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SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND COMPANY / UNDERTAKING

PREPARATION NAME : ZL-60C

USE : Fluorescent Penetrant

COMPANY IDENTIFICATION : MAGNAFLUX® a Div of ITW LTD


FARADAY RD, SOUTH DORCAN IND EST,
SWINDON, ENGLAND, SN3 5HE

EMERGENCY TELEPHONE : 01793 524566

2. COMPOSITION INFORMATION ON INGREDIENTS

INGREDIENT NAME EC No CAS No % W/W SYMBOL R PHRASES *

DISTILLATES (PETROLEUM), 265-149-8 64742-47-8 50 - 75 % Xn R65, R66


HYDROTREATED LIGHT
ALCOHOL ALKOXYLATE - 111905-54-5 < 20 % Xi, N R41, R51/53
ALCOHOL ETHOXYLATE - 68131-40-8 < 15 % Xi, N R36/38, R51/53
TERPINEOL 232-268-1 08000-41-7 <5% Xi R38

Other Ingredients : .Fluorescent dyes, Soyabean oil, Phosphate ester

Note : Risk phrases in this section apply only to raw materials, not necessarily to finished products. See section 15.
*See Section 16 for risk phrase text

3. HAZARDS IDENTIFICATION

Risk of serious damage to eyes.


Harmful : may cause lung damage if swallowed. Repeated exposure may cause skin dryness or
cracking.
Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment.
Contaminated surfaces may be slippery.

4. FIRST AID

EYE CONTACT ² Flush eyes with large amounts of water for at least 10 minutes and seek
immediate medical attention.

SKIN CONTACT ² Flush with water, use soap if available. Contaminated clothing
should be washed before re-use.

INHALATION ² Inhalation of sufficient vapour to cause ill effects unlikely.


Remove to fresh air. Keep at rest. Call for medical attention if symptoms
occur.

INGESTION ² Do not induce vomiting. Seek prompt medical attention.

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SAFETY DATA SHEET

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA ² Carbon dioxide, Foam, Dry chemical, Water fog or spray. Do not use
water jet.

SPECIAL FIRE FIGHTING ² Evacuate immediate area. Shut off “fuel” to fire. If possible keep
PROCEDURES unaffected containers cool with water spray. Heated drums may
burst violently.

HAZARDOUS DECOMPOSITION
PRODUCTS ² Smoke, soot, oxides of carbon on combustion. Burning vapour may
give off toxic fumes.

PROTECTIVE EQUIPMENT ² Self contained breathing apparatus and suitable protective clothing
should be worn in fire fighting conditions.

6. ACCIDENTAL RELEASE MEASURES

SPILL CLEAN UP METHODS ² Eliminate sources of ignition. Contain spilled liquid with sand or
earth. Mop up or absorb onto an inert absorbent. Large spills should
be pumped into containers pending disposal.

ENVIRONMENTAL
PRECAUTIONS ² Prevent liquid from entering drains sewers and watercourses. Notify
the Environment Agency or water authorities if a major spillage
occurs. Prevent chemical contaminating soil.

PERSONAL PRECAUTIONS ² Wear suitable protective clothing to protect from splashes.

7. HANDLING & STORAGE

USAGE PRECAUTIONS ² Keep away from sources of ignition. Wear suitable protective
clothing such as chemical resistant gloves, apron & goggles / face
mask to protect from splashes. Avoid contact with the skin and eyes.
Do not breathe product spray or mist. Ensure adequate ventilation
when in use.

STORAGE PRECAUTIONS ² Store in a cool dry area away from heat and sources of ignition.
Recommended storage temperature ² 10°C to 30°C.
Keep containers out of direct sunlight. Keep containers closed when
not in use. Rotate stock and check regularly for leakers.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Occupational exposure figures have been set for some of the components of this preparation based on
EH-40 (latest revision) or manufacturers recommendation.
TID = Total inhalable dust. MRL = Manufacturers recommended limit OES = Occupational exposure standard

INGREDIENT NAME STD LT Exp (8 Hrs) ST Exp (15 Min)


3 3
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT OES 5 mg/m (Oil Mist) 10 mg/m (Oil Mist)

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SAFETY DATA SHEET

WORKPLACE EXPOSURE

Concentrations of product mists and sprays in the working atmosphere must be kept as low as is
reasonably practicable. Exposure should be minimised by the use of appropriate containment,
engineering control and ventilation measures. Where this is not possible, personal protective
equipment should be worn as indicated below where appropriate.

Respiratory protection ² Use a respirator with appropriate canister type filter cartridge if
spraying in confined or unventilated area’s.

Hand protection ² Use chemical resistant gloves recommended by glove manufacturer


as being suitable for kerosenes, if hand exposure is unavoidable.
Marigold blue nitrile, Long Nitrosolve or Green Supersolve
(Breakthrough time 480 minutes, permeation rate 96 mg m2 after
breakthrough, degradation level 2) are suitable, although other types
may be more suitable in other circumstances.

