RiskPoll MultiMedia model for toxic metals --- Introduction A model for the assessment of the collective dose

and health impacts associated with routine emissions of toxic metals to air.
Version 1.00 (Last modified: October 1, 2003)

Documentation:
Pathway Analysis for Population-Total Health Impacts of Toxic Metal Emissions

D c mn tio o u e ta n

E u tio s qa n

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Main references:
[1] EPA 1998: "Human Health Risk Assessment Protocol for Hazardous Waste Combustion Facilities", Support Materials, USEPA Region 6 U.S. EPA Multimedia Planning & Permitting Division Office of Solid Waste, Center Combustion Science & Engineering.

http://www.epa.gov/epaoswer/hazwaste/combust/riskvol.htm#volume1
[2] IAEA 2001: "Generic Models for use in Assessing the Impact of Discharges of Radioactive Substances to the Environment", Safety Series No. 19, International Atomic Energy Agency, Vienna, Austria. [3] IAEA 1994: "Handbook of Parameter Values for the Prediction of Radionuclide Transfer in Temperate Environments", Technical Series No. 364. Produced in collaboration with the International Union of Radioecologists, International Atomic Energy Agency, Vienna, Austria.

Contact information:
Dr. A. Rabl, Centre d'Energetique, Ecole des Mines, 60 boul. St. Michel, F-75272 Paris Cedex 06, FRANCE

ari.rabl@ensmp.fr
Dr. J.V. Spadaro in c/o Rabl

JAASSpadaro@aol.com
Internet address

http://www.arirabl.com

>>>>> End of Introduction <<<<<

RiskPoll MultiMedia model for toxic metals --- Input data and Calculations
(calculations based on 1998 EPA methodology)

Nota bene >>> Entries in green-colored cells indicate user input data <<< >>> Entries in blue-colored cells are default input data <<< >>> Place mouse pointer over cell wit h red co rner to read additional comments <<<

Units and Abbreviations

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To do list - Idiot proof user input data

Input data - part 1 of 5 General parameters, annual food consumption, land use and depletion velocities

Input data - part 2 of 5 Transport in soil

Input data - part 3 of 5 Transport in water and fish contamination

Input data - part 4 of 5 Crop and Feedstock contamination

General param eters (3 in puts)

Variable M tcut reg nort hern Description Rate of pollutant emission to air Cutoff time Regional population Population Northern hemisphere (for Hg calculations) <<------------------ User input ------------------>> Default Units Value 1000 kg/yr 1000 100 yr 100 80 pers/km2 80 pers/km2 20.9 <<--------------- MKSI units --------------->> Value Units 3.17E-05 kg/s 3.15E+09 s 8.00E-05 pers/m2 2.09E-05 pers/m2

C oncentration in SOIL ( 17 inputs )

Variable Lsoil Rsed Ren soil dsoil Description Unit soil loss Sedimentary delivery ratio Soil enrichment ratio Soil bulk density Soil depth --- ingestion Soil depth --- pasture Soil depth --- crops Soil volumetric water content Soil-water partition coefficient --- As Soil-water partition coefficient --- Cd Soil-water partition coefficient --- Cr Soil-water partition coefficient --- MeHg Soil-water partition coefficient --- Ni Soil-water partition coefficient --- Pb Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant Errosion soil loss constant --- ingestion As --- pasture As --- crops As --- ingestion Cd --- pasture Cd --- crops Cd --- ingestion Cr --- pasture Cr --- crops Cr --- ingestion MeHg --- pasture MeHg --- crops MeHg --- ingestion Ni --- pasture Ni --- crops Ni --- ingestion Pb --- pasture Pb --- crops Pb 10 cm/yr 10 <<------------------ User input ------------------>> Default Units Value 1.61 kg_soil/(m2.yr) 1.61 0.11 0.11 1 1 1500 kg_soil/m3 1500 1 cm 1 10 cm 10 20 cm 20 0.2 m3_wat/m3_soil 0.2 0.03 m3_wat/kg_soil 0.03 0.08 m3_wat/kg_soil 0.08 0.02 m3_wat/kg_soil 0.02 7 m3_wat/kg_soil 7 0.07 m3_wat/kg_soil 0.07 0.9 m3_wat/kg_soil 0.9 <<--------------- MKSI units --------------->> Value Units 5.11E-08 kg_soil/(m2.s) 1.07E-01 1.00E+00 1.50E+03 kg_soil/m3 1.00E-02 m 1.00E-01 m 2.00E-01 m 2.00E-01 m3_wat/m3_soil 2.90E-02 m3_wat/kg_soil 7.50E-02 m3_wat/kg_soil 1.90E-02 m3_wat/kg_soil 7.00E+00 m3_wat/kg_soil 6.50E-02 m3_wat/kg_soil 9.00E-01 m3_wat/kg_soil 3.61E-10 3.61E-11 1.80E-11 3.62E-10 3.62E-11 1.81E-11 3.60E-10 3.60E-11 1.80E-11 3.62E-10 3.62E-11 1.81E-11 3.62E-10 3.62E-11 1.81E-11 3.62E-10 3.62E-11 1.81E-11 3.17E-09 7.26E-09 7.26E-10 3.63E-10 2.81E-09 2.81E-10 1.41E-10 1.10E-08 1.10E-09 5.52E-10 3.02E-11 3.02E-12 1.51E-12 3.25E-09 3.25E-10 1.62E-10 2.35E-10 2.35E-11 1.17E-11 11 30 cm/yr cm/yr 11 30 3.49E-09 9.51E-09 2.38E-08 3.34E-08 3.34E-09 1.67E-09 1.29E-08 1.29E-09 6.47E-10 5.08E-08 5.08E-09 2.54E-09 1.39E-10 1.39E-11 6.95E-12 1.49E-08 1.49E-09 7.46E-10 1.08E-09 1.08E-10 5.40E-11 4.10E-08 4.10E-09 2.05E-09 1.61E-08 1.61E-09 8.06E-10 6.22E-08 6.22E-09 3.11E-09 5.32E-10 5.32E-11 2.66E-11 1.85E-08 1.85E-09 9.27E-10 1.68E-09 1.68E-10 8.39E-11 7.73E-01 7.73E+00 1.55E+01 1.97E+00 1.97E+01 3.93E+01 5.10E-01 5.10E+00 1.02E+01 5.97E+01 5.97E+02 1.19E+03 1.71E+00 1.71E+01 3.42E+01 1.89E+01 1.89E+02 3.78E+02 1/s 1/s 1/s 1/s 1/s 1/s

Concentration in WATER and FISH (17 inputs)

