Iit Paper 2-011

Sri Chaitanya IIT Academy.A.P.
1 :: IIT JEE 2011 Paper - I ::
Sri Chaitanya’s Solutions to

IIT – JEE - 2011
(PAPER – 1)
Time: 3 Hours Maximum Marks: 240
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose
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ita
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h a
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C. Question paper format and marking scheme :

13. The question paper consists of 3 Parts (Chemistry, Physics and Mathematics). Each part consists of four
sections
14. In Section I (Total Marks : 21), for each question you will be awarded 3 marks if you darken ONLY the
bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other
cases, minus one (–1) mark will be awarded.
15. In Section II (Total Marks : 16), for each question you will be awarded 4 marks if you darken ALL the
bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. There are no
negative marks in this section.
16. In Section III (Total marks : 15), for each question you will be awarded 3 marks if you darken ONLY the
bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other
cases, minus one (–1) mark will be awarded.
17. In Section IV(Total Marks : 28), for each question you will be awarded 4 marks if you darken ONLY the
bubble corresponding to the correct answer and zero marks otherwise. There are no negative marks
in this section
Sri Chaitanya “IIT” Academy, Plot No 512, Ayyappa Society, Madhapur, Hyderabad - 500081
: 040-23119393, Website : www.srichaitanya.net
Sri Chaitanya IIT Academy.A.P. 2 :: IIT JEE 2011 Paper - I ::
IIT JEE 2011 (PAPER - I)

PART I : CHEMISTRY
SECTION – I ( Total Marks : 21)
( SINGLE CORRECT CHOICE TYPE )
This section contains 7 multiple choice questions. Each question has four choices A,B,C and D out of
which ONLY ONE is correct.
1. Dissolving 120 g of urea (mol. wt. 60) in 1000g of water gave a solution of density 1.15
g/mL. The molarity of the solution is
a) 1.78 M b) 2.00M c) 2.05 M d) 2.22 M
Ans : C
Sol : Molarity = 2m
1000M
y
m
1000d g / cc   M .MWsolute
d e m
 M  2.05M
A c a
I IT gradually and the conductivity of the
2.
y a   versus the volume of AgNO is
AgNO (aq). was added to an aqueous KCl solution
3
n
a i ta
solution was measured. The plot of conductance  3
i C h
Sr
a) (P) b) (Q) c) (R) d) (S

Ans : D
Sol : Equation : K   Cl   Ag  NO3  K   NO3  AgCl
In the early stages of the titration, addition of silver nitrate, the conductance does not
change very much because the Cl– ions are replaced by NO3 ions; both has almost same
ionic conductance. After the end point is passed, the excess of the added salt causes a sharp
increase in conductance.
 K   73.52 S cm 2 mole 1  Cl   76.34 S cm 2 mole 
 Ag   61.92 S cm 2 mole   NO  71.44 S cm 2 mole 

3
3. Among the following compounds, the most acidic is
a) p-nitrophenol b) p-hydroxybenzoic acid
c) o-hydroxybenzoic acid d) p-toulic acid
Ans : C
Sol : Ortho effect present in ortho-hydroxy benzoic acid
4. The major product of the following reaction is
m y
a d e
c) T A c
a) b)
a I I d)
n y
Ans : A
h a ita
ri C
OS KOH
O
-
N K+
N-H 

O O
Br- CH2Cl
Sol :
O
N CH2 Br
5. Extra pure N2 can be obtained by heating
a) NH3 with CuO b) NH4NO3 c)  NH 4 2 Cr2O7 d) Ba  N3  2
Ans : D
Sol : Pure N2 is prepared by heating Ba(N3)2
Ba  N3 2  3N 2   Ba
6. Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl  , CN  and
H2O, respectively, are
a) octahedral, tetrahedral and square planar
b) tetrahedral, square planar and octahedral
c) square planar, tetrahedral and octahedral
d) octahedral, square planr and octahedral
Ans : B
Sol : [ NiCl4 ]2  d 8  Sp 3Tetrahedral
[ NiCN 4 ]2  d 8  dsp 2 Square planar
m y
[ Ni  H 2O 6 ]2  d 8  sp 3d 2 Octahedral Shape
a d e
A c
Tto its artifical disintegration in two ways,
a I I
7. Bombardement of aluminum by   particle
n y leads
ita
(i) and (II) as shown. Products X, Y and Z respectively are,
C h a
27
Al
(ii)
30
P Y
Sri
13 15
(i)
30
Si  X 30
14
14 Si  Z
a) proton, neutron, positron
b) neutron, positron, proton
c) proton, positron, neutron
d) positron, proton, neutro
Ans : A
Sol : X= 11H , Y=10 n , Z= 0+1e
SECTION – II ( Total Marks : 16)
( MULTIPLE CORRECT ANSWERS TYPE)
This section contains 4 multiple choice questions. Each question has four choices A,B,C and D out of
which ONLY or More may be correct.
8. Amongst the given options, the compound(s) in which all the atoms are in one plane in all
the possible conformations (if any), is (are)
H H
H
C-C
a) b) H2C = C = O c) H - C C-C d) H2C = C = CH2
H2C CH2 CH2
Ans : BC
Sol : CH2 = C = CH2 allene system the compound is non planar
m y
a d e
9. According to kinetic theory of gases
T A c
a I I
a) collisions are always elastic
b) heavier molecules transfer t

