AIEEE -2011 MODEL GRAND TEST

This paper was prepared by Senior faculty members of ICON, NEON Programmes,
SRI CHAITANYA EDUCATIONAL INSTITUTIONS, Vijayawada.
INSTRUCTIONS 3) Lewis acid 4) Lewis base 1) 7 × 10-7 × (188)-1

This Grand Test Paper contains 90 ques- 9. Which of the following statements is not cor- 2) 7 × 10-7 × 188
tions, 30 each in Chemistry, Physics and rect? 3) 14 × 10–7 × (188)-1 4) 14 × 10–6 ×188 2) 150 ml of 0.1 M H2C2O4
Mathematics. 1) Zeolites are mixed oxides of Fe and Al 20. In a cubic close packed structure the lattice 3) 50 ml of 0.1 M H2C2O4

Chose the best option, out of 4 options given 2) Beryl is a cyclic silicate points are occupied by atoms of x, 25% of 4) 50 ml of 0.2 M H2C2O4
under each question and mark separately in 3) Caisson sickness is due to dissolved N2 in the tetrahedral voids by atoms of y and 27. Reductive ozonolysis of a Hydrocarbon
Key-Sheet. blood 50% of octahedral voids by atoms of z. The C4H6 gives one mole of each formalde-

Maximum time allowed for answering and 4) O3, NO and PAN are components of pho- composition is hyde, carbon dioxide and acetaldehyde.
marking is 3 hrs. tochemical smog. 1) x2yz 2) xyz 3) x2yz2 4) xy2z The hydrocarbon is

Question numbers 1, 2, 5, 11, 12, 24, 36, 38, 10. ∆G° for the reaction x+y z is-4.606 21. A carbohydrate, galactose is present in 1) CH3 - CH2 - C ≡ CH 2) CH3 - C ≡ C - CH3
40, 56, 58, 60, 65, 68, 70, 75, 78 and 82 car- K.cal, the value of equilibrium constant of 1) Terpenes 2) Glycerophosphatides 3) CH2 = C = CH -CH3 4) CH2 = CH-CH = CH2
ries each 8 marks. An incorrect attempt car- the reaction at 227°C is 3) Glycolipids 4) Phospho inositides 28. For a certain reaction, 10% of the reactant
ries –2 marks each. 1) 0.01 2) 2 3) 10 4) 100 decomposes in one hour. 20% in two hours
HO Red hot HNO + Con. H SO

All other questions carries each 4 marks. An 22. CaC2 ⎯→
2
A ⎯→ B ⎯⎯→
3 2 4
C and 30% in 3 hours. The unit of the rate
11. In the following complex Ions, square pla- Fe tube 100° C
incorrect attempt carries –1 mark. nar structures are Compound C is constant will be

