MATERIAL SAFETY DATA SHEET

Product Name: R-2035

Revision Date: 17.10.2003 Page 1 of 7

CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME : R-2035

COMPANY IDENTIFICATION: ONDEO NALCO BRASIL LTDA.

ROD. ÍNDIO TIBIRIÇA 3201- BAIRRO DO RAFFO
SUZANO - S.P.

TELEPHONE: 4745.4700

EMERGENCY TELEPHONE NUMBER(S) :

ABIQUIM/PROQUÍMICA : 0800 118270 (TOLL FREE NATIONWIDE IN BRAZIL)

ONDEO NALCO EMERGÊNCIAS : 0800 161655 (TOLL FREE NATIONWIDE IN BRAZIL)

2 – COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL DESCRIPTION:

Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15
for the nature of the hazard(s).

Hazardous Substance(s) CAS # % (w/w)

Methanol 67-56-1 60.0 - 100.0

3 – HAZARDS IDENTIFICATION
WARNING Flammable.

Contains methanol. Irritating to eyes and skin. Methanol may cause central nervous system effects or
permanent vision damage if inhaled, swallowed or absorbed through the skin in large amounts. Do not get in
eyes, on skin, on clothing. Do not take internally. Wear suitable protective clothing. Keep container tightly
closed. Water in contact with the product will cause slippery floor conditions.

Empty product containers may contain residual product. Do not reuse container unless properly
reconditioned.

PRIMARY ROUTES OF EXPOSURE : Eye, Skin

EYE CONTACT : Can cause moderate irritation.

INGESTION : Not a likely route of exposure. Can cause blindness.

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 MATERIAL SAFETY DATA SHEET

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3 – HAZARDS IDENTIFICATION cont.

SKIN CONTACT : Methanol may be absorbed through the skin and cause central nervous system effects
which may result in permanent visual changes including blindness. Can cause moderate irritation.

INHALATION : Not a likely route of exposure. Repeated or prolonged exposure may irritate the respiratory
tract.

SYMPTOMS OF EXPOSURE ACUTE: Inhalation of high concentrations of organic solvents can cause
nausea, dizziness, vomiting, stupor or unconsciousness.
CHRONIC: Frequent or prolonged contact with product may defat and dry the skin, leading to discomfort
and dermatitis.

AGGRAVATION OF EXISTING CONDITIONS: Skin contact may aggravate an existing dermatitis condition.

4 – FIRST AID MEASURES

EYE CONTACT : Immediately flush eye with water for at least 15 minutes while holding eyelids open. If
symptoms develop, seek medical advice.

SKIN CONTACT : Immediately flush with plenty of water for at least 15 minutes. For a large splash, flood
body under a shower. If symptoms develop, seek medical advice.

INGESTION : Induce vomiting if the patient is fully conscious. If conscious, washout mouth and give water
to drink. Get immediate medical attention.

INHALATION : Remove to fresh air, treat symptomatically. Get medical attention.

NOTE TO PHYSICIAN : Based on the individual reactions of the patient, the physician's judgement should
be used to control symptoms and clinical condition.

CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water.

5 – FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA : Alcohol foam, Carbon dioxide, Dry powder, Other extinguishing agent suitable
for Class B fires, For large fires, use water spray or fog, thoroughly drenching the burning material. Water
mist may be used to cool closed containers.

FIRE AND EXPLOSION HAZARD: May evolve oxides of carbon (COx) under fire conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING: In case of fire, wear a full face positive-
pressure self contained breathing apparatus and protective suit.

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 MATERIAL SAFETY DATA SHEET

Product Name: R-2035

Revision Date: 17.10.2003 Page 3 of 7

6 – ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Restrict access to area as appropriate until clean-up operations are complete.
Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).
Stop or reduce any leaks if it is safe to do so. Ventilate spill area if possible. Ensure clean up is conducted
by trained personnel only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks,
etc.) readily available. Notify appropriate government occupational health and safety and environmental
authorities.

ENVIRONMENTAL PRECAUTIONS: Do not contaminate surface water.

