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ChemistryPartI

IITJEE 2010

PARTIChemistry
SECTIONI
SingleCorrectChoiceType
ThisSectioncontains 8multiplechoicequestions.Eachquestionhasfourchoices(A),(B),
(C)and(D)outofwhichONLYONEiscorrect.
1.

Thebondenergy(inkcalmol1)ofa C C singlebondisapproximately
(A) 1
(B)
10
(C) 100
(D) 1000

1.

(C) Itisafact.Itisnearly84kcalmol1

2.

ThespecieswhichbydefinitionhasZEROstandardmolarenthalpyofformationat298Kis
(A) Br2(g)

(B) Cl2 (g)

(C) H2O(g)

(D) CH4 (g)

2.

(B) Cl2(g)isgasinelementalstate Br2 isnotofbecauseitisliquidinelementalstate.

3.

Theionizationisomerof[Cr(H2O)4Cl(NO2)]Cl is
(A) [Cr(H2O)4(O2N)]Cl2
(B) [Cr(H2O)4Cl2](NO2)
(C) [Cr(H2O)4Cl(ONO)]Cl
(D) [Cr(H2O)4Cl2(NO2)]H2O

3.

(B) [Cr(H2O)4 Cl(NO2)]Cl and

4.

TheCorrectstructureofethylenediamineteraaceticacid(EDTA)is

4.

[Cr(H2O)4Cl2](NO2)areionizationisomers.

(A)

(B)

(C)

(D)

(C) Itisafact

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5.

Thesynthesisof3octyneisachievedbyaddingabromoalkaneintoamixtureofsodiumamide
andanalkyne.Thebromoalkaneandalkynerespectivelyare
(A) BrCH2CH2CH2CH2CH3and CH3CH2C CH
(B) BrCH2CH2CH3and CH3CH2CH2C CH
(C) BrCH2CH2CH2CH2CH3and CH3C CH
(D) BrCH2CH2CH2CH3and CH3CH2C CH

5.

B
(D) CH3 CH2C CH
CH3-CH2-CC-
SN2 CH3-CH2-CH2-CH2Br

CH3CH2C CCH2CH2CH2CH3
6.

Thecorrectstatementaboutthefollowingdisaccharideis

(A)
(B)
(C)
(D)

Ring (a) ispyranosewith aglycosidiclink

Ring (a) isfuranosewith aglycosidiclink
Ring (b) isfuranosewith aglycosidiclink
Ring (b) ispyranosewith aglycosidiclink

6.

(A) AisapyranoseringandisDformsoglucosideis a.

7.

Plotsshowingthevariationoftherateconstant(k)withtemperature(T)aregivenbelow.The
plotthatfollowsArrheniusequationis

7.

(A)

(B)

(C)

(D)

(A) K=A.eEa/RT = Ea /RT

e
IfTiszeroK 0

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8.

Inthereaction

theproductsare

(A)

(B)

(C)

(D)
H

8.

(D)

OMe HBr

O
+

Me

Br-

OH+MeBr

SECTIONII
MultipleCorrectChoiceType
Thissectioncontains5multiplechoicequestions.Eachquestionhasfourchoices(A),(B),(C)
and(D)outofwhichONEORMOREmaybecorrect.

9.

Inthereaction

NaOH(aq)/Br2 theintermediate(s)is(are)

(A)

(B)

(C)

(D)

O
Br

9.

(AC)
Br

Br

10. Thereagent(s)usedforsofteningthetemporaryhardnessofwateris(are)
(A) Ca3(PO4)2
(B) Ca(OH)2
(C) Na2CO3
(D) NaOCl
10. (BC)Na2CO3+Ca(HCO3)2 CaCO3 +NaHCO3
Ca(OH)2 CaO+H2O
CaO+Ca(HCO3)2 2CaCO3 +H2O

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11. Aqueoussolutionsof HNO3, KOH, CH3COOH,and CH3COONa ofidenticalconcentrationsare

provided.Thepair(s)ofsolutionswhichformabufferuponmixingis(are)
(A) HNO3and CH3COOH
(B) KOH and CH3COONa
(C) HNO3and CH3COONa
(D) CH3COOH and CH3COONa

11. (CD) CH3CONa+HNO3 CH3 - C - OH+NaNO3

O

CH3COOH and CH3 - CONa .

12. IntheNewmanprojectionfor2,2dimethylbutane

(A) H and H

(B) H and C2H5

X and Y canrespectivelybe

(C) C2H5and H

(D) CH3and CH3

CH3

12. (D)

CH3 - C - CH2 - CH3

CH3

13. Amongthefollowing,theintensivepropertyis(propertiesare)
(A) Molarconductivity
(B) electromotiveforce
(C) resistance
(D) heatcapacity
13. (AB)resistanceandheatcapacitybothdependonmass.
SECTIONIII
ParagraphType
Thissectioncontains2paragraphs.Baseduponthefirstparagraph2multiplechoicequestions
andbaseduponthesecondparagraph3multiplechoicequestionshavetobeanswered.Each
ofthesequestionshasfourchoices(A),(B),(C)and(D)outofwhichONLY ONEiscorrect.
Paragraphforquestions14to15
Theconcentrationofpotassiumionsinsideabiologicalcellisatleasttwentytimeshigherthan
theoutside.Theresultingpotentialdifferenceacrossthecellisimportantinseveralprocesses
suchastransmissionofnerveimpulsesandmaintainingtheionbalance.Asimplemodelforsuch
aconcentrationcellinvolvingametal M is:
M(s)|M+(aq0.05molar)||M+(aq1molar)|M(s)
Fortheaboveelectrolyticcellthemagnitudeofthecellpotential|Ecell|=70mV.
14. Fortheabovecell
(A) Ecell <0 DG>0
(C) Ecell <0 DG>0

(B) Ecell >0 DG<0

(D) Ecell >0 DG<0

14. (B) Thereactionshouldbespontaneousandhence DG <0.