Maximum number of marks in each subject A) [Cr(NH3)6 ]+3 B) [Zn (NH3)4]+2 1) 2, 4, 6-Trinitro toluene 1) sec-1 2) mole-1.lit.sec-1
is 144 and a Grand Total of 432 marks. 2) Meta dinitro benzene 3) mole lit-1 sec-1 4) mole. sec-1
C) [Ni(CO)4] D) [Cu(NH3)4 ]+2
CHEMISTRY E) [Ni (CN)4]-2 F) [ Ag(NH3)2 ] +1 3) 1, 3, 5-Trinitro benzene 29. Some statements about Ellingham diagram
4) Dinitro toluene are given below
1. One mole of a gas confined in a two lit flask 1) A, B and E 2) D & E
exerts a pressure of 11 atm. at 27°C. If the 23. Which of the following reaction does not A) Increases in the slope of the line on +ve
3) B, C, D, E 4) A, B, C, D
value of ‘b’ is 0.05 L mol-1, the value of ‘a’ is yield amine? side indicates are phase transformation
12. 0.1 molal aqueous solution of sodium bro-
1) 6.46 atm. L2 mol-2 2) 6.46 L-2 atm.mol2 mide freezes at -0.335°C at one atm pres- 1) C2 H5Br + NH3 → B) Metal oxide decomposes on its own at the
3) 12.92 atm.L2 mol-2 4) 12.92 L-2 atm.mol2 2) CH3CH = N - OH + (H) ⎯→
Na/ ErOH temperature when ∆G° becomes +ve
sure. The value of Kf is 1.86°C mol-1. The
2. Dipolemoment of ‘Y’ is greater than ‘X’, if ‘X’ percentage dissociation of the salt in solu- H+ C) Oxide of the upper layer can be reduced
3) CH3CN + H2O ⎯→ by the element whose oxidation is repre-
and ‘Y’ are tion is
LiAlH4 sented by the lower line
1) X = CCl4 and Y = CH4 1) 58 2) 80 3) 90 4) 98 4) CH3CONH2 + 4(H) ⎯→
2) X = NF3 and Y = NH3 24. In the following arrangements incorrect The correct statements are
13. Penicillins may be represented by the for-
3) X = H2O and Y = H2S mula C9H11N2O4 S - R. What is the name sequence is 1) Only A 2) A & B only
4) X = HF and Y = HBr assigned, If R is -CH2 OH 1) Bond energy: Cl2 > Br2 > F2 > l2 3) B & C only 4) A,B & C
3. Among the following strongest base is 2) Reducing nature: H3PO4 > H3PO3 > H3PO2 30. Oxidation of toluene to benzaldehyde by
1) Penicillin -K 2) Penicillin -F
3) Oxidising power: CO2 < SiO2 < SnO2 < PbO2 chromyl chloride is called as
1) C6H5NH2 2) m-NO2C6H4NH2 3) Penicillin -G 4) Penicillin -X
4) Basic nature: NH3 > PH3 > As H3 > SbH3 1) Etard’s reaction
3) p - NO2C6H4NH2 4) C6H5CH2NH2 14. Identify the wrong statement in the following:
25. The spin multiplicity for the orbital electron 2) Fittig reaction
4. Arrange the following resonating structures 1) The colour of tripositive lanthanide ions
3) Rosenmud’s reaction
