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Jair C. C. Freitas
Programa de Ps-graduao em Fsica UFES Programa de Ps-graduao em Qumica - UFES
Sumrio Aula 01
Fundamentos de RMN:
Princpios fsicos.
Propriedades nucleares. Precesso de spins. Paramagnetistmo nuclear. Frequncia de Larmor. Condio de ressonncia.
Jair C. C. Freitas
Hahn (1949): ecos de spin. Packard (1951): deslocamento qumico em etanol. Andrew, Lowe (1959): RMN no estado slido. Ernst (1964): RMN com transformada de Fourier.
Prmio Nobel de Qumica - 1991.
Jair C. C. Freitas
k =1
Z A Z = ( N / ) l k + g sp s k + g sn s k k = Z +1 k =1 k =1
I
//
efetivo =
I I ( I + 1)
2
I = I
126 112
1i13/2 3p 1/2 3p 3/2 2f5/2 2f7/2 1h 9/2
j =l +s
3p 2f 1h
j = l 1/ 2
Notao:
82 92
1h 11/2 3s 1/2 2d 3/2 2d 5/2 1g 7/2
3s 2d
58
1g
50 40
1g 9/2 2p 1/2 1f5/2 2p 3/2 1f7/2
n lj
2p 1f
28 20 20
2s 1d
8
1p
8
1p 1/2 1p 3/2
2 j +1
2
1s
2
1s 1/2
Jair C. C. Freitas
I = jn I = jp jn j p I jn + j p
Jair C. C. Freitas
13C
I = 1/2
1p 1/2 1p 3/2 1s 1/2 1p 1/2 1p 3/2 1s 1/2
14N
I=1
1p 1/2 1p 3/2 1s 1/2 1p 1/2 1p 3/2 1s 1/2
Z=6
N=7
Z=7
N=7
27Al
I = 5/2
1d 5/2 1p 1/2 1p 3/2 1s 1/2 1d 5/2 1p 1/2 1p 3/2 1s 1/2
29Si
I = 1/2
2s 1/2 1d 5/2 1p 1/2 1p 3/2 1s 1/2 2s 1/2 1d 5/2 1p 1/2 1p 3/2 1s 1/2
Z = 13
N = 14
Z = 14
N = 15
Jair C. C. Freitas
I
1/2 1/2 1 1/2 1/2 5/2 1/2 1/2 5/2 7/2 3/2 3/2
(mltiplos de N) 2,7928 0,7024 0,4036 0,2831 2,6287 3,6414 0,5553 1,1317 3,4680 4,6490 0,2700 0,3600
Q
(barns) 0 0 0,01 0 0 0,150 0 0 0,400 0,400 1,300 1,500
H C
13
14
N N F
15
19
27
Al Si P
29
31
55
Mn Co Gd Gd
59
155
157
Jair C. C. Freitas
Jair C. C. Freitas
Jair C. C. Freitas
Jair C. C. Freitas
Bibliografia recomendada
Fundamentos de RMN: Os ncleos atmicos e a RMN, J. C. C. Freitas, T. J. Bonagamba. In: J. D. Figueroa Villar (editor), Fundamentos e Aplicaes de Ressonncia Magntica Nuclear, no 1, AUREMN, 1999. Spin dynamics, M. H. Levitt. John Wiley & Sons, 2002. Principles of magnetic resonance, C. P. Slichter. Springer, 1996. Ressonncia magntica nuclear: fundamentos, mtodos e aplicaes, V. M. S. Gil, C. F. G. C. Geraldes. Fundao Calouste Gulbekian, 1987. NMR nomenclature. Nuclear spin properties and conventions for chemical shifts (IUPAC recommendations 2001), R. K. Harris, E. D. Becker, S. M. Cabral de Menezes, R. Goodfelow, P. Granger. Pure Appl. Chem. 2001;73:1795-1818.
Jair C. C. Freitas