when the computer is off. Nantero, a computer memory company, expects to fabri-
cate a nonvolatile CNT memory chip with several times the existing capacity.9
Schedule. CNTs are still in their beginning stages and will not quickly change the
current silicon industry which has been around for decades. The integration of CNTs
into modern electronics faces problems of compatibility with current electronic designs.
Even though CNTs have been used to make transistors, there still aren’t techniques us-
nanocomputing.8 It will take years, some experts estimate 10-15, before CNTs will be
able to gain a foothold in the electronics industry.9 In the near future, it is likely that
CNTs will only be used in high-tech applications, and not for general use.
Cost. The cost of using CNTs in nano-computing is the most important concern.
Research costs will be very high. Also, machinery and production costs will be large due
to the lack of current methods for fabricating CNT nanocomputers. NanoMarkets LC, a
market research consulting firm, estimates that CNTs will generate $3.6 billion in new
business in the electronics and semiconductor sector in 2009, which has a current reve-
nue of several hundred billion dollars. They also estimate that nanotube based memo-
ries such as DRAM will be able to enter laptop and cell phone markets generating hun-
Demand. The demand for smaller, more powerful computer chips is obvious in
today’s markets. With over a billion computers in use and over 200 million computers
16
sold a year, there is always a demand for better computers. However, even with the high
demand for electronics it will be years before CNT nano-computing could compete with
the current semiconductor industry. There is only a small potential demand from gov-
ernments and companies that can afford high-tech CNT computer chips.
17
Results
tial as a profitable product. A higher rating will imply a more desirable choice as a po-
tential marketable product. For instance, a high demand rating means a larger con-
sumer demand, while a high cost rating means lower overall costs for production.
Schedule. Although research in CNT technology has been moving forward for
several years and much has been accomplished in the field, advances that have been
made have still not resulted in many manufactured products. Paper batteries require a
few more years of research, so they receive a medium rating, while composite materials
and displays are currently being manufactured, so they receive a high rating. Nanocom-
puting technologies still require many years of research, so their rating is low.
Schedule Rating
High
Medium
Low
Paper Batteries Composites Displays Nanocomputers
A high score for composites and displays shows that both are ready for
production without further development, while the lower scores for the others
means that production for either is unlikely without further research.
18
batteries require additional research and receive a medium rating, while composites re-
ceive a high rating because virtually no more work is required to put nanotubes into
composite production. Displays receive a medium-high rating as they have been proven
to work already, but they need to be manufactured efficiently. Nanocomputers still re-
quire a lot of research before production can begin: they receive a low rating again.
Cost Rating
High
Medium
Low
mand, a product can receive a high rating in the other two categories, but fail as a mar-
ketable product. Paper batteries have the largest, giving them a high rating, while
composites are used only when needed in performance applications, resulting in a low
rating. Displays and nanocomputers have an obviously high consumer demand, but
there are more electronics that require batteries than ones that require displays or com-
Demand Rating
High
Medium
Low
Overall. The standards of judgment chosen reveal different strengths and weak-
nesses for each product. Only a combination of cheap, quick production with a high de-
mand will result in the most profitable product. Although composites were rated im-
pressively well in schedule and cost, the lack of consumer demand would make for a fail-
ing product. Only displays, which didn’t receive perfect ratings, scored well all around.
Their high consumer demand in addition to their immediate marketability make them
Conclusion
products to make with available CNT sources. After extensive research and synthesis of
technology, incorporated with CNT technology, makes for a marketable product that is
both cost-effective and ready for production. In a future report, additional research
should be done to determine a detailed cost analysis of producing and selling CNT field
emission displays.
21
References
cations," Crit. Rev. in Solid St. and Materials Sci. 26 (3), 145-249 (2001).
http://www.technologyreview.com/NanoTech/wtr_16326,303,p1.html
Properties, and Applications of Carbon Nanotubes,” Ann. Rev. of Mat. Research 33,
419-501 (2003).
http://www.technologyreview.com/computing/12109/
10. S. J. Wind, J. Appenzeller, R. Martel, V. Derycke, and Ph. Avouris, "Vertical scaling
of carbon nanotube field-transistors using top gate electrodes," Appl. Phys. Lett. 80,
3817 (2002).
22
List of Figures
1. Moore’s Law: transistor count doubles every two years. (p. 14)
2. Schedule Rating: composites and displays receive the highest rating. (p. 17)
3. Cost Rating: composites receive the highest rating, with displays close behind. (p. 18)
4. Consumer Demand Rating: paper batteries receive the highest rating. (p. 19)
List of Tables
Glossary of Terms
tensile strength: the maximum stress a material can withstand when subjected to
electrical conductivity: the ability a material has for electricity to flow through it
nanotechnology: a subfield of materials science that deals strictly with objects whose
allotrope: a pure form of an element that has a unique physical structure intrinsically
supercapacitors: electronic devices that store electronic charge for immediate and
dual-storage battery supercapacitors: batteries that store charge for low usage
over a long period of time or high usage over a short period of time; basically a
plasma display: a type of flat panel display in which gases are heated to a plasma state
rear-projection display: a type of large screen television that works like a self-
liquid crystal display: a type of flat panel display in which each pixel is made of a
filter that regulates color and contrast of the light passing through it
cathode ray tube: a type of display technology that directs electrons through a tube
field-emission display: a type of flat panel display that combines cathode ray tube
pixel: the smallest item of information in a digital image; a pixel can only be one color
at a time
single-wall carbon nanotubes: the least common, but purest CNT form, consisting
transistor sends high or low voltage that is interpreted by the computer processor
as a 1 or a 0