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CopiedfromNYJCChemistrylecturenotes
Heatevolvedbyfuel=Heatabsorbedbywater=mcT Hc=(+/)Heatevolved/amountoffuelused
Na(g)+Cl(g)
Hat
Na(s)+Cl2(g)
Hf
NaCl(s)
Hsol=HhydHlaB
NaCl(s)+aq
Stage1 HlaS
Hsol
Na+(aq)+Cl(aq)
Na+(g)+Cl(g)+aq
Stage2 Hhyd
Entropy,S,isthemeasureoforderofasystem.
DisorderEntropy S=SnalSini1alUnits=JK1mol1
Factors
Reason
tempentropy Thehigherthetemperature,themoreenergythe systempossesses.Therearemorewaysto distributetheenergypacketsamongthe par.clesnow.Asaresult,thesystembecomes moredisordered,entropyincreases. Changeinphase Thechangefromsolidtoliquidtogasinvolves SolidLiquidGas moleculeshavingamoredisorderedorrandom Entropy arrangementwithinthechemicalsystem.Hence entropyincreases(S>0).Increaseinentropy fromliquidtogasisgreaterthanforsolidtoliquid asithasagreaterincreaseinvolume. No.ofpar.cles Entropy Thegreaterthenumberofmolecules,themore randomanddisorderedthesystembecomes. Therearemorewaysofarrangingthemolecules. Henceentropyincreaseswhenthenumberofgas moleculesincreases.
Dissolving Whenanionicsoliddissolvesinwater,theionsexperienceagreat ofSolids increaseindisorderastheybreakawayfromthesolidlaZce, leadingtoincreaseinentropy.However,thewatermolecules Generally, becomemoreorderedaroundtheionsandexperienceadecrease Entropy inthedisorder,causingadecreaseinentropy.Formostionic solidsthataresolubleinwater,thedisorderingprocessesare usuallydominant.Thustheoveralleectisanincreaseindisorder andentropyofthesystemupondissolvinginwater. in volumeof gases Entropy Agasspontaneouslyexpandstooccupythewholecontainer. Expansionofvolumeleadstoincreaseinentropy.Thisisbecause, inalargervolumeofspace,therearemorewaysforthe moleculestoarrangethemselves.
G=HTS
whereT=temperature(inKelvin) Gisthestandardfreeenergy changeneededtoconvertreactants intoproductsatstandardcondi.ons.
IfG<0,reac.ontakesplacespontaneously. IfG>0,reac.oncannottakeplacespontaneously. IfG=0,reac.onreachesequilibrium. Thetemperatureatwhichthereac.onturns fromnonspontaneoustospontaneouscanbe determinedbyseZngG=0andsolvingforT.
Examples
aremetastableunderallcondi.onsandonlyexistbecause theac.va.onenergyofthereac.onissohigh. e.g.organiccombus.onreac.ons,explosives,some decomposi.onreac.ons e.g.Photosynthesis