of formic acid in order of decreasing stability with 4f n and 4f14 - n configurations is similar is 2S +1 where ‘S’ is total electrons spin.
−
O 4) Gattermann - Koch reaction
O O 2) Basic nature increases from La (OH)3 to The spin multiplicity for stage (i) (ii) and (iii)
⏐⏐ ⏐⏐ ⊕ are respectively PHYSICS
H - C - OH ←→ H - C - Lu(OH)3
- OH
I II 3) Lanthanides are obtained by the reduction 1) 1, 1, 1 2) 1, 2, 3 3) 1, 1, 3 4) 1, 3, 1
31. A solid shell looses half its weight in water.
−
O⊕
O
O of anhydrous halides with Na or Mg metals (ii) (iii) Relative density of shell is 5. What fraction
⏐ ⏐ 4) Lanthanides liberate H 2 gas form hot of its volume is hallow?
←→ H- C - OH ←→ H - C -OH
⊕ −
O water. 1) 3/5 2) 2/5 3) 1/5 4) 4/5
III IV 15. One mole of nitrogen is mixed with three 32. A particle is projected from ground with
1) II > I > III > IV 2) I > II > III > IV moles of hydrogen in a closed 3 litres ves- speed u at a angle θ with the horizontal.
3) III > II > IV > I 4) IV > III > I > II sel. 20% of nitrogen is converted in to NH3. Radius of curvature
5. Number of optical stereoisomers present for 1 3
The KC for the reaction ⎯ N2 + ⎯ H 2 NH3 26. KMnO4 reacts with oxalic acid according to 1) is maximum at the heightest point
butane -2, 3 -diol is 2 2
is the equation 2) is minimum at the point of projection
1) 1 2) 2 3) 3 4) 4
1) 0.20 lit mole–1 2) 0.36 lit mole–1 2MnO4–1+5 C2O4–2 +16 H+→2Mn+210CO2+8 H2O 3) is same at all the points
6. Some statements are given regarding formal
3) 0.46 lit mole–1 4) 0.60 lit mole–1 20 ml of 0.1M KMnO4 is equivalent to u2 cos2 θ u2
charge 4) varies from ⎯ to ⎯
16. Identify the wrong statement 1) 150 ml of 0.2 M H2C2O4 g g cos θ
A) In O3 molecule, formal charge of oxygen
1) HCl decreases the degree of dissociation
atoms are +1, -1, 0
of H2S
B) The lowest energy structure is the one with ´’ü¿®˝ ü∑ÁJ≤ƒ Ö¢Á’Ø˛q -´-Jq-öÃ
the smallest formal charges on the atoms
2) For a polyprotic acid, order of dissociation
constants is : Ka1 > Ka2 > Ka3
éÌúÁj-Èé-Ø√™¸™E ´’ü¿®˝ ü∑ÁJ≤ƒ Ö¢Á’Ø˛q ߪ‚E-´-JqöÃ
C) Formal charge of an atom always same in
3) At 0°C, the ionic product of water,
ü¿÷®Ω-N-ü∆u -N-üµ∆-†ç-™ °æ-©’ éÓ®Ω’q™x v°æ¢Ë-¨»-EéÀ ´’£œ«∞«
any structure of a molecule Ŷµºu-®Ω’n© †’ç* ü¿®Ωë«-Ææ’h©’ éÓ®Ω’-ûÓçC.
Kw = 10-14 mol2 L-2
¢Á’iÆæ÷-®˝-™E Ç™¸ ÉçúÕߪ÷ ÉØ˛-Æœd-ô÷uö¸ Ç°∂ˇ Æ‘pî˝ éÓ®Ω’q©’: È®çúË∞¡x °‘@, ´‚úË∞¡x úÕvU, -à-ú≈-C °‘@
The correct statements are
ÉØ˛Æ- ô-dœ ÷uö¸ Ç°∂ˇ Æ‘pî˝ Åçú˛ £œ«ßª’J- çí˚