n y
a momentum to the wall of the container.
a i more
hof molecules have very high velocity
r i C
c) only a small number
d) between Scollisions, the molecules move in straight line with constant velocities.
Ans : A,B,C,D
Sol :Conceptual
10. The correct statement(s) pertaining to the adsorption of a gas on a solid surface is (are)
a) Adsorption is always exothermic
b) Physisorption may transform into chemisorption at high temperature
c) Physisorption increases with increasing temperature but chemisorption decreases with

increasing temperature
d) Chemisorption is more exothermic than physisorption, however it is very slow due to

higher energy of activation.
Ans : ABD
Sol: Physical adsorption decreases with increasing of temperature according Leachtlier ‘s Principle
11. Extraction of metal from the ore cassiterite involves
a) carbon reduction of an oxide re b) self-reduction of a sulphide ore
c) removal of copper impurity d) removal iron impurity
Ans : ACD
Sol : Sn is extracted by the reduction of SnO2 with carbon

SnO2  C  Sn  2CO
Sn mainly contains Iron impurities which are removed by blowing air to convert Fe into
FeO. Sn also contains tracer of Cu
SECTION – III ( Total Marks : 15)

( PARAGRAPH TYPE)
m y
a d e
This section contains 2 paragraphs. Based upon one of the paragraphs 2 multiple choice questions
and based on the other paragraph 3 multiple choice questions have to be answered. Each of these
A c
questions has four choices A,B,C and D out of which ONLY ONE is correct.
T
Passage-I :
a I I
n y
h a ita
ri C
S
An acylic hydrocarbon P, having molecular formula C6 H10 , gave acetone as the only or--
ganic product through the following sequence of reactions, in which Q is an intermediate
organic compound.
12. The structure of compound P is
a) CH3CH2CH2CH2 - C C-H b) H3CH2C - C C - CH2CH3
c) d)
Ans : D
13. The structure of the compound Q is
a) b)
c) d)
Ans : B
Sol for Q no 12 to 13 :
m y
a d e
CH3 CH3 O
T A c CH3 OH
a I I
y
CH3 - C - C dil . H 2 SO4 / HgSO4
C - H   CH3 - C 1 NaBH 4 / ethanol
C - CH3   CH3 - C CH - CH3
n
 2dil .acid
CH3
h a ita CH3 CH3
C
(P) (Q)
S ri
con. H 2 SO4
(catalytic amount)
CH3 CH3 CH3
CH3 - C C - CH3 CH3 - C CH - CH3 CH3 - C CH - CH3
CH3
1 O3 CH3 CH3
 2  Zn / H 2O
CH3
2 CH3 - C O
Passage- II :
When a metal rod M is dipped into an aqueous colourless concentrated solution of

compound N, the solution turns light blue. Addition of aqueous NaCl to the blue solution
gives a white precipitate O. Addition of aqueous NH3 dissolves O and given an intense blue
solution
14. The metal rod M is

a) Fe b) Cu c) Ni d) Co
Ans : B
15. The compound N is
m y )
a) AgNO3 b) Zn(NO3)2
a d e
c) Al(NO3)3
d) Pb(NO 3 2
Ans : A
T A c
a I I
16. The final solution contains
a n y
a) [Pb(NH ) ] and [CoCl )it
3 4
C
2+
h a ] 3 4
2- b) [Al(NH3)4]3+ and [Cu(NH3)4]2+
S i
c) [Ag(NH ) ] rand [Cu(NH ) ]
3 2
+
3 4
2+ d) [Ag(NH3)2]+ and [Ni(NH3)6]2+
Ans : C
Sol : for Q. no 14 to 16 :
Cu +2Ag NO3  Cu  NO3  2  2Ag 

M  N
NaCl  Na   aq   Cl   aq 
Ag   Cl   AgCl 
White  O 
2
Cu 2  4  NH 3   Cu  NH 3 4 
Deep blue colour
SECTION – IV ( Total Marks : 28)
( INTEGER ANSWER TYPE)
This section contains 7 questions. The answer to each of the questions is a single-digit integer, ranging
from 0 to 9. The bubble corresponding to the correct answer is to be darkened in the ORS.
17. The work function   of some metals is listed below. The number of metals which will
show photoelectric effect when light of 300 nm wavelength falls on the metal is
Metal Li Na K Mg Cu Ag Fe Pt W
  eV  2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75
Ans : 4
m y
Sol : E= +KE
a d e
For photo electric effect, condition is E >
T A c 
a I I
Metals exhibits : Li, Na, K, Mg
a n y
i t
18. To an evacuated vessel with movable
a
piston under external pressure of 1 atm., 0.1 mol of He
h
and 1.0 mol of an unknown
i
0
Cgas behaviour, the total volume (in litre) of the gases at 0 C is close to
compound (vapour pressure 0.68 atm. at 0 C) are introduced.
S r
Considering the ideal 0
Ans : 7
Sol : Unknon Compound may be Soid (or) liquid
Let given volume of vessel : ‘V’
for unknown compound
PV = nRT
0.68 X V = ng (0.0821 X 273)____ 1
For total gaseous mixture pressure = external. pressure
PV = nRT
1 X V =(ng + nHe)(0.0821 X 273)____ 2
from 1 and 2
ng = 0.2125, ntotal = 0.3125
V = 7 lit
19. Reaction of Br2 with Na2CO3 in aqueous solution gives sodium bromide and sodium bromate
with evolution of CO2 gas. The number of sodium bromide molecules involved in the
balanced chemical equation is
Ans : 5
Sol : 3Br2  3Na2CO3  5 NaBr  NaBrO3  3CO2
20. The difference in the oxidation numbers of the two types of sulphur atoms in Na2S4O6 is
Ans : 5
O
O
(0) (0)
NaO - S - S - S - S - ONa
Sol : (+5) (+5)
m y
e atoms = +5
O
O
The difference between the O.S of two different types ofa
c d
A
sulphur
I IT gives glycine (Mol. Wt. 75), alanine

