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SOLUTIONS OF STRONG ACIDS AND BASES

-- Quiz

Question 1.

Rubidium hydroxide is a strong base. Compute [Rb+] and [OH-] for a solution that is
prepared by dissolving 2.0 g of RbOH in enough water to make 200.0 mL of solution.
(Atomic weights: Rb = 85.47, O = 16.00, H = 1.008

a) 1.9 x 10-2, 1.9 x 10-2


b) 1.9 x 10-2, 5.3 x 10-13
c) 9.8 x 10-1, 9.8 x 10-1
d) 9.8 x 10-2, 9.8 x 10-2
e) 5.3 x 10-13, 1.9 x 10-2

Question 2.

Calcium hydroxide is a strong base. Compute [Ca2+] and [OH-] for a solution that is
prepared by dissolving 0.60 g of Ca(OH) 2 in enough water to make 1500.0 mL of
solution.
(Atomic weights: Ca = 40.08, O = 16.00, H = 1.008)

a) 8.1 x 10-3, 8.1 x 10-3


b) 5.4 x 10-3, 9.1 x 10-13
c) 5.4 x 10-3, 5.4 x 10-3
d) 5.4 x 10-3, 1.1 x 10-2
e) 8.1 x 10-3, 1.6 x 10-2

Question 3.

Calculate the [Cl-], and [H3O+] in an aqueous solution containing 0.020 moles of HCl in
50.0 mL of water.

a) 2.0 x 10-2, 2.0 x 10-2


b) 4.0 x 10-1, 2.5 x 10-13
c) 4.0 x 10-2, 4.0 x 10-2
d) 4.0 x 10-1, 4.0 x 10-1
e) 2.5 x 10-13, 4.0 x 10-1

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
CONJUGATE ACIDS AND BASES -- Quiz
Question 1.

What is the conjugate base of aniline, C6H5NH2?

a) C6H5NH2-
b) C6H5NH-
c) C6H5NH+
d) C6H5NH2+
e) C6H5NH3+

Question 2.

What is the conjugate acid of H2PO4-?

a) H2PO4
b) H3PO4
c) HPO4-
d) H2PO4+
e) HPO42-

Question 3.

What is the conjugate base of H2PO4-?

a) H2PO4
b) HPO42-
c) HPO4-
d) H3PO4
e) H2PO4+

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
pH CALCULATIONS FROM ACID
CONCENTRATION -- Quiz
Question 1.

The hydronium ion concentration of a a glass of beer is 5.0 x 10-5 M. What is the pH of
the beer?

a) 5.30
b) 4.70
c) 4.30
d) 3.30
e) 5.70

Question 2.

A vinegar has a hydrogen ion concentration of 7.5 x 10-3 M. What is the pH of the
vinegar?

a) 3.75
b) 2.88
c) 2.12
d) 3.88
e) 3.12

Question 3.

The hydronium ion concentration of Milk of Magnesia is 3.2 x 10-11 M. What is the pH of
the solution?

a) 10.20
b) 10.70
c) 10.50
d) 9.50
e) 9.20

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
pH FOR A SOLUTION OF A BASE -- Quiz
Question 1.

The hydroxide ion concentration of the oceans is about 1.4 x 10-6. What is the pH?

a) 5.85
b) 7.85
c) 8.85
d) 7.15
e) 8.15

Question 2.

The hydroxide ion concentration of a wine is 7.1 x 10-11 M. What is the pH of the wine?

a) 10.15
b) 3.15
c) 2.85
d) 2.15
e) 3.85

Question 3.

A saturated solution of Sr(OH)2 has a [Sr2+] of 0.15 M. What is the pH of the solution?

a) 0.50
b) 12.78
c) 13.28
d) 13.20
e) 13.48

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
HYDRONIUM ION CONCENTRATION FROM
pH -- Quiz
Question 1.

The pH of the contents of the human stomach is about 1.0. Calculate the value of [H3O+]
in the stomach at 25oC.

a) 1 x 10-13
b) 0.01
c) 1 x 10-14
d) 1
e) 0.1

Question 2.

The pH of a 0.012 M solution of niacin is 3.39. What is the [H3O+]?

a) 2.5 x 10-3
b) 2.5 x 10-4
c) 4.1 x 10-3
d) 1.2 x 10-2
e) 4.1 x 10-4

Question 3.

