UNIVERSITY DEPARTMENTS

ANNA UNIVERSITY CHENNAI :: CHENNAI 600 025 REGULATIONS 2008 CURRICULUM FROM

III & IVSEMEST ERS FOR

B.T ECH. RUBBER AND PLASTICS T ECHNOLOGY

SEMESTER III CODE NO COURSE TITLE L T P C THEORY MA 9211 RP 9201 AU 9201 AE 9201 AU 9202 EI 9211 PRACTICAL PR 9202 PR 9203 Mathematics III 3 1 0 4 Physical & Organic Chemistry Engineering Fluid Mechanics Solid Mechanics 3 1 0 4 3 0 0 3 0 0 3 2 TOTAL SEMESTER IV CODE NO COURSE TITLE L T P C THEORY PR 9251 Theory of Machines 3 1 0 4 Numerical Methods 3 1 0 4 MA 9261 Basics of Polymers 3 0 0 3 RP 9251 RP 9252 RP 9253 RP 9254 PRACTICAL RP 9261 EI 9261 Rubber Materials Polymer Physics 3 0 0 3 3 0 0 3 3 0 0 3 0 0 3 2 0 0 3 2 TOTAL 24 Fundamentals of Chemical Engg. Operations 26 Electronics & Instrumentation

3 0 0 3 3 1 0 4 3 1 0 4

Thermodynamics and Thermal Engineering

Computer Aided Parts & Assembly Drawing Mechanical Sciences Laboratory 0 0 3 2

Polymer Chemistry Lab

Electrical and Electronics Engineering Lab

MA9211 III

MATHEMATICS L T P C1 0 4 3

Aim: To facilitate the understanding of the principles and to cultivate the art of formulating physical problems in the language of mathematics. Objectives: To introduce Fourier series analysis which is central to many applications in engineering apart f rom it s use in solving boundary value problems To acquaint the student with Fourier transform techniques used in wide variety of situations in which the functions used are not periodic To introduce the effective mathematical tools for the solutions of partial differential equations that model physical processes To develop Z- transform techniques which will perform the same task for discrete time systems as Laplace Transform, a valuable aid in analysis of continuous time systems

1. FOURIER 9+3 SERIES Dirichlets conditions General Fourier series Odd and even functions Half-range Sine and Cosine series Complex form of Fourier series Parsevals identity Harmonic Analysis. 2. FOURIER TRANSFORM 9+3 Fourier integral theorem Fourier transform pair-Sine and Cosine transforms Properties Transform of elementary functions Convolution theorem Parsevals identity. 3. PARTIAL DIFFERENTIAL EQUATIONS 9+3 Formation S olutions of first order equations Standard types and Equations reducible to standard types Singular solutions Lagranges Linear equation Integral surf ace passing through a given curve Solution of linear equations of higher order with constant coefficients. 4. APPLI CATIONS OF PARTIAL DIFFERENTIAL EQUATIONS 9+3 Method of separation of Variables Solutions of one dimensional wave equation and one-dimensional heat equation Steady state solution of two-dimensional heat equation Fourier series solut ions in Cartesian coordinates.

5. Z TRANSFORM AND DIFFERENCE EQUATIONS 9+3 Z-transform Elementary properties Inverse Z-transform Convolution theorem Initial and Final value theorems Formation of difference equation Solution of difference equation using Z-transform. L: 45, T: 15, Total : 60 TEXT BOOKS Grewal, B.S. Higher Engineering Mathematics, Khanna Publications (2007) REFERENCE S 1) Glyn James, Advanced Modern Engineering Mathematics, Pearson Education (2007) 2) Ramana, B.V. Higher Engineering Mathematics Tata McGraw Hill (2007). 3) Bali, N.P. and Manish Goyal, A Text Book of Engineering 7 Lakshmi Publications (P) Limited, New Delhi.
th

Edition (2007)

