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Name: Anas Alam Faizli Student ID No.

CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
SEPTEMBER SEMESTER 2009

SAFETY, HEALTH AND ENVIRONMENTAL ISSUE MANAGEMENT – EMSH5103

ASSIGNMENT (45%)

LECTURER

IR MURALINDRAN KOVINDASAMY

STUDENT

ANAS BIN ALAM FAIZLI


 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
SEPTEMBER SEMESTER 2009

SAFETY, HEALTH AND ENVIRONMENTAL MANAGEMENT – EMSH5103

ASSIGNMENT (45%)

INSTRUCTIONS: ANSWER ALL QUESTIONS.

PART A

Question 1
Calculate the incident rate (IR) for a company with 200 employees, working 45 hours/week
and has a recorded injuries of 10. Use OSHA constant of 200,000 man-hours.
[20 marks]
Incident rates (IR) are a metric used to benchmark and gauge the safety performance of a
company. It is also a trending number based on the injury if you had worked 200,000
hours as used by OSHA as benchmark. The calculation is based from OSHA 300. OSHA
requires that an OSHA 300 log be completed and posted every year. Why 200,000 hours?
Simply put, that is the hour worked by 100 employees, averaging 40 hours/week over a 50
weeks span (two weeks taken away for holidays).
For this calculation however, we will assume that the weeks are not taken away and the
company worked for 52 weeks/year.
In order to calculate the IR, we need to have the Total Number of Hours Work, :-
Total Man-Hours = Total No of Employees x Working hours per week x 52
= 200 x 45 x 52
= 468,000 Man-Hours

Incident Rate (IR) = Recordable Injuries x OSHA constant


------------------------------------------------
Total Man-Hours

Incident Rate (IR) = 10 x 200,000


----------------
468,000

= 4.2735


 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
Question 2
Environmental Impact Assessment is vital for major projects list five (5) objectives and
briefly explains each of the objectives.
[20 marks]
Following the wash away of Bota Bridge in 1967 and the flooding of Kuala Lumpur in
1970, various studies and suggestions have been moved forward to address
environmental issues in Malaysia until in 1986 the Environmental Impact Assessment
(EIA) has became mandatory in Malaysia with the insertion of section 34(A) in the
Malaysian “Environmental Quality Act”.
The objectives of the Environmental Impact Assessments are as follows:

1) To ensure environmental factors are considered in the decision making process – this
is essential where EIA will play as a planning mechanism to prevent environmental
problems from occurring by having a detailed assessment of the environmental effects
and impacts due to the project implementation. This is critical to avoid serious and
irreversible damage to environment. Simply put it is to examine and select the best
from the available project options.
2) To ensure possible adverse environmental impacts are identified, avoided or
minimised and also predict significant residual environment impacts – It will help
ensure that potential problem are foreseen and addressed during early stage in the
project planning and design which will avoid costly mistakes in project implementation;
during or after and includes remedial action to make the action environmentally
acceptable. This also assists in identifying key impacts and measure for mitigation for
environmental damages.
3) To provide proper outline for project implementation which relates to environment –
this involves identification, assessment and method statement, measures and
standard which shall be included in all phases of the project from design to
implementation, testing and commissioning. This will determine the significant residual
environment impacts predicted.
4) To protect the human health and safety – EIA will ensure all aspects of human health
and safety is taken into consideration on how the project will directly impact the quality


 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
of life and the capacity of the site can accept the environmental changes to be taken
place. This will minimize or mitigate and enhance social aspects to the community
which will also identify the cost and benefits of the project to the community.
5) To include and specify environmental monitoring and audit requirements – where the
implementation and the effectiveness of the environmental protection control
measures is adopted. This will provide continuous quality check on the environmental
controls implementation.
6) As an information to the public about the project proposal – which helps describe the
proposed project and other relevant works which is a public concerns.

