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MATERIAL SAFETY DATA SHEET

SUNIGUM® P95
MSDS No : SNGP95 Issue No : 4.00 Page : 1

1. Identification of the substance and company

Trade name SUNIGUM P95


Chemical name Acrylate rubber
CAS number 25852-38-4(for polymer)
Type of product and use Plastic modifier
Company identification * OMNOVA Solutions Inc
1380 Techway Drive
Akron, OH 44306-2532
U.S.A.
Contact msds@eliokem.com
Emergency phone number
- Company * +1.330.628.9925 - +1.330.628.6500
- Chemical Transportation Emergency CHEMTREC United States: + 1.800.424.9300
CHEMTREC International: + 1.703.527.3887

Composition/information on the components

Hazardous Components % Weight CAS No. EINECS/ELINCS/CE No.


Calcium carbonate 7 to 10 471-34-1 207-439-9

2. Hazards identification

Emergency Overview If ignited by excessive heat or open flame, this product will burn.
Appearance Powder.
Physical state at 25°C Solid.
Colour White.
Odour Not applicable.
Potential Health Effects
Primary Routes of Entry Inhalation
Short Term Exposure Inhalation of fine particulates may cause mild irritation of the respiratory
tract. May cause mild transient eye irritation.
Long Term Exposure Repeated and prolonged inhalation of dust in excess of respirable dust
levels may lead to a benign pneumoconiosis (dust in the lungs). This
condition may cause some impairment of lung function which may be
reversible with reduced exposure.

3. Information on ingredients

Chemical family Polymer


8 Hour TWA (mg/m3) CaCO3, 10 (Particles not otherwise specified).

4. First aid measures

Inhalation If overcome by exposure, remove victim to fresh air immediately.


Skin contact Wash skin thoroughly with mild soap/water.
Eye contact Irrigate with plenty of water. Particulates should be removed from the eye by
trained medical personnel only.
Ingestion No specific procedures are expected to be required.

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Quick-FDS [15822-53097-01000-019543] - 2011-04-26 - 14:44:58


MATERIAL SAFETY DATA SHEET

SUNIGUM® P95
MSDS No : SNGP95 Issue No : 4.00 Page : 2

5. Fire - fighting measures

Flash point (°C) Not applicable.


Explosion limits
- Lower (%) Not established.
- Upper (%) Not established.
Extinguishing media Carbon dioxide, dry chemicals, foam, water spray (fog).
Special exposure hazards Burning material may emit noxious fumes.
Special intervention methods Self contained breathing apparatus.
NFPA rating Health: 1;
Fire: 1;
Reactivity: 0;
Specific:
Hazard rating 0=Insignificant; 1=Slight; 2=Moderate; 3=High; 4=Extreme

6. Accidental release measures

After spillage / leakage No special procedures required.


Sweep or shovel spills into appropriate container for disposal.

7. Handling and storage

Storage Store in dry, well-ventilated area. Keep away from heat and sources of
ignition.
Handling Avoid generating dust. Use safety glasses.

8. Exposure controls / personal protection

Industrial hygiene Use adequate ventilation to keep vapour concentrations below applicable
standard.
Residual monomers Trace amounts of monomers may be released during use of this material.
Personal protection Approved dust respirator. Where contact with eyes or skin is likely, wear
suitable protection.
Ventilation protection There should be enough fresh air flowing past the user to keep the dust
levels below 10 mg/M3 total and 5 mg/M3 respirable (Nuisance dust TLV -
8-hr. time weighted average) (CaCO3)

9. Physical and chemical properties

Density at 25°C (kg/m3) 1120


Bulk density at 25°C (kg/m3) 500
Solubility in water at 20°C (µg/l) Insoluble.
Solubility (Other) Partially soluble in aromatic hydrocarbons, esters and ketones.
Thermal decomposition > 200°C
Others Minimum Ignition Energy (mJ) , > 1200
KST (bar.m.s-1), 58; ST1 (VDI 3673); VMP (bar/s), 215; Pmax (bar), 5.9

10. Stability and reactivity

Stability Stable
Materials to avoid For calcium carbonate, avoid fluorine and magnesium.
Conditions to avoid None under normal conditions.
Hazardous decomposition products CO, CO2, HCN, Normal hydrocarbon combustion products expected.

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Quick-FDS [15822-53097-01000-019543] - 2011-04-26 - 14:44:58


MATERIAL SAFETY DATA SHEET

SUNIGUM® P95
MSDS No : SNGP95 Issue No : 4.00 Page : 3

11. Toxicological information

Physiological effects May cause irritation by inhalation or in contact with eyes.


Rat oral LD50 (mg/kg) Not established.
Rabbit dermal LD50 (mg/kg) Not established.
Rat inhalation LC50 (ppm) Not established.

12. Ecological information

Biodegradation Not soluble in water, so only minimally biodegradable.

13. Disposal considerations

Disposal If possible, Recycle. Burn solid waste.


Dispose in a safe manner in accordance with local/national regulations.

14. Transportation information

Classification Not classified.


- UN No.
- IMO-IMDG code
- ICAO/IATA
Basic description Not applicable.
Freight Description Rubber ,Synthetic, Crude, in powder or pellet form.
Primary hazard class Not applicable.
Subsidiary hazard class Not applicable.
Labels required Not applicable.
Reportable quantity Not applicable.

15. Regulatory information

Other The components of this preparation are included in, or are exempt from:
Australian AICS
Canadian DSL
Chinese IECS
European EINECS
Japanese ENCS
Korean ECL
New Zealand TSA
US TSCA
USA This product does not contain a SARA S-313 Toxic Chemical above the de
minimis thresholds.
The partitioning agent(s) is considered hazardous as defined by the OSHA
Hazard Communication Standard CFR Title 29 1910.1200.
Canada This product (including the partitioning agents) is not defined as a controlled
product by the Canadian WHMIS legislation.
WHMIS Classification None.
SARA 311/312 Classification Immediate (acute)

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Quick-FDS [15822-53097-01000-019543] - 2011-04-26 - 14:44:58


MATERIAL SAFETY DATA SHEET

SUNIGUM® P95
MSDS No : SNGP95 Issue No : 4.00 Page : 4

16. Other information

Further information This material is a high molecular weight polymer


Reasons for revision *: modifications since the previous version.

Revised date 21/4/11 Supersedes 27/1/10 Printed : 21/04/11

The information provided above is intended as guidance relating to the safe handling, use, processing, storage,
transportation, disposal and release of the material listed. Nothing contained herein is to be considered as an express
or implied warranty or performance or quality specification. The information relates only to the specific material
designated and may not apply for such material when used in combination with any other materials or in any process,
except as otherwise specified herein. The information contained herein is believed to be true and correct as of the
date that this Material Safety Data Sheet was issued. The material described herein is produced for commercial and
industrial use and unless otherwise specifically designated by the manufacturer in writing have not received any
specific regulatory approvals including, without limitation, approvals for food contact or medical/surgical applications,
such as medical devices.

End of document
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Quick-FDS [15822-53097-01000-019543] - 2011-04-26 - 14:44:58

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