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Sampel

Simplo Duplo Triplo 1


Berat 0.0533 0.053 0.0571 2
Volume Titrasi 14.5 14.5 15.8 3
N Na2S2O3 0.1031 0.1025 0.1013 4
N Rata2 0.1023 5
6
Blanko 46.7 7
8
9
10
11
12
13
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16
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18
19
20
Rata-Rata Bilangan

Cohran Test
C = D2max/Ʃ Di2 Jika :
C = Cohran’s statistic test C < nilai tabel : pasangan data tidak outlier
Dmax = largest difference between duplicates C > nilai tabel: pasangan data outlier, keduanya
Di = difference of each pair of duplicates untuk m yang sama
m = number of samples measured in duplicate

Sampel A B D = A-B S = A+B D2=(A-B)2


1 8.796 8.753 0.043 17.549 0.002
2 8.890 8.796 0.094 17.686 0.009
3 9.273 9.280 -0.007 18.554 0.000
4 8.938 9.254 -0.316 18.192 0.100
5 9.846 9.471 0.375 19.318 0.141
6 10.190 10.070 0.119 20.260 0.014
7 10.624 10.262 0.362 20.886 0.131
8 9.624 9.953 -0.329 19.577 0.108
9 10.120 9.986 0.134 20.106 0.018
10 10.379 10.323 0.055 20.702 0.003
∑ Jumlah 10 0.530 192.828 0.526
Rata2 () 9.641 0.096 19.28
SD 0.609
RSD
(SD/rata2) 0.063

D2max 0.002 Maka, C = 0.004


∑Di2 0.526

Table Cohran
m 7 8 9 10 11 12 13 14 15 16 17 18 19 20
95% 0.727 0.68 0.638 0.602 0.57 0.541 0.515 0.492 0.471 0.452 0.434 0.418 0.403 0.389

Mean Square Between (MSB)


∑(S-)2 13.5789 Maka, MSB = 0.7544
2(n-1) 18

Mean Square Within (MSW)


∑(D-)2 0.517 Maka, MSW = 0.0258
2n 20

S2within = √MSW = San = 0.1608


S2 sampling = (MSB-MSW)/2 = 0.3643

X 9.641
CV (RSD) 0.063
tho 0.6093
San/tho 0.2639

Dari perhitungan diatas didapatkan :


Cohran = 0.004 PASS
Nilai Cohran
jika n=10, 0.602

Value San/tho 0.2639 PASS


San/tho teoritis 0.5
Berat Sampel V Titrasi IV
1.0363 38.9 8.796
0.9980 39.2 8.753
1.0396 38.8 8.890
1.0363 38.9 8.796
1.0239 38.6 9.273
1.0095 38.7 9.280
1.0340 38.8 8.938
1.0260 38.6 9.254
1.0286 38.1 9.846
1.0426 38.3 9.471
1.0445 38.5 10.190
1.0440 38.6 10.070
1.0018 38.5 10.624
1.0245 38.6 10.262
1.0250 39.1 9.624
1.0563 38.6 9.953
1.0389 38.6 10.120
1.0398 38.7 9.986
1.0630 38.2 10.379
1.0184 38.6 10.323
Rata-Rata Bilangan Iodin (g/mg O2) 9.641

(S-)2 (D-)2
3.006 0.003
2.550 0.000
0.532 0.011
1.189 0.170
0.001 0.078
0.954 0.001
2.569 0.071
0.086 0.181
0.677 0.001
2.014 0.002
13.579 0.517