4) The acid used for making acid buffer
1) A only 2) B and C only úÕ§Òx´÷, àú≈C úÕ§Òx´÷ éÓ®Ω’q©’, Ç®Ω’-ØÁ-©© 鬩-°æ-J-
should have the pH range of pKa+1 to Åçú˛ £œ«ßª’-Jçí˚ °æ©’ éÓ®Ω’q™x v°æ¢Ë-¨»-EéÀ ü¿®Ω-ë«-Ææ’h©’
3) Only B 4) A and B only N’A Ö†o ÆæJd-°∂œ-Èéö¸ éÓ®Ω’q©’.
pKa-1
Å®Ω|ûª: °‘-@ éÓ®Ω’q-©èπ◊ úÕvU §ƒÂÆj Öçú≈L. úÕvU °∂æL-û√©
éÓ®Ω’-ûÓçC. Ñ ÆæçÆæn ߪ‚E-´-Jqöà ǰ∂ˇ ¢Á’iÆæ÷-®˝èπ◊
7. Which of the following statements are not
17. Equivalent conductance of 1M propanoic ņ’•ç-üµ¿çí¬ ÖçC.
true?
acid is 10 ohm-1 cm2.eq-1 and that at infi- éÓ®Ω’q-© -N-´®√-©’: HáÆˇÑúŒ (£œ«ßª’-Jçí˚ Éç°-®·-®˝- éÓÆæç áü¿’-®Ω’-îª÷-Ææ’h-†o-¢√®Ω’ èπÿú≈ ü¿®Ω-ë«Ææ’h îËߪ’-´îª’a.
A) Both Be and Al become passive by nite dilution 200 ohm-1 cm2 eq-1. The pH of ¢Á’çö¸), °‘@ úÕ§Òx´÷ ÉØ˛ éÀxE-éπ™¸ LçTy-Æœdé˙q °∂æ®˝ Æ‘pî˝ ü¿®Ω-ë«Ææ’h: The Registrar, Directorate of Distance
conc. HNO3 Education, Mother Teresa Women's University
the acid solution is ™«çÍíyñ¸ §ƒü∑∆-©@, Æ‘pî˝ ÂÆjØ˛q Åçú˛ õ„é¬o-©@, °‘@
B) The composition of lime and silica in port- 1) 1.3 2) 3.3 3) 6.8 4) 7 úÕ§Òx´÷ ÉØ˛ †÷u®Ó–ÇúÕ-ߪ÷-©@, áçáÆ‘q (ÇúÕ-ߪ÷-©@, Ê°®Ω’† éÌúÁj-Èé-Ø√-™¸™ îÁ©’x-¶«-ô-ßË’u™« BÆœ† úŒúŒ °æç°œ
land cement are 61.5% & 22.5% ü¿®Ω-ë«-Ææ’h §ÚÆæ’d ü∆y®√ §Òçü¿-´îª’a.
18. Gold number of few colloids are given
°∂‘V© N´-®√©’: áçHà, áçÆ‘à, áçà, áçáÆ‘q, âöÃ
Æ‘pî˝ ™«çÍíyñ¸ §ƒü∑∆-©@, áçáÆˇ ÑúŒ (£œ«ßª’-Jçí˚
C) Methyl orange is used to distinguish
below. Éç°-®·-®˝-¢Á’çö¸), °‘£«-î˝úŒ (ÇúÕ-ߪ÷©@, Æ‘pî˝
Na2CO3 and NaHCO3 ™«çÍíyñ¸ §ƒü∑∆-©@), §ÚÆˇd ú≈éÌd-®Ω™ ¸ °∂™ -≠œ°ˇ éÓ®Ω’q-©èπ◊ ®Ω÷.300. °‘@ éÓ®Ω’q-©èπ◊ ®Ω÷.150. °‘@
Gelatin = 0.005 starch = 25
D) Except Li, remaining alkali elements form ûªCûª®√©’ ÖØ√o®·. °æ‹-Jh N´-®√-©èπ◊ ¢Á¶¸-ÂÆjö¸ úÕ§Òx´÷ éÓ®Ω’q-©èπ◊ ®Ω÷.125. Åçúø®˝ ví¬úø’u-ßË’ö¸/
egg albumin = 0.08 gum arabic = 0.10
carbides directly îª÷úø´îª’a. úÕ§Òx´÷/ ÆæJd-°∂œ-Èéö¸ éÓ®Ω’q-©èπ◊ ®Ω÷.110.
1) Both A & C 2) Both A & B Which is best protective colloid
-*®Ω’-Ø√-´÷:All India Institute of Speech and -N-´®√-©èπ◊ -¢Á-¶¸ÂÆj-ö¸ -îª÷-úø-´-a.
3) Both C & D 4) A, B & C 1) gelatin 2) starch
Hearing, Manasagangothri, Mysore-570 006. ü¿®Ω-ë«-Ææ’h© Æ‘yéπ-®Ω-ùèπ◊ *´J ûË-D: ¢Ë’ 31.
8. Al(OH) + OH-⎯→ Al(OH)-. Here Al(OH)
3 4 3
3) egg albumin 4) gum arabic Karnataka. ¢Á¶¸-ÂÆjö¸
acts as 19. How many grams of AgBr will dissolve in 20 lit ¢Á¶¸-ÂÆjö¸: www.aiishmysore.in www.motherteresawomenuniv.ac.in
1) Lowry acid 2) Lowry base of water at 25°C (Ksp for AgBr = 4.9×10-13)