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Vicki P. McConnell
Fig. 45.1 Composite structural truss (a) aboard Hubble Space Telescope (b)aligns primary and secondary
mirrors. (Sources:NASA, Perkin Elmer.)
moisture absorption than epoxies and greater Coronograph Spectrometer (UVCS), designed
toughness than either epoxies or BMIs. Lastly, as an occulted telescope to focus on solar
HST’s high-resolution spectrograph optical winds (McConnell, 1993~).As with HST, opti-
bench was manufactured by Hercules cal mechanisms require accurate and
Aerospace Co. (Magna, UT) to specifications repeatable positioning, so UVCS’s design cen-
from Ball Aerospace Systems Group (Boulder, tralized upon a three-segment carbon
CO). Carbon fiber/epoxy offers CTE equal to fiber/epoxy structure. Ball Aerospace Systems
quartz and maintains 2 m (6.5 ft) of optical sur- Group and COI built the seven-sided truss of
faces to within 0.0254 mm (0.001 in). flat panels that result in cylindrical shape.
Launched in December 1995, the Solar and Some 80 separate stability requirements had to
Heliospheric Observatory (SOHO) was be met, along with strict mass requirements
designed to be pointed directly at the Sun to (the structure weighs 21.7 kg (48 lb) but sup-
study the interactions between the Sun and ports 91.6 kg (202 lb) of instrumentation), and
Earth’s environment. The largest moving the ability to survive launch loads of 18G.
instrument aboard SOHO is the Ultraviolet High-modulus pitch-based carbon fiber /epoxy
970 Scientific applications of composites
prepreg met weight, mass and optical stabil- to the central cylinder, large curved and coni-
ity parameters with no outgassing or cal shell structure, mirror support sleeves, and
microcracking. Especially thin prepreg solar array panels. Eastman Kodak built the
(0.063 mm (0.0025 in) cured ply thickness) 2643 long optical bench that forms the main
also enhanced the thermal conductivity of the structural element, with carbon fiber skins
fiber, an added stability factor (Kilpatrick, over honeycomb core.
1992).
LDEF composite specimen testbed
AXAF orbiting observatory Proof positive of the hostile effects of space
Slated for launch from the Space Shuttle in startled cosmonauts on the Mir space station
August 1998, the Advanced X-Ray in 1992 when they found not a shred
Astrophysics Facility spacecraft will bridge remained of the Soviet flag after a year in
the gap between the two Great Observatories orbit on the station's exterior. Further proof
currently in orbit: Hubble Space Telescope and comes in data retrieved from NASA's Long
Compton Gamma Ray Observatory. Duration Exposure Facility (or LDEF), a 12-
TRW (Redondo Beach, CA) is prime con- sided circular spacecraft launched into low
tractor for AXAF and the spacecraft will Earth orbit (LEO) from the Challenger shuttle
contain four sets of unique cylindrical, grazing in April 1984 and retrieved in 1990 (Fig. 45.2).
incidence mirrors. These are mounted concen- By 1993, postflight analysis of the 86 experi-
trically in a nested array. Carbon fiber/epoxy ment trays containing more than 10 000
is used in equipment compartments attached different material specimens has been carried
out by a team of international scientists. (Fig. 45.3). Atomic oxygen is identified as the
Research on LDEF's composites specimens most detrimental factor to polymer-matrix
has provided a benchmark for next-genera- composites, especially on uncoated surfaces
tion space materials, such as those that make (George, 1992). Erosion has been observed to
their way onto the international space station 0.127 mm (0.005in) (about one ply of laminate)
(Stein, 1993). on leading edge components made from car-
The six-year duration of LDEF's exposure bon fiber with epoxy, polyimide and
to the LEO space environment provided the polysulfone matrices.
longest term flight data ever retrieved for Micrometeroid damage was not cata-
analysis at that time. Post-retrieval sympo- strophic on any LDEF specimens, but can
siums have shared analytical conclusions, compromise surfaces and lead to substrate
and NASA selected M/Vision software from erosion (Blair, 1992) (Fig. 45.4).Another con-
PDA Engineering (Costa Mesa, CA) as one clusion drawn based on post-flight analysis
format for the sizeable LDEF Materials was that predicting erosion rates and formu-
Database which contained research informa- lating material with enhanced A 0 resistance
tion on about 35% of the LDEF materials by should key on fiber resistance as the dominant
the end of 1994. factor. A prediction model for A 0 erosion
An important conclusion drawn from LDEF yield in polymer materials has been developed
specimen analysis is that environmental (Tennyson, 1993), based on the repeatable
effects are dependent upon the location of atomic composition of the polymer.