n y a
21. A decapeptide (Mol. Wt. 796) on complete hydrolysis
ta in the decapeptide is
and phenylalanine. Glycine contributes 47.0% to the total weight of the hydrolysed products.
h a
The number of glycine units ipresent
i C
Ans : 6
Sr
Sol : 100 ________ 958
47
47 ________ ?  958  450.12
100
The weight of glycine present in 958 decapeptide is 450.12.
the molecular weight of one glycine is 75
450.12
no. of glycines =  6.00  6
75
22. The total number of alkenes possible by dehydrobromination of 3-bromo
3-cyclopentylhexane using alcoholic KOH is
Ans : 5
Sol :
Br
C-C-C-C-C-C C-C-C-C-C-C C-C-C-C=C-C

C-C-C-C-C-C
+
+
cis + trans
C-C-C=C-C-C
m y
a d e
T A c cis + trans
a I I
n y
ita
23. The maximum number of electrons that can have principal quantum number, n=3, and spin
h a
quantum number, ms =-1/2, is
C
Ans : 9 S ri
Sol : In third orbit 3s, 3p, 3d sub levels are present and a total of nine orbitals are present. Each
orbital has one electron with ms = –1/2
PART II : PHYSICS
==============================================================
SECTION – I (Total Marks : 21)
( SINGLE CORRECT CHOICE TYPE )
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) for
its answer, out of which ONLY ONE is correct
24. The wavelength of the first spectral line in the Balmer series of hydrogen atom is 6561 A0 ,
The wavelength of the second spectral line in the Balmer series of singly-ionized helium
atom is
0 0 0 0
a) 1215 A b) 1640 A c) 2430 A d) 4687 A
Ans : A
1 2 1 1
Sol :   1  2 2  32 
m y
1  
a d e
1 2 1 1
T A c
2
 2  2  2 
2 4 
a I I
n y
ita
2 1 5 4  16 5
  
1 4 4  9 12

C h a
93
2 
6561 5
S ri
 1215 A0
9 3
25. A ball of mass (m) 0.5 kg is attached to the end of a string having length (L) 0.5 m. The ball is
rotated on a horizontal circular path about vertical axis. The maximum tension that the string
can bear is 324 N. The maximum possible value of angular velocity of ball (in radian/s) is
a) 9 b) 18 c) 27 d) 36
Ans : D
1 1 2
Sol : 324   w w  2 18 w= 36
2 2
26. A meter bridge is set-up as shown, to determine an unknown resistance ‘X’ using a standard
10 ohm resistor. The galvanometer shows null point when tapping - key is at 52 cm mark.
The end-corrections are 1 cm and 2cm respectively for the ends A and B. The determined
value of ‘X’ is
a) 10.2 ohm b) 10.6 ohm c) 10.8 ohm d) 11.1 ohm
m y
Ans :B
a d e
c
 10
IT A
Sol :
y a I
n
2
2
Y

10
h a ita
52  1 48  2
ri C
X  10 x S
53
50
X = 10.6
27. A 2 F capacitor is charged as shown in figure. The percentage of its stored energy dissi-
pated after the switch S is turned to position 2 is
a) 0% b) 20% c) 75% d) 80%
Ans : D
Sol : q0  2V
q1 q2

2 8
4q1  q2
q1  q2  2V
5q1  2V
2 
q1   V 
5 
8 
q2   V 
5 
4 2 64 2
2 V V
1 4V 1 25 1 25
 
2 2 2 2 2 8
4 2 16 2
4V 2 = V + V
y
25 25
4V 2  1 
1 4

d em
2 25
A ca
4V 2 
25  1  4 20
 x100 = 80
I IT
25 25
n y a
ita
28. A police car with a siren of frequency 8kHz is moving with uniform velocity 36km/hr to-
h a
wards a tall building which reflects the sound waves. The speed of sound in air is 320 m/s. The
C heard by the car driver is
frequency of theisiren
S r
a) 8.50 kHz b) 8.25 kHz c) 7.75 kHz d) 7.50 kHz
Ans : A
Aol : frequency reflucted by wall ‘f’
 320 
f '  8  103  
 320  10 
 320  10 
frequency heared by car driver f "   f'
 320 
32 33
f "  8  103 
31 32
33
 8  103 
31
 8.50 kHz
29. 5.6 liter of helium gas at STP is adiabatically compressed to 0.7 liter. Taking the initial
temperature to be T1 , the work done in the process is
9 3 15 9
a) RT1 b) RT1 c) RT1 d) RT1
8 2 8 2
Ans: A
R
Sol: W T1  T2 
l
l
1 1  k
TV
 1
l V 
T1 V 1  T2  1 
8
T2  4T1
m y
W=
9 RT1
a d e
8
A c
, where IisTa constant. The flux through the shaded