RP9201 PHYSICAL CHEMISTRY

&

ORGANIC 3 0 0 3

1. Chemical Kinetics And Catalysis 9 Chemical Kinetics Order Molecularity rate of reaction activation energy Polymerization kinetics Catalysis Surf ace science Application of catalysis Phase rule - applicat ions. 2. Electro Chemistry / Corrosion 9 Electro Chemistry Electrochemical series Transport numbers and ionic mobility Buffer indicators - redox reaction potentiometric, conductometric, polarographic studies Galvanic cells Electrolysis Thermodynamic parameters. 3. Structure and Reactivity in Organic Compounds: 9 Bonding in Organic Compounds- Structure-property relationships - Electronic effects like inductive, mesomeric, electromeric and hyper conjugation effects free radicals, carbo cations, carbanions, elementary ideas about stereo chemistry 4.Details of Reaction Mechanisms: 9 Free radical substitutions, Electophilic addition, Aromatic Elect rophilic substitutions, Nucleophilic additions, condensation reactions, nucleophilic substitutions in aliphatic and aromatic compounds, cyclo additions, rearrangements, uses of these reactions in polymer preparation

5.Organic substances of importance to polymer technology: Amines, heterocyclic compounds furan, thiophene, pyrrole, pyridine, quinoline, iso quinoline, imidazoles, thiazoles Preparation , properties and uses of simple monomers like ethylene, propylene, isobutylene, butadiene, styrene, methyl methacrylate , diisocyanates, glycols, polyols, epichlorohydrin, fluoro alkenes, acrylonitrile, vinyl chloride, vinyl acetate Total 45 REFERENCE S 1. Glasstone, S., and Lewis, D., Elements of Physical Chemistry, Macmillan India Press, Madras, 1995. 2. Maron and Pruton C.F. , Physical Chemistry Macmillan, 1990. 3. Morrison and Boyd, Organic Chemistry Prentice Hall, N.Dli 1992 4. Finar I.L., Textbook of Organic Chemistry, ELBS, 1996.

AU9201 THERMODYNAMICS ENGINEERING

AND

THERMAL 3 1 0 4

Objective To introduce fundamental concepts in thermodynamics, heat tramsfer, propulsion and refrigeration and air conditioning. BASIC THERMODYNAMICS 16 Systems, Zeroth low, First law. Steady flow energy equation. Heat and work transfer in flow and non-flow processes. Second law, Kelvin-Planck statement - Clausius statement - Concept of Entropy, Clausius inequality, Entropy change in non-flow processes. Properties of gases and vapours. AIR CYCLE AND COMPRESSORS 12 Otto, Diesel, Dual combustion and Brayton cycles. effective pressure, Reciprocating compressors.

Air standard efficiency .

Mean

STEAM AND JET PROPULSI ON 12 Properties of steam Rankine cycle Steam Nozzles Simple jet propulsion system Thrust rocket motor Specific impulse. REFRIGERATION AND AIR-CONDITIONING 10 Principles of Psychrometry and refrigeration - Vapour compression - Vapour absorption types - Co-efficient of performance, Properties of refrigerants B asic Principle and types Air conditioning. HEAT 10 TRANSFER

Conduction in parallel, radial and composite wall Basics of Convective heat transfer - Fundamentals of Radiative heat transfer Flow through heat exchangers. L = 45, T = 15, Total = 60 (Use of standard thermodynamic tables, Mollier diagram and Ref rigerant property tables are permitted) TEXT BOOKS1. Nag.P.K., Engineering Thermodynamics, Tata McGra w-Hill, New Delhi, 2007. 2. Rathakrishnan E., Fundamentals of Engineering Thermodynamics, Prentice-Hall India, 2005. REFERENCE 1. Ramalingam K.K. Thermodynamics, Sci-Tech Publications, 2006 S 2. Holman.J.P., Thermodynamics, 3rd Ed. McGraw-Hill, 2007. 3. Venwylen and Sontag, Classical Thermodynamics, Wiley Eastern, 1987 4. Arora C.P, Thermodynamics, Tata McGra w-Hill, New Delhi, 2003. 5. Merala C, Pother, Craig W, Somerton, Thermodynamics for Engineers, Schaum Outline Series, Tata McGraw-Hill, New Delhi, 2004.