composite hardware on a spacecraft - leading An LDEF follow-on spacecraft, the
or trailing edge, shielded or unshielded from European Retrievable Carrier (EURECA) was
degradation factors (only metal matrix com- retrieved by the shuttle Endeavor in June, 1993
posites with aluminum matrices showed no after 11 months in a 370 km (230 mile) orbit.
location-dependent degradation; magnesium- EURECA's mission focused on materials and
matrix composites oxidized on sample edges) fluids in low microgravity and LEO exposure
Fig. 45.3 LDEF orientation in orbit. (Reprinted with permission of Bland A. Stein, NASA Langley Research
Center.)
972 Scientific applications of composites
(cryogenic to 2760°C (5000°F)). R&D efforts necting rods and other engine parts. Thin-
resulted in innovative materials science gauge titanium aluminide foil has been tested
among five composite categories (Mcconnell, in heart valve assemblies and pacemaker cases.
1990), with more than 2000 airframe and Adaptation of computational fluid dynamics
scramjet propulsion components, structure, (CFD) - the study of high-speed laminar air
and systems built (Table 45.1). flow developed to maximize NASP's body con-
Until October 1994, NASP represented the figuration - has proven useful in analyzing
hypersonic flagship program of the USA. At aircraft and automotive aerodynamics, as well
that time, the initial program goals transitioned as blood flow in artificial hearts. Dr. Steve
into the hypersonic system technology pro- Charles of the Center for Retina Vitreous
gram (HYSTP), funded jointly by the US Air Surgery (Memphis, TN) began work with the
Force and NASA and which will focus on Rockwell Science Center (Thousand Oaks, CA)
development of hypersonic scramjet propul- in February 1992 to apply NASP-developed
sion. Yet resulting scientific R&D from the CFD to modeling fluid flow inside the eye. CFD
NASA program generated considerable tech- will help analyze the role played by rapid eye
nology transfer to a broad range of commercial motion (up to 600"/s) in retinal detachment,
applications, including oilfield pipe, auto and possibly enhance the precision of surgical
engines and hip joint implants. One of the tita- procedures. Dr. Charles performs some 15 000
nium MMCs developed did not exist before the vitreous retinal surgeries annually and ulti-
NASP program and is 100 times more resistant mately expects to use CFD to design a new
to corrosion than standard aircraft titanium. suite of surgical tools, 'applying hard science
An aluminum/beryllium alloy tested in NASP rather than guesswork to the entire tool set'.
heat exchanger prototypes has since found
application in computer actuator arms, provid- 45.2.3 DELTA CLIPPER EXPEFUMENTAL
ing a 20% increase in data access speed. Big LAUNCH VEHICLE (DC-X SSTO)
Three automakers have studied NASP-devel-
oped titanium MMCs and alloys to cut weight Under a $60 million contract from the Ballistic
by 50% in valves, piston rings, cam shafts, con- Missile Defense Organization, McDonnell
Douglas Aerospace (Huntington Beach, CA) -73°C (-100"F), the aeroshell incorporated
developed its Delta Clipper experimental pro- built-in longitudinal longerons to handle
totype (DC-X) to prove the practicality, engine/truss, parachute deployment and
reliability, operatability and cost efficiency of a landing gear loads.
reusable single-stage-to-orbit (SSTO) flight Glass fiber/epoxy was used in the 762 mm
vehicle. Comparative figures suggest that (2.5 ft) tall nose cone since it required signal
reusable rockets like a full-scale DC-X could transparency for antennae. McDonnell
reduce commercial/military payload delivery Douglas decided that carbon fiber/epoxy
costs to under $500/lb - an attractive alterna- skins over syntactic foam in the DC-X base
tive to the $10 OOO/lb for the Space Shuttle heat shield provided the best material system
(1993 figures). for meeting weight, price, and scheduling
The one-third scale DC-X prototype had demands. The shield (about 396 mm (13 ft) on
completed five suborbital flight tests before a side) featured a unique 'super circle' sec-
being grounded by an on-board explosion that tional design, joined with titanium fasteners.