Question 3
The annual losses from accidents in a small construction firm are expected to be $25,000
per year. These estimates only include direct losses. An investment of $35,000 in safety
countermeasures will reduce these direct annual loss values to $10,000 per year. The
projected life for this investment is five years at an estimated annual interest rate of 15%.
The present worth of the annual savings from the safety countermeasures is;
[20 marks]

Net present value (NPV) can be used for this calculations, it is define as the total present
value (PV) of a time series of cash flows. It is a standard method using time value of
money to appraise future value of money. Each cash inflow/outflow is discounted back to
PV. Then they are totalled together, therefore NPV is the sum of all , where
t: the time of the cash flow
i: the discount rate (rate of return)
Rt: the net cash flow (amount of cash, inflow minus outflow) at time t
Using numbers from the question:
Number of Years = 5
Investment = $35,000
Annual Loss Value Reduction / Annual Savings = $15,000,
Interest Rate / Discount Factor = 15%


 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
Years Investment / Saving Cash Flow (real Discount factor Discounted Cash
(n) time ) (DF) = 15% Flow
0 Safety countermeasures -35000 1 -35000
initial investment
1 Annual loss saving 15000 0.8696 13043
2 Annual loss saving 15000 0.7561 11342
3 Annual loss saving 15000 0.6575 9863
4 Annual loss saving 15000 0.5718 8576
5 Annual loss saving 15000 0.4972 7458
TOTAL ( NPV ANNUAL 50,282
LOSS SAVING )

Present value of annual loss saving:


Year 1 = $13,043
Year 2 = $11,342
Year 3 = $9,863
Year 4 = $8,576
Year 5 = $7,458
Present value of total annual loss saving:
= NPV Annual loss saving
= Total Discounted Cash Flow of Annual Loss Saving (Year 1 to Year 5)
= $50,282


 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
PART B
Question 1
Develop an Emergency Response Plan (ERP) for hazardous chemical transported by
tankers from manufacturing facility to a processing plant. This truck will be using public
roads during its journey before reaching the destination. This ERP should consist of the
followings;
a) Objective of Emergency Response Plan
b) Emergency Response Team
c) Emergency Response Procedure
d) Spill Prevention and Precaution Measure
e) Emergency Response Communication Plan

[40 marks]

WARISAN ATX is a company that involves with highly hazardous chemical, i.e Acetone.
OSHA requires each employer to have a specific employee emergency response plan
(ERP). Thus, ERP is developed as below for the facility and the transportation of the said
material from the manufacturing facility to a processing plant via tanker using public roads.

EMERGENCY RESPONSE PLAN


NOTE: Companies should not attempt any hazardous waste operations unless employees
have been trained in accordance with the provisions of OSHA Standard 1910.120. Without
this training, the only option open to a company is evacuation and notification of
appropriate agencies capable of handling this type of situation.

OBJECTIVE
The goals of this emergency response plan are, in order of priority, to protect the lives and
health of Warisan ATX employees, and protect and minimize damage to company
property in the event of an emergency and guide the employees on the action plan for all
emergencies that might occur inside the manufacturing facility or during the transportation
of the hazardous acetone from the manufacturing facility to the processing plant.


 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
The objectives of this plan are:
· To evacuate and account for all employees, visitors and the public if occur outside;
· To contact local emergency service organizations;
· To assemble the company’s Emergency Response Team (ERT) for implementation of
the response plan;
· Preparation for, and identification and handling of chemical related accidents.
· Management of leaking or otherwise compromised tankers and chemicals.
· Emergency disposal of hazardous chemicals, and spill prevention measures.
· Contact pertinent regulatory agencies;
· Conduct search-and-rescue operations, turnoff utilities, control any hazardous chemical
spills or releases;
· Prevent further property damage through protective measures or by removing property;
· Perform cleanup and salvage as needed;
· Conduct post-incident critique and evaluation;
· File any applicable reports with regulatory agencies.
· To ensure company operations return to normal.
The procedure might not have cover every emergency situation that could occur, but
however it will provide guidelines to enable employees of Warisan ATX to react and
respond to the majority of the emergencies. The employees could only handle minimal
emergency situation and everything above the appropriate level will be escalated to the
ERP team and then to the local authority.