AE9201 ENGINEERING FLUID MECHANICS 4 Objectives:

3 1 0

BASIC 15 CONCEPTS Introduction Fluid properties Newtons viscosity law Classification of fluids and fluid motion Fluid statics Hydrostatic force on submerged surf aces stability of floating bodies Dimensional analysis The Buckingham-Pi theorem Significant dimensionless groups Flow similarity and model studies BASIC EQUATIONS OF FLUID FLOW 15 ANALYSIS nd Basic laws for a system in integral form Conservation of mass Newtons 2 law Laws of thermodynamics Application of the basic laws for a control volume Kinematics Motion of a fluid particle Fluid deformation Differential analysis of fluid motion Continuity equation Differential momentum equation The Navier Stokes equations INCOMPRESSIBLE INVI SCID FLOW 8 Eulers equations of motion Bernoullis equations Applications Methods of pressure measurement Flow measurement Orifice plate Venturi meter Irrotational flow Stream function and velocity potential Laplace equation Elementary plane f lows INCOMPRESSIBLE VISCOUS FLOW 8 Fully developed laminar flow bet ween infinite parallel plates Laminar and turbulent flow through pipes Velocity profiles Energy considerations in pipe flow

Calculation of head loss Pipe flow problems Hydraulic and energy grade lines Moodys diagram FLUID MACHINERY 14 Introduction and classification of fluid machines Turbo machinery analysis The angular momentum principle Euler turbo machine equation Velocity triangles Application to fluid systems W orking principle of turbines, fans, blowers, pumps and compressors. L = 45, T = 15, Total = 60 TEXT BOOKS 1. Shames I H, Mechanics of Fluids, Kogakusha, Tokyo, 1998 2. Robert W Fox & Alan T Mc.Donald, Introduction to fluid Mechanics, John Wiley and Sons, 1995 REFERENCE BOOKS 1. Yuan S W, Foundations of fluid Mechanics, Prentice-Hall, 1987 2. Milne Thompson L M, Theoretical Hydrodynamics, MacMillan, 1985 3. Rathakrishnan, E, Fundamentals of Fluid Mechanics, Prentice-Hall, 2007 AU9202 SOLID MECHANICS 3 1 0 4 AXIAL LOADING 12 Stresses and strains Hookes law stress and strain diagrams - elastic constants statically determinate and indeterminate problems in tension & compression thermal stresses impact loading. STRESSES IN BEAMS 10 Shear force & bending moment diagrams bending stresses shear stress variation in beams of symmetric sections beams of uniform strength. DEFLECTION OF BEAMS 12 Double integration method Macaulays method moment area method conjugate beam method principle of superposition Strain Energy in axial, bending, torsion and shear loadings. Castiglianos theorems and their applications.

TORSION SPRINGS COLUMNS 14 Torsion of solid and hollow circular shafts shear stress variation power transmission in shafts open and closed-coiled helical springs st resses in helical springs classification of columns Euler buckling columns with different end conditions.

BIAXIAL 12

STRESSES

Stresses in thin-walled pressure vessels combined bending, torsion and axial loading of circular shafts Mohrs circle and its construction determination of principal stresses. Total 60 TEXT BOOK 1. Gere & Timoshenko, Mechanics of Materials, McGraw Hill, 1993 2. William Nash, Strength of Materials, Tata McGraw Hill, 2004 REFERENCE : 1. Dym,C.L., and Shames,I.H., Solid Mechanics, McGraw Hill, Kogakusha, 1973. Tokyo, 2. Stephen Timoshenko, Strength of Materials, Vol I & II, CBS Publishers and Distributors, Third Edition. 3. R.K.Rajput, Strength of Materials, S. Chand and Co., 1999. 4. Timoshenko,S. and Young,D. H., Elements of Strength of Materials, T.Van Nost rand Co. Inc., Princeton, N.J., 1977.