A beer has a pH of 4.30. What is the [H3O+]?

a) 2.0 x 10-5
b) 2.0 x 10-4
c) 3.0 x 10-4
d) 5.0 x 10-4
e) 5.0 x 10-5

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
HYDROXIDE ION CONCENTRATION FROM
pH -- Quiz
Question 1.

The pH of arterial blood is 7.40. What is the [OH-]?

a) 4.0 x 10-8
b) 4.0 x 10-6
c) 2.5 x 10-6
d) 4.0 x 10-7
e) 2.5 x 10-7

Question 2.

The pH of a saturated solution of Mg(OH)2 is 10.50. What is the molarity of the


magnesium ion?

a) 3.2 x 10-3
b) 5.0 x 10-10
c) 3.2 x 10-4
d) 1.6 x 10-3
e) 1.6 x 10-4

Question 3.

A shampoo solution has pH of 5.20. What is the [OH-]?

a) 6.3 x 10-9
b) 1.6 x 10-8
c) 2.0 x 10-5
d) 6.3 x 10-8
e) 1.6 x 10-9

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
EFFECT OF TEMPERATURE ON Kw -- Quiz
Question 1.

The value of the ion product constant for water, Kw, at 0oC is 1.2 x 10-15 M2. Compute the
[H3O+] of a neutral aqueous solution at 0oC. Is an aqueous solution with a pH = 7.3
acidic, basic or neutral at 0oC?

a) 3.5 x 10-8, acidic


b) 3.5 x 10-7, basic
c) 3.5 x 10-8, basic
d) 3.5 x 10-7, acidic
e) 3.5 x 10-8, neutral

Question 2.

Given that Kw for water is 2.4 x 10-14 M2 at 37oC, compute the [H3O+] of a neutral
aqueous solution at 37oC (normal human body temperature). Is a pH = 6.81 solution
acidic, basic, or neutral at 37oC?

a) 1.55 x 10-7, neutral


b) 1.55 x 10-7, acidic
c) 6.56 x 10-8, basic
d) 1.55 x 10-7, basic
e) 6.56 x 10-8, neutral

Question 3.

The value of the ion product constant for water, Kw, at 60oC is 9.6 x 10-14 M2. Compute
the [H3O+] of a neutral aqueous solution at 0oC. Is an aqueous solution with a pH = 6.51
acidic, basic or neutral at 0oC?

a) 3.1 x 10-7, neutral


b) 3.1 x 10-7, acidic
c) 3.1 x 10-8, acidic
d) 3.1 x 10-7, basic
e) 3.1 x 10-8, basic

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
STRENGTH OF CONJUGATE ACID AND
BASE PAIRS -- Quiz
Question 1.

The Ka values for HSO4- and H2PO4- are 1.2 x 10-2 and 6.3 x 10-8 respectively. Therefore it
follows the HSO4- is a _____ acid than H2PO4- and SO42- is a _____ base than HPO42-.

a) stronger, stronger
b) stronger, weaker
c) weaker, stronger
d) weaker, weaker

Question 2.

Given the following Ka values, determine which species is the strongest base.
HF 6.8 x 10-4

HNO2 4.5 x 10-4

HCNO 2.2 x 10-4

a) HF
b) CNO-
c) NO2-
d) F-
e) HCNO

Question 3.

The Ka values for HCNO and HNO2 are 2.2 x 10-4 and 4.5 x 10-4 respectively. Therefore it
follows the HCNO is a _____ acid than HNO2 and CNO- is a _____ base than NO2-.

a) weaker, weaker
b) weaker, stronger
c) stronger, weaker
d) stronger, stronger

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
ACID EQUILIBRIUM AND LECHATELIER'S
PRINCIPLE -- Quiz
Question 1.

What change will occur for the following reaction if a few drops of HCl are added?
HF + H2O F- + H3O+

a) no change in the fraction of HF dissociated


b) an increase in the fraction of HF dissociated
c) a decrease in the fraction of HF dissociated

Question 2.

What change will be observed for the following reaction if a few drops of NaOH are
added?
HNO2 + H2O NO2- + H3O+

a) no change in the fraction of acid dissociated


b) a decrease in the fraction of acid dissociated
c) an increase in the fraction of acid dissociated

Question 3.

What change will be observed for the following reaction if a solution of NaOBr is added?
HOBr + H2O OBr- + H3O+

a) no change in the fraction of acid dissociated


b) an increase in the fraction of acid dissociated
c) a decrease in the fraction of acid dissociated

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
MANIPULATING Ka VALUES -- Quiz
Question 1.

