Beruflich Dokumente
Kultur Dokumente
IRONMAKING COURSE
BLAST FURNACE
1
Blast Furnace
Ironmaking Course
Definition of Volume and Productivity
Ironmaking Course
Blast Furnace Facilities and Cross Section
Ironmaking Course
Blast Furnace Charging Systems
Ironmaking Course
Series 3-parallel
3-parallel hopper
hopper Bell
Bell
Series Hopper
Hopper Top,
Top, Central
CentralFeed
Feed BLT®
BLT®with
with Central
CentralFeed
Feed BLT®
BLT®with
with RRHH
Central Less Top® (CST)
Less Top® (CST)
Central Feed
Feed Rotating Receiving Hopper
Rotating Receiving Hopper (Sollac)
(Sollac)
Compact
Compact type
type Bell
Bell Less
Less
Parallel
Parallel Hopper
Hopper Top
Top Mini
Mini Bell
Bell Less
Less Top®
Top® Top®
Top®
Ironmaking Course
Advantages of the Bell Less Top® System:
1. Burden Distribution
• More flexibility
• More Stable Operation
3. Reduced Maintenance
• Increased Furnace Campaign Life
• Increased Furnace Availability
Ironmaking Course
Blast Furnace Facilities
Body of the Furnace
Ironmaking Course
Blast Furnace Facilities
Body of the Furnace
The furnace can be charged with iron ore lumps, pellets, and/or sinter; coke and flux.
These are carried to the top of the furnace with skips or belt conveyors, and are
distributed, (not tipped) into the furnace.
At the same time, preheated air (around 1250°C) is injected through the tuyeres,
which are nozzles at the bottom of the furnace.
The coke is partially burned by the injected hot air both to produce heat, and to
generate carbon monoxide (CO). Since coke is relatively expensive, some furnaces
inject coal, tar, natural gas or oil along with the air as supplemental fuels to reduce
coke usage.
The carbon monoxide travels upward through the shaft, and removes oxygen from the
iron ores on their way down, leaving metallic iron. By the time the charge reaches the
base of the furnace, the heat generated there melts the iron. The resulting molten “hot
metal” is tapped at regular intervals by opening the “tap hole” in the bottom of the
furnace so that it can flow out.
The fluxes combine with impurities in the coke and ore to form the slag, which floats
on the hot metal and is removed through the “granulation system” (another auxiliary
equipment).
The hot metal from the furnace is collected in specially-constructed railway
containers, called “torpedo cars”. The torpedo cars carry the molten iron to the
steelmaking furnace. Ironmaking Course
Blast Furnace Operation
Blast Furnace Operation
Blast furnaces are operated continuously without shutdown for years (nowadays
around 20 years) or more. If the furnace were allowed to cool, thermal stresses can
cause damage to the refractory bricks.
Eventually, the refractory bricks in the furnace will wear away, and at that point
the furnace is emptied and shut down so that it can be relined with new bricks. The
period between shutdowns is referred to as a “campaign”.
Hot metal taken directly from the blast furnace contains about 94,5% of Fe, 4 -
4.5% carbon, as well as a number of other elements. This is referred to as “pig
iron” and is the mainl raw material to be converted to steel by refining in the
steelmaking process, which reduces the carbon content and removes other
impurities like (P, S , Si) to make stronger and more workable and useful product
(=steel).
Ironmaking Course
Behaviour of Different Elements in the BF Process
GAS
GAS
GAS
GAS
Fe3O4 Mn3O4
FeO MnO
SLAG
FeO MnO P2O5 K2O SiO2 CaO Al2O3
Ironmaking Course
Blast Furnace Slag
Metals are generally extracted from ores which are Typical Slag Composition
always associated with impurities, mainly oxides,
called gangue. Typical Range
During the extraction of the metal, the gangue is CaO 40% 34-42%
removed, by addition of flux, and form the slag, an
homogeneous melt (solution) of oxides, which is MgO 10% 6-12%
insoluble in the metal. SiO2 36% 28-38%
Blast furnace slag is formed from the acidic gangue Al2O3 10% 8-20%
of the metallic burden, ashes of the coke and Total 96% 96%
auxiliary injected fuels and basics fluxes as
limestone and/or dolomite.