EI9211 03

ELECTRONICS & INSTRUMENTATION

30

UNIT I ELECTRONIC COMPONENTS AND DEVICES 10 Resistors, Capacitors, Inductors and Transformers - properties, types. Simple PN Junction Diodes, Zener diode, Bipolar Junction transistor and Field Effect Transistors operating principles and characteristics. Other Devices UJT, SCR, LED, Photodetectors. UNIT II ANALOG CIRCUITS 10 Rectifier and Power Supply Circuits, clipper, clamper using diodes, Operational Amplifiers (Ideal) properties and typical circuits like differentiator, integrator, summer, comparator, single-stage BJTs and FETs amplifiers Multistage Amplifier Principles(Qualitative Treatment only). UNIT III DIGITAL CIRCUITS Basics of Boolean Logic Logic Gates, Flip-Flops, Shift-Registers, Counters, 10 Decoders/Drivers, Timer, Display Devices, A/D and D/A Converters. UNIT IV MEASUREMENTS AND INSTRUMENTS 7 efinitions of Accuracy, Precision, Sensitivity, Resolution, Linearity, Range, D Measurement of Electrical Quantities Voltmeter, Ammeter, Watt-Meter, DMM, DSO, Transducers and signal conditioning syst ems for pressure, CRO, temperature, acceleration measurements (Qualitative Treatment only). UNIT V MICROPROCESSORS AND APPLICATIONS 8 rchitecture of 8085 processors, Address Modes, Instruction set, simple A programming like addition, subtraction, multiplication, logical operation, Peripherals and Interfacing 8255, 8251. Applications like motor control, keyboard and PC interface, Introduction to Microcontrollers. TOTAL 45

T EXT BOOK
1. Millman.J. and Halkias.C., Integrated Electronics, Tata McGraw Hill, 2004. 2. Paul Horowitz and Wilfred Hill The Art of Electronics, Cambridge University press,1989. 1. Donald P Leach, Albert Paul Malvino and Goutam Saha, Digital Principles & Applications,6E, Tata McGraw Hill, 2006. 2. A.K.Sawhney, A course in Electrical and Electronic Measurement and Instrumentation, Dhanpat Raj. and Sons, New Delhi, 1999 3. Helfrick.A.D., and Cooper.W.D., Electronic Instrumentation and Measurement techniques, Prentice Hall of India, 1998. 4. Gaonkar. Ramesh S, Microprocessor Architecture Programming and Applications with 8085, 5th Ed. Penram International Publishing (India). 2003 . 5. Kenneth J.Ayala., The 8051 Microcontroller Architecture Programming and Applications, 2ed, Penram International Publishing (India).2004. PR9202 DRAWING COMPUTER AIDED MACHINES & P ART

REFERENCES

Objective: To train the st udents in construction of machine elements and assembly Drawing Train the students to allocate geometrical tolerances and to develop part drawing 1. Instruction to machine drawing & production drawing classification of drawingBIS conventions Orthogrphic and sectional views. Reviews of the concepts of limits, tolerance, fits, surface roughness, and symbols terminology used in Production drawing. 2. Machine element joints Types of joints Screw fasteners Pin joints, couplings welded joints. 3. Computer Aided Production Drafting Detailed part drawing and assembly drawings (with suitable tolerances, machine sumbols, specification of fit). 1) Screw jack 2) Shaper tool head 3) Non return valve 4) Plummer block 5) Foot step drawing 6) Machine vice 7) Four jaw chuck of lathe 8) Lathe tail stock 9) Square tool post 10) Universal coupling 11) Hydraulic & Pneumatic Assembly TEXT : BOOKNarayana K.L., Kannaiah P and Venkata Reddy Production Drawing Ne w 1. age International Limited, Delhi 2004.