Given Ka values of 1.8 x 10-4 and 6.8 x 10-4 for HCO2H and HNO2 respectively, calculate
the equilibrium constant for the following reaction.
HCO2- + HNO2 HCO2H + NO2-

a) 0.26
b) 8.6 x 10-4
c) 5.0 x 10-4
d) 1.2 x 10-7
e) 3.8

Question 2.

Given Ka values of 1.0 x 10-10 and 6.8 x 10-8 for C6H5OH and C5H5NH+ respectively,
calculate the equilibrium constant for the following reaction.
C6H5O- + C5H5NH+ C6H5OH + C5H5N

a) 0.15
b) 6.8 x 10-8
c) 6.8 x 10-2
d) 1.5 x 10-3
e) 6.8 x 102

Question 3.

Given Ka values of 5.6 x 10-10 and 1.7 x 10-5 for NH4+ and CH3CO2H respectively,
calculate the equilibrium constant for the following reaction.
NH4+ + CH3CO2- NH3 + CH3CO2H

a) 3.3
b) 0.30
c) 1.7 x 10-5
d) 3.0 x 104
e) 3.3 x 10-5

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
HYDRONIUM ION [H3O+] FROM
IONIZATION CONSTANT -- Quiz
Question 1.

What is the hydronium ion concentration of a 0.380 M acid solution of an acid whose
ionization constant is 1.58 x 10-9?

a) 4.16 x 10-9
b) 1.26 x 10-5
c) 6.45 x 10-5
d) 2.45 x 10-5
e) 6.00 x 10-10

Question 2.

What is the hydronium ion concentration of a 0.110 M acid solution of an acid whose
ionization constant is 5.45 x 10-7?

a) 6.00 x 10-7
b) 2.22 x 10-3
c) 7.38 x 10-4
d) 2.45 x 10-4
e) 4.96 x 10-8

Question 3.

What is the hydronium ion concentration of a 0.160 M acid solution whose ionization
constant is 1.62 x 10-9?

a) 1.00 x 10-4
b) 2.59 x 10-10
c) 4.03 x 10-5
d) 1.61 x 10-5
e) 1.01 x 10-8

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
HYDRONIUM ION [H3O+] CONCENTRATION
FROM IONIZATION OF HYDRATED METAL
IONS -- Quiz
Question 1.

What is the hydronium ion concentration of a 0.04 M solution of Ni2+ solution of


nickel(II) perchlorate? The acidity constant of the following reaction is 5 x 10-10.
Ni2+(aq) + 2 H2O Ni(OH)+(aq) + H3O+

a) 4 x 10-5
b) 1 x 10-5
c) 1 x 10-4
d) 2 x 10-5
e) 4 x 10-6

Question 2.

What is the hydronium ion concentration of a 0.02 M solution of Cu2+ solution of


copper(II) perchlorate? The acidity constant of the following reaction is 5 x 10-9.
Cu2+(aq) + 2 H2O Cu(OH)+(aq) + H3O+

a) 7 x 10-4
b) 1 x 10-4
c) 5 x 10-4
d) 7 x 10-5
e) 1 x 10-5

Question 3.

What is the hydronium ion concentration of a 0.03 M solution of Fe2+ solution of iron(II)
perchlorate? The acidity constant of the following reaction is 5 x 10-9.
Fe2+(aq) + 2 H2O Fe(OH)+(aq) + H3O+

a) 1 x 10-4
b) 7 x 10-5
c) 4 x 10-4
d) 7 x 10-4
e) 1 x 10-5

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
IONIZATION CONSTANT FROM
HYDRONIUM ION [H3O+] CONCENTRATION --
Quiz
Question 1.

What is the ionization constant of an acid if the hydronium ion concentration of a 0.100
M solution is 7.66 x 10-4 M?

a) 5.93 x 10-6
b) 6.20 x 10-5
c) 7.66 x 10-3
d) 7.66 x 10-5
e) 5.87 x 10-6

Question 2.

What is the ionization constant of an acid if the hydronium ion concentration of a 0.500
M solution is 1.70 x 10-4 M?

a) 5.78 x 10-8
b) 2.89 x 10-8
c) 1.70 x 10-3
d) 1.16 x 10-7
e) 3.62 x 10-7

Question 3.