damaged the composite aeroshell. Despite this Both the prime and subcontractor worked to
accident, DC-X landed safely and the shell the philosophy of building real structures to
was repairable. Data collected in the first flight collect and prove data before moving on to
test series formed the advanced technology more expensive program goals, something of a
backbone for an upgraded DC-XA vehicle, first in such R&D efforts.
developed jointly by McDonnell Douglas The durability of composite aeroshell mate-
(now the Boeing Co.) and NASA (with some rials and overall system design was proven in
$43 million in NASA funding) in 1995. The the June 1994 explosion; according to the pro-
DCX-A was renamed the Clipper Graham in gram director, the 1220by 4570 mm (4 by 15 ft)
1996, and completed several milestone flights vertical tear would probably have demolished
that year: altitude of 10 300 ft with 550 ft lat- other launch vehicles. McDonnell Douglas
eral movement, and a second flight 26 hours developed and fabricated a robust carbon
after the first to demonstrate rapid turn- fiber/epoxy liquid hydrogen tank for DCX-A
around. in 1996,8 ft in diameter and 16 ft tall, but 33%
Rapid prototyping played an essential role lighter than previous aluminium alloy tanks.
in the cost effectiveness of building the DC-X
prototype, including construction of compos-
45.2.4 GROUND-BASED SCIENTIFIC
ite aeroshell, nose cone, and base heat shield
INSTRUMENTS
components (McConnell, 1993~). The aeroshell
and nose cones were fabricated by Scaled
Wind tunnel blade
Composites (Mojave, CA); five aerodynamic
composite flaps on the carbon fiber/epoxy While CFD places air-flow analysis within the
aeroshell provided the ability to ascend nose domain of computer mathematics, there is
first and return to Earth for a 'tail sitter' land- nothing quite like proving an aerodynamic
ing. Composites accommodated the program's concept in a wind tunnel. At NASA's Ames
ambitious scheduling with rapid aeroshell Research Center (Moffett Field, CA), different-
construction (nine months) and by allowing sized wind tunnels can accommodate small
continuing modifications without huge cost models of experimental structures and shapes
overruns. Lay-up of woven fabric composite as well as full-scale vehicles (such as tractor
skins over foam core resulted in aeroshell wall trailers and an F/A-18 aircraft). Compressors
thickness range of 12.7-38.1 mm (0.5-1.5 in). generate high-speed air flow with rotating
Besides enduring external temperatures to blades, usually constructed of aluminum or
149°C (300°F) and internal temperatures to laminated wood. In the Ames tunnel with a
976 Scientific applications of composites
3352 mm (11ft) test section, composite design sandwich structure of syntactic foam core
and prototyping work supported by Dr. Clem covered with hybrid glass and carbon
Hiel, a former NASA senior design engineer, fiber/epoxy skins laid up at 0/+30/-30 ori-
and his associates has examined the potential entation. Though syntactic foam can typically
of using composite blades in the compressor, be four to eight times higher in weight than
which is capable of speeds to 711 rev/min. traditional foams, mechanical properties are
These blades would offer the advantages of several orders of magnitude higher. This is
improved damage tolerance, longer fatigue due to the energy-absorbing capacity of glass
life, higher damping and improved safety in microspheres inside the foam core, which
the event of catastrophic failure. also localize damage when they are crushed.
Design of a prototype composite blade in In addition, local regions of skin failure are
1995 (Fig. 45.7) (which is 1067 mm (42 in) clearly visible to the unaided eye by an exter-
long, 406 mm (16 in) wide at the root, taper- nal imprint. Carbon fiber skins served as the
ing to 241 mm (9.5 in) at the tip) featured a structural backbone by providing high spe-
cific strength and stiffness, while the foam
core supported skins against impact. Glass
fiber skins acted as sacrificial protective coat-
ing and visual enhancement of impact
damage during residual strength assessment.
Dr. Hiel reports that the prototype composite
blade tested to seven times the expected com-
bination of centrifugal and air loads, and was
clearly capable of carrying higher loads when
the test fixture failed. Manufacturing the
blade through resin transfer molding (RTM)
could result in a blade that would compete
with aluminum in acquisition costs while
reducing weight significantly (Hiel, 1993).
Particle accelerators
To study the exotic mixture of protons, neu-
trons, nuclei and the smallest particles of
matter - quarks - inside the atom, physicists
have turned to complex scientific instruments
that generate enough voltage and acceleration
to create high-energy particle collision.