Variable f_Aland f_Aland, fw f_Aland, imp f_Aland, perv f_Aland, ing f_Aland, past f_Aland, crop Xsoil, ing Description Fraction of total surface area covered by land Fraction of land that is covered by fresh water Fraction of land area that is impervious Fraction of land area that is pervious Fraction of land area for ingestion calculations Fraction of land area for pasture calculations Fraction of land area for crops calculations Soil transfer factor ingestion Soil transfer factor ingestion Soil transfer factor ingestion Soil transfer factor ingestion Soil transfer factor ingestion Soil transfer factor ingestion --- As --- Cd --- Cr --- MeHg --- Ni --- Pb <<------------------ User input ------------------>> Default Units Value 0.35 0.35 0.02 0.02 0.10 0.10 0.90 0.40 0.40 0.10 0.10 0.40 0.40 <<--------------- MKSI units --------------->> Value Units

Conc entration in VEGETATIO N (35 in puts)

Variable fwet fint Description Fraction of wet deposition that adheres to plant Interception fraction on edible plant - Crops Interception fraction on edible plant - Pasture Interception fraction on edible plant - Silage Fraction of cropland irrigated Annual mean irrigation rate Dry deposition velocity --- As Dry deposition velocity --- Cd Dry deposition velocity --- Cr Dry deposition velocity --- MeHg Dry deposition velocity --- Ni Dry deposition velocity --- Pb Wet deposition velocity --- As Wet deposition velocity --- Cd Wet deposition velocity --- Cr Wet deposition velocity --- MeHg Wet deposition velocity --- Ni Wet deposition velocity --- Pb Plant surface loss constant Exposure time of edible plant per harvest - Crops Exposure time of edible plant per harvest - Pasture Exposure time of edible plant per harvest - Silage Yield per planted area - Crops Yield per planted area - Pasture Yield per planted area - Silage Plant concentration from foliar absorption - Crops, As Plant concentration from foliar absorption - Crops, Cd Plant concentration from foliar absorption - Crops, Cr Plant concentration from foliar absorption - Crops, MeHg Plant concentration from foliar absorption - Crops, Ni Plant concentration from foliar absorption - Crops, Pb Plant concentration from foliar absorption - Pasture, As Plant concentration from foliar absorption - Pasture, Cd Plant concentration from foliar absorption - Pasture, Cr Plant concentration from foliar absorption - Pasture, MeHg Plant concentration from foliar absorption - Pasture, Ni Plant concentration from foliar absorption - Pasture, Pb Plant concentration from foliar absorption - Silage, As Plant concentration from foliar absorption - Silage, Cd Plant concentration from foliar absorption - Silage, Cr Plant concentration from foliar absorption - Silage, MeHg Plant concentration from foliar absorption - Silage, Ni Plant concentration from foliar absorption - Silage, Pb 18 0.16 0.12 0.16 2.24 0.24 0.8 1/yr yr yr yr kg_dw/m2 kg_dw/m2 kg_dw/m2 18 0.16 0.12 0.16 2.24 0.24 0.8 <<--------------------- User input --------------------->> Default Units Value 0.6 0.6 0.39 0.39 0.5 0.5 0.46 0.46 <<--------------- MKSI units --------------->> Value Units 6.00E-01 3.90E-01 5.00E-01 4.60E-01 1.20E-01 3.49E-09 2.45E-03 2.45E-03 2.45E-03 0.00E+00 2.45E-03 1.35E-03 2.45E-03 2.45E-03 2.45E-03 0.00E+00 2.45E-03 1.35E-03 5.71E-07 5.05E+06 3.78E+06 5.05E+06 2.24E+00 2.40E-01 8.00E-01 1.14E+03 1.14E+03 1.14E+03 1.11E-02 1.14E+03 6.26E+02 1.27E+04 1.27E+04 1.27E+04 1.25E-01 1.27E+04 7.03E+03 3.75E+03 3.75E+03 3.75E+03 3.67E-02 3.75E+03 2.07E+03

Annual food consu mption rates (7 in puts)

Variable Qwater Qmilk Qmeat Qfruit&veg Qrootveg Qgrain Qfreshfish Qseafish Description Water Milk Meat Above ground fruits and vegetables Below ground vegetables Grains Fresh water fish Seawater fish <<------------------ User input ------------------>> <<--------------- MKSI units --------------->> Default Units Value Value Units 0.6 m3_wat/(pers.yr) 0.6 1.90E-08 m3_wat/(pers.s) 250 kg_milk/(pers.yr) 250 7.93E-06 kg_milk/(pers.s) 100 kg_fw/(pers.yr) 100 3.17E-06 kg_fw/(pers.s) 189 kg_fw/(pers.yr) 189 8.39E-07 kg_dw/(pers.s) 100 kg_fw/(pers.yr) 100 6.34E-07 kg_dw/(pers.s) 117 kg_fw/(pers.yr) 117 3.19E-06 kg_dw/(pers.s) 3 kg_fw/(pers.yr) 3 9.51E-08 kg_fw/(pers.s) Not used at the moment

sw
kds

firr Virr 7.97E+03 2.03E+04 5.25E+03 1.15E+03 1.76E+04 1.07E+05 9.80E-05 9.80E-05 9.80E-05 2.26E-07 9.80E-05 5.40E-05 7.81E-04 7.70E-04 7.83E-04 4.71E-07 7.72E-04 3.38E-04 4.90E-04 4.90E-04 4.90E-04 1.13E-06 4.90E-04 2.70E-04 3.88E-05 9.87E-05 2.56E-05 5.62E-06 8.58E-05 5.20E-04 1.41E-03 1.46E-03 1.40E-03 7.45E-06 1.45E-03 1.18E-03 (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) kg/(m2.s)/(kg/m3_air) Vdry

m/s m/s m/s m/s m/s m/s m/s m/s m/s m/s m/s m/s m/s 1/s s s s kg_dw/m2 kg_dw/m2 kg_dw/m2 (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air)

ksoil, er

Fdep_wat/Cair

Direct deposition to water --- As Direct deposition to water --- Cd Direct deposition to water --- Cr Hg deposition to water and conversion to MeHg Direct deposition to water --- Ni Direct deposition to water --- Pb Runoff from pervious surfaces to water --- As Runoff from pervious surfaces to water --- Cd Runoff from pervious surfaces to water --- Cr Runoff from pervious surfaces to water --- MeHg Runoff from pervious surfaces to water --- Ni Runoff from pervious surfaces to water --- Pb Runoff from impervious surfaces to water --- As Runoff from impervious surfaces to water --- Cd Runoff from impervious surfaces to water --- Cr Runoff from impervious surfaces to water --- MeHg Runoff from impervious surfaces to water --- Ni Runoff from impervious surfaces to water --- Pb Errosion from pervious surfaces to water --- As Errosion from pervious surfaces to water --- Cd Errosion from pervious surfaces to water --- Cr Errosion from pervious surfaces to water --- MeHg Errosion from pervious surfaces to water --- Ni Errosion from pervious surfaces to water --- Pb Total pollutant flux to water --- As Total pollutant flux to water --- Cd Total pollutant flux to water --- Cr Total pollutant flux to water --- MeHg Total pollutant flux to water --- Ni Total pollutant flux to water --- Pb