30. Consider an electric field
y a I
E  E0 xˆ E0
area (as shown in the figure) due ton

a i t a this field is
i C h
Sr
  
E0 a 
a) 2E0 a b) 2E0 a c) E0 a d)
2
Ans : C
2a
 
Sol : area  2a 2 E. A  E 2a 2 cos 450  Ea 2
450
x
SECTION – II (Total Marks : 16)
( MULTIPLE CORRECT CHOICE TYPE )
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
for its answer, out of which ONE or MORE may be correct
31. A metal rod of length ‘L’ and mass ‘m’ is pivoted at one end. A thin disk of mass ‘M’ and
radius ‘R’(<L) is attached at its center to the free end of the rod. Consider two ways the
disc is attached; (case A) the disc is not free to rotate about its center and (case B) the disc
is free to rotate about its center. The rod - disc system performs SHM in vertical plane
after being released from the same displaced position. Which of the following statement(s)
is (are) true ?
a) Restoring torque in case A = Restoring torque in case B
b) Restoring torque in case A < Restoring torque in case B
c) Angular frequency for case A > Angular frequency for case B
m y
d e
d) Angular frequency for case A < Angular frequency for case B
a
Ans : AD
A
T casec
a I I
a n y
Sol : Torque about point of suspenstion is same in both
a it
case A :
 MR 2
 
i C h 2
 ML 
ml 2 
   k
Sr
 2 3 
case B ; In case B ; Disc is not going to get any torque about its centre.
all of it’s point have acceleration that is equal to acceleration of end point of rod.
 l2 
   ML2  m    k
 3
k
 W2 
 2 ml 2 
 mL  3 
 
k
W1  2
 MR 2 ml 2 
 2  ML 
 3 
W2  W1
32. A composite block is made of slabs A, B, C, D and E of different thermal conductivities
(given in terms of a constant K) and sizes (given in terms of length, L) as shown in the
figure. All slabs are of same width. Heat ‘Q’ flows only from left to right through the
blocks. Then in steady state
a) heat flow through A and E slabs are same
m y
e
b) heat flow through slab E is maximum
c) temperature difference across slab E is smallest

c a d
d) heat flow through C = heat flow through BI+I A
Theat flow through D
n y a
Ans :ABCD
a i t a
C
33. An electron and a proton
i h are moving on straight parallel paths with same velocity. They
S r
enter a semi-infinite region of uniform magnetic field perpendicular to the velocity. Which
of the following statement(s) is/are true ?
a) They will never come out of the magnetic field region
b) They will come out travelling along parallel paths
c) They will come out at the same time
d) They will come out a different times
Ans : BD
mv
Sol : r  qB
They go in different direction but come out along parallel paths.
2 m
T
qB
as ‘m’ is different ‘T’ also different

34. A spherical metal shell A of radius RA and a solid metal sphere B of radius RB   RA  are
kept far apart and each is given charge ‘+Q’. Now they are connected by a thin metal wire.
Then
 A RB
a) E Ainside  0 b) QA  QB c)   R d) E Aon surface  EBon surface
B A
Ans : ABCD
Sol : a) EA = 0
Q A QB
b) R  R RA  RB QA  QB
A B
m y
c)  R  V
a d e
T A c

d) E  2
a I I
0
so E 
n y
a ita – III (Total Marks : 15)
SECTION
i C h (COMPREHENSION TYPE)
Sr
and based on the paragraph 3 multiple choice questions have to be answered. Each of these questions
has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Paragraph for Question Nos. 35 to 36
A dense collection of equal number of electrons and positive ions is called neutral plasma.
Certain solids containing fixed positive ions surrounded by free electrons can be treated as
neutral plasma. Let ‘N’ be the number density of free electrons, each of mass ‘m’. When
the electrons are subjected to an to electric field, they are displaced relatively away from
the heavy positive ions. If the electric field becomes zero, the electrons begin to oscillate
about the positive ions with a natural angular frequency '  p ' which is called the palsma
frequency. To sustain the oscillations, a time varying electric field needs to be applied that
has an angular frequency  , where a part of the energy is absorbed and a part of it is re-
flected. As  approaches  p , all the free electrons are set to resonance together and all
the energy is reflected. This is the explanation of high reflectivity metals.
35. Taking the electric charge as ' e ' and the permittivity as '  0 ' , use dimesional analysis to
determine the correct expression for  p .
Ne m 0 Ne 2 m 0
a) m 0 b) c) d)
Ne m 0 Ne 2
Ans : C

Sol :    T 1
T
1
2  I 2T 2  M 1L3T 2
Ne L3
D. f . of 
m 0 M 1  I 2T 2
m y
a d e
c
D.f. = T 1
I T A
. Take a
y I
36. Estimate the wavelength at which plasma reflection will occur for a metal having the den-
sity of electrons
in proper SI units.
it a n
N  4  1027 m 3 and  0  1011
, where these quantities are
m  10 30
C h a
a) 800 nm
Ans : B Sr i b) 600nm c) 300nm d) 200nm