SCOPE
· Define the emergency response team
· Elaborate on emergency response procedures
· Establish the emergency response communication plan
· Characterize spill prevention and precaution measure
· Fire fighting in the event of an outbreak
· Handling and storage of Acetone
· Contain leakage and spills
· Protect human lives and property


 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
EMERGENCY RESPONSE TEAM
Responsibility
The Responsibility falls on the Warisan ATX HSE Manager, Rashid Aziz 012 743 5538
ERP Coordinator
· To be available 24 hours a day
· Will serve as a focal point and responsible for all emergencies respond issues.
Facility Management
· Evaluate the number and types of hazards expected based on past experience and
general knowledge to plan and develop Emergency Response Plan specifics;
· Provide training to all employees for their roles in all emergency plans;
· Conduct drills to practice response to emergency situations;
· Conduct an annual drill to practice confined-space rescue;
· All other activities necessary to the development and implementation of an effective
Emergency Response Plan;
· Make emergency response team assignments.
Maintenance Manager
· Maintain sufficient inventory of emergency response equipment;
· Ensure maintenance and inspection of emergency response equipment;
· Help train emergency response team members.
Logistic Manager
· Ensure tankers are fully inspected, serviced prior to transportation
· Ensure tankers to use dedicated and assigned public roads only
Dedicated ERT Team
· Assist in the training of emergency response teams;
· Assume active positions on the response teams.
Safety manager
· Provides assistance in developing and carrying out emergency response plans.
TRAINING
WARISAN ATX will train all employees on the procedures contained in this plan. New
employees will be trained upon hiring, and re-trained any time the employees
responsibilities under the plan change or whenever the plan changes.


 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 

The company will provide copies of all emergency response plans to be kept in employee
handbooks and operation manuals, and will post copies on employee bulletin boards.
The company also will designate and train a sufficient number of employees to assist in
the safe and orderly evacuation of employees and visitors. These employees will be
trained and re-trained as needed.
Training will cover:
· Emergency reporting;
· Evacuation routes;
· Alarm systems;
· Specific assigned duties.
· Crash course driving.
Periodic drills will be held to ensure that all employees know the appropriate action to take
in case of an emergency. The company will provide additional training and frequent drills
for employees with specific emergency-response duties; and invite local emergency
service units to participate in training whenever possible.

EMERGENCY RESPONSE PROCEDURES


Types of Emergency
• Acetone spills inside the manufacturing facility
• Acetone spills during offloading to tanker in the facility
• Acetone spills while transportation of the tankers
• Acetone spills during offloading to processing facility
• Road accidents during transportation of Acetone
• All above can consequence to outbreak of fire
Emergency Responds Communication Plan
INCIDENT REPORTING
Management Notification
If an emergency, or situation that could become an emergency, occurs, inform
management immediately through HSE department at extension 2300 or 03-45282300.
Razali Majid, ERP coordinator will maintain an up-to-date emergency notification list.


 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
Emergency Response Team Notification
ERP coordinator will contact each ERP team member via SMS. A group name has been
setup and one SMS will be distributed to each team member. ERP coordinator will also
calls each ERP team leader and team leader will contact each members.
Employee Notification
The alarm system, public address system, or direct supervisory contact can be used to
notify employees of emergency situations in the facility. Dial ext 1000 and press *, wait for
a tone and start the announcement. ERP coordinator will make the announcement if there
is a need.
External Notification
Call (911) to contact the local fire or police department, emergency medical service or
other emergency-response units. The Fire Department will come to evaluate the problem.
Contact Subang Jaya Medical Centre if someone is hurt and the Police if there is a need
for security. If the spill material exceeds the alarm level please contact Department of
Safety and Health (DOSH). 
Corporate Notification
Contact the Iriani Zulkifli 014 788 3390 ext 2500 of the public relations department if media
coverage of the situation is expected. Also, contact the corporate office as soon as
possible of property damages, theft, or cargo losses.
The following corporate officials are to be contacted:
Sheila Zulkifli ext 2290
Irma Shamsul ext 2487
EMERGENCY PROCEDURES
Spill Prevention and Precaution Measure
Incidental vs. Large Scale Spills
In terms of size, Warisan ATX has identified two levels of spills;
1. Incidental Spills
2. Large Scale Spills
Any leak, odor or spill that has been identified as an incidental spill can and will be
handled in house by our ERT using spill containment and personal protective equipment
that is currently available. If personal protective equipment above level "C" is required,