Analysis of the collisions in this 'quark soup'
could reveal mysteries among the building
blocks of matter.
At Newport News, VA, the Southeastern
University Research Association oversees
operation of the Continuous Electron Beam
Fig. 45.7 Wind tunnel blade made of carbon Accelerator Facility (CEBAF). Here a continu-
fiber/epoxy skins over syntactic foam core (left) ous electron beam with up to 4 billion eV of
weighs 50% less than aluminum counterpart. energy is steered by superconducting magnets
(Source:NASA Ames Research Center.) through up to four orbits of an underground
978 Scientific applications of composites
ground tunnel in Ellis County, TX. The SSC posite prototype support post tubes were fab-
design was based on a dual ring of 10 000 elec- ricated to test various designs to balance
tromagnets accelerating needle-thin proton multiple performance parameters with cost
beams at 20 trillion eV cryogenic temperature constraints (Sondericker 1991; Nicol 1992,
and ultrahigh vacuum. After a decade of work 1993; Hiller, 1991, 1992, 1993). Material and
and investment of $2 billion, however, process systems examined included continu-
Congress cancelled the program. While much ous carbon fiber/epoxy laminates,
was made in the national press about the injection-molded chopped glass fiber/PEI,
wasted effort (and the huge hole in the and RTMd glass fiber/bismaleimide.
ground), SSC composites research has yielded Machine-woven near-net shape preforms were
unprecedented results that were directly also considered, along with RTMd phenolic
applicable to other ongoing high-energy triazine (McConnell, 1991a) (Fig.45.9). In other
physics applications (such as the Relativistic components, such as coil spacers and end
Heavy Ion Collider at Brookhaven National parts, the predominant prototyping method
Laboratory in Upton, NY, the Tevatron was machining glass fiber/epoxy, though
Collider at Fermi National Accelerator options considered included highly
Laboratory in Batavia, IL, the Tokomak crosslinked BMI doughs and other polyimide
Physics Experiment in Princeton, NJ, and the resins with chopped glass, fabricated by low-
European International Thermonuclear pressure techniques such as structural RTM.
Experimental Reactor). 'Magnets were built for SSC that were never
For SSC dipole magnets (each nearly 18 288 seen before in the world', recounts John
mm (60 ft) long and weighing 11 340 kg (12.5 Morena, who served as the primary compos-
tons)) and smaller quadrupole magnets, com- ites materials and processes advisor on the
Fig. 45.9 Glass fiber/epoxy end saddles were fabricated and tested for Superconducting Supercollider
magnets. (Source:Brookhaven National Laboratory.)
Applications 979
project. ’There were many “lessons learned” as Under the National Maglev Initiative in
a result of the years of composite materials 1992, four maglev teams developed concept
development and applications,’ he adds. ’This definitions with funding from the Intermodal
initial work has provided the composites com- Surface Transportation Efficiency Act (ISTEA).
munity with the ability to predict the All concepts were geared toward transport
performance of advanced composites and vehicles capable of 482 km/h (300 mph)
other polymer materials in cryogenic and high speeds and incorporated some utilization of
energy physics applications. These original composites. Among team members in the
materials are now used in MRI, superconduct- early ‘90s were aerospace companies Beech
ing magnet energy storage, magnetic Aircraft and Grumman Corp. Drawing on its
levitation systems, fusion, power transmission extensive aerospace design/fabrication exper-
and space applications.’ Others involved in tise, Grumman Corp. - Aerostructures Div.
magnet prototyping were General Dynamics, (Bethpage, NY), began development of a 2/3-
Westinghouse Electric, Babcock & Wilcox, as scale electromagnetic system, based on
well as the Fermi and Brookhaven laboratories superconducting iron core magnets spaced
and the SSC on-site laboratory. Morena notes a50 mm (2 in) from guideway rails. According
particular materials characterization study to Richard Gran, Director of Advanced
conducted as part of Supercollider R&D: sub- Concepts at Grumman, ‘the advantage of this
jecting thermoset and thermoplastic resin design as compared to a repulsive magnet sys-
systems to high proton irradiation at cryogenic
tem is that no secondary suspension system is
temperatures (lo9rads at 4.2K).One intriguing required; passenger compartment acceleration
result: undercuring some thermoset compos- is monitored (Shaw, 1993).Though Grumman
ites can increase their longevity in the cold intended to finish construction and testing of
irradiation environment without sacrificing its first magnet by April, 1994, funding issues
performance (Morena, 1994). precluded completion: The company merged
with Northrop Corp. (Los Angeles) and then
with Lockhead Martin by 1997, no maglev
45.2.5 MAGLEV TRANSPORT SYSTEMS OF THE
development existed within the newly framed
FUTURE
business entities.