Sol :   2 n  n 
2
c c  2
c  n    
n 
c  2 3 108  2
 
Ne2 4 1027  1.6 1019 
2
m 0 1030 1011
  585  109  600 nm
Paragraph for Question Nos. 37 to 39
Phase space diagrams are useful tools in analyzing all kinds of dynamical problems. They
are especially useful in studying the changes in motion as initial position and momentum
are changed. Here we consider some simple dynamical systems in one-dimension. For
such systems, phase space is a plane in which position is plotted along horizontal axis and
momentum is plotted along vertical axis. The phase space diagram is x(t) vs. p(t) curve in
this plane. The arrow on the curve indicates the time flow. For example, the phase space
diagram for a particle moving with constant velocity is a straight line as shown in the fig-
ure. We use the sign convention in which position or momentum upwards (or to right) is
positive and downwards (or to left) is negative
m y
a d e
T A c
37.
a I I
The phase spacem diagram for a ball thrown vertically up from ground is
n y
a ita
i C h
a)
Sr b)
c) d)
Ans : D
Sol : Vertically thrown particle comes back to original position till the particle reaches the high-
est position of its path, its momentum is +ve. After that, it terns to zero and them negative
38. The phase space diagram fro simple harmonic motion is a circle centrred at the origin. In
the figure, the two circles represent the same oscillator but for different initial conditions,
and E1 and E2 are the total mechanical energies respectively. Then
a) E1 = 2 E 2 b) E1 = 2 E 2 c) E1 = 4 E 2 d) E1 = 16 E 2
Ans : C
Sol :
1 2
Energy  ka  a 2
E1 a12
 4
m y
2 E2 a22
a d e
 E1  4 E2
A c
Tsubmerged in water,
39. I I
adiagram for one cycle of this
Consider the spring-mass system, with the mass
n y
ta
as shown in the figure. The phase space
system is
h a i
i C
Sr
a) b)
c) d)
Ans : A
Sol : As the block oscillates, due to viscous effects, its total energy decreases continuously and
so its amplitude decreases continuously. Assuming that the block is initially pulled down
and released, its momentum will increase upwards till it reaches the mean position
SECTION –IV( Total Marks : 28)
( INTEGER ANSWER TYPE)
This section contains 7 questions . The answer to each of the questions is a single -digit integer, ranging
40. Steel wire of length ‘L’ at 40°C is suspended from the ceilling and then a mass ‘m’ is hung
from its free end. The wire is cooled down from 40°C to 30°C to regain its original length
‘L’. The coefficient of liner thermal expansion of the steel is 10–5/°C, Young’s modulus of
steell is 1011 N/m2 and radius of the wire is 1mm. Assume that L>> diameter of the wire.
Then the value of ‘m’ in kg is nearly
Ans : 3
mgL
Sol : Y= , e=  L t
Ae
m y
mgL
a d e
Y
A LL
T A c
a I I
n y
ita
M  10
1011 
22
7 h a
 1 106 105  10
C
S ri
m  3.14  3
41. The activity of a freshly prepared radioactive sample is 1010 disintegrations per second,
whose mean life is 109s. The mass of an atom of this radioisotope is 10–23 kg. The mass (in
mg) of the radioactive sample is
Ans : 1
10 1
Sol : 10  N
109
 N  1019
 total mass
 10 25  1019 kg
 10 6 kg  1 mg
42. A block moving on an inclined plane making an angle 45° with the horizontal and the coef-
ficient of friction is  . The force required to just push it up the inclined plane is 3 times
the force required to just prevent from sliging down. If we define N = 10 then N is
Ans : 5
 mg mg   mg  mg 
Sol : 3     
 2 2  2 2  
3 1     1   
3  3  1  
4  2
  1/ 2
10  5
A boy is pushing a ring of mass 2 kg and radius 0.5 m with a sticke m y
43.
stick applies a force of 2 N on the ring and rolls it withouta
c d a shown in the figure. The
I A slipping with an acceleration of

T between the stick and the ring is (P/
olling always occurs and the coefficient of Ifriction
2
0.3m/s . The coefficient of friction between the ground and the ring is large enough that
n y a
ta
10). The value of P is
h a i
i C
Sr
Ans : 4
Sol : F = N 2 +      (i)
a
 p  NR   NR  2mR 2     ii 
R N
solving (i) and (ii), 

  and 0.36
but    is not a possible solution
   
 p  3.6  4
44. Four solid spheres each of diameter 5 cm and mass 0.5 kg are placed with their centers at
the corners of a square of side 4cm. The moment of inertia of the system about the diago-
nal of the square is N x 10-4 kg - m 2 , then N is
Ans : 9
2
2 2  a 
Sol : 4  MR  2  M   I
5  2
2 2
2  5 2
  4 102 
4  5    10   2 5   
5  2   2 
N 11 104
N=9
45. A long circular tube of length 10 m and radius 0.3 m carries a current I along its curved
y
surface as shown. A wire-loop of resistance 0.005 ohm and of radius 0.1 m is placed inside
m
a d e
the tube with its axis coinciding with the axis of the tube. The current varies as
T A c
I = I0 cos(300 t ) where I0 is constant. If the magnetic moment of the loop is
N 0 I 0 sin  300 t  , then ‘N’ is
a I I
n y
h a ita
ri C
S
Ans : 6
I
Sol : ni 
l
 I cos
B 0 0 300t
l
d 0 I 0  300 
V  sin 300t  R 2
dt l
0 I 0 R 2  300 
V sin 300t
l
V
i 2
R m  i R
46. Four point chargs, each of +q, are rigidly fixed at the four corners of a square planar soap
film of side ‘  ’. The surface tension of the soap film is  . The system of charges and
1/ N
 q2 
planar film are in equilibrium, the a =   , where ‘k’ is a constant. Then N is
 
