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Towards the 18th century, Lavoisier hypothesized the Oxygen Theory of Acid. This
was an unjustified generalization from the fact that many acids can be produced by
combination of non-metallic oxide with water e.g. H2SO3, H2CO3 and so contain
oxygen. The name oxygen is, in fact, from oxus(sour) and gennao(to produce).Davy’s
proof that chlorine is an element containing no oxygen and that hydrochloric acid is
produced by combination of hydrogen and chlorine finally disproved the oxygen
theory.
In early 19th century, it was gradually recognized that the element essential to an acid
is hydrogen. But this hydrogen in the compound must be capable of being replaced
by a metal with the formation of salt e.g.
At this time acid could be defined as a compound which turns blue litmus to red
and contains hydrogen which can be replaced directly or indirectly with a metal
By 1880, with the introduction of the ionic ideas, replaceable hydrogen is recognized
as hydrogen which is capable of ionizing to H+.
So acid could be defined as a compound which, in water yields hydrogen ions,
e.g.
Hence from the Ionic Theory point of view, acid can be regarded as a compound
which has a tendency to lose one or more proton (i.e. H+) per molecule. Conversely a
base can be regarded as a substance which has the tendency to gain one or more H+
per molecule or ion.
This relation can be expressed in the equation:
That is, for every acid, there exists a base, which is produced when the acid loses a
proton H+.
The acid which loses a H+ ion readily is a strong acid and the acid which loses a
proton with difficulty is a weak acid. It is obvious that must have a weak conjugate
base and vive versa e.g.:
An alkali is a substance which is soluble in water and produces the hydroxyl base,
OH- in solution.
Properties of Acids