What is the ionization constant of an acid if the hydronium ion concentration of a 0.400
M solution is 1.40 x 10-4 M?

a) 4.90 x 10-8
b) 1.40 x 10-6
c) 1.22 x 10-9
d) 1.40 x 10-3
e) 1.96 x 10-8

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
IONIZATION CONSTANT OF HYDRATED
METAL IONS FROM HYDRONIUM ION [H3O+]
CONCENTRATION -- Quiz
Question 1.

What is the acidity constant for the following reaction given that the hydronium ion
concentration of a 0.1 M solution of Zn2+ solution of zinc perchlorate is 5.5 x 10-6?
Zn2+(aq) + 2 H2O Zn(OH)+(aq) + H3O+

a) 3 x 10-10
b) 5 x 10-6
c) 3 x 10-12
d) 5 x 10-12
e) 5 x 10-10

Question 2.

What is the acidity constant for the following reaction given that the hydronium ion
concentration of a 0.03 M solution of Fe2+ solution of iron(II) perchlorate is 1.2 x 10-5?
Fe2+(aq) + 2 H2O Fe(OH)+(aq) + H3O+

a) 5 x 10-9
b) 4 x 10-12
c) 4 x 10-8
d) 1 x 10-8
e) 1 x 10-10

Question 3.

What is the acidity constant for the following reaction given that the hydronium ion
concentration of a 0.04 M solution of Ni2+ solution of nickel(II) perchlorate is 4.5 x 10-6?
Ni2+(aq) + 2 H2O Ni(OH)+(aq) + H3O+

a) 5 x 10-10
b) 2 x 10-10
c) 5 x 10-12
d) 4 x 10-6
e) 2 x 10-12

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
pH FROM ACID CONCENTRATION AND
IONIZATION CONSTANT -- Quiz
Question 1.

The value of Ka in water at 25oC for uric acid is 4.0 x 10-6 M. Calculate the pH of an
aqueous solution with a total concentration of uric acid equal to 0.050 M.

a) 4.70
b) 3.10
c) 3.35
d) 2.35
e) 2.70

Question 2.

What is the pH of a 0.180 M acid solution whose Ka = 3.52 x 10-7?

a) 4.70
b) 3.22
c) 3.60
d) 3.90
e) 2.85

Question 3.

What is the pH of a 0.490 M acid solution whose Ka = 4.53 x 10-9?

a) 4.02
b) 5.22
c) 4.33
d) 4.17
e) 5.43

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
CALCULATIONS USING QUADRATIC
FORMULA -- Quiz
Question 1.

The value of Ka in water at 25oC for chloroacetic acid is 1.35 x 10-3 M. Calculate the pH
of an aqueous solution with a total concentration of chloroacetic acid equal to 0.10 M.

a) 1.96
b) 2.14
c) 3.65
d) 1.35
e) 3.35

Question 2.

The value of Ka in water at 25oC for dichloroacetic acid is 1.8 x 10-2 M. Calculate the pH
of an aqueous solution with a total concentration of dichloroacetic acid equal to 0.10 M.

) 1.46
b) 1.60
c) 2.00
d) 1.23
e) 1.76

Question 3.

Calculate the pH at 25oC of a solution that is 0.10 M in Fe(NO3)3. The acid dissociation
constant for the reaction given below is 1.0 x 10-3.
Fe(H2O)63+ + H2O H3O+ + Fe(H2O)5(OH)52+

a) 2.02
b) 2.50
c) 2.30
d) 2.00
e) 2.10

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
QUALITATIVE OBSERVATIONS ON THE HYDROLYSIS OF SALTS --
Quiz
Question 1.

Consider the following salts. Which one(s) when dissolved in water will produce a
neutral solution?
1) CaCl2

2) Sr(NO3)2

3) K2CO3

a) only 1
b) only 2
c) 2 and 3
d) 1 and 2
e) only 3

Question 2.

Consider the following salts. Which one(s) when dissolved in water will produce a basic
solution?
1) NaNO3

2) K2S

3) Na2CO3

a) only 2
b) 1 and 2
c) only 3
d) 2 and 3
e) only 1

Question 3.

Consider the following salts. Which one(s) when dissolved in water will produce an
acidic solution?
1) NH4Cl

2) KHSO4

3) NaCN

a) only 2
b) only 3
c) only 1
d) 1 and 2
e) 2 and 3

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
ACID/CONJUGATE BASE RATIOS -- Quiz
Question 1.