Ans : 3
q q
Sol : a
q q
m y
2 Aq 2 2 2q 2
  y.a
a d e
c
2
a2
 
A
a 2
I IT
a
1
 q2  3
n y
ita
 a    N  3
 y
C h a
S ri
PART III : MATHEMATICS

SECTION – I (Total Marks : 21)
(Single Correct Answer Type)
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct
  
47. Let P   : sin   cos   2 cos  and Q   : sin   cos   2 sin  be two sets. Then 
a) p  Q and Q  P   b) Q  P
c) P  Q d) P = Q
Ans: D
Sol: P  sin   cos   2 cos 
m y
sin   2 cos   cos 
a d e
  T A c
sin   2  1 cos 
a I I
    tany
i
sin  2 1  2 1 2  1 cos 
C h a
2 sin   sin   cos 
S ri
2 sin   cos   sin 
 PQ
48. Let the straight line x  b divide the area enclosed by y  1  x 2  , y  0 , and x  0 into two
1
parts R1  0  x  b  and R2  b  x  1 such that R1  R2  . Then b equals
4
3 1 1 1
a) b) c) d)
4 2 3 4
Ans : B
b 1
2 2 1
Sol :  1  x  dx   1  x  dx 
4
0 b
1
b
2
49. Let  and  be the roots of x 2  6 x  2  0 , with    . If an   n   n for n  1, then the
a10  2as
value of 2a9 is
a) 1 b) 2 c) 3 d) 4
Ans : C
Sol : a10   10   10       9   9     8   8 
 a10  6a9  2a8
50. A straight line L through the point (3,–2) is inclined at an angle 600 to the line 3x  y  1 .
also intersects the x–axis, then the equation of L is
a) y  3 x  2  3 3  0 b) y  3 x  2  3 3  0
m y
c) 3y  x  3  2 3  0
a d e d) 3 y  x  3  2 3  0
Ans : B
T A c
Sol : Let ‘m’ be the slope of the required line
a I I
n y
ta
m 3
 3
h
1 m 3
a i
i C
m0 or
Sr m 3
51. Let  x0 , y0  be the solution of the following equations

ln 2 ln 3
 2x  3y
3ln x  2ln y
Then x0 is
1 1 1
a) b) c) d) 6
6 3 2
Ans : C
Sol :  log 2  log 2  log x   log 3  log 3  log y  --------1
log 3  log x   log 2  log y  -------------2
From 1 & 2
1
log x   log 2  x 
2
ln 3
x sin x 2
52. The value of  sin x 2  sin ln 6  x 2 dx is
ln 2  
1 3 1 3 3 1 3
a) ln b) ln c) ln d) ln
4 2 2 2 2 6 2
Ans : A
Sol : Put x 2  t
log3
1 sin t
  dt
2 log 2 sin t  sin  log b  t 
1  log 3  log 2  1  3
m y
 
2 2
  log  
 4  2
a d e
A c
Tthree vectors. A vector in the plane of
 
53. Let a  i  j  k , b  i  j  k and c  iˆ  ˆj  kˆ

a I I
be

v

a
n y
ita
  1
and b , whose projection on c is , is given by
h
Cb) a 3
a) i  3 j  3k
S ri 3i  3 j  k c) 3i  j  3k d) i  3 j  3k
Ans : C
  
Sol : Let v  a   b
 
Projection v on c
  
 a   b .c



1
c 3
 2
SECTION - II (Total Marks : 16)
(Multiple Correct Answer Type)
This Section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE or MORE may be correct.
54. L et f : f :    be a function such that f(x + y) = f(x) + f(y), x, y   .
If f(x) is differentiable at x = 0, then
a) f(x) is differentiable only in a finite interval containing zero
b) f(x) is continuous x  
c) f '  x  is constant x  
d) f(x) is differentiable except at finitely many points
m y
Ans : B,C
a d e
Sol : From the given data   be the linear function.
f x
T A c
Let the eccentiricty of the hyperbola ya
I Ix2 y2
55.
i n  1
be reciprocal to that of the ellipse x +
tathorugh a focus of the ellipse, then
a2 b2
2
h a
4y = 4. If the hyperbola passes
C
a) the equation
i
Srof the hyperbola is x2 y 2
 1
3 2
b) a focus of the hyperbola is (2, 0)
5
c) the eccentricity of the hyperbola is
3
d) the equation of the hyperbola is x2 – 3y2 = 3

