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CHEMISTRY
Paper 2 Two hours and thirty minutes DO NOT OPEN THE QUESTION BOOKLET UNTIL BEING TOLD TO DO SO 1. Write your name and index number in the spaces provided.
Tuliskan nama dan angka giliran anda pada ruang yang disediakan.
Full mark
Marks
1 2 3 A 4 5 6 7 B 8 9 C 10 TOTAL
9 9 10 10 11 11 20 20 20 20
3. Candidate is required to read the information at the back page of the question booklet.
Calon dikehendaki membaca maklumat di halaman belakang kertas soalan ini .
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Diagram 1.1 shows the set up of the apparatus used in an experiment to determine the melting point of a substance M.
Rajah 1.1 menunjukkan susunan radas yung digunakan untuk menentukan takat lebur bahan M.
Diagram 1.1
Rajah 1.1
1(a)(i) i)
(a)
(i)
... [1 mark]
[1 markah]
1(a)(ii)
(ii)
... [1 mark]
[1 markah]
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(b)
Diagram 1.2 shows a graph of temperature against time when solid of substance M is heated.
Rajah 1.2 menunjukkan graf suhu melawan masa apabila pepejal bahan M dipanaskan.
Diagram 1.2
Rajah 1.2
(i)
1(b)(i)
... [1 mark]
[1 markah]
(ii)
1(b)(ii)
... [1 mark]
[1 markah]
(iii)
... [1 mark]
[1 markah]
1(b) (iii)
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(iv)
(c)
Diagram 1.3
Rajah 1.3
(i) 1(c)(i)
(ii) 1(c)(ii)
... [1 mark]
[1 markah]
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Diagram 2 shows the set up of apparatus of two types of cells. Rajah 2 menunjukkan susunan radas dua jenis sel.
Cell I
Sel I
Cell II
Sel II
Diagram 2
Rajah 2
(a) (i)
2(a)
[2 markah]
Cell I : ..
Sel I
2(b)
(c)
(i)
2(c)(i)
[1 mark]
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2(f)
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(ii) 2(c)(ii)
[1 mark]
[1 markah]
2(c) (iii)
(iii)
... [1 mark]
[1 markah]
(d)
Zinc electrode and zinc sulphate solution in Cell II are replaced by iron electrode and iron (II) sulphate solution. State the changes to the voltmeter reading. Explain your answer.
Elektrod zink dan larutan zink sulfat dalam sel II digantikan dengan elektrod ferum dan larutan ferum (II ) sulfat, Nyatakan perubahan kepada bacaan voltmeter. Terangkan jawapan anda..
2(d)
[2 marks]
[2 markah]
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Diagram 3 shows the apparatus set-up for the preparation of zinc sulphate from zinc carbonate and an acid.
Rajah 3 menunjukkan susunan radas untuk penyediaan zink sulfat daripada zink karbonat dengan suatu asid.
(a)
[1 mark]
[1 markah]
3(a)
(b)
(i)
3(b)(i)
[2 marks]
[2 markah]
(ii)
3(b)(ii)
[1 mark]
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(c)
(i)
3(c)(i)
[1 mark]
[1 markah]
(ii) 3(c)(ii)
[2 marks]
[2 markah]
(d)
Zinc sulphate
Zink sulfat
+ X
X sulphate + zinc
X sulfat + zink
3(d)(i)
(i)
[1 mark]
[1 markah]
(ii) 3(d)(ii)
What is observed when aqueous ammonia is added in excess to zinc sulphate solution?
Apakah yang diperhatikan apabila ammonia akueus ditambah kepada larutan zink sulfat sehingga berlebihan?
[2 marks]
[2 markah]
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Vinegar is aqueous ethanoic acid. The concentration of ethanoic acid in the vinegar was determined by titrating the vinegar with 0.10 mol dm-3 sodium hydroxide solution using phenolphthalein as an indicator. The result of the experiment is shown in Table 4.
Cuka adalah larutan asid etanoik. Kepekatan asid etanoik dalam cuka ditentukan melalui pentitratan dengan 0.10 mol dm -3 larutan natrium hidroksida dengan menggunakan fenoftalein sebagai penunjuk. Keputusan eksperimen di tunjukkan dalam Jadual 4.