Vwet

Mro_perv/Cair

Land use distribution ( 5 inputs)

Variable Aland, crop f_Aland, crop, irr Aland, past Aland, forest Aland, other Description Cropland Fraction of irrigated cropland Pasture Forests Other <<------------------ User input ------------------>> Default Units Value 1.38E+08 hectares 1.38E+08 0.12 0.12 8.30E+07 hectares 8.30E+07 1.57E+08 hectares 1.57E+08 9.40E+07 hectares 9.40E+07 Total . . . . . 4.72E+08 hectares <<--------------- MKSI units --------------->> Value Units 1.38E+12 m2 1.20E-01 8.30E+11 m2 1.57E+12 m2 9.40E+11 m2 4.72E+12 m2

1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s m/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s m/s m/s m/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s Bfish 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s 1/s yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr Vwat/Awshed kb Mtot_wat/Cair

kp tp

Yp

Mro_imp/Cair

Cpl,foliar/Cair

Mer_perv/Cair

Dep letion veloc ities f or metals ( 8 inputs)

Vro Variable Rainfall Arsenic (As) Vdry Vwet Cadmium (Cd) Vdry Vwet Chromium (Cr-VI) Vdry Vwet Mercury res_Hg hmix Vdry _Hg Vwet _Hg f_MeHg Nickel (Ni) Vdry Vwet Lead (Pb) Vdry Vwet Description Mean precipitation rate <<------------------ User input ------------------>> Default Units Value 750 mm/yr 750 <<--------------- MKSI units --------------->> Value Units 2.38E-08 m/s ksoil, ro Annual mean surface runoff from pervious area Runoff soil loss constant Runoff soil loss constant Runoff soil loss constant Runoff soil loss constant Runoff soil loss constant Runoff soil loss constant Runoff soil loss constant Runoff soil loss constant Runoff soil loss constant Runoff soil loss constant Runoff soil loss constant Runoff soil loss constant Atmospheric residence time of elemental Hg Height of troposphere Dry deposition velocity of elemental Hg Wet deposition velocity of elemental Hg Fraction of Hg transformed into Methly Hg 1.4 10 yr km cm/s cm/s 1.4 10 1.13E-02 1.13E-02 0.05 4.42E+07 1.00E+04 1.13E-04 1.13E-04 5.00E-02 s m m/s m/s Runoff soil loss constant Runoff soil loss constant Runoff soil loss constant Runoff soil loss constant Runoff soil loss constant Runoff soil loss constant m/s m/s Virr Vevap Rainfall ksoil, leach --- ingestion As --- pasture As --- crops As --- ingestion Cd --- pasture Cd --- crops Cd --- ingestion Cr --- pasture Cr --- crops Cr --- ingestion MeHg --- pasture MeHg --- crops MeHg --- ingestion Ni --- pasture Ni --- crops Ni --- ingestion Pb --- pasture Pb --- crops Pb

Dry deposition velocity Wet deposition velocity

0.25 0.25

cm/s cm/s

2.45E-01 2.45E-01

2.45E-03 2.45E-03

m/s m/s

Dry deposition velocity Wet deposition velocity

0.25 0.25

cm/s cm/s

2.45E-01 2.45E-01

2.45E-03 2.45E-03

m/s m/s

Dry deposition velocity Wet deposition velocity

0.25 0.25

cm/s cm/s

2.45E-01 2.45E-01

2.45E-03 2.45E-03

m/s m/s

dwc dbs Cbs Csussol bs fwc

Water column depth Upper benthic sediment layer Bed sediment concentration Total suspended solids concentration Bed sediment porosity Fraction of water body conc. in water column - As Fraction of water body conc. in water column - Cd Fraction of water body conc. in water column - Cr Fraction of water body conc. in water column - MeHg Fraction of water body conc. in water column - Ni Fraction of water body conc. in water column - Pb Water flow rate through watershed Benthic rate burial constant

1 3 0.1 10 0.6

m cm kg_sed/L mg_soil/L m3_wat/m3_sed

1 3 0.1 10 0.6

1.00E+00 3.00E-02 1.00E+02 1.00E-02 6.00E-01 9.05E-01 8.05E-01 9.30E-01 4.84E-02 8.24E-01 2.71E-01 1.43E-08 8.82E-08 8.38E-09 1.72E-08 6.16E-09 8.40E-08 1.55E-08 6.44E-08 3.78E+00 1.84E+00 5.15E+00 3.78E-01 2.05E+00 4.93E-01 1.08E+05 1.23E+05 1.04E+05 3.08E+03 1.20E+05 2.28E+05 1.00E+05 1.02E+05 9.98E+04 1.54E+02 1.02E+05 6.35E+04 1.00E+05 1.02E+05 9.98E+04 1.44E+02 1.02E+05 6.30E+04

m m kg_sed/m3_wat kg_soil/m3_wat m3_wat/m3_sed

Broot

Plant-soil bioconcentration factor - Green veg, As Plant-soil bioconcentration factor - Green veg, Cd Plant-soil bioconcentration factor - Green veg, Cr Plant-soil bioconcentration factor - Green veg, MeHg Plant-soil bioconcentration factor - Green veg, Ni Plant-soil bioconcentration factor - Green veg, Pb Plant-soil bioconcentration factor - Root veg, As Plant-soil bioconcentration factor - Root veg, Cd Plant-soil bioconcentration factor - Root veg, Cr Plant-soil bioconcentration factor - Root veg, MeHg Plant-soil bioconcentration factor - Root veg, Ni Plant-soil bioconcentration factor - Root veg, Pb Plant-soil bioconcentration factor - Grains, As Plant-soil bioconcentration factor - Grains, Cd Plant-soil bioconcentration factor - Grains, Cr Plant-soil bioconcentration factor - Grains, MeHg Plant-soil bioconcentration factor - Grains, Ni Plant-soil bioconcentration factor - Grains, Pb Plant-soil bioconcentration factor - Animal feed, As Plant-soil bioconcentration factor - Animal feed, Cd Plant-soil bioconcentration factor - Animal feed, Cr Plant-soil bioconcentration factor - Animal feed, MeHg Plant-soil bioconcentration factor - Animal feed, Ni Plant-soil bioconcentration factor - Animal feed, Pb

6.33E-03 1.25E-01 4.88E-03 2.94E-02 9.31E-03 1.36E-02 8.00E-03 6.40E-02 4.50E-03 9.90E-02 8.00E-03 9.00E-03 4.00E-03 6.20E-02 4.50E-03 3.00E-01 6.00E-03 9.00E-03 3.60E-02 3.64E-01 7.50E-03 3.00E-01 3.20E-02 4.50E-02

(kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil)