The toxic compound 2,4-dinitrophenol (used in biological research to inhibit energy


production in cells) has Ka = 1.1 x 10-4 M. In an experiment, a solution of 2,4-
dinitrophenol was prepared with the pH adjusted to 7.40. Calculate the ratio of the
concentrations of the dissociated ion to the undissociated acid.

a) 1.2 x 102
b) 2.8 x 103
c) 4.7 x 103
d) 1.4 x 101
e) 3.2 x 103

Question 2.

Sodium benzoate (NaC7H5O2) is used as a food preservative. The Ka of benzoic acid is


6.46 x 10-5 M. What is the ratio of the concentration of benzoic acid to the concentration
of benzoate ion in a food with pH = 3.00?

a) 21
b) 15
c) 6.0
d) 24
e) 0.065

Question 3.

Nitrites, such as NaNO2, are added to processed meats and hamburger as a preservative.
When nitrite ion is ingested, it reacts with stomach acid to form nitrous acid, HNO2.
Given Ka = 4.47 x 10-4 M for nitrous acid, compute the value of the ratio of
[HNO2]/[NO2-] in the stomach when the hydronium ion concentration is 0.10 M.

a) 64
b) 2.2 x 102
c) 1.4 x 102
d) 84
e) 1.1 x 102

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
HYDROLYSIS CONSTANT FROM
IONIZATION CONSTANT -- Quiz
Question 1.

What is the hydrolysis constant of the CN- ion? The ionization constant of HCN is 4.4 x
10-10.

a) 4.4 x 10-4
b) 2.3 x 10-10
c) 2.3 x 10-5
d) 2.3 x 10-4
e) 4.4 x 10-5

Question 2.

What is the hydrolysis constant of the OBr- ion? The ionization constant of HOBr is 2.0
x 10-9.

a) 5.0 x 10-5
b) 5.0 x 10-9
c) 5.0 x 10-6
d) 2.0 x 10-6
e) 2.0 x 10-4

Question 3.

What is the hydrolysis constant of the CNO- ion? The ionization constant of HCNO is 3.5
x 10-4.

a) 2.9 x 10-4
b) 3.5 x 10-10
c) 2.9 x 10-11
d) 3.5 x 10-11
e) 2.9 x 10-10

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
HYDROXIDE ION CONCENTRATION FROM
HYDROLYSIS -- Quiz
Question 1.

What is the hydroxide ion concentration of 0.880 M CN-? The ionization constant of
HCN is 4.4 x 10-10.

a) 5.2 x 10-4
b) 4.4 x 10-10
c) 5.2 x 10-3
d) 4.5 x 10-3
e) 4.5 x 10-6

Question 2.

What is the hydroxide ion concentration of 0.660 M OI-? The ionization constant of HOI
is 2.0 x 10-11.

a) 5.2 x 10-3
b) 2.0 x 10-11
c) 4.5 x 10-6
d) 1.8 x 10-2
e) 5.2 x 10-2

Question 3.

What is the hydroxide ion concentration of 0.750 M NCO-? The ionization constant of
HNCO is 3.5 x 10-4.

a) 4.9 x 10-4
b) 1.4 x 10-6
c) 2.6 x 10-4
d) 4.6 x 10-6
e) 2.1 x 10-11

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
HYDRONIUM ION CONCENTRATION FROM
HYDROLYSIS -- Quiz
Question 1.

What is the hydronium ion concentration in a 0.680 M CN- solution? (Ka HCN = 4.4 x
10-10)

a) 3.0 x 10-10
b) 2.5 x 10-12
c) 2.1 x 10-8
d) 1.2 x 10-12
e) 2.1 x 10-5

Question 2.

What is the hydronium ion concentration in a 0.440 M OI- solution? (Ka HOI = 2.0 x 10-
11
)

a) 8.0 x 10-12
b) 6.7 x 10-13
c) 3.3 x 10-3
d) 4.5 x 10-6
e) 3.3 x 10-12

Question 3.

What is the hydronium ion concentration in a 0.50 M NO2- solution. The Ka of HNO2 is
4.5 x 10-4.

a) 3.0 x 10-8
b) 3.0 x 10-9
c) 5.0 x 10-10
d) 1.0 x 10-8
e) 4.5 x 10-10

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
pH FROM HYDROLYSIS -- Quiz
Question 1.