REFERENCE BOOKS: 1. Bhat N.D., Machine Drawing, Charotar Publishing House, Anand 2000 2. Nagtal G.R., Machine Drawing, Khanna Publishers, New Delhi 1994. 3. Sache Singh & P.L. Shah Fundamentals of Machine Drawing, rentice Hall India, 2003. P

PR9203

MECHANICAL SCIENCES LAB 2

0 0 3

OBJECTIV E To train the students in testing and quantifying the mechanical properties of Engineering Materials, Engines and Heat Exchangers

LIST EXPERIMENTS 1. Tension Test 2. Torsion Test 3. Testing of springs 4. Impact test i) Izod, ii) Charpy

OF

5. Hardness test i) Vickers, ii) Brinell, iii) Rockwell, iv) Shore 6. Deflection of Beams 7. Dye Penetrant Test 8. Performance test on a 4 storke engine 9. Viscosity determination of the given fluid 10. Moment of inertial of connecting rod 11. Determination of Effectiveness of a parallel and counter flow heat exchangers 12. Valve timing of a 4 stroke engine and port timing of a 2 stroke engine

PR9251 THEORY OF MACHINES 3 1 0 4 Objectives: To understand the basic concepts of mechanisms and machinery 1.MECHANISMS 14 Definition Machine and Structure Kinematic link, pair and chain classification of Kinematic pairs Constraint & motion Degrees of freedom - Slider crank single and double Crank rocker mechanisms Inversions, applications Introduction to Kinematic analysis and synthesis of simple mechanisms Determination of velocity and acceleration of simple mechanisms. 2.FRICTION 12 Types of friction friction in screw and nut screw jack pivot, collar and thrust bearings plate and cone clutch belt (flat & vee) and rope drives creep in belts open and crossed belt drives Ratio of tensions Effect of centrifugal and initial tensions condition f or maximum power transmission. 3.GEARING AND CAMS 12 Gear Types and profile nomenclature of spur & helical gears laws of gearing interference requirement of minimum number of teeth in gears gear trains simple, compound and reverted gear t rains determination of speed and torque in epicyclic gear trains cams different types of followers Cam Types of cams and followers Cam design for diff erent follower motions. 4.BALANCING 11 Static and dynamic balancing single and several masses in different planes primary and secondary balancing of reciprocating masses Balancing of single and multi cylinder engines Governors and Gyroscopic effects. 5.VIBRATION 11 Free, forced and damped vibrations of single degree of freedom systems force transmitted to supports vibration Isolation vibration absorption torsional vibration of shafts single and multirotor syst ems geared shafts critical speed of shafts. Total 60 TEXT BOOK 1. Bansal Dr.R.K. Theory of Machines Laxmi Publications (P) Ltd., New Delhi 2001 2. Rattan S.S. Theory of machines Tata McGraw Hill publishing Co., New Delhi, 2002.

REFERENCE S 1. Rao J.S.and Dukkipati R.V. Mechanism and Machine Theory Second Edition, Wiley Eastern Limited, 1992.

10

2. Malhotra D.R. and Gupta H.C The Theory of machines Satya Prakasam, Tech. India Publications, 1989 3. Gosh A and Mallick A.K. Theory of Machines and Mechanisms affiliated east west press, 1989 4. Shigley J.E. and Uicker J.J. Theory of Machines and Mechanisms McGraw Hill, 1986. 5. Burton Paul Kinematics and Dynamics of Machinery, Prentice Hall, 1979.

MA9261 METHODS

NUME

RICAL L T P C1 0 4 3

Aim: This course gives a complete procedure for solving numerically different kinds of problems occurring in engineering and technology. Objectives: The students would be acquainted with the basic concepts of numerical methods and their applications.

1. SOLUTION OF EQUATIONS AND EIGENVALUE PROBLEMS 9 +3 Solution of algebraic and transcendental equations Fixed point iteration method Newton-Raphson method Solution of linear system of equations Gauss Elimination method Pivoting Gauss-Jordan methods Matrix Inversion by Gauss-Jordan method Iterative methods of Gauss-Jacobi and Gauss-Seidel Eigenvalues of a matrix by Power method and by Jacobis method. 2. INTERPOLATION AND APPROXIMATION 9+3 Interpolation with unequal intervals Lagrange interpolation Newtons divided difference interpolation Cubic Splines Interpolation with equal intervals Newtons forward and backward difference f ormulae. 3. NUME RICAL DIFFERENTATION AND INTEGRATION 9+3 Approximation of derivatives using interpolation polynomials Numerical integration using Trapezoidal, Simpsons 1/3 and Simpsons 3/8 rules Rombergs method Two point and three point Gaussian quadrature formulae Evaluation of double integrals by Trapezoidal and Simpsons rules. 4. INITIAL VALUE PROBLEMS FOR ORDINARY DIFFERENTIAL EQUATIONS 9+ 3 Single step-methods Taylors series method Eulers method Fourth order Runge-Kutta method for solving first and second order equations Multi-step methods Milnes and Adams-Bashforth predictor-corrector methods for solving first order equations.