Eye protection ² Wear goggles/face mask to protect eyes from splashes.

Skin protection ² Wear chemical resistant overalls if skin contact is likely.

9. PHYSICAL & CHEMICAL PROPERTIES

APPEARANCE : YELLOW/GREEN LIQUID


ODOUR : MILD PINE
pH : NEUTRAL
BOILING POINT : 230°C
MELTING POINT : N/A
FLASH POINT (PMCC) : 93°C (Minimum)
FLAMMABILITY (Limits in Air) : 1.0% TO 6% (VOL %)
AUTOFLAMMABILITY : > 200°C
EXPLOSIVE PROPERTIES : N/A
OXIDISING PROPERTIES : N/A
VAPOUR PRESSURE : < 0.5 mm Hg @ 20°C
VAPOUR DENSITY (Air = 1) : > 1
RELATIVE DENSITY : 0.88 g/ml
SOLUBILITY IN WATER : EMULSIFIES
PARTITION COEFFICIENT : N/D
EVAPORATION RATE (BuAc = 100) : < 0.1
VISCOSITY (ASTM D-445) : 7 cSt @ 38°C

N/A = Not Applicable. N/D = Not Determined. Properties relate to the bulk liquid only unless otherwise stated.

10. STABILITY & REACTIVITY

STABILITY ² Stable under normal conditions of use and


applications.

HAZARDOUS POLYMERISATION ² None.

MATERIALS & CONDITIONS TO AVOID ² Strong oxidising agents.

HAZARDOUS DECOMPOSITION PRODUCTS ² None under normal conditions of storage and use.
Smoke, soot, oxides of Carbon on combustion.

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SAFETY DATA SHEET

11. TOXICOLOGICAL INFORMATION

INHALATION ² Inhalation of high product concentrations when spraying can be irritating to


the respiratory tract. No evidence of sensitisation potential.

INGESTION ² Not a likely route of entry, however, ingestion may cause irritation of the
mouth, throat and digestive tract.
Small amounts of product aspirated into the respiratory system
during ingestion or from vomiting may cause bronchopneumonia or
pulmonary edema.

EYE CONTACT ² Severely irritating to eyes.

SKIN CONTACT ² Frequent or prolonged contact with the product may produce irritation
and /or skin dryness and cracking. No evidence of sensitisation potential.

CHRONIC TOXICITY ² Ingredients in this preparation are not classified as carcinogenic or


mutagenic according to the CHIP 3 regulations.

12. ECOLOGICAL INFORMATION

Based on data for component materials.

This product is miscible with water.


The product is predicted to have a low / medium potential to bioaccumulate.
The product is considered to be a moderate toxic hazard to aquatic organisms.
It is expected to be moderately toxic to mammalian wildlife.
Has the potential to biodegrade at low concentrations.

13. DISPOSAL

Seek the advice of an approved waste disposal contractor for disposal at a licensed facility in
accordance with local, state or national legislation.

The Special Waste Regulations 1996 apply to the disposal of this material. Other provisions are the
Waste Framework Directive (75/442/EEC), the Hazardous Waste Directive (91/689/EEC), the
Environmental Protection Act 1990 and the Environment Act 1995.

14. TRANSPORT INFORMATION

UN Number 3082
UN Class 9, MISCELLANEOUS DANGEROUS SUBSTANCES AND ARTICLES Packing Group III
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
IMO / IMDG UN 3082, 9
IATA / ICAO UN 3082, 9
RID / ADR UN 3082, 9

Carriage

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SAFETY DATA SHEET

15. REGULATORY INFORMATION

LABEL FOR SUPPLY

Harmful Dangerous for the


environment

RISK PHRASES R41 Risk of serious damage to eyes.


R51/53 Toxic to aquatic organisms, may cause long term adverse effects in the
aquatic environment.
R65 Harmful : may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.

SAFETY PHRASES
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S39 Wear eye/face protection.
S61 Avoid release to the environment. Refer to
special instructions / safety data sheet.
S62 If swallowed do not induce vomiting: seek medical advice immediately
and show this container or label.

Regulatory References

¹ Health & Safety at Work Act 1974


¹ Control of Substances Hazardous to Health Regulations 1988
¹ Occupational Exposure Limits EH 40
¹ Chemical (Hazard Information & Packaging for Supply) Regulations 2002. (CHIP 3)
¹ EC Directive 91/155/EEC
¹ Dangerous Preparations Directive 1999/45/EC

16. OTHER INFORMATION

R Phrases in full
R41 Risk of serious damage to eyes.
R36 Irritating to eyes.
R38 Irritating to skin.
R51/53 Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment.
R65 Harmful : may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking..

Revision Date : 10/04/2008 Rev : 05 Replaces Rev 04 (01/10/04)

Revision Summary : SDS updated in compliance with the Chemical (Hazard Information & Packaging
for Supply) Regulations 2002. (CHIP 3)

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