METHODS FOR CLEANING UP: Dick to prevent further movement and contain with absorbent material,
such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into
recovery or salvage drums for disposal.

7- HANDLING AND STORAGE

HANDLING: Maintain emergency equipment (for fires, spills, leaks, etc.) readily available. Wear protective
equipment describe in Section 8 (Exposure Controls/Personal Protection) when handling the product

PRECAUTIONS FOR SAFETY HANDLING: When handling this product use, whenever possible, local
exhaust system in a well-ventilated area. Wear individual protective equipment describe in Section 8
(Exposure Controls/Personal Protection) when handling the product.

DIRECTIONS FOR SAFETY HANDLING: Avoid contact with eyes, skin and clothing. Do not take internally.
Handle the product in a ventilated area. Wear individual protective equipment describe in Section 8
(Exposure Controls/Personal Protection).

STORAGE CONDITIONS: Store separately Heat and sources of ignition including static discharges. Store
separately from incompatible materials. Store the containers tightly closed. Store in suitable labeled
containers. Keep the product in fresh and dry area and, if possible, in covered areas.

INCOMPATIBLE MATERIALS OR SUBSTANCES: Strong oxidizers.

UNSUITABLE CONSTRUCTION MATERIAL: Packing material for the product should be compatible with its
physical-chemical characteristics.

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 MATERIAL SAFETY DATA SHEET

Product Name: R-2035

Revision Date: 17.10.2003 Page 4 of 7

8 - EXPOSURE CONTROLS/PERSONAL PROTECTION

OCCUPATIONAL EXPOSURE LIMITS: Available exposure limits for the substance(s) are shown below.

ACGIH/TLV :Substance(s) Methanol TWA: 200 ppm , 262 mg/m3 (Skin)

STEL: 250 ppm , 328 mg/m3 (Skin)

OSHA/PEL :Substance(s) Methanol TWA: 200 ppm , 260 mg/m3 (Skin)

STEL: 250 ppm , 325 mg/m3 (Skin)

* A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route,
including mucous membranes and the eyes.

ENGINEERING MEASURES: General ventilation is recommended in the area where product is being
handled.

RESPIRATORY PROTECTION: If significant mists, vapors or aerosols are generated an approved

respirator is recommended. An organic vapor cartridge with dust/mist prefilter or supplied air may be used.
In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece
SCBA should be used. If respiratory protection is required, institute a complete respiratory protection
program including selection, fit testing, maintenance and inspection

HAND PROTECTION: Wear gloves when handling this product. Nitrile gloves, Rubber gloves, Butyl gloves,
Neoprene gloves, PVC gloves, Cloth gloves.

EYE PROTECTION: Wear chemical splash goggles.

SKIN PROTECTION: Wear impervious apron and boots.

HYGIENE RECOMMENDATIONS: If clothing is contaminated, remove clothing and thoroughly wash the
affected area. Launder contaminated clothing before reuse. Keep an eyewash fountain available. Keep a
safety shower available.

9 - PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE Liquid
APPEARANCE Clear Colorless
ODOR Slight, Alcoholic
SPECIFIC GRAVITY 0.79 @ 60 °F / 16 °C
DENSITY 6.6 lb/gal
SOLUBILITY IN WATER Complete
FREEZING POINT -97 °F / -72 °C
BOILING POINT 148 °F / 64 °C
VAPOR PRESSURE 97 mm Hg @ 60 °F / 16 °C

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 MATERIAL SAFETY DATA SHEET

Product Name: R-2035

Revision Date: 17.10.2003 Page 5 of 7

9 - PHYSICAL AND CHEMICAL PROPERTIES cont.

EVAPORATION RATE 5.9
VAPOR DENSITY 1.1 (Air = 1)
FLASH POINT : 58 °F / 14 °C ( Open Cup )
LOWER EXPLOSION LIMIT : 7.3 V%
UPPER EXPLOSION LIMIT : 36 V%
AUTOIGNITION TEMPERATURE : 867 °F / 464 °C ASTM D-2155-66

NOTE: These physical properties are typical values for this product.