Four major components amount to about 96% of the Definitions of Basicity
slag (CaO, SiO2, Al2O3 and MgO)
During the process, firstly a primary slag is formed B2 CaO/SiO2
during melt process and before the solution of the B3 (CaO+MgO)/SiO2
coke ash components into the slag.
(CaO+MgO)/
B4
After the the primary slag progress to a final slag. (SiO2+Al2O3)
Ironmaking Course
Blast Furnace Cross Section:
Internal view
Raw
Materials
COUNTERCURRENT Exhaustion
PROCESS Gas
Coke
Ore
Granular
Zone
Coesive
Zone
GOOD Dripping
Zone
PERMEABILITY IN
THE BED IS Tuyere
ESSENTIAL!!! Tap
Hole
Slag
Pig Iron
Hearth
Ironmaking Course
Solid Move Down and Gas
Come Up Inside the Blast
Furnace GRANULAR ZONE
ORE LAYER
GAS SOLID
hot gases cross the bed burden top charged is COKE LAYER
of coke and ore, heating heated
them and accomplish the TEMP. BEGIN
MELTING
chemical reactions of the
process. iron oxide reduction
reactions are started. COESIVE
LAYER
TEMP.
combustion of coke (C) MELTING
with pre-heated air (O2) the reduced iron oxides
produces energy to are melted. FLUXO
COKE DE GÁS SOFTENING
burden heating and & MELTING
WINDOW
reduction. ZONE
pig iron and slag are
settled in the hearth COKE
COMBUSTION
and separated by
pre-heated air (1100°C) density, from where SLAG
is injected into tuyeres. they are tapping. METAL
Ironmaking Course
Companhia
Vale do Rio Doce
IRONMAKING COURSE
18
Coke Production
Ironmaking Course
Coke Oven View
Coke Guide
Charging Car
Coke Ovem View
Drawing Machine
Ironmaking Course
Coke Oven Operations
Discharge
Ironmaking Course
Coke Quality Evaluation
Size Distribution
Tumble Index
CO2 Reactivity
Chemical Analysis
Ironmaking Course
Preparation of the blast furnace
burden
Lump ores:
The lump ore are naturally mined ores that are crushed and screened to a
certain grain size before their use. However, as a result of preparation and
enrichment processes in the iron ore mines to increase the Fe content, very
fine-grained ores are generated which have to undergo agglomeration before
used in blast furnace. This is done by means of pelletizing and sintering.
Ironmaking Course
Preparation of the blast furnace
burden
Components of the charge to a blast furnace:
Pellets:
Pelletizing involves the forming of ore fines (pellet feed) and concentrates with grain
sizes of well under 1 mm into pellets measuring around 10 to 15 mm in diameter. To
do this, the ore mix is moistened and a binding agent added. The "green" pellets are
then formed in rotating drums or on rotary discs . These green pellets are dried and
indurated at temperatures of more than 1000 °C. This can take place in shaft or
rotary furnaces or on a travelling grate. Pellet plants are generally located at the iron
ore producers.
Sinter:
The sintering is performed at sintering plants, measuring more than 4 m in width and
over 100 m in length. Sintering involves charging a mix of ore fines together with
coke breeze, fluxes, in-plant returns and return fines, and igniting the coke breeze
contents in the surface by means of gas flames in an ignition furnace. A stream of
gas or air is drawn from top to bottom through the mix. A flame front passes through
the thick layer over the strand length and agglomerates the mix into coarse lumps of
ore. Normally, sintering plants are located on the works sites of the steel producers.
Ironmaking Course
Preparation of the blast furnace
burden
Fluxes:
When metal is smelted, the metal is separated from its impurities by melting,
with the impurities forming a molten slag on top of the metal. Many of the
impurities associated with iron ore are difficult to melt, and so they will not
form a proper slag easily, which retards the smelting process.
To make these impurities easier to melt, fluxes are added Limestone (CaCO3)
or dolomite ((Ca,Mg)CO3) are two typical fluxes used in blast furnaces.
When a large amount of sulfur needs to be removed from the furnace charge,
limestone is the preferred flux. Limestone is also a better flux to use if slag
from the blast furnace is to be used as a raw material for cement manufacture.