Titration II
Penitratan II
Titration III
Penitratan III
0.00 23.40
23.40 47.00
0.00 23.50
Table 4
Jadual 4
(a)
[1 mark]
[1 markah]
4(a)
(b)
4(b)
[1 markah]
[1 mark] (c) (i) Complete Table 4 by calculating the volume of sodium hydroxide solution used in each titration
Lengkapkan Jadual 4 dengan menghitung isipadu larutan natrium hidroksida yang digunakan dalam setiap pentitratan.
4(c)(i)
[1 mark]
[1 markah]
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(ii)
Calculate the average volume of 0.10 mol dm-3 of sodium hydroxide solution used to neutralize 25.00 cm3 of vinegar.
Hitung isipadu purata larutan natrium hidroksida 0.10 mol dm-3 yang digunakan untuk meneutralkan 25.00 cm3 cuka.
4(c)(ii)
[1 mark]
[1 markah]
(d)
(i)
Calculate the number of moles of sodium hydroxide used to neutralize 25.0 cm3 of vinegar.
Hitung bilangan mol natrium hidroksida yang digunakan untuk meneutralkan 25.00 cm3 cuka.
4(d)(i) [1mark]
[1 markah]
(ii)
4(d)(ii) [3 marks]
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(e)
The experiment is repeated using 0.10 mol dm-3 of barium hydroxide to replace sodium hydroxide. Predict the volume of barium hydroxide solution required to neutralize 25.00 cm3 of vinegar. Explain your answer.
Eksperimen diulangi menggunakan larutan barium hidroksida 0.10 mol dm -3 menggantikan larutan natrium hidroksida.. Ramalkan isipadu larutan barium hidroksida yang diperlukan untuk menutralkan 25.00 cm3 cuka. Terangkan jawapan anda.
[2 marks]
[2 markah]
4(e)
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In an experiment, 50.0 cm3 of hydrogen peroxide solution is mixed with 1.0 g of manganese(IV) oxide powder. The total volume of oxygen gas liberated is measured at 30 seconds intervals. Table 5 shows the result of the experiment.
Dalam satu eksperimen, 50.0 cm3 larutan hydrogen peroksida di campurkan dengan 1.0g serbuk mangan(IV) oksida. Jumlah isipadu gas oksigen yang dibebaskan diukur setiap 30 saat. Jadual 5 menunjukkan keputusan ekperimen.
Time (s)
Masa (s)
30
60
90
120
150
180
210
5(a)
(a)
[1 mark]
[1 markah]
(b) 5(b)
[1 mark]
[1 markah]
(c)
Plot a graph of the volume of oxygen gas against time on page 13.
Plotkan graf isipadu gas oksigen melawan masa pada muka surat 13.
[3 marks]
[3 markah]
(d) 5(d)
How long does it take for the decomposition of hydrogen peroxide to be completed?
Berapa lamakah masa yang diambil untuk penguraian lengkap hidrogen peroksida?
[1 mark]
[1 markah]
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5(c)
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(e)
(i)
5(e)(i) [2 marks]
[2 markah]
(ii)
5(e)(ii) (f)
[1 mark]
[1 markah]
The experiment is repeated using 2.0 g of manganese(IV) oxide. The reaction stops at 120 seconds. Explain.
Eksperimen diulangi menggunakan 2.0 g mangan(IV) oksida. Tindak balas berhenti pada 120 saat. Terangkan.
5(f) [2 marks]
[2 markah]
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5(f)
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Diagram 6 shows the apparatus set-up to determine the heat of displacement of copper from its salt solution by lead powder.
Rajah 6 menunjukkan susunan radas untuk menentukan haba penyesaran kuprum daripada larutan garamnya oleh serbuk plumbum.
Diagram 6
Rajah 6
50 cm3 of 0.2 mol dm-3 copper(II) sulphate is poured into a polystyrene cup. The initial temperature of the solution is recorded. Excess lead powder is added into the copper(II) sulphate solution, stirred and the maximum temperature is recorded. Table 6 shows the result of the experiment.
