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Note: Attempt FIVE questions in all, including QUESTION NUMBER 8 which is COMPULSORY.
All questions carry equal marks.
1. (a) Why do the lines in the atomic spectra more closer with increasing wave lengths?
4. (a) Define:
(i) Ore (ii) Mineral (iii) Native state (iv) Flux (v) Slag.
(i) Semi conductors (ii) Varieties of glass (iii) Thin films (iv) Portland cement.
6. (a) What properties of the transition elements are consistent with their being metals? (b) Explain how
sigma (s ) and pi (p ) bonding help each other synergestically in stablizing the compound.
(c) The dz2 orbital is considered to be the LCAO of two orbitals. Which orbitals are they and how do they
combine.
(d) Which of the complex ion namely [Fe(CN6)] 3- and [ Fe(OH2] 2+ is an outer orbital complex and
why? —
7. (a) What is thermal pollution of water? Is it necessarily undesirable?
(b) Distinguish between softening and de-mineralizing of water. Does demineralization soften water?
(c) Name the five principal Air pollutants and identify a source of each of these pollutants.
COMPULSORY QUESTION
8. Select and write the correct answer only in the answer book. Don’t reproduce the question:
(3) A process in which the system, after undergoing various process, returns to its initial state is called
a/an:
(5) Which of the following statements is not correct regarding galvanic cells?
(c) Electrons flow around the external circuit from cathode to anode.
(d) When the e.m.f. of the cell is positive, cell reaction is spontaneous.
(6) The spectral line obtained when an electron jumps from n =6 to n= 2 belongs to the:
n5 ® n4 ; n4 ® n3 ; n3 ® n2 ;
(a) n5 ® n4 (b) n4 ® n4 ® n3
(c) n3 ® n2 (d) Same in all transitions.
(15) The Oxide containing chlorine in its highest Oxidation state is:
(a) Ni (b) Sb
(c) Pt (d) In
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