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Reference Integrated Chemistry Today (2nd Ed.), L.H.M Chung, Book 1A, 74–78
Reading
a) Conductivity of electrolyte
Cation
1 bromide ion → 1 bromine atom + 1 electron 1 lead ion + 2 electrons → 1 lead atom
2 bromine atoms → 1 bromine molecule many lead atoms → liquid lead metal
many bromine molecule → brown bromine gas
or or
Br-(l) → Br(l) + e- (the electrons flow to the battery) Pb2+(l) + 2e- → Pb(l)
2Br (l) → Br2(g) (the electrons flow from the battery)
Both bromide ions (Br -) and lead(II) ions (Pb2+) discharge during electrolysis and become bromine (Br) and lead
(Pb) atoms.
The continuous discharges of ion, movements of ions and movements of electrons in the external circuit keep the
current flow in the circuit.
N.B. 1. Bromide ion (Br -) is not the same as bromine atom (Br), bromide ion (Br -) carries a negative charge
while bromine atom (Br) is electrically neutral.
2. There is no connection between the polarity of an electrode and the name of the electrode, the name
of an electrode is solely depending on the direction of movement of cations and anions. i.e. a positive
electrode may be known as anode or cathode in different situations.
e.g. The positive electrode of an electrolytic cell is known as an anode.
The positive electrode of an electrochemical cell is known as a cathode.
V. Bonding in compounds Part 5 Page 3
Use of equation
Reactants → Products
There are several different types of equations. e.g. word equation, unbalanced equation, balanced equation, half -
ionic equation and ionic equation. They are used in different situation depending on the usage.
word equation hydrogen gas + oxygen gas This can only be obtained from the direct observation of
(Represent the → water experiment.
macroscopic
meaning only)
balanced 2H2(g) + O2(g) → 2H2O(l) The number of atoms on the right hand side equals to the
equation number of atoms on the left hand side. i.e. the no. of atoms is
(Represent the unchanged.
macroscopic There are exactly 4 H atoms and 2 O atoms on both sides.
meaning and It shows that 2 hydrogen molecules react with 1 oxygen
more molecule to produce 2 water molecules.
microscopic
meaning)
N.B. Formula is a short hand in chemistry, it is used to represent a substance. e.g. hydrogen gas consists of
hydrogen molecules, therefore, the formula of hydrogen gas is H2. Just the symbol H is not correct in this
case, because in hydrogen gas, no isolated H atom can be found.
The decomposition of liquid lead(II) bromide by electrolysis into lead metal and bromine gas can be represented
by
The use of half-ionic equation and ionic equation will be discussed in the latter part of the course.
V. Bonding in compounds Part 5 Page 4
1 chloride ion → 1 chlorine atom + 1 electron 1 copper ion + 2 electrons → 1 copper atom
2 chlorine atoms → 1 chlorine molecule many copper atoms → reddish brown copper metal
many chlorine molecules → yellowish green chlorine gas
Overall equation
The net effect of electrolysis of copper(II) chloride solution is the same as decomposition of copper(II) chloride
into copper metal and chlorine gas.
It is also observed that the colour of the solution turns paler and paler during electrolysis.
N.B. The subscript (s), (l), (g) and (aq) are used to denote the physical state of a substance. They means solid,
liquid, gaseous and aqueous (water solution) respectively.
The arrow sign '→' in an equation is similar to the equal sign '=' in mathematics. If the same species
appears on both sides of the equation, they can be canceled out.
V. Bonding in compounds Part 5 Page 5
b) Coloured ions
In the above experiment, what makes the colour of the blue copper(II) solution turn paler ? It is found that almost
all solution containing copper(II) ions are blue in colour e.g. copper(II) sulphate and copper(II) nitrate.
Therefore, it is believed that the blue colour of copper(II) chloride solution is from the copper(II) ion. As the
concentration of the copper(II) ion decreases in the electrolysis, the solution gets paler.
By comparing the colour of different solutions, it is found that some ions are coloured in aqueous medium. The
colours of the ions are summarized as follows :
N.B. Usually, only the metal ion containing transition metal has colour.
e.g. iron(III) ion (Fe3+(aq)), containing transition metal iron, is yellow in colour.
e.g. permanganate ion (MnO4-(aq)) ,containing transition metal manganese, is deep purple in colour.
e.g. nitrate ion (NO3-(aq)), containing no transition metal, is colourless.
Besides the substance itself, the colour of a substance also depends on the environment. e.g. I2 is a black solid if it
is pure, it forms a brown solution in alcohol but forms a purple solution in organic solvent.
Similarly, the colour of an ion also depends on the environment. The colour of the ions listed above are only
correct in dilute aqueous solution.
e.g. Aqueous solution of copper(II) sulphate is blue in colour but anhydrous (absolutely dry) copper(II) sulphate is
white in colour.
Concentrated copper(II) chloride solution is green but dilute copper(II) chloride solution is blue.
Aqueous solution of cobalt(II) chloride is pink but it is blue in colour when absolutely dry.
V. Bonding in compounds Part 5 Page 6
c) Migration of ions
The presence of coloured ion is further supported by the experiment of migration of ions.