11

5. BOUNDARY VALUE PROBLEMS IN ORDINARY AND PARTIAL DIFFERENTIAL EQUATIONS 9+3 Finite difference methods for solving two-point linear boundary value problems. Finite difference techniques for the solution of two dimensional Laplaces and Poissons equations on rectangular domain One dimensional heat-flo w equation by explicit and implicit (Crank Nicholson) methods - One dimensional wave equation by explicit method. L: 45, T: 15, Total : 60 TEXT BOOKS 1. Grewal, B.S. and Grewal,J.S., Numerical methods in Engineering and Science, 6t h Edition, Khanna Publishers, New Delhi, (2004). rd Edition 2. Sankara Rao, K. Numerical methods for Scientists and Engineers, 3 Prentice Hall of India Private Ltd., New Delhi, (2007).

REFERENCE S th 1. Chapra, S. C and Canale, R. P. Numerical Methods for Engineers, Edition, 5 Tata McGraw-Hill, New Delhi, (2007). th Edition, 2. Gerald, C. F. and Wheatley, P. O., Applied Numerical Analysis, 6 Pearson Education Asia, New Delhi, (2006). 3. Brian Bradie, A friendly introduction to Numerical analysis, Pearson Education Asia, New Delhi, (2007).

RP9251 POLYMERS

BASICS OF 3 0 0 3

1. INTRODUCTION 6 History of Macromolecules structure of natural products like cellulose, rubber, proteins concepts of macro molecules Staudingers theory of macromolecules difference between simple organic molecules and macromolecules. 2. ADDITION POLYMERIZATION 12 Chemistry of Olefins and Dienes double bonds Chemistry of free radicals monomers functionality Polymerization: Initiation types of initiation free radical polymerization cationic polymerization anionic polymerization coordination polymerization industrial polymerization bulk, emulsion, suspension and solution polymerization techniques Kinetics Copolymerization concepts. 3. CONDENSATION POLYMERIZATION 9 Simple condensation reactions Extension of condensation reactions to polymer synthesis functional group reactivity polycondensation kinetics of polycondensation- Carothers equation Linear polymers by polycondensation Interfacial polymerization crosslinked polymers by condensation gel point. 4. 9 MOLECULAR WEIGHTS OF POLYMERS

12

Difference in molecular weights between simple molecules and polymers number average and weight average molecular weights Degree of polymerization and molecular weight molecular weight distribution Polydispersity molecular weight determination. Different methods Gel Permeation Chromatography Osmometry, Light Scattering. 5. TRANSITIONS IN POLYMERS 8 First and second order transitions Glass transition, Tg multiple transitions in polymers experimental study significance of transition temperatures crystallinity in polymers effect of crystallization in polymers factors affecting crystallization crystal nucleation and growth relationship between Tg and Tm Relationship between properties and crystalline structure. REFERENCE S 1. Billmeyer.F.W.,Jr, Text Book of Polymer Science, Ed. WileyInterscience, 1984. nd 2. Seymour.R.B., and Carraher.C.E., Jr., Polymer Chemistry, Ed., Marcel 2 Dekker, 1988. 3. Gowariker.V.T., Viswanathan.N.V., and Sreedar.J. , Polymer Science, Wiley Eastern Ltd., 1988. 4. Joel,R.F; Polymer Science and Technology, Eastern Economy Edition, 1999. 5. Rodriguez, F., Cohen.C., Oberic.K and Arches, L.A., Principles of Polymer Systems, 5 t h edition, Taylor and Francis, 2003. TOTAL 45