Ans : B,D
3
Sol : Ecentricity of ellipse
2
2
 Ecentricity of Hyper bola =
3
Focus of ellipse =  
3, 0 ,  3, 0 
Focus lies on the hyper bola then a  3 , b = 1
56. Let M and N be two 3  3 non - singular skew - symmetric matrices such that MN = NM.
If PT denotes the transpose of P, then M2N2(MTN)–1(MN–1)T is equal to
a) M2 b) –N2 c) –M2 d) MN
Ans : wrong
Reason : 3  3 non singular skew -symmetrices does’t exist.
Sol : Among the given options option C may be correct.
57. The vector(s) which is/are coplanar with vectors iˆ  ˆj  2kˆ and iˆ  2 ˆj  kˆ , and perpen-
dicular to the vector iˆ  ˆj  kˆ is /are
a) ĵ  kˆ b) iˆ  ˆj c) iˆ  ˆj d)  ĵ  kˆ
Ans : A,D
 
  

m y
Sol: Required vector =  a  b  c
a d e
SECTION - III (TotalIT A c
y a I Marks : 15)
ita n (Paragraph Type)

h a
and based on the other paragraph 3 multiple choice questions have to be answered. Each of these
C
S i
questions has four choices (A), (B), (C) and (D) out of with ONLY ONE is correct.
r Paragraph for Question Nos. 58 and 59
Let U1 and U2 be two urns such that U1 contains 3 white and 2 red balls, and U2 contains only
1 white ball. A fair coin is tossed. If head appears then 1 ball is drawn at random from U1 and
put into U2. However, if fail appears then 2 balls are drawn at random from U1 and put into
U2. Now 1 ball is drawn at random from U2.
58. The probability of the drawn ball from U2 being white is
13 23 19 11
a) b) c) d)
30 30 30 30
Ans : B
1 3 2 2 1  1  3C 2 3 2C2 1 3C .2C1
1 2
Probability = 2  5 x 2  5 x 2   2  5C x 3  5C x 3  5C x 
3
   2 2 2
23

30
59. Given that the drawn ball from U2 is white, the probability that head appeared on the coin is
17 11 15 12
a) b) c) d)
23 23 23 23
Ans : D
1 3 2 2 1
x  x
2  5 2 5 2 
Sol : Required conditional Probability = 23
30
Paragraph for Question Nos. 60 and 62
Let a, b and c be three real numbers satisfying
m y
1 9 7 
a d e
T A c
 a b c  8 2 7   0 0 0 ..................(E)
7 3 7 
a I I
n y
ita
60. If the point P(a, b, c), with reference to (E), lies on the plane 2x + y + z = 1, then the
h
value of 7a + b + c is
a
Cb) 12
a) 0
S ri c) 7 d) 6
Ans : D
61. Let  be a solution of x3 – 1 = 0 with Im(  )>0. If a = 2 with b and c satisfying (E), then
3 1 3
the value of a
 b  c is equal to
  
a) –2 b) 2 c) 3 d) –3
Ans : A
62. Let b = 6, with a and c satisfying (E). If  and  are the roots of the quadratic equation
n

1 1
ax + bx + c = 0, then    
2
n 0   
6
a) 6 b) 7 c) d) 
7
Ans : B
Sol : 60, 61, 62.
a  8b  7c  0
9a  2b  3c  0
abc  0
 a  x, b  6 , c  7
60. Now 2a  b  c  1
 2  6  7  1
  1
m y
Hence a = 1, b = 6, c = –7
a d e
T A c
 7a  b  c  6
a I I
n y
61. a  2  2
h a ita
ri C
S
 b  12, C  14
3 1 3
 a
 b  3  2
W W W
62. b  6   1
 a  1, c  7
 ax 2  bx  c  0  x 2  6 x  7  0
   1,  =-7
1 1 6
  
  7
n

1 1
     7
n 0   
SECTION - IV (Total Marks : 28)
(Integer Answer Type)
This section contains 7 questions. The answer to each of the questions is a single - digit integer, ranging
63. Let f : [1,  )  [2,  ) be a differentiable function such that f(1) = 2.
x
3
If 6 f  t  dt  3 x f  x   x for all x  1, then the value of f(2) is
1
Ans : 6
Sol : 2.6  f  x   3.xf 1  x   3 f  x   3 x 2
xf 1  x   f  x   x 2
1
f 1  x  f  x  x
x
If 
1
m y
x
a d e
1
f  x  .   1dx
T A c
x
a I I
f  x
n y
ita
 xc
n
f  x   x2  c
C h a
f 1  2
S ri
2  1 c
c 1
f  x   x2  x
f  x  4  2  c
64. If z is any complex number satisfying z  3  2i  2 , then the minimum value of 2 z  6  5i

is
Ans : 5
5 5i
Sol : 2 2  3  i  2 z  3  2i  2i 
2 2
9i
 2 1z  3  2i 
2
9
 2
2 5
p
65. Let a1, a2, a3, ..........,a100 be an arithmetic progression with a1 = 3 and SP =  a , 1  p  100 .
i 1
i
Sm
For any integer n with 1  n  20 , let m = 5n. If S does not depend on n, then a2 is
n
Ans : 9
m
S m 2  
6  m  1 d 
 5  6   5n  1 d 
Sol : S n n  s
 6   n  1 d  6   n  1 d
2
Which is independed of n if d  6a1  6

 a2  a1  d  9
m y
66. Consider the parabola y2 = 8x. Let 1 be the area of the triangle formed by the end points of
d e
a be the area of the triangle
its latus rectum and the point
1
P ,
T A c