10 
 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
(refers to the PPE procedure: Warisan Atx/PPE/2009/32a) then the incident will no longer
be considered "incidental." Under the direction of the Warisan Atx ERP coordinator, a spill
no longer or not considered incidental will be referred to one or all of the following;
1. Fire Department Sentul Raya
2. Police Department Sentul Raya
3. DOSH Office in Jalan Tun Razak
Incidental Leaks, Releases and Spills
Incidental release or spill shall mean a small scale discharge, leak, release or spill that can
be absorbed, neutralized or otherwise controlled at the time of the incident by employees
of Warisan ATX. In order for the Hazardous Material discharge, leak, release or spill to be
considered incidental, there can be no potential health risks, potential for explosion or fire
and no risk of personal injury. In the event of an accident, explosion, fire, leak, release or
spill the first priority must be personal health and safety. The following is the
recommended practice that should be followed in the event of a hazardous material
incident;
1. Tell others in the area to evacuate
2. Evacuate the area or room
3. Contact ERP Coordinator ·
Give him as much information as possible:
1. Your name
2. Location of the incidents
3. What happened
4. Number of injuries
5. Acetone has vaporized or is in liquid condition
A. INCIDENTAL ACETONE LEAK or SPILL
1. You have a small chemical spill in the laboratory, inform ERP coordinator;
2. the name of the chemical or hazardous material involved, and how much leaked or
was spilled
3. if anyone is injured, and the extent of the injuries
4. whether or not personnel have evacuated the area/room
5. if the door to the facility or laboratory is closed

11 
 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
6. if the facility / laboratory is equipped with a fume hood
7. what is being done to mitigate the hazard
8. where you are calling from
B. LARGE SCALE CHEMICAL LEAK or SPILL
1. Notify personnel in the area that the spill has occurred and to evacuate
2. Leave the room immediately
3. Close the door to the laboratory as you leave
4. Contact the ERP coordinator
Inform the ERP Coordinator
1. your name
2. phone number from where you are calling
3. locationi where the incident has occurred
4. if there is or was an explosion or fire
5. how many people are injured
6. the extent of the injuries
7. what is being done for those injured
8. if the Acetone has vaporized or in liquid form
9. how much was spilled
10. has the material been contained
11. who is the name of the supervisor
C. PERSONAL INJURY CHEMICAL LEAK or SPILL
Small Incident (no ambulance required)
1. Immediately remove all clothing affected by spill
2. Flush the area for at least 15 minutes
3. Refer attached MSDS to determine additional first aid measures, if any
Eye Injury – Chemical
1. Immediately flush the eye for at least 15 minutes. Affected eye should be lower
than the uninjured eye
2. Contact HSE Department
Large Incident - Ambulance Required
1. Notify other personnel in the facility or laboratory