An important criterion for flux selection is availability and cost, and dolomite is
often more readily available and less expensive than limestone.by gas chemical
reactions
Ironmaking Course
Preparation of the blast furnace
burden
All the iron ore charged contain oxygen, which has to be removed through
reduction in the blast furnace process. To do this, carbon is used.
The most important source of carbon is metallurgical coke, which nowadays is
produced in modern, environmentally friendly coking plants. The coke ovens,
are heated by the coking coal in coking chambers, closed off from the outside
air, in the course of which the volatile constituents such as coke oven gas, tar,
benzol, hydrogen sulphide and ammonia are expelled, collected and recycled
for other uses.
Coke:
Ironmaking Course
Carbon Consumption in the Blast Furnace
(Thyssen Stahl AG, Germany)
CARBON
FUNCTION CONSUMPTION (%)
(kg/t HM)
Ironmaking Course
Main Mechanism of Fines Generation on
Ironmaking
MECHANICAL STRENGTH
Related to amount of fines generated by mechanical force
(handling)
DECREPITATION
Related to amount of fines generated by thermal shock
Ironmaking Course
PROPERTIES OF IRON ORE AND METALLURGICAL COAL AND COKE
IRON
IRON ORE
ORE COAL
COAL // COKE
COKE
••Chemical ••Chemical
Chemicalcomposition:
composition:fixed
fixedC,
C,
Chemicalcomposition:
composition:Fe,
Fe,SiO2,
SiO2,
Chemical
Chemical Al2O3, ashes,
ashes,S,
S,PPand
andalkalis
alkalis
Al2O3,Mn,
Mn,S,S,P,
P,Alkalis
Alkalis
Properties
Properties ••Loss ••Macerals:
Macerals:Volatile
Volatilematter
matter
Lossof
ofIgnition
Ignition(LOI)
(LOI)
••Moisture ••Replacement ratio
Replacement ratio
Moisture
••Moisture
Moisture
••Size ••Size
Sizedistribution
distribution
Sizedistribution
distribution
••Average ••Mean
Meansize
size
Averagemean
meansize
size
Physical
Physical ••Porosity ••Bulk density
Bulk density
Porosity
Properties
Properties ••Mechanical ••Porosity
Porosity
Mechanicalstrength
strength
••Mechanical
Mechanicalstrength
strength
••Mineralogical
Mineralogicalcomposition
composition
••Microstructure ••Combustibility
Combustibility
Microstructure
••Crystal ••Mineralogical
Mineralogicalcomposition
composition
Metallurgical
Metallurgical Crystalsize
size
••Morphology ••Microstructure
Microstructure
And Morphology
And Thermal
Thermal ••Softening ••Crystal
Crystalsize
size
Properties Softeningand
andmelting
meltingproperties
properties
Properties ••Reduction ••Morphology
Morphology
Reduction disintegration
disintegration
properties ••Coke
CokeStrength
Strengthafter
afterReaction
Reaction
properties
••Reactivity
Reactivity
Ironmaking Course
HIGH PRODUCTIVITY ON BLAST FURNACE
MAIN
MAIN DRIVER:
DRIVER: HIGHER
HIGHER PERMEABILITY
PERMEABILITY
COKE
COKE // COAL
COAL PROPERTIES
PROPERTIES TO
TO GUARANTEE
GUARANTEE
HIGH
HIGHBLAST
BLAST FURNACE
FURNACEPERMEABILITY
PERMEABILITY
•• Physical
PhysicalProperties
Propertiesof ofthe
theCoke
Cokeand
andCoal
Coal
•• Narrow size distribution range
Narrow size distribution range
•• High
Highmechanical
mechanicalstrength.
strength.