What is the pH of a 0.50 M NO2- solution. The Ka of HNO2 is 4.5 x 10-4.

a) 7.54
b) 8.04
c) 8.30
d) 8.52
e) 7.76

Question 2.

What is the pH of a 0.10 M C6H5O- solution? The Ka of C6H5OH is 1.0 x 10-10.

a) 10.51
b) 11.04
c) 11.20
d) 11.50
e) 10.82

Question 3.

What is the pH of a 0.41 M OCl- solution? (Ka of HOCl = 3.0 x 10-8)

a) 10.30
b) 11.22
c) 10.88
) 10.57
e) 11.51

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
HYDRONIUM ION CONCENTRATION FOR A
BUFFER SOLUTION -- Quiz
Question 1.

What is the hydronium ion concentration of a solution of 0.700 M acid and 0.440 M of its
conjugate base if the ionization constant is 3.59 x 10-8?

a) 2.47 x 10-7
b) 2.26 x 10-8
c) 5.71 x 10-8
d) 8.98 x 10-8
e) 1.13 x 10-7

Question 2.

What is the hydronium ion concentration of a solution of 0.260 M acid and 0.640 M of its
conjugate base if the ionization constant is 2.06 x 10-6?

a) 1.25 x 10-5
b) 4.21 x 10-7
c) 8.37 x 10-7
d) 2.50 x 10-6
e) 5.07 x 10-6

Question 3.

What is the hydronium ion concentration of a solution of 0.720 M acid and 0.240 M of its
conjugate base if the ionization constant is 4.38 x 10-6?

a) 1.05 x 10-6
b) 1.46 x 10-6
c) 1.31 x 10-5
d) 6.08 x 10-6
e) 3.15 x 10-5

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
pH OF A BUFFER SOLUTION -- Quiz
Question 1.

What is the pH of a solution of 0.17 M acid and 0.50 M of its conjugate base if the
ionization constant is 2.87 x 10-9?

a) 9.59
b) 9.01
c) 9.98
d) 9.71
e) 9.31

Question 2.

What is the pH of a solution of 0.49 M acid and 0.29 M of its conjugate base if the
ionization constant is 5.92 x 10-8?

a) 8.21
b) 7.00
c) 7.46
d) 7.72
e) 7.98

Question 3.

What is the pH of a solution of 0.81 M acid and 0.65 M of its conjugate base if the
ionization constant is 4.92 x 10-7?

a) 6.40
b) 6.21
c) 6.81
d) 6.62
e) 5.80

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
pH FOR BUFFER SOLUTION FROM pKa --
Quiz
Question 1.

What is the pH of a solution of 0.46 M acid and 0.36 M of its conjugate base if the pKa =
5.51?

a) 5.20
b) 4.90
c) 4.70
d) 5.62
e) 5.40

Question 2.

What is the pH of a solution of 0.17 M acid and 0.81 M of its conjugate base if the pKa =
8.62?

a) 8.58
b) 7.94
c) 9.52
d) 9.68
e) 9.30

Question 3.

What is the pH of a solution of 0.31 M acid and 0.29 M of its conjugate base if the pKa =
6.28?

a) 7.21
b) 7.00
c) 6.81
d) 7.42
e) 6.25

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
POLYPROTIC ACIDS -- Quiz
Question 1.

Selenious acid (H2SeO3), a diprotic acid, has K1 = 3.0 x 10-3 and K2 = 5.0 x 10-8. What is
the [H3O+] of a 0.50 M solution of selenious acid?

a) 5.5 x 10-2
b) 3.9 x 10-2
c) 6.8 x 10-2
d) 1.5 x 10-1
e) 1.5 x 10-2

Question 2.

Hydrosulfuric acid (H2S) has K1 = 1.1 x 10-7 and K2 = 1.0 x 10-13. What is the hydronium
ion concentration of a 0.10 M solution of H2S?

a) 3.3 x 10-5
b) 1.0 x 10-4
c) 1.1 x 10-7
d) 1.0 x 10-5
e) 3.3 x 10-4

Question 3.

Selenious acid (H2SeO3), a diprotic acid, has K1 = 3.0 x 10-3 and K2 = 5.0 x 10-8. What is
the [HSeO4-] of a 0.50 M solution of selenious acid?

a) 5.5 x 10-2
b) 3.9 x 10-2
c) 1.5 x 10-2
d) 1.5 x 10-1
e) 6.8 x 10-2

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
STRENGTH OF ACIDS -- Quiz

Question 1.