12 
 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
2. With Personal Protective Equipment (gloves etc.) remove all clothing. Chemicals
will pool in belts, pockets and shoes
3. Contact HSE Department
4. Flush the entire body, eye or face for at least 15 minutes or until the arrival of the
ERP team
D. EXPLOSION or FIRE
1. Notify occupants of the area or room
2. Evacuate the area, laboratory or room
3. Close the door to the room as you exit
4. Activate the building Fire Alarm
5. Contact the ERP Coordinator
Inform the ERP Coordinator
1. Your name
2. the number you are calling from
3. location where the fire is located
4. if there are any injuries
o how many
o the extent of injuries
5. cause of the fire
o chemical
o electrical
o gas
6. if there are additional laboratory hazards in the area or room
o flammable gases or liquids
o poisons
o radioactive or biological materials
If trained and the fire is small…
1. Select the appropriate fire extinguisher
2. Check the door to the room (if cool), open it
3. Extinguish the fire. After the extinguisher has been used, notify the HSE
Department

13 
 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
In general, these are the actions that can be taken while waiting for the ERP team
Accidental Release/Chemical Spills of Acetone
Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal
protective equipment. Isolate hazard area. Keep unnecessary and unprotected personnel
from entering. Contain and recover liquid when possible. Use non-sparking tools and
equipment. Collect liquid in an appropriate container or absorb with an inert material (e. g.,
vermiculite, dry sand, earth), and place in a chemical waste container. Do not use
combustible materials, such as saw dust. Do not flush to sewer! If a leak or spill has not
ignited, use water spray to disperse the vapors, to protect personnel attempting to stop
leak, and to flush spills away from exposures.
Fire Fighting
No employee shall fight a fire that is beyond the incipient stage (able to be put out with a
fire extinguisher), enter if the building is on fire to conduct search and rescue, or provide
advanced medical care and treatment. These situations must be left to emergency
services professionals, who have the necessary training, equipment and experience.
First Aid Measures
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is
difficult provide oxygen. Call HSE Department.
If ingestion, vomiting may occur spontaneously. Do not Induce. Keep head below hips to
prevent aspiration into lungs. Call HSE Department.
If skin contact, immediately flush skin with plenty of water for 15 minutes. Remove
contaminated clothing and shoe. Call HSE Department.
If eye contact, flush eyes with plenty of water for at least 15 minutes lifting upper and lower
eyelids occasionally. Call HSE Department.
Tanker/Transportation Accident
Transporter will immediately switch off engine and all electrical devices. Wait until vapor
hazard is removed. Do not let people to surround the area. Ensure that people are
informed of the danger and ask them to move away. Check for spills/leak that might occur
after the accident. Phone the Fire Department at 911 and also Warisan ATX HSE
Department. Do not start back the engine and all other electrical devices.

14 
 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
EVACUATION PROCEDURES
Emergency Control Points for Facility
Emergency Mustering Area
The Emergency Mustering Area will be at main mustering assembly hall in front of the
outside main entrance of the facility.
Emergency Control Post
The Emergency Post will be set up besides the mustering area.
Emergency Evacuation
After the senior manager on the scene determines that evacuation is necessary, the
evacuation alarm will be sounded, with instructions issued over the public address system.
The normal format of the Evacuation announcement is:

"Attention all employees! We have an emergency. This is not a drill. Please remain calm.
All employees shall leave their work places immediately. Proceed to assemble at
mustering area"

The production/maintenance supervisors will then lead and assists in the evacuation.

All employees will turn back their punch cards to able the production and maintenance
supervisors including the ERP team to ensure that all employees have left the facility.

Production/Maintenance Supervisors
· Lead employees from work areas when the evacuation alarm sounds;
· Assist any employees with disabilities;
· Escort employees to (Designated Assembly Area);
· Account for all employees upon reaching the designated assembly area;
· Notify human resources of any employee not accounted for;
· Ensure that employees stay in the assembly area.

MSDS for Acetone is attached for further understanding of the chemicals involved in this
facility.