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((Chemstry Solutions PII) 4

15. Ifthe0.05molarsolutionof M+ isreplacedbya0.0025molar M+solution,thenthemagnitude

ofthecellpotentialwouldbe
(A) 35mV
(B) 70mV
(C) 140mV
(D) 700mV
15. (C) 0.070= Emf -

x=Emf -

.06
log.05
1

.06
log.0025
1

.070 log.05 - 1.3

=
=
x log.0025 - 2.6
x=.072103 =140
Paragraphforquestions16to18
Copperisthemostnobleoffirstrowtransitionmetalsandoccursinsmalldepositsinseveral
countries.Oresofcopperincludechalcanthite(CuSO4.5H2O),atacamite(Cu2Cl(OH)3),cuprite
(Cu2O), copper glance (Cu2S) and malachite (Cu2(OH)2CO3). However, 80% of the world
copperproductioncomesfromtheorechalcopyrite(CuFeS2).Theextractionofcopperfrom
chalcopyriteinvolvespartialroasting,removalofironandselfreduction.
16. Partialroastingofchalcopyriteproduces
(A) Cu2S and FeO
(B) Cu2O and FeO
(C) CuS and Fe2O3
(D) Cu2O and Fe2O3
16. (A) Partialroastingof CuFeS2gives Cu2S and FeO.Ironispreferentiallyoxidised.
17. Ironisremovedfromchalcopyriteas
(A) FeO
(B) FeS

(C) Fe2O3

(D) FeSiO3

(C) S2

(D) SO2

17. (D) FeO+SiO2 FeSiO3

18. Inselfreduction,thereducingspeciesis
(A) S
(B) O2
18. (C) Cu2S+2Cu2O 6Cu+SO2
SECTIONIV(IntegerType)
ThissectioncontainsTENquestions.Theanswertoeachquestionisasingledigitinteger
rangingfrom0to9.ThecorrectdigitbelowthequestionnumberintheORSistobebubbled.
19. Thenumberofneutronsemittedwhen 235
92 Uundergoescontrollednuclearfissionto
142
90
54Xeand38Sr is:

19. (3)

235

142

90

1
92 U 54Xe+ 38Sr+ 0n

235=232+x
x=3.

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20. Thetotalnumberofbasicgroupsinthefollowingfromoflysineis

20. (2)

- C - O isConjugatebase,NH2isbasic, NH3+isacidic

Totalno.is2.
21. Thetotalnumberofcyclicisomerspossibleforahydrocarbonwiththemolecularformula
C4H6is.
21. (5)
22. Intheschemegivenbelow,thetotalnumberofintramolecularaldolcondensationproduction
formedfromYis
1.O

1.NaOH(aq)

2.Zn,H2O

2.heat

22. (1)

Sinceitissymmetricalonlyonealdolproductispossible.

23. Amongstthefollowing,thetotalnumberofcompoundssolubleinaqueous NaOH is

23. (4) COOHgroupandOHgroupreatswithNaOH.

24. Amongstthefollowing,thetotalnumberofcompoundswhoseaqueoussolutionturnsredlitmus
paperblueis
KCN
K2SO4
(NH4)2C2O4
NaCl
Zn(NO3)2
FeCl3
K2CO3
NH4NO3
LiCN
24. (3) KCNK2CO3 andLiCNTheyarethesaltsofweakacidandstrongbase.

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25. BasedonVSEPRtheory,thenumberof90degree FBF anglesin BrF5 is

F
F

25. (0)

F
Br

F
XX

Dueto LPBP repulsionthebondangledecreasesaxialanglenolongerremains90otherangle

alsosuffersdistortion.
26. Thevalueof n inthemolecularformula BenAl2Si6O18is
26. (3) 2n+23+6(4)+18(2)=0

2n=6

n=3

27. Astudentperformsatitrationwithdifferentburettesandfindstitrevaluesof25.2mL,25.25mL,
and25.0mL.Thenumberofsignificantfiguresintheaveragetitrevalueis
27. (3) Asperrules
28. TheconcentrationofRinthereactionR Pwasmeasuredasafunctionoftimeandthe
followingdataisobtained :
[ R ]
( m o l a r )

1 . 0

0 . 7 5

0 . 4 0

0 . 1 0

t ( m i n . )

0 . 0

0 . 0 5

0 . 1 2

0 . 1 8

Theorderofthereactionis
28. (0) (.25/.05)=5 again(0.35/0.07)=5
rateremainconstantirrespectiveofchangeofconcentration.

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((Chemstry Solutions PII) 7