1 Petrobras - Petróleo Brasileiro S.A. No. 4309671 Rev.

0
Refinaria do Nordeste - RNEST Job S-01411
DK-2800 Lyngby, Denmark Hydrogen Generation Unit - U-35 Page 1 of 4
Clients Doc. No. I-FD-5290.00-2311-941-HTP-011

Job S-01411 WBS 44

Specification
for
Chemicals

Rev. Description Date Made by Chd. Appd.

0 First issue 19-FEB-2008 VIRP SKA SKA
Information contained herein is confidential and must not be used by or conveyed to any third party without our written authorisation - Haldor Topsøe A/S
1 Petrobras - Petróleo Brasileiro S.A. No. 4309671 Rev. 0
Refinaria do Nordeste - RNEST Job S-01411
DK-2800 Lyngby, Denmark Hydrogen Generation Unit - U-35 Page 2 of 4
Clients Doc. No. I-FD-5290.00-2311-941-HTP-011

1. General Information

This specification covers the chemicals required within the HTAS battery limit of the
hydrogen plant.

2. Chemicals for BFW Preparation

2.1 Phosphate

Quality Commercial grade crystallised Na3PO4 * 12H2O suitable for boiler

feed water conditioning. Sample and certified specification to be
submitted to the boiler vendors for approval. The chemical must
not contain any sulphur or chlorine compounds.

Consumption Approximately 500 kg/year

2.2 Morpholine
Quality Commercial grade morpholine (tetrahydro-1,4 isoxazine) suitable
for boiler feed water conditioning. Sample and certified
specification to be submitted to the boiler vendors for approval.
The morpholine must not contain any sulphur or chlorine
compounds.

Consumption Approximately 25500 kg/year

3. Chemicals for HDS Section

3.1 DMDS
Quality Commercial grade DMDS, max. 1% DMS

Consumption
Start-up (presulphiding new catalyst) 900 kg
Normal operation, max. 950 kg/year

Information contained herein is confidential and must not be used by or conveyed to any third party without our written authorisation - Haldor Topsøe A/S
1 Petrobras - Petróleo Brasileiro S.A. No. 4309671 Rev. 0
Refinaria do Nordeste - RNEST Job S-01411
DK-2800 Lyngby, Denmark Hydrogen Generation Unit - U-35 Page 3 of 4
Clients Doc. No. I-FD-5290.00-2311-941-HTP-011

3.2 Methanol
Quality: as per IMPCA’s specification

Appearance Clear and free of suspended matter

Purity % WT on dry basis Min. 99.85

Acetone mg/kg Max. 30

Colour PT-CO Max. 5

Water % W/W Max. 0.1

Distillation range at 760 mm Hg Max. 1,0° C to include 64,6° ± 0,1°

Specific gravity 20°/20° 0.791-0.793

Potassium permanganate
Min. 60
Time test at 15° C, minutes
Ethanol mg/kg Max. 50
Chloride as Cl - mg/kg Max. 0.5

Sulphur mg/kg Max. 0.5

Hydrocarbons pass test

Carbonisable Substances
(Sulfuric Acid Wash Test) Max. 30
Ot-Co Scale
Acidity as
mg/kg Max. 30
Acetic acid
Total iron mg/kg Max. 0.1

Non volatile matter mg/1000 ml Max. 8

Consumption per:
Start-up (normal startup) 2200 kg
Start-up (with TK-250 presulphiding) 14000 kg
Shut-down 550 kg

Information contained herein is confidential and must not be used by or conveyed to any third party without our written authorisation - Haldor Topsøe A/S
1 Petrobras - Petróleo Brasileiro S.A. No. 4309671 Rev. 0
Refinaria do Nordeste - RNEST Job S-01411
DK-2800 Lyngby, Denmark Hydrogen Generation Unit - U-35 Page 4 of 4
Clients Doc. No. I-FD-5290.00-2311-941-HTP-011

4. Safety Instructions

The vendors of chemicals are to supply toxicological information and instructions

regarding safe handling and proper storage of the pure chemicals.

Information contained herein is confidential and must not be used by or conveyed to any third party without our written authorisation - Haldor Topsøe A/S