15 
 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 

ACETONE

1. Product Identification
Synonyms: Dimethylketone; 2-propanone; dimethylketal
CAS No.: 67-64-1
Molecular Weight: 58.08
Chemical Formula: (CH3)2CO
Product Codes:
J.T. Baker: 5008, 5018, 5356, 5580, 5965, 5975, 9001, 9002, 9003, 9004, 9005, 9006,
9007, 9008, 9009, 9010, 9015, 9024, 9036, 9125, 9254, 9271, A134, V655
Mallinckrodt: 0018, 2432, 2435, 2437, 2438, 2440, 2443, 2850, H451, H580, H981

2. Composition/Information on Ingredients
Ingredient CAS No Percent Hazardous
--------------------------------------- ------------ ------------

Acetone 67-64-1 99 - 100% Yes

3. Hazards Identification
Emergency Overview
--------------------------
DANGER! EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPOR MAY
CAUSE FLASH FIRE. HARMFUL IF SWALLOWED OR INHALED. CAUSES
IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. AFFECTS

16 
 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
CENTRAL NERVOUS SYSTEM.

SAF-T-DATA(tm) Ratings (Provided here for your convenience)


-----------------------------------------------------------------------------------------------------------
Health Rating: 2 - Moderate
Flammability Rating: 3 - Severe (Flammable)
Reactivity Rating: 0 - None
Contact Rating: 3 - Severe
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD;
PROPER GLOVES; CLASS B EXTINGUISHER
Storage Color Code: Red (Flammable)
-----------------------------------------------------------------------------------------------------------

Potential Health Effects


----------------------------------

Inhalation:
Inhalation of vapors irritates the respiratory tract. May cause coughing, dizziness, dullness,
and headache. Higher concentrations can produce central nervous system depression,
narcosis, and unconsciousness.
Ingestion:
Swallowing small amounts is not likely to produce harmful effects. Ingestion of larger
amounts may produce abdominal pain, nausea and vomiting. Aspiration into lungs can
produce severe lung damage and is a medical emergency. Other symptoms are expected to
parallel inhalation.
Skin Contact:
Irritating due to defatting action on skin. Causes redness, pain, drying and cracking of the
skin.
Eye Contact:
Vapors are irritating to the eyes. Splashes may cause severe irritation, with stinging,
tearing, redness and pain.
Chronic Exposure:
Prolonged or repeated skin contact may produce severe irritation or dermatitis.
Aggravation of Pre-existing Conditions:
Use of alcoholic beverages enhances toxic effects. Exposure may increase the toxic
potential of chlorinated hydrocarbons, such as chloroform, trichloroethane.

4. First Aid Measures


Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention.
Ingestion:

17 
 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
Aspiration hazard. If swallowed, vomiting may occur spontaneously, but DO NOT
INDUCE. If vomiting occurs, keep head below hips to prevent aspiration into lungs. Never
give anything by mouth to an unconscious person. Call a physician immediately.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated
clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean
shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Get medical attention.

5. Fire Fighting Measures


Fire:
Flash point: -20C (-4F) CC
Autoignition temperature: 465C (869F)
Flammable limits in air % by volume:
lel: 2.5; uel: 12.8
Extremely Flammable Liquid and Vapor! Vapor may cause flash fire.
Explosion:
Above flash point, vapor-air mixtures are explosive within flammable limits noted above.
Vapors can flow along surfaces to distant ignition source and flash back. Contact with
strong oxidizers may cause fire. Sealed containers may rupture when heated. This material
may produce a floating fire hazard. Sensitive to static discharge.
Fire Extinguishing Media:
Dry chemical, alcohol foam or carbon dioxide. Water may be ineffective. Water spray may
be used to keep fire exposed containers cool, dilute spills to nonflammable mixtures,
protect personnel attempting to stop leak and disperse vapors.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained
breathing apparatus with full facepiece operated in the pressure demand or other positive
pressure mode.

6. Accidental Release Measures


Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal
protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and
unprotected personnel from entering. Contain and recover liquid when possible. Use non-
sparking tools and equipment. Collect liquid in an appropriate container or absorb with an
inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container.
Do not use combustible materials, such as saw dust. Do not flush to sewer! If a leak or spill
has not ignited, use water spray to disperse the vapors, to protect personnel attempting to
stop leak, and to flush spills away from exposures. US Regulations (CERCLA) require

18 
 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
reporting spills and releases to soil, water and air in excess of reportable quantities. The toll
free number for the US Coast Guard National Response Center is (800) 424-8802.