50 cm3 larutan kuprum(II) sulfat 0.2 mol dm-3 dimasukkan ke dalam sebuah cawan polistirena. Suhu awal larutan direkodkan. Serbuk plumbum berlebihan ditambah ke dalam larutan kuprum(II) sulfat, campuran dikacau dan suhu tertinggi larutan direkodkan.. Jadual 6 menunjukkan keputusan eksperimen
Initial temperature / oC
Suhu awal
28.0 33.0
Maximum temperature / oC
Suhu tertinggi
Jadual 6
Table 6
(a)
Give one suggestion on how the above apparatus can be improved to get a better result.
Berikan satu cadangan bagaimana radas di atas dapat diperbaiki untuk mendapatkan keputusan yang lebih baik.
[1 mark]
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6(a)
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(b) 6(b)
[1 mark]
[1 markah]
6(c)
(c)
[1 mark]
[1 markah]
(d)
(i)
6(d)(i) [1 mark]
[1 markah]
(ii)
Calculate the amount of heat released in the experiment. [Density of solution = 1.0 g cm-3 and specific heat capacity of water = 4.2 J g-1oC-1]
Hitung jumlah haba yang dibebaskan dalam eksperimen.. [ Ketumpatan larutan = 1.0 g cm 3 dan muatan haba tentu larutan air = 4.2J g-1 oC-1]
6(d)(ii)
[1 mark]
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(iii)
[1 mark]
[1 markah]
6(d) (iii)
(e)
6(e) [2 marks]
[2 markah]
(f)
What happens to the temperature change if lead powder is replaced by magnesium powder? Explain.
Apakah berlaku kepada perubahan suhu jika serbuk plumbum digantikan dengan serbuk magnesium? Terangkan.
[3 marks]
[3 markah]
6(f)
Section B
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[20 marks] [20 markah] Answer any one question from this section.
Jawab mana-mana satu soalan daripada bahagian ini..
(a)
Diagram 7.1 shows the position of chlorine and iodine in the Periodic Table of Elements.
Rajah 7.1 menunjukkan kedudukan klorin dan iodin di dalam Jadual Berkala Unsur.
Cl I
Diagram 7.1
Rajah 7.1
Which group does these elements belongs to? Explain why chlorine is more reactive than iodine.
Dalam kumpulan manakah unsur ini terletak? Terangkan mengapa klorin lebih reaktif berbanding iodin?
[4 marks]
[4 markah]
(b)
Diagram 7.2 shows the reaction between potassium with water. The experiment is repeated using sodium to replace potassium. Observations are recorded in Table 7.1
Rajah 7.2 menunjukkan tindak balas antara kalium dengan air. Eksperimen di ulangi menggunakan natrium menggantikan kalium. Permerhatian dicatatkan di dalam jadual 7.1
Diagram 7.2
Rajah 7.2
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Element
Unsur
Proton number
Nombor proton
Observation
Pemerhatian
Potassium
Kalium
19
Metal moves very vigorously on the surface of water. Colourless solution formed and changed red litmus paper blue.
Bergerak sangat cergas di permukaan air. Larutan tanpa warna yang terhasil menukarkan warna kertaslitmus merah kepada biru
Sodium
Natrium
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Metal moves vigorously on the surface of water with a hissing sound. Colourless solution is formed and changed red litmus paper blue.
Bergerak cergas di permukaan air dengan bunyi hiss. Larutan tanpa warna terbentuk menukarkan kertas litmus merah kepada biru
Table 7.1 Jadual 7.1 (i) Based on the proton number, explain why both elements show similar chemical properties.
Berdasarkan nombor proton, terangkan menunjukkan sifat kimia yang sama. mengapa kedua-dua unsur
[2 marks]
[2 markah]
(ii)
Write a balanced chemical equation for the reaction between potassium and water.
Tulis persamaan kima seimbang untuk tindak balas kalium dan air.
[2 marks]
[2 markah]
(iii)
Describe briefly why the solutions obtained in both reactions turns red litmus paper blue.
Terangkan secara ringkas mengapa larutan yang diperolehi menukarkan kertas litmus merah kepada biru.