10 - STABILITY AND REACTIVITY

STABILITY : Stable under normal conditions.

HAZARDOUS POLYMERIZATION : Hazardous polymerization will not occur.

CONDITIONS TO AVOID : Heat and sources of ignition including static discharges.

MATERIALS TO AVOID : Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid,
perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors.

HAZARDOUS DECOMPOSITION PRODUCTS: In the event of combustion COx may be formed. Do not
breathe smoke or fumes. Wear suitable protective equipment.

11 - TOXICOLOGICAL INFORMATION
The following results are for the product.

ACUTE ORAL TOXICITY :

Species LD50 Tested Substance
Rat 5.6 - 9 g/kg Product
Rating : Non-Hazardous

ACUTE DERMAL TOXICITY :

Species LD50 Tested Substance
Rabbit 15,800 mg/kg Product
Rating : Non-Hazardous

ACUTE INHALATION TOXICITY :

Species LC50 Tested Substance
Rat 145 mg/l (1 hrs) Product
Rating : Non-Hazardous

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 MATERIAL SAFETY DATA SHEET

Product Name: R-2035

Revision Date: 17.10.2003 Page 6 of 7

11 - TOXICOLOGICAL INFORMATION cont.

CARCINOGENICITY : None of the substances in this product are listed as carcinogens by the International
Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American
Conference of Governmental Industrial Hygienists (ACGIH).

HUMAN HAZARD CHARACTERIZATION : Based on our hazard characterization, the potential human
hazard is: High

12 - ECOLOGICAL INFORMATION
As any other chemical, it should be avoided its direct discharge into lakes, streams, ponds, tanks,
watercourses and its absorption by the soil.

ECOTOXICOLOGICAL EFFECTS : No toxicity studies have been conducted on this product.

ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION

Based on our hazard characterization, the potential environmental hazard is: High

13 - DISPOSAL CONSIDERATIONS
PRODUCT: The disposal of this product should follow the local, state and federal regulations. If required,
local environmental organ may be consulted.

PRODUCT RESIDUES: The disposal of this product should follow the local, state and federal regulations. If
required, local environmental organ may be consulted.

EMPTY CONTAINERS: The disposal of this product should follow the local, state and federal regulations. If
required, local environmental organ may be consulted.

14 - TRANSPORT INFORMATION
PROPER SHIPPING NAME/HAZARD CLASS MAY VARY BY PACKAGING, PROPERTIES AND MODE
OF TRANSPORTATION. TYPICAL PROPER SHIPPING NAMES FOR THIS PRODUCT ARE:

LAND TRANSPORT :

Proper Shipping Name : METHANOL

Technical Name(s) :
UN/ID No : UN 1230
Hazard Class - Primary : 3
Packing Group : II
Flash Point : 14 °C / 58 °F

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 MATERIAL SAFETY DATA SHEET

Product Name: R-2035

Revision Date: 17.10.2003 Page 7 of 7

14 - TRANSPORT INFORMATION cont.

AIR TRANSPORT (ICAO/IATA) :
Proper Shipping Name : METHANOL
Technical Name(s) :
UN/ID No : UN 1230
Hazard Class - Primary : 3
Hazard Class - Secondary : 6.1
Packing Group : II

MARINE TRANSPORT (IMDG/IMO) :

Proper Shipping Name : METHANOL
Technical Name(s) :
UN/ID No : UN 1230
Hazard Class - Primary : 3.2
Hazard Class - Secondary : 6.1
Packing Group : II

15 - REGULATORY INFORMATION
NFPA 704M / HMIS RATING:
2/2-HEALTH 3/3-FLAMMABILITY 0/0-REACTIVITY
0 = insignificant 1 = slight 2 = moderate 3 = high 4 = extreme

16 – OTHER INFORMATION
This product material safety data sheet provides health and safety information. The product is to be used in
applications consistent with our product literature. Individuals handling this product should be informed of
the recommended safety precautions and should have access to this information. For any other uses,
exposures should be evaluated so that appropriate handling practices and training programs can be
established to insure safe workplace operations. Please consult your local sales representative for any
further information

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