•• Lower
Lower blast momentumin
blast momentum inraceway
raceway HIGH
HIGH
•• Lower
Lower volatile mattercoal
volatile matter coalinjection
injection
•• Metallurgical properties
Metallurgical properties
•• High
HighCoke
CokeStrength
Strength after
afterReaction
Reaction(CSR)
(CSR) PERMEABILITY
PERMEABILITY
•• Low ash content to promote lower slag
Low ash content to promote lower slag rate rate
AND
AND
PRODUCTIVITY
PRODUCTIVITY
BURDEN
BURDEN(Iron (IronOre)
Ore)PROPERTIES
PROPERTIES TO TO GUARANTEE
GUARANTEE
HIGHER BLAST FURNACE
HIGHER BLAST FURNACE PERMEABILITYPERMEABILITY BLAST
BLAST
•• Physical
PhysicalProperties
Propertiesof ofthe
theBurden
Burden
•• Narrow
Narrow size
size distribution
distribution range
range FURNACE
FURNACE
•• Good
Good mechanical strength and
mechanical strength and low
low fine
fine
•• Metallurgical properties
Metallurgical properties
•• Low
Low swelling
swelling
•• Good
Good softening
softening and
and melting
melting properties
properties
•• Low
Low reduction disintegration properties
reduction disintegration properties
•• Lower
Lower gangue to
gangue to decrease
decrease the
the slag
slag rate
rate
•• Lower
Lower lump
lump ore
ore rate;
rate; higher
higher pellet
pellet and
and sinter
sinter
Ironmaking Course
GOOD HOT METAL QUALITY AND LOW COST
MAIN
MAIN DRIVER:
DRIVER: LOWER
LOWER CONSUMPTION
CONSUMPTION AND
AND GOOD
GOOD CHEMICAL
CHEMICAL COMPOSITION
COMPOSITION
COKE
COKE AND
AND COAL
COAL PROPERTIES
PROPERTIESFOR
FOR GOOD
GOOD
QUALITY
QUALITY AND LOW PRODUCTION COST
AND LOW PRODUCTION COST
Physical
PhysicalStability
Stability
•• High
Highmechanical
mechanicalstrength
strengthandandhigh
highyield.
yield.
•• Metallurgical properties
Metallurgical properties
•• High
HIGH
HIGH HOT
HOT
HighCoke
CokeReactivity
Reactivity(CRI)
(CRI)
•• High
High replacement ratioof
replacement ratio ofthe
thecoal
coalinjection.
injection.
•• Low ash, P, and S content.
Low ash, P, and S content. METAL
METAL
•• High
HighInjection
Injectionrate
rate(PCI)
(PCI)
QUALITY
QUALITY
AND
AND LOW
LOW
METALLIC
METALLIC BURDEN
BURDEN PROPERTIES
PROPERTIES FOR
FOR GOOD
GOOD PRODUCTION
PRODUCTION
QUALITY AND LOW PRODUCTION COST
QUALITY AND LOW PRODUCTION COST
•• Physical
PhysicalProperties
Propertiesof ofthe
theBurden
Burden
COST
COST
•• Low
Lowfines
finesgenerated
generatedand
andhigh
highyield
yield
•• Metallurgical properties
Metallurgical properties
•• Low
Lowreduction
reductiondisintegration
disintegrationproperties
properties
•• Low S and
Low S and P P
•• Lower
Lower gangue,
gangue, totodecrease
decreasethe
theslag
slagrate
rate
•• Higher lump ore rate
Higher lump ore rate
**AA method
methodtotoproduce
producehigh
highreactivity
reactivityand
andstrength
strengthcoke
cokeisisbeing
beinginvestigating
investigatingby
byuse
useCa
Caas
ascatalyze
catalyzeelements
elements
Ironmaking Course
Lump Ore and Metallic Burden Evaluation
Chemical analysis
Classify ores into several grades
Decrepitation Test
Sample degradation during heating on the blast furnace
Blast Furnace
1400 Slag
a
1500 Liquid Metal
Ironmaking Course
REQUIRED PROPERTIES FOR BLAST FURNACE
METALLIC CHARGE
BLAST FURNACE INSIDE Requered Properties
Size Distribution
Resistance
and
Resistance Resistance Resistance
Pre-heating adherent
Granular
Reduction fines
Decrepitation
RDI Swelling CSR/CSI
RDI
Reduticibility Reactivity
Softening and
Softening Melting
High Temperature Properties
and Melting Gaseous Flow
Redistribution
Dripping
Dripping
Carburization
Ironmaking Course
INITIAL QUESTIONS
Ironmaking Course
Blast Furnace Cross PERMEABLE REGIONS