J. T. Baker SOLUSORB® solvent adsorbent is recommended for spills of this product.

7. Handling and Storage


Protect against physical damage. Store in a cool, dry well-ventilated location, away from
any area where the fire hazard may be acute. Outside or detached storage is preferred.
Separate from incompatibles. Containers should be bonded and grounded for transfers to
avoid static sparks. Storage and use areas should be No Smoking areas. Use non-sparking
type tools and equipment, including explosion proof ventilation. Containers of this material
may be hazardous when empty since they retain product residues (vapors, liquid); observe
all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection


Airborne Exposure Limits:
Acetone:
-OSHA Permissible Exposure Limit (PEL): 1000 ppm (TWA)
-ACGIH Threshold Limit Value (TLV): 500 ppm (TWA),
750 ppm (STEL) A4 - not classifiable as a human carcinogen
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures
below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred
because it can control the emissions of the contaminant at its source, preventing dispersion
of it into the general work area. Please refer to the ACGIH document, Industrial
Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded and engineering controls are not feasible, a half-face
organic vapor respirator may be worn for up to ten times the exposure limit, or the
maximum use concentration specified by the appropriate regulatory agency or respirator
supplier, whichever is lowest. A full-face piece organic vapor respirator may be worn up to
50 times the exposure limit, or the maximum use concentration specified by the appropriate
regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances
where the exposure levels are not known, use a full-face piece positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in
oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls,
as appropriate, to prevent skin contact.
Eye Protection:

19 
 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain
eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties


Appearance:
Clear, colorless, volatile liquid.
Odor:
Fragrant, mint-like
Solubility:
Miscible in all proportions in water.
Specific Gravity:
0.79 @ 20C/4C
pH:
No information found.
% Volatiles by volume @ 21C (70F):
100
Boiling Point:
56.5C (133F) @ 760 mm Hg
Melting Point:
-95C (-139F)
Vapor Density (Air=1):
2.0
Vapor Pressure (mm Hg):
400 @ 39.5C (104F)
Evaporation Rate (BuAc=1):
ca. 7.7

10. Stability and Reactivity


Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Concentrated nitric and sulfuric acid mixtures, oxidizing materials, chloroform, alkalis,
chlorine compounds, acids, potassium t-butoxide.
Conditions to Avoid:
Heat, flames, ignition sources and incompatibles.

11. Toxicological Information


20 
 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 

Oral rat LD50: 5800 mg/kg; Inhalation rat LC50: 50,100mg/m3; Irritation eye rabbit,
Standard Draize, 20 mg severe; investigated as a tumorigen, mutagen, reproductive
effector.
--------\Cancer Lists\-------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- --------
Acetone (67-64-1) No No None

12. Ecological Information


Environmental Fate:
When released into the soil, this material is expected to readily biodegrade. When released
into the soil, this material is expected to leach into groundwater. When released into the
soil, this material is expected to quickly evaporate. When released into water, this material
is expected to readily biodegrade. When released to water, this material is expected to
quickly evaporate. This material has a log octanol-water partition coefficient of less than
3.0. This material is not expected to significantly bioaccumulate. When released into the
air, this material may be moderately degraded by reaction with photochemically produced
hydroxyl radicals. When released into the air, this material may be moderately degraded by
photolysis. When released into the air, this material is expected to be readily removed from
the atmosphere by wet deposition.
Environmental Toxicity:
This material is not expected to be toxic to aquatic life. The LC50/96-hour values for fish
are over 100 mg/l.

