CHEM324-Cumulative Session 1.

January 27, 2011

WORKSHEET
I. Chapter 1: Energy Conversion E = w + q Design a typical day of a person and calculate and plot the amount of work, w, and heat, q, (in joules) used for 24 hours.
Procedures 1. Create a student and define his or her physical property. (age, weight, typical body temperature, volume of air intake into a lung, typical pulse/minute, blood pressure, personality, etc.). 2. Create a schedule of daily activities starting from 0:00 AM to 0:00 AM of the next day. Please make at least 8 activities. By mainly using the internet, find the resources for calculating the required/received amount of energy (work or heat) for each activity. (Use Google Search to find an appropriate link.) 3. Plot the total amount of energy change every hour, and create your MS-Excel file REQUIREMENTS The person needs breathe all the time. The person needs to sleep at least 6 hours/day. The person needs to eat at least 2 times a day.

II. Chapter 1: Temperature Dependence in Enthalpy HT2-T1 = n Cm,P (T2 T1) Calculate the enthalpy change H due to breathings per day at different cities.
Procedures 1. Create a person and define his or her physical property. (typical body temperature, volume of air intake into a lung, and typical breathing rate). 2. Use the internet, and find out todays temperature and atmospheric pressure of Geneseo. 3. Calculate the enthalpy change as this person breath for a day at outside. Use the molar heat capacity of the air at constant pressure, Cm,P, as 30 J/K mol. 4. Repeat the procedure 3 for two other cities. Then, plot them as a bar graph in MS-Excel file.

III. Chapter 1: Thermodynamics Carnot Cycle

= 1/ (1 + c)

Using the efficiency calculated from Carnot Cycle , simulate the cost of operating the AC (Air Conditioner) of different brand models. The AC should be capable of being cooler and heater for the hot months and cold months, respectively. Procedures 1. Survey the web and find AC from three different brands, price, and coefficient of performance (COP).

CHEM324-Cumulative Session 1.
January 27, 2011

2. Calculate and plot the total cost of operation (AC and fee of electricity) for five years by using the following conditions and the background knowledge. 3. Plot the cost of operation of each product for five years. [Note that this graph intends to show which product is cost effective.]

Conditions (Note that you need to use the values given in bold face.) Cold Months: This family wishes to maintain their house at comfortable temperature for six months (October, November, December, January, February, and March). With an appropriate amount of heat capacity of air and the area of the rooms, the energy per 7 month was calculated to be 3.5 10 kJ for each month. Hot Months: This family wishes to maintain their house at comfortable temperature for four months (June, July, August, and September). With an appropriate amount of heat capacity of air and the area of the rooms, the energy per month was calculated to be 2.5 107 kJ for each month.

Background Knowledge The coefficient of performance and efficiency for an ideal Carnot pump.

|q| = |wT|
wT: the work, which must be supplied by electrical energy : efficiency q: the heat needs to be transferred

In order to make a simple situation, the efficiency of the work () is given as:

= 1/ (1 + c)
where c is a coefficient of performance (COP) . NOTE: Although you usually the COP value is displayed, the definition of the COP is

c= Tcold / [Thot Tcold]

READ- Submission of your work. 1. You can submit only Excel files to DropBox by 11:30 pm. [The worksheet is NOT required.]
2. Submit only ONE Excel file. [Your file should contain three Worksheets, and each worksheet should contain the result of each section.]

CHEM324-Cumulative Session 1.
January 27, 2011

I. Energy Conversion: E = w + q
Physical Description of a Person

(Chapter 1)

Male, 22 years old, 60 kg, inhaling volume of the lung 0.5 L, breathing rate 12 times/minute, pulse rate 55 pulses/minute, body temperature 37 oC, pressure of the outside 1 atm
Daily Activities Breathing/hour Amount of Energy (J) / hour 101.3(J/L atm)(1 atm 0.5L) 12breath/minute 60 min/hr = 36468 J 101.3(J/L atm)(1 atm 0.5L) 6 breath/minute 60 min/hr= 18234 J 0.35 L milk, 15 g corn flakes, orange = 550000J Time of the activity 5AM-9PM (16 hours) 0-5AM 9PM-0AM (8 hours) 5 AM Reference Class Note

Sleep/hour

Class Note

Breakfast

Dinner

3 g bread, 500g steak, orange juice, banana, salad = 950000J Chocolate (20x M&M) 50000 J

6 PM

http://www.foodnet.com

Snacks

3PM & 7 PM 6-7 AM & 7-8PM

http://www.foodnet.com

Jogging

Club activity(Soccer) Prowling the snow Bed making

150000J/hour and breathing twice fast 101.3(J/L atm)(1 atm 0.5L) 24breath/minute 60 min/hr = 75975 J -300000 J/hour

http://www.sports.net.com

4-6 PM

-120000 J/hour

6-7 PM

http://www.snow.com

5000 J/min

8:509:00PM 1PM1:10 PM 7PM7:30PM

http://www.sleep.net

Vacuuming

1000 J/min

http://www.cleaning.com

Washing Dishes

-5000 J/min

http://www.washing.com

CHEM324-Cumulative Session 1.
January 27, 2011

II. Temperature Dependence in Enthalpy: HT2-T1 = n Cm,P (T2 T1)

Physical Description of a Person
inhaling volume of the lung 0.5 L, breathing rate 15 times/minute, body temperature 37.0 oC City Geneseo T (oC) /P (atm) 4.44 oC 1 atm Heat Loss from Breathing Reference Number of moles of the air =PV/RT = 1 atm 0.75 (L)/[0.082(L atm/K mol)268.706(K)] = 0.02270 mol H = n Cm,p T =0.02270 (mol) 30 (J/K mol) (36 oC 4.44 oC) = 28.229 (J) Heat Loss from Breathing =10.6 (J) 15 (breath/minute ) 60 (min/hour) 24(hour/day) =609.8 kJ/day

(Chapter 1)

Ref.
http://www.geneseoweather.c om

Mumbai, India

26.11 C 0.9986 atm

o

Number of moles of the air= 0.02035 mol H = n Cm,p T= 6.65 (J) Heat Loss from Breathing =143.64 kJ/day

Copenhagen, Denmark

2.22 C 1.015 atm

o

Number of moles of the air= 0.02286 mol H = n Cm,p T= 26.894 (J) Heat Loss from Breathing =580.92 kJ/day

CHEM324-Cumulative Session 1.
January 27, 2011

III. Thermodynamics-Carnot Cycle (Chapter 1)

Surveyed AC Company (Model) G&E (Gentle Electric) KITACHI Price ($) 500 2.65 COP www.gande.com Ref.

1350

6.15

www.kitachi.com

TOSHIPA

850

3.26

www.toshipa.com

Electric Bill Company Heaven Power Charge Ref. $0.0714/ kW-hour for the first www.heavenpower.com 600kWh and $0.0410 for each kWh thereafter.

Total Operating Cost (5 years) Company (Model) Gentle Electric KITACHI TOSHIPA Total Operating cost ($) For 5 years $6248 $4730 $5905