Section: Emphasis to ORE
Softening & Melting COKE
COHESIVE ZONE
Zone FUSING IRON
AND SLAG GAS
LINES
PERMEABLE
High heat consumption region, COKE SLITS
where is accomplished:
The greatest part of iron oxides
ACTIVE
reduction LOOSE-
Metal and slag melting PACKED
Ironmaking Course
Importance of Softening & Melting Zone
Pressure drop in
the granular zone
HIGH HIGH PCI
PRODUCTIVITY OPERATION
Ironmaking Course
TEST SUMMARY
∆ Temperature (Te-Ts)
Reduction Degree at Ts Rs
Ironmaking Course
CORRELATION BETWEEN INDEXES AND THE BLAST FURNACE
RI
Reduction index at 900ºC
Ts200
Start of pressure drop
over 200mmH2O
R1000
Reduction index at 1000ºC
∆T
R1100 Te200-Ts200
Reduction index at 1100oC
Te200
End of pressure drop
over 200mmH2O
R1200
Reduction index at 1200oC Td
Start of dripping
of metal or slag
S(S’) value
Integration of pressure drop
with respect to temperature(or time)
Ironmaking Course
INDUSTRIAL TESTING EQUIPMENT - VALE
Drop Measurement
Metallic
Burden (70mm)
Coke (20mm)
Ironmaking Course
TYPICAL RESULTS
Softening Melting
100,0 6000
90,0
5000
80,0 Shrinkage
60,0
50,0 3000
40,0
2000
30,0 Ts: 1243°C
Te: 1473°C
20,0 S: 59.51 kg.°C/cm2
1000
dPmax: 5419 mmH2O
10,0
Cohesive Zone
0,0 0
800 900 1000 1100 1200 1300 1400 1500 1600
Temperature (°C)
Ironmaking Course
Vale’s Technical Support to Customers
Technical Methodology
Behaviour in
agglomeration and
metallurgic processes
Characteristics and
product quality
Ore dressing
behaviour
Geological and
mineralization
processes
Ironmaking Course
Vale’s Technical Support to Customers
Physical Simulation (1)
Lump
Steel Mills
Pig iron
Sinter Sinter
feed Steel
Sinter Plant
Pellets
Pellet BF BOF
feed
Pelletizing
Parameters
Sinteriza
Sintering ção
pot
Piloto
Characterization
Pilot Plants
Pelotização
Pelletizing
Piloto pot
Metallurgical tests Softening
Forno and melting &
de Amolecimento
furnace
Chemical Analysis
Ironmaking Course
Vale’s Technical Support to Customers
Numerical Simulation (1)
Global thermal balance
Rolling
Sintering
Hot Metal
BOF
Steel
BF
Pelletizin
Casting
DRI
LUMP Direct reduction FEA
Ironmaking Course
Vale’s Technical Support to Customers
Numerical Simulation (2)
Blast Furnace Fluid-dynamic Model
(CFD)
CFD Model considers:
¾ Fluid and solid flows
¾ Burden distribution
¾ Softening and melting of burden components
¾ Void fraction inside furnace
¾ Temperature dependence of kinetic parameters
¾ Heat and mass balances
Outputs:
¾ Different operational practices
¾ Productivity
¾ Coke rate
¾ Position and thickness of cohesive zone
¾ Operation with high PCI
Environmental aspects
63% Sínter
¾ 27% Pe lotas
10% Granulado
Ironmaking Course
Vale’s Technical Support to Customers
Numerical Simulation (3)
Blast Furnace Fluid-dynamic Model
(CFD)
Increase production ?
increase PCI ?
Need for
model/operator
interaction
CFD Operator
Ironmaking Course
Vale’s Technical Support to Customers
Numerical Simulation (4)
Ironmaking Course
Vale’s Technical Support to Customers
Physical and Numerical Simulation
Steelmaking chain
Lump
PIG IRON STEEL
Sinter
SINTERING
Pellets
Sinter Feed
BF
BOF
Sintering Neural Optimization of iron ore Computational Fluid Dynamic Model BOF model
Network Model mix (linear programming)
BF inner state predictions
Numerical simulation
PHYSICAL SIMULATION
Ironmaking Course
Value in Use (VIU)
Concept (1)
Generation of Models
Organize
and Process Data Base Structure
INFO and classification
Data Mining
Operational
Data INFOrmation Generation
(Data Base)
Client
Technical Visits
Situation
Ironmaking Course
Thanks for your attention!!!
Ironmaking Course