2
on the parabola, and 2
2
I I 
aend points of the latus rectum. Then is

n y 1
ta
formed by drawing tangents at P and at the 2
h a i
Ans : 2
i C
 Sr 
1
Sol : 1  y1  y2  
y2  y 3 y3  y1
8a
1
1   y1  y2  y2  y3  y3  y1 
16a
1
 2
2
  sin     d
  , where     . Then the value of d  tan    f    is
1
67. Let f    sin  tan 
  cos 2  4 4
Ans : 1
 sin  
Sol : Put tan 1   
 cos 2 
sin 
 tan  
cos 2
 sin   tan 
d
 f    tan   f    1
d  tan  
68. The minimum value of the sum of real numbers a , a , 3a , 1, a and a10 with a > 0 is
–5 –4 –3 8
Ans : 8
Sol : AM  GM
1 1 1 1 1
      1  a8  a10
a5 a4 a3 a3 a3
 88 1  8
1 1 1
 
69. The positive integer value of n > 3 satisfying the equation sin    sin  2  sin  3  is
n  n   n 
Ans : 7
m y
Sol : Sin
2
n
.Sin
3
n
 Sin

n
 2 3 
 Sin n  Sin n 
 
a d e
T A c
 cos

 cos
5 
 cos  cos
3
 cos
2
a I I
 cos
4
n n n n
n y n n
 cos
3
n
 cos
5
n a
 cos
h
2
n ita
 cos
4
n
4
riC 3 
 2 sin
nSsin  2 sin
n n
sin
n
 3
 sin 4  sin 0
n n
 7    
 2 cos   sin    0
 2 n   2n 
7
 cos 0  n>3
2n
7 
   2k  1
2n 2
7
  odd integer
n
n7

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Sri Chaitanya IIT Academy.A.P.

1 :: IIT JEE 2011 Paper - I ::

Sri Chaitanya’s Solutions to

C. Question paper format and marking scheme :

IIT JEE 2011 (PAPER - I)

a) (P) b) (Q) c) (R) d) (S

 Ag   61.92 S cm 2 mole   NO  71.44 S cm 2 mole 

4. The major product of the following reaction is

5. Extra pure N2 can be obtained by heating

a) NH3 with CuO b) NH4NO3 c)  NH 4 2 Cr2O7 d) Ba  N3  2

a) octahedral, tetrahedral and square planar

b) tetrahedral, square planar and octahedral

c) square planar, tetrahedral and octahedral

d) octahedral, square planr and octahedral

Sol : [ NiCl4 ]2  d 8  Sp 3Tetrahedral

[ NiCN 4 ]2  d 8  dsp 2 Square planar

a) proton, neutron, positron

b) neutron, positron, proton

c) proton, positron, neutron

d) positron, proton, neutro

Sol : X= 11H , Y=10 n , Z= 0+1e

b) heavier molecules transfer t

a) Adsorption is always exothermic

b) Physisorption may transform into chemisorption at high temperature

c) Physisorption increases with increasing temperature but chemisorption decreases with

d) Chemisorption is more exothermic than physisorption, however it is very slow due to

a) carbon reduction of an oxide re b) self-reduction of a sulphide ore

c) removal of copper impurity d) removal iron impurity

Sol : Sn is extracted by the reduction of SnO2 with carbon

SECTION – III ( Total Marks : 15)

12. The structure of compound P is

a) CH3CH2CH2CH2 - C C-H b) H3CH2C - C C - CH2CH3

h a ita CH3 CH3

CH3 CH3 CH3

CH3 - C C - CH3 CH3 - C CH - CH3 CH3 - C CH - CH3

When a metal rod M is dipped into an aqueous colourless concentrated solution of

14. The metal rod M is

15. The compound N is

Cu +2Ag NO3  Cu  NO3  2  2Ag 

  eV  2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75

ng = 0.2125, ntotal = 0.3125

Sol : 3Br2  3Na2CO3  5 NaBr  NaBrO3  3CO2

I IT gives glycine (Mol. Wt. 75), alanine

C-C-C-C-C-C C-C-C-C-C-C C-C-C-C=C-C

a) 10.2 ohm b) 10.6 ohm c) 10.8 ohm d) 11.1 ohm

a) 0% b) 20% c) 75% d) 80%

area (as shown in the figure) due ton

a) Restoring torque in case A = Restoring torque in case B

b) Restoring torque in case A < Restoring torque in case B

c) Angular frequency for case A > Angular frequency for case B

a) heat flow through A and E slabs are same

c) temperature difference across slab E is smallest

a) They will never come out of the magnetic field region

b) They will come out travelling along parallel paths

c) They will come out at the same time

d) They will come out a different times

They go in different direction but come out along parallel paths.

as ‘m’ is different ‘T’ also different

Ans : B Sr i b) 600nm c) 300nm d) 200nm

  585  109  600 nm

I A slipping with an acceleration of

solving (i) and (ii), 

but    is not a possible solution