13. Disposal Considerations


Whatever cannot be saved for recovery or recycling should be handled as hazardous waste
and sent to a RCRA approved incinerator or disposed in a RCRA approved waste facility.
Processing, use or contamination of this product may change the waste management
options. State and local disposal regulations may differ from federal disposal regulations.
Dispose of container and unused contents in accordance with federal, state and local
requirements.

14. Transport Information


Domestic (Land, D.O.T.)

-----------------------
Proper Shipping Name: ACETONE

21 
 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
Hazard Class: 3
UN/NA: UN1090
Packing Group: II
Information reported for product/size: 188L

International (Water, I.M.O.)


-----------------------------
Proper Shipping Name: ACETONE
Hazard Class: 3
UN/NA: UN1090
Packing Group: II
Information reported for product/size: 188L

15. Regulatory Information


--------\Chemical Inventory Status - Part 1\--------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ----
Acetone (67-64-1) Yes Yes Yes Yes

--------\Chemical Inventory Status - Part 2\---------------------------


--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- ---
Acetone (67-64-1) Yes Yes No Yes

--------\Federal, State & International Regulations - Part 1\----------


-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------
Acetone (67-64-1) No No Yes No

--------\Federal, State & International Regulations - Part 2\----------


-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Acetone (67-64-1) 5000 U002 No

Chemical Weapons Convention: No TSCA 12(b): No CDTA: Yes


SARA 311/312: Acute: Yes Chronic: No Fire: Yes Pressure: No
Reactivity: No (Pure / Liquid)
Australian Hazchem Code: 2[Y]E
Poison Schedule: None allocated.
WHMIS:

22 
 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
This MSDS has been prepared according to the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all of the information required by the CPR.

16. Other Information


NFPA Ratings: Health: 1 Flammability: 3 Reactivity: 0
Label Hazard Warning:
DANGER! EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPOR MAY
CAUSE FLASH FIRE. HARMFUL IF SWALLOWED OR INHALED. CAUSES
IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. AFFECTS CENTRAL
NERVOUS SYSTEM.
Label Precautions:
Keep away from heat, sparks and flame.
Keep container closed.
Use only with adequate ventilation.
Wash thoroughly after handling.
Avoid breathing vapor.
Avoid contact with eyes, skin and clothing.
Label First Aid:
Aspiration hazard. If swallowed, vomiting may occur spontaneously, but DO NOT
INDUCE. If vomiting occurs, keep head below hips to prevent aspiration into lungs. Never
give anything by mouth to an unconscious person. Call a physician immediately. If inhaled,
remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least
15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. In all
cases, get medical attention.
Product Use:
Laboratory Reagent.
Revision Information:
No Changes.
Disclaimer:
*************************************************************************
Mallinckrodt Baker, Inc. provides the information contained herein in good faith but
makes no representation as to its comprehensiveness or accuracy. This document is
intended only as a guide to the appropriate precautionary handling of the material by
a properly trained person using this product. Individuals receiving the information
must exercise their independent judgment in determining its appropriateness for a
particular purpose. MALLINCKRODT BAKER, INC. MAKES NO
REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED,
INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF
MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH
RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT

23 
 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
TO WHICH THE INFORMATION REFERS. ACCORDINGLY,
MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR
DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS
INFORMATION.
*************************************************************************
***********************
Prepared by: Environmental Health & Safety
Phone Number: (314) 654-1600 (U.S.A.)

24 
 
Name: Anas Alam Faizli Student ID No. CGS 00385017
Centre of Graduate Studies MPM Intake: January 2009

 
 
ASSIGNMENT – EMSH5103
 
REFERENCE

1. Harold Kerzner (2006) Project Management: A Systems Approach to Planning,


Scheduling, and Controlling, John Wiley & Sons Inc.
2. Zuriati Zakaria, Maimon Abdullah – Universiti Kebangsaan Malaysia, (2003)
Environmental Impact Assessment in Thailand, South Africa, Malaysia and
Denmark
3. David L. Goetsch (2008) Occupational Safety and Health for Technologists,
Engineers and Managers

25 
 

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