One potential application of SSC research on Also intent upon prototyping a maglev sys-
superconducting magnets could be magnetic tem is Maglev 2000 of Florida Corp. (Stuart,
levitation (or maglev) of high-speed trains EL.) formed by SSC materials/processes con-
over elevated guideways. Maglev is consid- sultant and co-inventor John Morena with
ered by many to be the transportatiodfreight physicist Dr. John Danby and nuclear engi-
solution of the future. Composites offer a neer/rocket scientist Dr. James Powell. Danby
whole list of attributes in vehicle/guideway and Powell are considered the pioneers of USA
structure and in superconducting coils and maglev technology. Prior to publishing their
electromagnetic shielding: high strength and first papers on magnetic levitation (Powell,
stiffness with low weight, nonconductivity, 1996), Danby reports that concepts of electro-
nonpermeability, corrosion resistance, low dynamic levitation and propulsion had
thermal conductivity and high heat capability surfaced periodically but were not considered
at low temperature. Overall weight savings of practical. Early in his career, he worked on
carbon fiber/epoxy or phenolic vehicle floor building particle accelerators while Powell was
beams and shell structure (sandwich panels of involved in advanced reactors. ’Fixed field
honeycomb core with carbon fiber/epoxy magnets on a moving vehicle can induce cur-
skins) could better aluminum by 15%of body rents underneath or around the vehicle
weight (Cope, 1993). sufficient to levitate it,’ explains Danby. ’This
980 Scientific applications of composites
1991b. Progress report: composites in space- trains. Paper 66-WA/RR-5 read at ASME
craft. Adv. Comp., July/Aug: 26-34.1992a. Flight Winter Annual Meeting Nov. 27-Dec. 1,in New
vehicles of the future. Adv. Comp., Jan/Feb: York City.
28-34. 1992b. Tough promises from cyanate Shaw, P.1993. Overview of maglev vehicle struc-
esters. Adv. Comp., May/June: 28-37. 1993a. tural design philosophy, material selection, and
Composites ride the rails. Adv. Comp., manufacturing approach. Paper read at Maglev
March/April: 28-37. 199310. Surviving space: a 93 conference May 19-21, at Argonne National
program and materials quandary. Higk- Laboratory.
Performance Composites, Nov/Dec: 22-28. 1993c: Sondericker, J.H. 1991. Alternate concepts for struc-
Focus on design: telescope structure. Higk- turally supporting the cold mass of a
Performance Composites, Nov/Dec: 54-56. superconducting accelerator magnet. Proc.
Morena, John. 1994. Invaluable materials science IlSSC 3, New York, Plenum Press, pp. 175-189.
from Super Collider. High-Performance Stein, Bland A. 1993. LDEF materials overview.
Composites, Jan/ Feb: 12-1 3. Second Post-Retrieval Symposium, LDEF-69
Nicol, Thomas H. 1992. SSC 50mm collider dipole Months in Space, NASA Conference Publication
cryostat single tube support post conceptual 3194, (ed. Arlene S. Levine), Vol. 3, pp. 741-789.
design and analysis. Proc. IISSC 4, New York: Tennyson, R.C. and Manuelpillai, G. 1993. Analysis
Plenum Press, pp. 747-755.. of LDEF micrometeroid/debris data and dam-
Nicol, Thomas H. 1993. Single tube support post age to composite materials. Second
thermal analysis and test results. Paper read at Post-Retrieval Symposium, LDEF-69 Months in
IISSC 5, May 6-8, in San Francisco, CA. Space, NASA Conference Publication 3194, (ed.
Peterson, Ivars. 1992. Flash tracks-building an eye- Arlene S. Levine), Vol3, pp. 493-512.
piece for a particle accelerator. Science News 142,
July 4: 8-9.
Powell, James and Danby, Gordon. 1966. High
speed transport by magnetically suspended