6.33E-03 1.25E-01 4.88E-03 2.94E-02 9.31E-03 1.36E-02 8.00E-03 6.40E-02 4.50E-03 9.90E-02 8.00E-03 9.00E-03 4.00E-03 6.20E-02 4.50E-03 3.00E-01 6.00E-03 9.00E-03 3.60E-02 3.64E-01 7.50E-03 3.00E-01 3.20E-02 4.50E-02

6.33E-03 1.25E-01 4.88E-03 2.94E-02 9.31E-03 1.36E-02 8.00E-03 6.40E-02 4.50E-03 9.90E-02 8.00E-03 9.00E-03 4.00E-03 6.20E-02 4.50E-03 3.00E-01 6.00E-03 9.00E-03 3.60E-02 3.64E-01 7.50E-03 3.00E-01 3.20E-02 4.50E-02 5.04E+01 2.33E+03 2.56E+01 3.36E+00 1.55E+02 3.39E+02 6.36E+01 1.19E+03 2.36E+01 1.13E+01 1.33E+02 2.24E+02 3.18E+01 1.16E+03 2.36E+01 3.43E+01 1.00E+02 2.24E+02 2.87E+02 7.33E+03 3.94E+01 6.58E+01 5.62E+02 1.98E+03

(kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air)

0.05

Dry deposition velocity Wet deposition velocity

0.25 0.25

cm/s cm/s

2.45E-01 2.45E-01

2.45E-03 2.45E-03

Annual mean irrigation rate Annual mean evapotranspiration rate Mean precipitation across Europe Leach soil loss constant Leach soil loss constant Leach soil loss constant Leach soil loss constant Leach soil loss constant Leach soil loss constant Leach soil loss constant Leach soil loss constant Leach soil loss constant Leach soil loss constant Leach soil loss constant Leach soil loss constant Leach soil loss constant Leach soil loss constant Leach soil loss constant Leach soil loss constant Leach soil loss constant Leach soil loss constant --- ingestion As --- pasture As --- crops As --- ingestion Cd --- pasture Cd --- crops Cd --- ingestion Cr --- pasture Cr --- crops Cr --- ingestion MeHg --- pasture MeHg --- crops MeHg --- ingestion Ni --- pasture Ni --- crops Ni --- ingestion Pb --- pasture Pb --- crops Pb

(m3/yr)/m2 1/s 1/s 1/s 1/s 1/s 1/s 1/s yr yr yr yr yr yr (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) (kg/m3_wat)/(kg/m3_air) Cpl,root/Cair

Dry deposition velocity Wet deposition velocity

0.14 0.14

cm/s cm/s cm/s cm/s cm/s

1.35E-01 1.35E-01 4.90E-01 2.26E-02 2.70E-01

1.35E-03 1.35E-03 4.90E-03 2.26E-04 2.70E-03

m/s m/s m/s m/s m/s

Vdep . Total deposition velocity (dry+wet) --- As, Cd, Cr, Ni Total deposition velocity (dry+wet) --- elemental Hg Total deposition velocity (dry+wet) --- Pb

kwat . Overall water loss constant --- As Overall water loss constant --- Cd Overall water loss constant --- Cr Overall water loss constant --- MeHg Overall water loss constant --- Ni Overall water loss constant --- Pb

wat . Time constant

Time constant Time constant Time constant Time constant Time constant

--- As --- Cd --- Cr --- MeHg --- Ni --- Pb

Cwat_tot/Cair .. Total water body concentration --- As Total water body concentration --- Cd Total water body concentration --- Cr Total water body concentration --- MeHg Total water body concentration --- Ni Total water body concentration --- Pb Cwctot/Cair . Water column concentration --- As Water column concentration --- Cd Water column concentration --- Cr Water column concentration --- MeHg Water column concentration --- Ni Water column concentration --- Pb Cwat,d/Cair Dissolved phase water concentration --- As = Xwater . Dissolved phase water concentration --- Cd Dissolved phase water concentration --- Cr Dissolved phase water concentration --- MeHg Dissolved phase water concentration --- Ni Dissolved phase water concentration --- Pb

Plant concentration from root uptake - Green veg, As Plant concentration from root uptake - Green veg, Cd Plant concentration from root uptake - Green veg, Cr Plant concentration from root uptake - Green veg, MeHg Plant concentration from root uptake - Green veg, Ni Plant concentration from root uptake - Green veg, Pb Plant concentration from root uptake - Root veg, As Plant concentration from root uptake - Root veg, Cd Plant concentration from root uptake - Root veg, Cr Plant concentration from root uptake - Root veg, MeHg Plant concentration from root uptake - Root veg, Ni Plant concentration from root uptake - Root veg, Pb Plant concentration from root uptake - Grains, As Plant concentration from root uptake - Grains, Cd Plant concentration from root uptake - Grains, Cr Plant concentration from root uptake - Grains, MeHg Plant concentration from root uptake - Grains, Ni Plant concentration from root uptake - Grains, Pb Plant concentration from root uptake - Animal feed, As Plant concentration from root uptake - Animal feed, Cd Plant concentration from root uptake - Animal feed, Cr Plant concentration from root uptake - Animal feed, MeHg Plant concentration from root uptake - Animal feed, Ni Plant concentration from root uptake - Animal feed, Pb

ksoil, total Soil loss constant Soil loss constant Soil loss constant Soil loss constant Soil loss constant Soil loss constant Soil loss constant Soil loss constant Soil loss constant Soil loss constant Soil loss constant Soil loss constant Soil loss constant Soil loss constant Soil loss constant Soil loss constant Soil loss constant Soil loss constant

--- ingestion As --- pasture As --- crops As --- ingestion Cd --- pasture Cd --- crops Cd --- ingestion Cr --- pasture Cr --- crops Cr --- ingestion MeHg --- pasture MeHg --- crops MeHg --- ingestion Ni --- pasture Ni --- crops Ni --- ingestion Pb --- pasture Pb --- crops Pb

Bioconcentration factor for freshwater fish --- As Bioconcentration factor for freshwater fish --- Cd Bioconcentration factor for freshwater fish --- Cr Bioconcentration factor for freshwater fish --- MeHg Bioconcentration factor for freshwater fish --- Ni Bioconcentration factor for freshwater fish --- Pb Cfish/Cair Transfer factor air to fish --- As = Xfish . Transfer factor air to fish --- Cd Transfer factor air to fish --- Cr Transfer factor air to fish --- MeHg Transfer factor air to fish --- Ni Transfer factor air to fish --- Pb

100 200 10 100000 200 50

kg/kgfish_fw/(kg/L) kg/kgfish_fw/(kg/L) kg/kgfish_fw/(kg/L) kg/kgfish_fw/(kg/L) kg/kgfish_fw/(kg/L) kg/kgfish_fw/(kg/L)