A filter paper is saturated with (soaked in) sodium sulphate solution. Sodium sulphate is an electrolyte which
makes the paper conductive. The solid potassium permanganate dissolves slowly and the ions becomes mobile.
Under the influence of the electricity, the position of the purple spot move towards the positive pole (anode). If the
purple spot doesn’t carry any charge, the spot should spread evenly on the filter paper instead of moving towards
the positive electrode only.
This proves the existence of negatively charged purple permanganate ion (MnO4-). There is no observable change
at the negative pole (cathode) because potassium ion (K+) is colourless. The migration of colourless potassium ion
is not visible.
A high grade quartz or diamond is colourless but most gemstones are coloured.Trace amount of coloured ion is
embedded in the colourless quartz to give the gemstone colour. Depending on which kind of ion is present,
different gemstones have different colours.
94 I 7 b iii
7b The table below lists some physical properties of lead, bromine and lead(II) bromide.
Lead Bromine Lead(II) bromide
Melting point 328 ºC -7 ºC 370 ºC
Electrical conductivity in the solid state Conducting Non-conducting Non-conducting
Electrical conductivity in the liquid state Conducting Non-conducting —
iii Will lead(II) bromide conduct electricity in the liquid state ? Explain your answer. 1
Yes, when molten / in liquid state, the Pb2+ and Br - ions can move freely / are mobile ∴ it conducts electricity.
1 mark
C Some candidates confused liquid state with aqueous state in their answers.
96 I 9 b i
9b A student carried out a copper-plating experiment in the laboratory using the set-up shown below :
97 I 6 a i ii iii iv
6a A student used the following experimental set-up to study the migration of ions.
The student placed a drop of potassium dichromate solution at A and a drop of a deep blue solution at C. It is
known that the two solutions do not react and the deep blue colour of the solution at C is due to the cation
present.
i Write the formula of the ion responsible for the orange colour of potassium dichromate. 1
Cr2O72- 1 mark
ii Why was the filter paper moistened with sodium sulphate solution ? 1
The sodium sulphate solution provides ions for the conduction of electricity / acts as an electrolyte / completes the
circuit. 1 mark
C Parts (i) and (ii) were well answered, but the performance of candidates in parts (iii) and (iv) was poor.
iii An electric current was passed through the circuit for some time. 4
(1) What would be the colour change at A ?
(2) What would be the colour change at B ? Explain your answer.
(1) The orange colour becomes paler / colourless / fades. 1 mark
(2) Green / brown / purple colour was observed. 1 mark
V. Bonding in compounds Part 5 Page 8
Explanation: Under the influence of the electric field, cations in the deep blue solution are attracted to the
negative pole (move to the left) and negative / Cr2O72- ions are attracted to the positive pole (move to the
right). 1 mark
Or, Under the influence of the electric field, the cations and anions are respectively attracted towards the
negative and positive poles. (1
mark)
The orange negative ions and the blue positive ions mix / meet at B to give the green colour. 1 mark
C Many candidates did not realize that ions migrate under the influence of an electric field. Some candidates
simply omitted part (iii). Of those who attempted this part, many wrongly considered the changes to be the result
of a redox reaction.
iv Using the same apparatus and materials, suggest how you could show that the colour changes in (iii) are NOT 2
due to diffusion.
reverse the polarity of the d.c. supply. 1 mark
or, connect the left hand electrode to the positive pole and the right hand electrode to the negative pole.
Observation: orange colour will appear at the left of A and blue colour will appear at the right of C. 1 mark
C In part (iv), many candidates suggested cutting off the d.c. supply. But they did not present their arguments
properly in terms of the direction of movement of the colour spots and the time required for such movement to
occur.
97 I 8 b i
8b Read the following paragraph concerning chromium and answer the questions that follow:
The Greek word "chroma" means colour. Many chromium-containing compounds and chromium containing
gemstones are beautifully coloured. The oxidation number of chromium in its compounds can be +2, +3 and +6.
i Jade. a green-coloured gemstone, is chromium-containing. Suggest what chromium ion present in jade is 1
responsible for its green colour.
chromium(III) / Cr3+ 1 mark
C Parts (i) were reasonably well answered.
90 26
C 26 Dry zinc chloride solid is a non-conductor of electricity
because
A. it is a non-electrolyte.
B. it exists as molecules.
C. its ions are not mobile.
D. metallic bonding is not present.
92 33
D 33 Which of the following ions is/are coloured ?
(1) Pb2+(aq)
(2) Cr3+(aq)
(3) MnO4-(aq)
A. (1) only
B. (3) only
C. (1) and (2) only
D. (2) and (3) only
V. Bonding in compounds Part 5 Page 9
98 5
Directions: Questions 4 and 5 refer to the following
experiment:
The circuit shown below is set up and the solid lead(II)
bromide is heated until it becomes molten.
99 13
B 13 Which of the following ions is responsible for the yellow
colour of topaz ?
A. Ni2+
B. Fe3+
C. Cr3+
D. Mn3+
V. Bonding in compounds Part 5 Page 10