RP9252 MATERIALS

RUBBER 3 0 0 3 8

1. Structure-Property Relationships in Rubbers: Rubber Elasticity Requirements for rubber elasticity Effect of chemical structure on the performance properties of rubbers Effect of structure on processing properties of elastomers 2. Natural . Rubber: Origin Natural Rubber Latex, tapping, processing, properties and applications Conversion of Latex into dry rubber Properties of dry rubber Classification based on technical specifications Modifications of Natural RubberApplications Synthetic polyisoprene. 3. Synthetic Elastomers:

16

Polybutadiene and SBR, Nitrile Rubber, Butyl Rubber and Polychloprene Rubbers Ethylene Propylene Rubber and Ethylene Vinyl acetate copolymers Elastomers based on modified polyethylene Acrylate rubbers Polysulphide rubbers- polyether rubbers polyalkenamers 4 . High Performance El astomers : 7

Fluoroelastomers and silicone elastomers, Manufacture, structure, Properties and applications

13

5.Polyurethanes and thermoplastics Elastomers: Reactions of di isocyanates polyols-chain extenders-types of urethane elastomers properties and uses - Requirements for thermoplastic elastomeric behaviour SBS and SIS Block copolymers Thermoplastic Polyurethane elastomers Thermoplastic-co-polyesters Thermoplastic elastomers based on Plastics Rubber Blends Dynamic Vulcanization.

TOTAL 45 REFERENCE S 1. Brydson, J.A., Rubber Chemistry, Allied science Publishers, London, 1978. 2. Morton.M., Rubber Technology, Chapman Hall, 1995. 3. I. Franta, Elastomers and Rubber Compounding materials, Elsevier, 1989. Blackely, D.C., Synthetic Rubbers their Chemistry and Technology.

RP9253 FUNDAMENTALS OPERATIONS

OF

CHEMICAL

ENGINEE

RING 3 0 0 3

1. Classification of Unit Operations - Heat transfer steady state Fourier law thermal conductivity conduction through plane wall cylindrical wall convection forced and natural convection radiation unsteady state heat transfer methods of solution- fuels and combustion stoichiometry 2. Heat exchange equipments double pipe and shell and tube heat exchangers, condensers Mass Transfer Principles of dif fusion, Ficks law theory of diffusion, Mass transfer coefficients and film theory Penetration theory. Distillation Vapour liquid equilibria, Simple distillation, Steam distillation, Continuous binary distillation, Industrial equipments f or distillation- industrial boilers. 9 3. Agitation of liquids Types of impellers, Selection criteria, Power consumption calculations for agitated vesse Absorption Principle and equipment (packed towers and plate columns). Adsorption Principles and equipment for absorption. 4. Drying Principles and def initions, Rate of batch drying, Equipments for drying. Humidification Humidity and saturation, dry bulb and wet bulb temperatures, percentage saturation, dew point, humid volume, humid heat, enthalpy, Equipment Water technology cooling towers, spray chambers. 5. Membrane Separation Processes - S eparation of gases and liquids, Dialysis, Membrance liquid liquid extraction, Pervaporation and reverse osmosis. Size reduction Laws of crushing, Equipment Classification, Crushers and grinders. Mechanical separations Screening and screening equipments, Filtration Principle and filtration equipment, filter media, filter aids, Gravity settlers, Cyclones and hydro cyclones.

TOTAL 45

14

REFERENCE S 1. Mc. Cabe, W.L., Smith, J.C., Unit Operations of Chemical Engineering, Hill. 1993. Mc.Graw 2. Badger, W.L., Banchero, J.T., Introduction to Chemical Engineering, Mc.Gra w Hill, UK, 1997. 3. Richardson and Coulson, Chemical Engineering, Vol. 1 & vol.2, Asian Books Pvt. Ltd., India. 1996. 4. Chattopadhyay, P., Unit Operations of Chemical Engineering Vol. I and Vol. II, Khanna Publishers, Delhi, 1998. 5. Foust A.S., Walzel.L.A., John Wiley - Principles of Unit Operations.