Which of the following is the weakest acid?

a) HClO
b) HCl
c) HBrO
d) HBr

Question 2.

Which of the following is the weakest acid?

a) H2SO3
b) H2SO4
c) H2SeO3
d) H2SeO3

Question 3.

Which of the following is the weakest acid?

a) H2SO4
b) H2SeO4
c) HSeO4-
d) HSO4-

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
PERCENT IONIZATION USING QUADRATIC
EXPRESSION – Quiz

Question 1.

What is the percent ionization of a 0.0217 M CH2ClCO2H solution? (Ka = 1.4 x 10-3)

a) 19%
b) 25%
c) 17%
d) 27%
e) 22%

Question 2.

What is the percent ionization of a 0.10 M HSO3NH2 solution? (Ka = 1.0 x 10-1)

a) 56%
b) 75%
c) 48%
d) 40%
e) 62%

Question 3.

What is the percent ionization of a 0.010 M HNO2 solution? (Ka = 4.4 x 10-4)

a) 15%
b) 12%
c) 17%
d) 10%
e) 19%

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
Ka FROM PERCENT IONIZATION – Quiz

Question 1.

A 0.10 M solution of HF is 8.1% ionized. What is the Ka?

a) 8.8 x 10-4
b) 8.4 x 10-4
c) 7.1 x 10-4
d) 6.4 x 10-4
e) 7.6 x 10-4

Question 2.

A 0.50 M solution of HSO4- is 14% ionized. What is the Ka?

a) 1.8 x 10-2
b) 2.2 x 10-2
c) 1.1 x 10-2
d) 1.4 x 10-2
e) 2.0 x 10-2

Question 3.

A 0.010 M solution of HNO2 is 19% ionized. What is the Ka?

a) 3.9 x 10-4
b) 5.4 x 10-4
c) 4.5 x 10-4
d) 5.0 x 10-4
e) 3.6 x 10-4

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
EQUIVALENT WEIGHT OF AN ACID -- Quiz
Question 1.

A 0.550 g sample of butyric acid is dissolved in 100.0 mL of water and titrated with 0.100
M NaOH to the phenolphthalein equivalence point. The volume of the base used is 62.4
mL. What is the molecular weight of butyric acid assuming one dissociable proton per
molecule?

a) 122
b) 160
c) 140
d) 88
e) 46

Question 2.

A 1.50 g sample of Vitamin C is dissolved in 100.0 mL of water and titrated with 0.250 M
NaOH to the methyl orange equivalence point. The volume of the base used is 34.1 mL.
What is the molecular weight of Vitamin C assuming one dissociable proton per
molecule?

a) 146
b) 164
c) 139
d) 176
e) 152

Question 3.

A 2.00 g sample of acetylsalicylic acid is dissolved in 100.0 mL of water and titrated with
0.200 M NaOH to the thymol blue equivalence point. The volume of the base used is 55.5
mL. What is the molecular weight of acetylsalicylic acid assuming one dissociable proton
per molecule?

a) 188
b) 168
c) 194
d) 180
e) 172

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project
pH DURING A TITRATION -- Quiz
Question 1.

A 25.00 mL sample of 0.100 M HCl is titrated with 0.100 M NaOH. What is the pH of the
solution at the points where 24.5 and 25.5 mL of NaOH have been added.

a) 3.30, 11.00
b) 3.30, 10.00
c) 3.00, 11.00
d) 3.30, 10.70
e) 3.00, 10.00

Question 2.

A 25.00 mL sample of 0.100 M CH3CO2H is titrated with 0.100 M NaOH. What is the pH
of the solution at the points where 24.5 and 25.5 mL of NaOH have been added. (Ka = 1.8
x 10-5)

a) 6.13, 9.85
b) 7.00, 8.00
c) 6.43, 11.00
d) 6.44, 9.85
e) 6.43, 11.00

Question 3.

What is the pH of a solution in which 20.0 mL of 0.10 M NaOH are added to 25.0 mL of
0.10 M HCl?

a) 1.15
b) 0.95
c) 1.95
d) 2.15
e) 1.55

© 1995, R.J. Tatz


The Ohio State University Dept. of Chemistry BETHA Project

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