100 200 10 100000 200 50

1.00E-01 2.00E-01 1.00E-02 1.00E+02 2.00E-01 5.00E-02 1.00E+04 2.04E+04 9.98E+02 1.54E+04 2.03E+04 3.18E+03

m3_wat/kgfish_fw m3_wat/kgfish_fw m3_wat/kgfish_fw m3_wat/kgfish_fw m3_wat/kgfish_fw m3_wat/kgfish_fw (kg/kgfish_fw)/(kg/m3_air) (kg/kgfish_fw)/(kg/m3_air) (kg/kgfish_fw)/(kg/m3_air) (kg/kgfish_fw)/(kg/m3_air) (kg/kgfish_fw)/(kg/m3_air) (kg/kgfish_fw)/(kg/m3_air)

Cpl,gv/Cair Total plant concentration - Green veg, As = Xgv . Total plant concentration - Green veg, Cd Total plant concentration - Green veg, Cr Total plant concentration - Green veg, MeHg Total plant concentration - Green veg, Ni Total plant concentration - Green veg, Pb Cpl,rv/Cair Total plant concentration - Root veg, As = Xrv . Total plant concentration - Root veg, Cd Total plant concentration - Root veg, Cr Total plant concentration - Root veg, MeHg Total plant concentration - Root veg, Ni Total plant concentration - Root veg, Pb Cpl,grain/Cair Total plant concentration - Grains, As = Xg rain . Total plant concentration - Grains, Cd Total plant concentration - Grains, Cr Total plant concentration - Grains, MeHg Total plant concentration - Grains, Ni Total plant concentration - Grains, Pb Cpl,forage/Cair Total plant concentration - Pasture, As = Xforage . Total plant concentration - Pasture, Cd Total plant concentration - Pasture, Cr Total plant concentration - Pasture, MeHg Total plant concentration - Pasture, Ni Total plant concentration - Pasture, Pb Cpl,silage/Cair Total plant concentration - Silage, As = Xsilage . Total plant concentration - Silage, Cd Total plant concentration - Silage, Cr Total plant concentration - Silage, MeHg Total plant concentration - Silage, Ni Total plant concentration - Silage, Pb

1.19E+03 3.47E+03 1.16E+03 3.37E+00 1.29E+03 9.66E+02 1.20E+03 2.33E+03 1.16E+03 1.13E+01 1.27E+03 8.51E+02 1.17E+03 2.29E+03 1.16E+03 3.43E+01 1.24E+03 8.51E+02 1.30E+04 2.01E+04 1.28E+04 6.59E+01 1.33E+04 9.01E+03 4.04E+03 1.11E+04 3.79E+03 6.58E+01 4.31E+03 4.05E+03

(kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air)

soil, total Time constant

Time constant Time constant Time constant Time constant Time constant Time constant Time constant Time constant Time constant Time constant Time constant Time constant Time constant Time constant Time constant Time constant Time constant

--- ingestion As --- pasture As --- crops As --- ingestion Cd --- pasture Cd --- crops Cd --- ingestion Cr --- pasture Cr --- crops Cr --- ingestion MeHg --- pasture MeHg --- crops MeHg --- ingestion Ni --- pasture Ni --- crops Ni --- ingestion Pb --- pasture Pb --- crops Pb

Xsoil . Soil transfer factor Soil transfer factor Soil transfer factor Soil transfer factor Soil transfer factor Soil transfer factor Soil transfer factor Soil transfer factor Soil transfer factor Soil transfer factor Soil transfer factor Soil transfer factor Soil transfer factor Soil transfer factor Soil transfer factor Soil transfer factor Soil transfer factor Soil transfer factor

--- ingestion As --- pasture As --- crops As --- ingestion Cd --- pasture Cd --- crops Cd --- ingestion Cr --- pasture Cr --- crops Cr --- ingestion MeHg --- pasture MeHg --- crops MeHg --- ingestion Ni --- pasture Ni --- crops Ni --- ingestion Pb --- pasture Pb --- crops Pb

7.97E+03 7.97E+03 7.96E+03 2.03E+04 2.01E+04 1.87E+04 5.25E+03 5.25E+03 5.25E+03 1.15E+03 2.19E+02 1.14E+02 1.76E+04 1.76E+04 1.67E+04 1.07E+05 4.41E+04 2.49E+04

(kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air)

Input data - part 5 of 5 Milk and Beef contamination

Concentration in M ILK and BEEF products (22 inputs)

Variable Qwater_beef Qforage_beef Qsilage_beef Qgrains_beef Qsoil_beef Bbeef Description Consumption of water by beef cattle Consumption of forage (pasture) by beef cattle Consumption of silage by beef cattle Consumption of grains (cereals) by beef cattle Soil ingested by beef cattle Biotransfer factor for beef cattle --- As Biotransfer factor for beef cattle --- Cd Biotransfer factor for beef cattle --- Cr Biotransfer factor for beef cattle --- MeHg Biotransfer factor for beef cattle --- Ni Biotransfer factor for beef cattle --- Pb <<------------------ User input ------------------>> Default Units Value 0.04 m3_wat/day 0.04 8.8 kg_dw/day 8.8 2.5 kg_dw/day 2.5 0.47 kg_dw/day 0.47 0.5 kg_soil/day 0.5 2.00E-03 1.20E-04 5.50E-03 7.80E-04 6.00E-03 3.00E-04 day/kg_fw day/kg_fw day/kg_fw day/kg_fw day/kg_fw day/kg_fw 2.00E-03 1.20E-04 5.50E-03 7.80E-04 6.00E-03 3.00E-04 <<--------------- MKSI units --------------->> Value Units 4.00E-02 m3_wat/s 8.80E+00 kg_dw/s 2.50E+00 kg_dw/s 4.70E-01 kg_dw/s 5.00E-01 kg_soil/s 2.00E-03 1.20E-04 5.50E-03 7.80E-04 6.00E-03 3.00E-04 s/kg_fw s/kg_fw s/kg_fw s/kg_fw s/kg_fw s/kg_fw

Qwater_dairy Qforage_dairy Qsilage_dairy Qgrains_dairy Qsoil_dairy Bmilk

Consumption of water by dairy cattle Consumption of forage (pasture) by dairy cattle Consumption of silage by dairy cattle Consumption of grains (cereals) by dairy cattle Soil ingested by dairy cattle Biotransfer factor for dairy cattle --- As Biotransfer factor for dairy cattle --- Cd Biotransfer factor for dairy cattle --- Cr Biotransfer factor for dairy cattle --- MeHg Biotransfer factor for dairy cattle --- Ni Biotransfer factor for dairy cattle --- Pb

0.06 13.2 4.1 3 0.4 6.00E-03 6.50E-06 1.50E-03 3.38E-04 1.00E-03 2.50E-04

m3_wat/day kg_dw/day kg_dw/day kg_dw/day kg_soil/day day/kg_milk day/kg_milk day/kg_milk day/kg_milk day/kg_milk day/kg_milk