[2 marks] [2 markah]
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(c)
Element
Unsur
Proton Number
Bilangan proton
C Na O Table 7.2
Jadual 7.2
6 11 8
(i) (ii)
Your answer must include diagrams showing the electron arrangement of compounds P and Q.
Jawapan anda mesti termasuk gambar rajah yang menunjukkan susunan electron bagi sebatian P dan Q.
[10 marks]
[10 markah]
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(a)
H H C = C H Cl Diagram 8
Rajah 8
(i)
Vinyl chloride can undergo polymerization. Suggest a name for the polymer formed and write a chemical equation for the reaction.
Vinil klorida boleh mengalami pempolimeran. Cadangkan satu nama bagi polimer terbentuk dan tulis persamaan kimia untuk tindak balas tersebut.
[2 marks]
[2 markah]
(ii)
[3 marks]
[3 markah]
(b)
Ammonia and sulphuric acid are two important chemicals produced in chemical industries. Ammonia gas reacts with aqueous sulphuric acid to form a nitrogenous fertilizer as shown in the equation.
Ammonia dan asid sulfurik adalah dua bahan kimia penting dihasilkan oleh industri kimia. Gas ammonia bertindak balas dengan asid sulfurik membentuk baja bernitrogen seperti yang ditunjukkan oleh persamaan.
2NH3 + H2SO4
(NH4)2 SO4
Calculate the mass of ammonium sulphate produced when an excess ammonia gas is passed into 100 cm3 of 2.0 mol dm-3 of aqueous sulphuric acid solution. [Molar mass of ammonium sulphate = 132 g mol-1]
Hitung jisim ammonium sulfat dihasilkan apabila gas ammonia berlebihan dialirkan ke dalam 100 cm3 asid sulfurik 2.0 mol dm-3. [Jisim molekul relatif ammonium sulfat = 132 g mol-1]
[3 marks] [3 markah]
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(c)
Pure aluminium rod is malleable while duralumin which is made of 95% aluminium and 5% copper is not. Explain how the difference in the composition contributes to the difference in properties of aluminium and duralumin. Rod aluminium tulen mudah dibengkokkan tetapi duralumin yang dibuat daripada 95% aluminium dan 5% kuprum sukar dibengkokkan Terangkan bagaimana perbezaan komposisi membezakan sifat aluminium dan duralumin. [5 marks]
[5 markah]
(d)
The equation below shows the ionization of a sodium soap molecule in water.
Persamaan di bawah menunjukkan pengionan molekul sabun natrium di dalam air.
Soap becomes less effective when the cleaning is carried out in acidic water. Explain.
Sabun menjadi kurang berkesan apabila pencucian menggunakan air berasid. Terangkan.
[2 marks]
[2 markah]
(e)
Amphicillin is an antibiotic. Patients are advised to finish the whole course of antibiotic prescribed even though he/she has recovered from the sickness. Explain.
Ampisilin adalah antibiotik. Pesakit dinasihatkan untuk menghabiskan ubat tersebut walaupun penyakitnya sudah sembuh. Terangkan.
[3 marks]
[3 markah]
Explain why aspirin is not advisable to be prescribed to patient with gastric problem.
Terangkan mengapa aspirin tidak digalakkan kepada pesakit yang mengalami penyakit gastrik.
[2 marks]
[2 markah]
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Section C
Bahagian C
[20 marks] [20 markah] Answer any one question from this section
Jawab mana-mana satu soalan.daripada bahagian ini.
(a)
Tin (stanum) is used to electroplate food can in industries. Explain why food in a dented can should not be consumed.
Stanum digunakan untuk menyadur tin makanan dalam industri. Terangkan mengapa makanan dalam tin yang kemek tidak boleh dimakan.
[4 marks]
[4 markah]
(b)
Cell I
Sel 1
Cell II
Sel II
Diagram 9.1
Rajah 9.1
Compare and contrast Cell I and Cell II. Your answer should include observation and half equation for the reaction at both electrodes.
Bandingbezakan Sel I dan Sel II. Jawapan anda mesti mengandungi pemerhatian dan setengah persamaan bagi tindak balas yang berlaku di kedua-dua elektrod .
[6 marks] [6 markah]
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(c)
Based on the above statement, describe an experiment to verify the reaction that occured is a redox reaction.
