Chemistry Dictionary: Rayleigh scattering Top Home > Library > Science > Chemistry Dictionary Scattering of electromagnetic

radiation by molecules in which the frequency of the scattered radiation is unchanged. This type of scattering was analysed by Lord Rayleigh in his papers in the late 19th century, which showed that the blue colour of the sky is a result of this type of light scattering, with molecules of the atmosphere of the earth scattering light from the sun.

Britannica Concise Encyclopedia: Rayleigh scattering Top Home > Library > Miscellaneous > Britannica Concise Encyclopedia Dispersion of electromagnetic radiation by particles with radii less than 1/10 the wavelength of the radiation. It is named for Baron Rayleigh, who described it in 1871. Since blue light is at the short wavelength end of the visible spectrum, it is scattered in the atmosphere much more than the longer-wavelength red light. This causes the blue colour of the sky, since the observer sees only the scattered light. The Rayleigh laws predict the variation of the intensity and the polarization of scattered light. For more information on Rayleigh scattering, visit Britannica.com. Wikipedia: Rayleigh scattering Top Home > Library > Miscellaneous > Wikipedia This article is about the optical phenomenon. For the magnetic phenomenon, see Rayleigh law.

Rayleigh scattering causes the blue hue of the daytime sky and the reddening of the sun at sunset

Rayleigh scattering is more dramatic after sunset. This picture was taken about one hour after sunset at 500m altitude, looking at the horizon where the sun had set. Rayleigh scattering (named after Lord Rayleigh) is the elastic scattering of light or other electromagnetic radiation by particles much smaller than the wavelength of the light. It can occur when light travels in transparent solids and liquids, but is most prominently seen in gases. Rayleigh scattering of sunlight in clear atmosphere is the main reason why the sky is blue: Rayleigh and cloud-mediated scattering contribute to diffuse light (direct light being sunrays). For scattering by particles similar to or larger than a wavelength, see Mie theory or discrete dipole approximation (they apply to the Rayleigh regime as well).

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1 Small size parameter approximation 2 Rayleigh scattering from molecules 3 Why is the sky blue? 4 See also 5 References 6 External links

Small size parameter approximation

Figure showing the more intense scattering of blue light by the atmosphere relative to red light. The size of a scattering particle is parametrized by the ratio x of its characteristic dimension r and wavelength :

. Rayleigh scattering can be defined as scattering in the small size parameter regime . Scattering from larger spherical particles is explained by the Mie theory for an arbitrary size parameter x. The Mie theory reduces to the Rayleigh approximation. The amount of Rayleigh scattering that occurs for a beam of light is dependent upon the size of the particles and the wavelength of the light; in particular, the scattering coefficient, and hence the intensity of the scattered light, varies for small size parameter inversely with the fourth power of the wavelength. The intensity I of light scattered by a single small particle from a beam of unpolarized light of wavelength and intensity I0 is given by:

where R is the distance to the particle, is the scattering angle, n is the refractive index of the particle, and d is the diameter of the particle. The angular distribution of Rayleigh scattering, governed by the (1+cos2) term, is symmetric about the plane normal to the incident direction of the light (i.e. about = 90), and so the forward scatter equals the backwards scatter. Integrating over the sphere surrounding the particle gives the Rayleigh scattering cross section

The Rayleigh scattering coefficient for a group of scattering particles is the number of particles per unit volume N times the cross-section. As with all wave effects, for incoherent scattering the scattered powers add arithmetically, while for coherent scattering, such as if the particles are very near each other, the fields add arithmetically and the sum must be squared to obtain the total scattered power.

Rayleigh scattering from molecules

A 5 mW green laser pointer is visible at night due to Rayleigh scattering and airborne dust. Rayleigh scattering from molecules is also possible. An individual molecule does not have a well-defined refractive index and diameter. Instead, a molecule has a polarizability , which describes how much the electrical charges on the molecule will move in an electric field. In this case, the Rayleigh scattering intensity for a single particle is given by[1]

The amount of Rayleigh scattering from a single particle can also be expressed as a cross section . For example, the major constituent of the atmosphere, nitrogen, has a Rayleigh cross section of 5.110-31 m2 at a wavelength of 532 nm (green light).[2] This means that at atmospheric pressure, about a fraction 10-5 of light will be scattered for every meter of travel. The strong wavelength dependence of the scattering (~-4) means that blue light is scattered much more readily than red light. In the atmosphere, this results in blue wavelengths being scattered to a greater extent than longer (red) wavelengths, and so one sees blue light coming from all regions of the sky. Direct radiation (by definition) is coming directly from the Sun. Rayleigh scattering is a good approximation to the manner

in which light scattering occurs within various media for which scattering particles have a small size parameter.

Why is the sky blue?

Colorado sky Further information: Diffuse sky radiation When one looks at the sky during the day, rather than seeing the black of space, one sees light from Rayleigh scattering off the air. Rayleigh scattering is inversely proportional to the fourth power of wavelength, which means that the shorter wavelength of blue light will scatter more than the longer wavelengths of green and red light. This gives the sky a blue appearance. Conversely, when one looks towards the sun, one sees the colors that were not scattered away the longer wavelengths such as red and yellow light. When the sun is near the horizon, the volume of air through which sunlight must pass is significantly greater than when the sun is high in the sky. Accordingly, the gradient from a red-yellow sun to the blue sky is considerably wider at sunrise and sunset. Rayleigh scattering primarily occurs through light's interaction with air molecules. Some of the scattering can also be from aerosols of sulfate particles. For years following large Plinian eruptions, the blue cast of the sky is notably brightened due to the persistent sulfate load of the stratospheric eruptive gases. Another source of scattering is from microscopic density fluctuations, resulting from the random motion of the air molecules. A region of higher or lower density has a slightly different refractive index than the surrounding medium, and therefore it acts like a short-lived particle that can scatter light.