0.06 13.2 4.1 3 0.4 6.00E-03 6.50E-06 1.50E-03 3.38E-04 1.00E-03 2.50E-04

6.00E-02 1.32E+01 4.10E+00 3.00E+00 4.00E-01 6.00E-03 6.50E-06 1.50E-03 3.38E-04 1.00E-03 2.50E-04

kg_dw/s kg_dw/s kg_dw/s kg_dw/s kg_soil/s s/kg_milk s/kg_milk s/kg_milk s/kg_milk s/kg_milk s/kg_milk

Cbeef/Cair Concentration in beef --- As = Xbeef . Concentration in beef --- Cd Concentration in beef --- Cr Concentration in beef --- MeHg Concentration in beef --- Ni Concentration in beef --- Pb Cmilk/Cair Concentration in milk --- As = Xmilk . Concentration in milk --- Cd Concentration in milk --- Cr Concentration in milk --- MeHg Concentration in milk --- Ni Concentration in milk --- Pb

2.67E+02 2.64E+01 7.10E+02 1.05E+00 8.48E+02 4.37E+01 1.21E+03 2.15E+00 2.94E+02 5.79E-01 2.10E+02 4.62E+01

(kg/kg_beef_fw)/(kg/m3_air) (kg/kg_beef_fw)/(kg/m3_air) (kg/kg_beef_fw)/(kg/m3_air) (kg/kg_beef_fw)/(kg/m3_air) (kg/kg_beef_fw)/(kg/m3_air) (kg/kg_beef_fw)/(kg/m3_air) (kg/kg_milk)/(kg/m3_air) (kg/kg_milk)/(kg/m3_air) (kg/kg_milk)/(kg/m3_air) (kg/kg_milk)/(kg/m3_air) (kg/kg_milk)/(kg/m3_air) (kg/kg_milk)/(kg/m3_air)

>>>>> End of Input data and Calculations <<<<<

RiskPoll MultiMedia model for toxic metals --- Dose output results
(calculations based on 1998 EPA methodology)

Unprotect sheet

Summary of main input data parameters

Output results

General parameters
Value 1.00E+03 5.00E-02 1.00E+02 Units kg/yr yr

Deposition velocity
Parameter Total deposition velocity (dry+wet) Dry deposition velocity Wet deposition velocity Units cm/s cm/s cm/s Arsenic 0.490 0.245 0.245 Cadmium 0.490 0.245 0.245 Chromium 0.490 0.245 0.245 Mercury 0.023 0.011 0.011 Nickel 0.490 0.245 0.245 Lead 0.270 0.135 0.135

Rate of pollutant emission to air Fraction of Hg transformed into Methly Hg Cutoff time

POPULATION and food consumption rates

Regional population Water Milk Meat Above ground fruits and vegetables Below ground vegetables Grains Fresh water fish Value 8.00E+01 6.00E-01 2.50E+02 1.00E+02 1.89E+02 1.00E+02 1.17E+02 3.00E+00 Units pers/km2 m3_wat/(pers.yr) kg_milk/(pers.yr) kg_fw/(pers.yr) kg_fw/(pers.yr) kg_fw/(pers.yr) kg_fw/(pers.yr) kg_fw/(pers.yr)

Soil pathway
Parameter Soil time constant Soil time constant Soil time constant Xsoil = Csoil / Cair Xsoil = Csoil / Cair Xsoil = Csoil / Cair --- Ingestion --- Pasture --- Crops --- Ingestion --- Pasture --- Crops Units yr yr yr (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) (kg/kg_soil)/(kg/m3_air) Arsenic 0.77 7.73 15.47 7 968 7 968 7 956 Cadmium 1.97 19.67 39.35 20 267 20 141 18 671 Chromium 0.51 5.10 10.19 5 249 5 249 5 249 Mercury 59.65 596.52 1193.03 1 155 0 219 0 114 Nickel 1.71 17.11 34.21 17 622 17 571 16 675 Lead 18.90 189.02 378.04 106 756 44 081 24 939

Vegetation pathway LAND parameters

Cropland Pasture Forests Other Fraction of irrigated cropland Fraction of total surface area covered by land Fraction of land that is covered by fresh water Fraction of land area that is impervious Mean precipitation rate Value 1.38E+08 8.30E+07 1.57E+08 9.40E+07 1.20E-01 3.50E-01 2.00E-02 1.00E-01 7.50E+02 Units hectares hectares hectares hectares Parameter Xgv = Cpl,gv_dw / Cair Xrv = Cpl,rv_dw / Cair Xgrain = Cpl,grain_dw / Cair Units (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) (kg/kg_dw)/(kg/m3_air) Arsenic 1 186 1 200 1 168 Cadmium 3 470 2 331 2 294 Chromium 1 161 1 159 1 159 Mercury 0 003 0 011 0 034 Nickel 1 291 1 269 1 236 Lead 0 966 0 851 0 851

Water and Fish pathway

Parameter Total pollutant flux through watershed Water time constant Xwater = Cwat,d / Cair Xfish = Cfish_fw / Cair Units kg/(m2.s)/(kg/m3_air) yr (kg/m3_wat)/(kg/m3_air) (kg/kgfish_fw)/(kg/m3_air) Arsenic 1.41E-03 3.78 100 219 10 025 Cadmium 1.46E-03 1.84 101 906 20 396 Chromium 1.40E-03 5.15 99 831 0 998 Mercury 7.45E-06 0.38 0 144 15 363 Nickel 1.45E-03 2.05 101 552 20 324 Lead 1.18E-03 0.49 62 981 3 177

mm/yr

SOIL parameters Milk and Meat pathway

Soil depth --- ingestion Soil depth --- pasture Soil depth --- crops Annual mean irrigation rate Soil-water partition coefficient --- As Soil-water partition coefficient --- Cd Soil-water Soil-water Soil-water Soil-water partition coefficient partition coefficient partition coefficient partition coefficient --- Cr --- MeHg --- Ni --- Pb Value 1.00E+00 1.00E+01 2.00E+01 1.10E+01 2.90E-02 7.50E-02 1.90E-02 7.00E+00 6.50E-02 9.00E-01 Units cm cm cm cm/yr m3_wat/kg_soil m3_wat/kg_soil m3_wat/kg_soil m3_wat/kg_soil m3_wat/kg_soil m3_wat/kg_soil Parameter Xbeef = Cbeef_fw / Cair Xmilk = Cmilk / Cair Units (kg/kg_beef_fw)/(kg/m3_air) (kg/kg_milk)/(kg/m3_air) Arsenic 0 267 1 207 Cadmium 0 026 0 002 Chromium 0 710 0 294 Mercury 0 001 0 001 Nickel 0 848 0 210 Lead 0 044 0 046

COLLECTIVE DOSE
Rate of pollutant emission to air Cutoff time Northern hemisphere population Mean breathing rate kg/yr yr pers/km2 m3_air/(pers.day) 1.00E+003 1.00E+002 20.9 20.6