Berdasarkan kenyataan di atas, huraikan satu eksperimen untuk membuktikan tindak balas yang berlaku merupakan tindak balas redoks.
Procedure Confirmatory test Explanation on oxidation and reduction processes Ionic equation [10 marks]
[10 markah]
Prosedur Ujian pengesahan Penerangan tentang proses pengoksidaan dan penurunan Persamaan ion
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(a)
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2 HCOOH + Mg (HCOO)2Mg + H2
[Relative Atomic Mass: C=12; O=16; H=1; molar volume of gas at room temperature and pressure is 24 dm3 mol-1 ] [Jisim atom relatif: C;12, O;16, H;1. isipadu molar sebarang gas pada suhu dan tekanan
bilik adalah 24 dm3 mol-1]
(i)
Calculate the maximum volume of hydrogen gas released if 50 cm3 of 0.2 mol dm-3 methanoic acid is reacted with 5 g magnesium.
Hitung isipadu maksima gas hidrogen yang terbebas jika 50 cm3 asid metanoik 0.2 mol dm-3 bertindak balas dengan 5 g serbuk magnesium. [3 marks] [3 markah]
(ii)
A sweet smelling substance is formed when methanoic acid is reacted with ethanol, C2H5OH. Name the substance and draw the structural formula.
Apabila asid metanoik bertindak balas dengan etanol, C2H5OH ester. Namakan dan lukis formula struktur ester tersebut membentuk
[2 marks] [2 markah]
(b)
Natural rubber is obtained from rubber tree as shown in Diagram 10.1. Aeroplane tyres as shown in Diagram 10.2 are produced by vulcanizing the natural rubber. Compare the following properties between natural rubber and vulcanized rubber Elasticity Heat resistance Explain the differences
Getah asli diperolehi dari pokok getah seperti ditunjukkan dalam Rajah 10.1. Tayar kapalterbang seperti dalam Rajah 10.2 dihasilkan melalui penvukanan getah asli. Bandingkan sifat berikut antara getah asli dan getah tervulkan. Kekenyalan Tahan haba Terangkan perbezaan tersebut. [5 marks] [5 markah]
(c)
Diagram 10.2
[See next page CONFIDENTIAL
Alcohol
Alkohol
Hydrocarbon
Hidrokarbon
Procedure
Prosedur
Equation
Persamaan
Confirmation of product
Pengesahan hasil
[10 marks]
[10 markah]
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1. C.
This question paper consists of three sections: Section A, Section B and Section
Kertas soalan ini mengandungi tiga bahagian: Bahagian A, Bahagian B dan Bahagian C..
2.
Answer all questions in Section A. Write your answers for Section A in the spaces provided in the question paper.
Jawab semua soalan dalam Bahagian A. Tuliskan jawapan bagi Bahagian A dalam ruang yang disediakan dalam kertas soalan.
3.
Answer one question from Section B and one question from Section C. Write your answers for Section B and Section C on the lined pages at the end of the question paper. Answer questions in Section B and Section C in detail. You may use equations, diagrams, tables, graphs and other suitable methods to explain your answer.
Jawap satu soalan daripada Bahagian B dan satu soalan daripada Bahagian C. Tuliskan jawapan bagi Bahagian B dan Bahagian C pada halaman bergaris di bahagian akhir kertas soalan ini. Jawab Bahagian B dan Bahagian C dengan terperinci. Anda boleh menggunakan persamaan, gambar rajah, jadual, graf dan cara lain yang sesuai untuk menjelaskan jawapan anda..
4. 5. 6. 7.
If you wish to cancel any answer, neatly cross out the answer.
Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan itu.
The diagrams in the questions are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan.
Marks allocated for each question or part question are shown in brackets.
Markah yang diperuntukkan kurungan. bagi setiap soalan atau ceraian soalan ditunjukkan dalam
8.
The time suggested to complete Section A is 90 minutes, Section B is 30 minutes and Section C is 30 minutes
Masa yang dicadangkan untuk menjawab Bahagian A ialah 90 minit, Bahagian B ialah 30 minit dan Bahagian C ialah 30 minit.
9. 10.
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