RP9254 POLYMER PHYSICS 3 0 0 3 1. SOLUTION PROPERTIES OF POLYMERS 8 Size and shape of the macromolecules Solubility parameter polymer/solvent interaction parameter Theta temperature size and molecular weight of polymer f rom the solution properties of polymers, Fractionation of Polymers. 2. FLOW BEHAVIOUR OF POLYMERS 4mportance of Rheology Newtonian and Non-newtonian flow behaviour Polymer I melt Rheology. 3. MECHANICAL PROPERTIES 13 Stress strain properties of polymers comparison with conventional materials tensile properties flexural strength impact strength fatigue endurance hardness tests mechanical relaxations in polymers temperature effect on the mechanical behaviour of polymers visco-elastic properties of polymers Damping characteristics crazing in glassy polymers Role of crazing in f racture macroscopical fracture theory Fracture and microstructure. 4. FRICTION AND WEAR IN POLYMERS Elastic deformation single contacts multiple contacts Rolling f riction sliding 8 f riction of rubbers and rigid polymers lubrication by fluids wear wear testing Abrasive wear. 5. ELECTRICAL PROPERTIES OF POLYMERS 7ntroduction Polar and Nonpolar polymers - charge carriers carrier mobility I Dielectric properties of polymers - Anti static and conductive of polymers Volume restivity measurements Molecular theories of dielectric relaxation in polymers Dielectric breakdown. 6. OPTICAL PROPERTI ES OF POLYMERS I 5ntroduction Isotropic polymers Anisotropic polymers Dichroism Oprical applications of polymers Transmission Rheoptical properties and application. TOTAL 45

15

REFERENCE S 1. Ulrich Eisele, Introduction to Polymer Physics Springs Verlag, New York, 1990. 2. Bill Meyer.F.W. Text Book of Polymer Science, Wiley Interscience Publications, 1994. 3. Bikales.N.M., Mechanical properties of Polymers, John Wiley & Sons, 1971. 4. Brown.R.P. , Physical Testing of Rubber Elsevier, 1986.

RP9261

POLYMER CHEMISTRY LAB 100

0 0 3

Lab Requirements Bunsen Burner 15Nos Electronic Balance 1 No Thermostatic Water bath 2 Nos Melting Point Apparatus 1 No Retort Stand 15Nos Samples and Glass wares Polymer Experiments: Identification of polymers by simple methods like density, melting burning point, characteristics, sol ubility and confirmatory test by chemical analysis. A. PLASTICS 1. Polyethylene 2. Polypropylene 3. Polystyrene 4. Polyvinyl Chloride 5. Polyamide 6. Polyethylene terephthalate 7. Polybutylene terephthalate 8. Polycarbonate 9. Polyacetal 10. Polyphenylene oxide 11. Polyphenylene sulphide 12. Phenol Formaldehyde 13. Urea formaldehyde 14. Melamine formaldehyde B. IDENTIFICATION OF RUBBERS BY SIMPLE METHODS 1. Natural Rubber (NR) 2. Polybutylene Rubber (BR) 3. Styrene Butadiene Rubber (SBR) 4. Isoprene Rubber (IR) 5. Isobutiene Isoprene Rubber (IIR) 6. Chloroprene Rubber (CR) 7. Acrylonitrile Butadiene Rubber (NBR) 8. Silicone Rubber REFERENC E 1. Identification of plastics and rubbers by simple methods , CIPET publications 2002 TOTAL 45 :

16

EI9261 ELECTRICAL AND ELECTRONICS ENGINEERING LAB 0 0 4 2

1. Load test on separately excited DC shunt generator. 2. Load test on DC shunt motor 3. Load test on S Transformer 4. Load test on Induction motor 5. Regulation of 3 alternator 6. Study of CRO 7. Logic gates 8. Operation amplifiers 9. Time constant of RC circuit 10. Characteristics of LVDT 11. Calibration of Rotometer 12. RTD and thermistor 13. Flapper Nozzle system
Total 60

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