(for mercury calculations)

VEGETATION parameters
Plant surface loss constant Yield per planted area - Crops Yield per planted area - Pasture Yield per planted area - Silage Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil Plant-soil bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor bioconcentration factor - Green veg, As - Green veg, Cd - Green veg, Cr - Green veg, MeHg - Green veg, Ni - Green veg, Pb - Root - Root - Root - Root - Root - Root veg, As veg, Cd veg, Cr veg, MeHg veg, Ni veg, Pb Value 1.80E+01 2.24E+00 2.40E-01 8.00E-01 6.33E-03 1.25E-01 4.88E-03 2.94E-02 9.31E-03 1.36E-02 8.00E-03 6.40E-02 4.50E-03 9.90E-02 8.00E-03 9.00E-03 4.00E-03 6.20E-02 4.50E-03 3.00E-01 6.00E-03 9.00E-03 3.60E-02 3.64E-01 7.50E-03 3.00E-01 3.20E-02 4.50E-02 Units 1/yr kg_dw/m2 kg_dw/m2 kg_dw/m2 (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) (kg/kg_dw)/(kg/kg_soil) Pathway Inhalation dose Ingestion dose Water consumption (no filtering) Milk consumption Meat consumption Freshwater fish consumption Grains consumption Root vegetables (below ground) Green vegetables (above ground) Total ingested dose Units kg/yr Arsenic 3.89E-03 Cadmium 3.89E-03 Chromium 3.89E-03 Mercury 2.20E-02 Nickel 3.89E-03 Lead 7.06E-03

kg/yr kg/yr kg/yr kg/yr kg/yr kg/yr kg/yr kg/yr

3.11E-02 1.56E-01 1.38E-02 1.56E-02 6.08E-02 1.24E-02 1.62E-02 3.06E-01

3.17E-02 2.79E-04 1.36E-03 3.17E-02 1.19E-01 2.41E-02 4.75E-02 2.56E-01

3.10E-02 3.80E-02 3.68E-02 1.55E-03 6.04E-02 1.20E-02 1.59E-02 1.96E-01

2.52E-04 4.24E-04 3.07E-04 1.35E-01 1.01E-02 6.62E-04 2.61E-04 1.47E-01

3.15E-02 2.72E-02 4.39E-02 3.16E-02 6.44E-02 1.31E-02 1.77E-02 2.29E-01

3.55E-02 1.08E-02 4.11E-03 8.96E-03 8.04E-02 1.60E-02 2.40E-02 1.80E-01

TOTAL DOSE TOTAL INTAKE FRACTION (x 106) TOTAL / Inhalation

kg/yr

3.10E-01 310 79.7

2.60E-01 260 66.8

2.00E-01 200 51.3

1.69E-01 169 7.7

2.33E-01 233 59.9

1.87E-01 187 26.5

- Grains, As - Grains, Cd - Grains, Cr - Grains, MeHg - Grains, Ni - Grains, Pb - Animal - Animal - Animal - Animal - Animal - Animal feed, As feed, Cd feed, Cr feed, MeHg feed, Ni feed, Pb

Table notes: (a) The inhalation dose from exposure to mercury assumes the pollutant is emitted as a vapor and then exists in the atmosphere mostly in elemental form Hg(0). (b) For ingested dose calculations, mercury is modeled as methyl mercury (MeHg). Only a small fraction of Hg is eventually converted into MeHg in water bodies. The fraction of Hg transformed into MeHg is user specified (parameter: f_MeHg, typical range is 1 to 10% of Hg emission). (c) As, Cd, Cr and Ni are treated as PM10; whereas Pb is modeled as PM2.5 if source is automotive emissions, but for power plants assume PM10. (d) Cr doses are values for oxidation state VI. The fraction of Cr-VI in the total emission is typically between 10 and 20% (e.g., www.epa.gov/ttncaal/t3/meta/m28497.html). (e) The inhalation dose corresponds to stack emissions of around 100 meters. For shorter stacks near cities (less than 40 m) and for industrial emissions, the inhalation dose should be multiplied by a factor of three (3). For tall stacks (greater than 200 m), meanwhile, the results should be divided by three (3). For mercury the global contribution dominates and the same inhalation dose applies to both power plant and industrial emissions. (f) The water consumption dose assumes that drinking water is not treated for toxic metal removal. (g) The Intake fraction is the pollutant intake expressed in mg per kg of emission.

WATER and FISH parameters

Water column depth Upper benthic sediment layer Total suspended solids concentration Bioconcentration factor for freshwater Bioconcentration factor for freshwater Bioconcentration factor for freshwater Bioconcentration factor for freshwater Bioconcentration factor for freshwater Bioconcentration factor for freshwater Value 1.00E+00 3.00E+00 1.00E+01 1.00E+02 2.00E+02 1.00E+01 1.00E+05 2.00E+02 5.00E+01 Units m cm kg_soil/m3_wat kg/kgfish_fw/(kg/L) kg/kgfish_fw/(kg/L) kg/kgfish_fw/(kg/L) kg/kgfish_fw/(kg/L) kg/kgfish_fw/(kg/L) kg/kgfish_fw/(kg/L)

>>>>> End of assessment results <<<<<

fish --- As fish --- Cd fish --- Cr fish --- MeHg fish --- Ni fish --- Pb

MILK and MEAT parameters

Consumption of water by beef cattle Consumption of forage (pasture) by beef cattle Consumption of silage by beef cattle Consumption of grains (cereals) by beef cattle Soil ingested by beef cattle Biotransfer Biotransfer Biotransfer Biotransfer Biotransfer Biotransfer factor factor factor factor factor factor for for for for for for beef beef beef beef beef beef cattle cattle cattle cattle cattle cattle --- As --- Cd --- Cr --- MeHg --- Ni --- Pb Value 4.00E-02 8.80E+00 2.50E+00 4.70E-01 5.00E-01 2.00E-03 1.20E-04 5.50E-03 7.80E-04 6.00E-03 3.00E-04 6.00E-02 1.32E+01 4.10E+00 3.00E+00 4.00E-01 6.00E-03 6.50E-06 1.50E-03 3.38E-04 1.00E-03 2.50E-04 Units m3_wat/day kg_dw/day kg_dw/day kg_dw/day kg_soil/day day/kg_fw day/kg_fw day/kg_fw day/kg_fw day/kg_fw day/kg_fw m3_wat/day kg_dw/day kg_dw/day kg_dw/day kg_soil/day day/kg_milk day/kg_milk day/kg_milk day/kg_milk day/kg_milk day/kg_milk

Consumption of water by dairy cattle Consumption of forage (pasture) by dairy cattle Consumption of silage by dairy cattle Consumption of grains (cereals) by dairy cattle Soil ingested by dairy cattle Biotransfer Biotransfer Biotransfer Biotransfer Biotransfer Biotransfer factor factor factor factor factor factor for for for for for for dairy cattle dairy cattle dairy cattle dairy cattle dairy cattle dairy cattle --- As --- Cd --- Cr --- MeHg --- Ni --- Pb

