Chapter 4 Quiz AP Chemistry Put all answers on a separate piece of paper. MULTIPLE CHOICE.

Choose the one alternative that best completes the statement or answers the question. 1) What are the spectator ions in the reaction between KOH (aq) and HNO3 (aq)? A) OH- only B) H+ and NO3 C) H+ and OHD) K + and NO3 E) K + and H + 2) Based on the equations below, which metal is the most active?

Pb(NO3)2 (aq) + Ni (s)

Pb(NO3)2 (aq) + Ag (s) Cu(NO3 )2 (aq) + Ni (s)

A) Pb B) Ag

Ni(NO3 )2 (aq) + Pb (s) No reaction Ni(NO 3 )2 (aq) + Cu (s)

C) N D) Ni E) Cu

3) In a titration of 35.00 mL of 0.737 M H2 SO4 , __________ mL of a 0.827 M KOH solution is required for

neutralization. A) 1.12

B) 39.3

C) 25.8

D) 62.4

E) 35.0

4) Aqueous potassium chloride will react with which one of the following in an exchange (metathesis) reaction? A) sodium bromide B) calcium nitrate C) lead nitrate D) sodium chloride E) barium nitrate 5) Oxalic acid is a diprotic acid. Calculate the percent of oxalic acid (H2 C2 O4 ) in a solid given that a 0.7984 g

sample of that solid required 37.98 mL of 0.2283 M NaOH for neutralization. A) 97.78 B) 28.59 C) 48.89 D) 22.83

E) 1.086

6) A 17.5 mL sample of an acetic acid (CH3 CO2 H) solution required 29.6 mL of 0.250 M NaOH for neutralization.

The concentration of acetic acid was __________ M. A) 0.423 B) 0.214 C) 134

D) 0.158

E) 6.88

7) A 25.5 mL aliquot of HCl (aq) of unknown concentration was titrated with 0.113 M NaOH (aq). It took 51.2 mL of the base to reach the endpoint of the titration. The concentration (M) of the acid was __________. A) 1.02 B) 0.114 C) 0.227 D) 0.113 E) 0.454 8) A 31.5 mL aliquot of HNO3 (aq) of unknown concentration was titrated with 0.0134 M NaOH (aq). It took 23.9

mL of the base to reach the endpoint of the titration. The concentration (M) of the acid was __________. A) 0.0204 B) 0.227 C) 0.0051 D) 1.02 E) 0.0102

9) A 31.5 mL aliquot of H2 SO4 (aq) of unknown concentration was titrated with 0.0134 M NaOH (aq). It took

23.9 mL of the base to reach the endpoint of the titration. The concentration (M) of the acid was __________. A) 0.227 B) 0.00508 C) 0.0102 D) 0.0204 E) 0.102

10) The net ionic equation for the reaction between aqueous solutions of HF and KOH is __________. H2O A) H+ + OHB) HF + KOH C) HF + OH-

H 2 O + K + + FH2 O + FH2 O + KF H2 O + K + + F-

D) HF + K + + OH -

E) H+ + F- + K + + OH-

11) Combining aqueous solutions of BaI2 and Na2 SO4 affords a precipitate of BaSO4 . Which ion(s) is/are spectator

ions in the reaction? A) SO4 2- and IB) Na+ only C) Ba2+ only

D) Na+ and IE) Ba2+ and SO4 212) Which ion(s) is/are spectator ions in the formation of a precipitate of AgCl via combining aqueous solutions of CoCl2 and AgNO3 ? A) NO3 - and ClB) NO3 C) Co2+ and Ag+ D) Cl-

E) Co2+ and NO3-

13) The balanced net ionic equation for precipitation of CaCO3 when aqueous solutions of Na2 CO3 and CaCl 2 are mixed is __________. Na2CO3 (aq) A) 2Na+ (aq) + CO3 2- (aq)

2NaCl (aq) B) 2Na+ (aq) + 2Cl - (aq) C) Na2 CO3 (aq) + CaCl2 (aq) 2NaCl (aq) + CaCO3 (s) NaCl (aq) D) Na+ (aq) + Cl - (aq) 2+ (aq) + CO3 2- (aq) CaCO3 (s) E) Ca
14) When aqueous solutions of AgNO3 and KI are mixed, AgI precipitates. The balanced net ionic equation is

__________. AgNO3 (aq) A) Ag+ (aq) + NO3 - (aq) AgI (s) B) Ag+ (aq) + I- (aq) C) AgNO3 (aq) + KI (aq) AgI (aq) + KNO3 (s)
D) AgNO3 (aq) + KI (aq) E) Ag+ (aq) + NO3 - (aq)

AgI (s) + KNO3 (aq)

AgNO3 (s)

15) When H 2 SO4 is neutralized by NaOH in aqueous solution, the net ionic equation is __________. A) SO4 2- (aq) + 2Na+ (aq) B) 2H + (aq) + 2NaOH (aq) C) H+ (aq) + OH- (aq)

Na2 SO4 (aq) 2H 2 O (l) + 2Na+ (aq) H2 O (l) 2H 2 O (l) + SO4 2- (aq)

D) H2 SO4 (aq) + 2OH- (aq) E) SO4 2- (aq) + 2Na+ (aq)

Na2 SO4 (s)

16) The spectator ions in the reaction between aqueous perchloric acid and aqueous barium hydroxide are __________. A) OH- and ClO4B) ClO4 - and Ba2+ C) H+ , OH- , ClO4 - , and Ba2+

D) H+ and OHE) H+ and Ba2+ 17) The spectator ions in the reaction between aqueous hydrofluoric acid and aqueous barium hydroxide are __________. A) OH- and FB) H+, OH- , F- , and Ba2+ C) Ba2+ only

D) F- and Ba2+ E) OH- , F- , and Ba2+

18) The spectator ions in the reaction between aqueous hydrochloric acid and aqueous ammonia are __________. A) H+ , Cl- , and NH 4 + B) H+ , Cl- , NH 3, and NH4 + C) H+ and NH3 D) Cl- only E) Cl- and NH4 + 19) Which of the following are strong acids? HI HNO3

HF HBr A) HI , HNO3 , HF , HBr B) HNO3 , HF , HBr

C) HI , HF , HBr D) HF , HBr E) HI , HNO3 , HBr

20) Which hydroxides are strong bases? Sr(OH) 2

KOH NaOH Ba(OH) 2

A) KOH, Ba(OH) 2

C) KOH, NaOH D) Sr(OH) 2 , KOH, NaOH, Ba(OH) 2 E) None of these is a strong base. 21) A neutralization reaction between an acid and a metal hydroxide produces __________. A) oxygen gas B) hydrogen gas C) ammonia D) sodium hydroxide E) water and a salt 22) Of the metals below, only __________ will not dissolve in an aqueous solution containing nickel ions. aluminum chromium barium tin potassium A) tin

B) KOH, NaOH, Ba(OH) 2

B) aluminum

C) barium

D) potassium

E) chromium

23) Which of these metals is the least easily oxidized? Na Au Fe Ca Ag A) Ca

B) Fe

C) Au

D) Na

E) Ag

24) Of the following elements, __________ is the only one that cannot be found in nature in its elemental form. Cu Hg Au Ag Na A) Hg

B) Na

C) Ag

D) Cu

E) Au

25) Of the following elements, __________ is the most easily oxidized. oxygen fluorine nitrogen aluminum gold A) gold

B) oxygen

C) fluorine

D) aluminum

E) nitrogen