RiskPoll MultiMedia model for toxic metals --(calculations based on 1998 EPA methodology)

Unprotect sheet

Collective dose or intake fraction by exposure pathway (mg intake per kg emitted pollutant)
Cutoff time Pathway Inhalation Water Cattle milk Cattle meat Freshwater fish Grains Root vegetables Green vegetables TOTAL 1.00E+002 yr Arsenic 3.9 31.1 156.2 13.8 15.6 60.8 12.4 16.2 310.1 Cadmium Chromium VI 3.9 3.9 31.7 31.0 0.3 38.0 1.4 36.8 31.7 1.6 119.5 60.4 24.1 12.0 47.5 15.9 260.0 199.5

Table notes: (a) The inhalation dose from exposure to mercury assumes the pollutant is emitted as a vapo (b) For ingested dose calculations, mercury is modeled as methyl mercury (MeHg). Only a sm The fraction of Hg transformed into MeHg is user specified (parameter: f_MeHg, typical ra (c) As, Cd, Cr and Ni are treated as PM10; whereas Pb is modeled as PM2.5 if source is autom (d) Cr doses are values for oxidation state VI. The fraction of Cr-VI in the total emission is typ (e) The inhalation dose corresponds to stack emissions of around 100 meters. For shorter sta the inhalation dose should be multiplied by a factor of three (3). For tall stacks (greater th For mercury the global contribution dominates and the same inhalation dose applies to bo (f) The water consumption dose assumes that drinking water is not treated for toxic metal rem (g) The Intake fraction is the pollutant intake expressed in mg per kg of emission.

To modify a graph, select chart and right mouse click to access chart options

Plot 1 of 3 (color format)

Collective dose by pathway as a p [table values as mg intake per kg emiss

Lead

Nickel

Mercury

Chromium VI

Cadmium

Arsenic

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Plot 3 of 3 (black and white format)

Collective dose by pathw [table values as mg intake per

Lead

Collective dose by pathw [table values as mg intake per

Lead

Nickel

Mercury

Chromium VI

Cadmium

Arsenic

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c metals --- Graph of collective dose

osure pathway

Mercury 22.0 0.3 0.4 0.3 134.9 10.1 0.7 0.3 168.8

Nickel 3.9 31.5 27.2 43.9 31.6 64.4 13.1 17.7 233.3

Lead 7.1 35.5 10.8 4.1 9.0 80.4 16.0 24.0 186.9

pollutant is emitted as a vapor and then exists in the atmosphere mostly in elemental form Hg(0). yl mercury (MeHg). Only a small fraction of Hg is eventually converted into MeHg in water bodies. parameter: f_MeHg, typical range is 1 to 10% of Hg emission). d as PM2.5 if source is automotive emissions, but for power plants assume PM10. -VI in the total emission is typically between 10 and 20% (e.g., www.epa.gov/ttncaal/t3/meta/m28497.html). d 100 meters. For shorter stacks near cities (less than 40 m) and for industrial emissions, (3). For tall stacks (greater than 200 m), meanwhile, the results should be divided by three (3). e inhalation dose applies to both power plant and industrial emissions. not treated for toxic metal removal. er kg of emission.

k to access chart options

pathway as a percentage of total ake per kg emission; Cutoff time 100 yr]
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Chromium VI

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e dose by pathway as a percentage of total s mg intake per kg emission; Cutoff time 100 yr]

e dose by pathway as a percentage of total s mg intake per kg emission; Cutoff time 100 yr]

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Plot 2 of 3 (fill-in pictures format)

Collective dose by pathway as a percentage of t [table values as mg intake per kg emission; Cutoff tim
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Cadmium

Arsenic

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a percentage of total ission; Cutoff time 100 yr]

LEGEND
Inhalation

Water

Cattle milk

Cattle meat

Freshwater fish

Grains

Root vegetables

Green vegetables

60%

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LEGEND

Input data
Rate of pollutant emission to air [kg/yr]

Doses, impacts and social costs

1000 100 80

General parameters (3 inputs)

Variable f_Infants Uv_cancer Uv_IQ_Loss Description Fraction of population below age of 1 year Social cost per cancer case Social cost for the loss of an IQ point <<------------------ User input ------------------>> Default Units Value 0.01 0.01 2000000 per cancer 2000000 3000 per IQ point 3000

Cutoff time [yr] Regional population [pers/km2]

Parameter

Description

Units

Arsenic

Cadmium

Chromium VI

Nickel

Lead

INHALATION pathway
Vdep sCR D_inhal I_inhal Cost_inhal Iu_inhal To do list - Add PPPGNP/cap table and discussion - Idiot proof user input data Total deposition velocity (dry+wet) Slope concentration response function Collective inhalation dose Collective impact Social cost from inhalation Unit impact from inhalation cm/s cancers/(pers.yr.kg/m3) kg/yr cancers/yr per yr cancers per kg 0.49 6.14E+04 3.89E-03 3.18E-02 6.36E+04 3.18E-05 0.49 2.57E+04 3.89E-03 1.33E-02 2.66E+04 1.33E-05 0.49 1.71E+05 3.89E-03 8.85E-02 1.77E+05 8.85E-05 0.49 3.43E+03 3.89E-03 1.78E-03 3.55E+03 1.78E-06 0.27 7.06E-03

Uv_inhal

Unit cost from inhalation

per kg

63.6

26.6

177.1

3.6

INGESTION pathway
sDR sDR_Pb D_food I_food I_food_Pb Cost_food Iu_food Iu_food_Pb Uv_food Slope dose response function Slope dose response function for Pb Collective ingestion dose Collective impact Collective impact for Pb Social cost from ingestion Unit impact from ingestion Unit impact from ingestion of Pb cancers/kg_absorbed IQ_points/kg_absorbed kg/yr cancers/yr IQ_points/yr per yr cancers per kg IQ points per kg 1.07 3.06E-01 3.28E-01 6.55E+05 3.28E-04 655.4 2.56E-01 1.96E-01 2.29E-01 3291 1.80E-01 5.92E+02 1.78E+06 0.592 1775.6

Unit cost from ingestion

per kg

TOTAL results
Collective dose Collective impact Collective impact of Pb Annual cost Unit impact Unit impact of Pb Unit cost kg/yr cancers/yr IQ_points/yr per yr cancers per kg IQ points per kg per kg 3.10E-01 3.59E-01 7.19E+05 3.59E-04 718.9 2.60E-01 1.33E-02 2.66E+04 1.33E-05 26.6 2.00E-01 8.85E-02 1.77E+05 8.85E-05 177.1 2.33E-01 1.78E-03 3.55E+03 1.78E-06 3.6 1.87E-01 5.92E+02 1.78E+06 5.92E-01 1775.6