Beruflich Dokumente
Kultur Dokumente
199 – 224
Detergents
Public Exam Questions :
Directions : Question 1 and question 2 refer to the making of soap as represented by the following
reaction :
H H
H C OOC(CH2)16CH3 H C OH
H C OOC(CH2)16CH3 H C OH
H H
1. What is / are the function(s) of the sodium hydroxide in this reaction?
(1) to act as a catalyst
(2) to neutralize the acid formed during the reaction
(3) to lower the solubility of soap in water so as to salt out the soap
A. (1) only
B. (1) and (2) only
C. (1) and (3) only
D. (2) and (3) only
2. Soap has a hydrophilic head and a hydrophobic tail. Which of the following combinations is
correct?
A. Na+ CH3(CH2)16
B. COO- CH3(CH2)16
C. Na+ CH3(CH2)16COO-
D. CH3(CH2)16COO- Na+
(HKCEE 1992)
3.
When a little detergent is added to a drop of water on a piece of woollen cloth as shown above,
the drop spreads. Which of the following statements correctly explains this observations?
A. The detergent dissolves readily in water.
B. The detergent has a polar end which is hydrophilic.
C. The detergent can form an emulsion with water.
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PLASTICS AND DETERGENTS Textbook (Book 3) : p.199 – 224
5. Which of the following problems are associated with the excessive use of soapless detergents?
(1) They can cause skin allergies.
(2) They form foam when discharged into rivers and lakes.
(3) They form scum when discharged into the sea.
A. (1) and (2) only
B. (1) and (3) only
C. (2) and (3) only
D. (1), (2) and (3)
(HKCEE 1998)
(HKCEE 1999)
9. Which of the following statements is correct for a soapy detergent but incorrect for a soapless
detergent?
A. Its structure consists of a hydrophilic part and a hydrophobic part.
B. It forms lather when shaken with distilled water.
C. It can be made by reacting a vegetable oil with an alkali.
D. It acts as an emulsifier in the cleaning process.
(HKCEE 2001)
10. Soap was prepared by heating fat with sodium hydroxide solution for some time. Concentrated
sodium chloride solution was then added to the resulting mixture. The purpose of adding
concentrated sodium chloride solution is
A. to help the precipitation of the soap.
B. to enhance the cleansing power of the soap.
C. to reduce the alkalinity of the soap.
D. to act as a preservative for the soap.
(HKCEE 2003)
12. 1st statement : Sodium carbonate can be used to soften hard water which contains calcium ions.
2nd statement : Sodium carbonate reacts with calcium ions in hard water to form a precipitate.
(HKCEE 2003)
14. Which of the following substances is NOT used for the preparation of soaps?
A. vegetable oil
B. sodium hydroxide solution
C. concentrated sodium chloride solution
D. concentrated sulphuric acid
(HKCEE 2005)
16.
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PLASTICS AND DETERGENTS Textbook (Book 3) : p.199 – 224
Suggested Answers :
1. B 2. B 3. D 4. D 5. A 6. C 7. C 8. C 9. C 10 A
.
11. B 12 A 13 A 14 D 15 B 16 17 18 19 20
. . . . . . . . .
21 22 23 24 25 26 27 28
. . . . . . . .
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PLASTICS AND DETERGENTS Textbook (Book 3) : p.199 – 224
1. statement (1) : correct. The tri-ester can be broken down to alkanoic acid and alkanol by water
(This process is known as hydrolysis) but the rate is very slow. Adding NaOH
can increase the rate of this reaction. NaOH is, in fact, a catalyst.
statement (2) : correct. After hydrolysis of tri-ester by water, an alkanoic acid is first formed. It
is then neutralized by NaOH.
CH3(CH2)16COOH(aq) + NaOH(aq) → CH3(CH2)16COO-Na+(aq)
statement (3) : wrong. It is not used to decrease the solubility of soap in water but it is the role
of concentrated sodium chloride.
Ans. : B
2. Na+ is not the hydrophilic head of the soap molecule, it is just the counter-ion of the soap ion.
Ans. : B
3. In this case, detergent acts as a wetting agent which can be explained by its presence of
hydrophobic tail and hydrophilic head. The hydrophobic tail can dissolve in oil, while the
hydrophilic head can dissolve in water.
A : wrong. Detergent can dissolve readily in both oil (hydrophobic tail) and water (hydrophilic
head).
B : wrong. This statement is correct but it is not the explanation of this case.
C : wrong. This statement is correct but it is not the explanation of this case. It can explain why
detergent can remove oil and dirt from an object.
D : correct. Before adding detergent, water can’t spread easily over the surface of an object
because of its high surface tension. After adding detergent, detergent can help to interrupt
the interaction between water molecules and hence reduce the surface tension of water. In
other words, water can spread over the surface of the object.
Ans. : D
Ans. : D
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PLASTICS AND DETERGENTS Textbook (Book 3) : p.199 – 224
5. statement (1) : correct. No matter it is soapy detergent or soapless detergent, when people use it
for a long time, they will suffer from skin allergies.
statement (2) : correct.
statement (3) : wrong. Soapless detergents usually do not form scum with Ca2+ and Mg2+ ions
which are present in sea water.
Ans. : A
6. statement (1) : wrong. This method is used to prepare soapy detergent. But for soapless
detergents, they are prepared using petroleum fractions.
For example :
statement (2) : correct. No matter it is soapy detergent or soapless detergent, it can reduce the
surface tension of water by interrupting the interaction between water molecules.
statement (3) : correct. No matter it is soapy detergent or soapless detergent, it can serve as an
emulsifying agent to remove grease or oil from the surface of an object during
cleaning process.
Ans. : C
Ans. : C
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PLASTICS AND DETERGENTS Textbook (Book 3) : p.199 – 224
8. statement (1) : wrong. Soaps are produced from ester but they are not ester, they are metal
carbonate compounds.
For example :
H H
H C OOC(CH2)16CH3 H C OH
H C OOC(CH2)16CH3 H C OH
H H
tri-ester glycerol soap
statement (2) : correct. Soap can reduce the surface tension of water by interrupting the
interaction between water molecules.
statement (3) : correct. Carbonate compounds are slightly alkaline.
Ans. : C
9. A : wrong. Both soapy and soapless detergents consist of hydrophilic part and hydrophobic part.
B : wrong. In distilled water, no or very low [Mg2+] or [Ca2+]. Both soapy and soapless
detergents do not form scum in distilled water. They form lather when shaken with distilled
water.
C : correct. It is the way to manufacture soapy detergent but not soapless detergent. Soapless
detergent can be manufactured from petroleumproducts.
D : wrong. Both soapy and soapless detergents serve as emulsifying agent in cleaning process.
Ans. : C
10. A : correct. Concentrated sodium chloride can decrease the solubility of soapy, thus soap can be
precipitated out.
B : wrong. The cleansing power of a soap depends on the structure of the soap.
C : wrong. Alkalinity depends on the hydrophilic head of the soap.
D : wrong. Sodium chloride is not a preservative.
Ans. : A
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PLASTICS AND DETERGENTS Textbook (Book 3) : p.199 – 224
Ans. : B
12. 1st statement : true. There is an ion exchange between Na+ ion and Ca2+ ion when sodium
carbonate is added to hard water.
2 statement : true. It is the correct explanation for the 1st statement. Ca2+ ions can be
nd
precipitated and Na+ ions then go to the water. This can help soften the hard
water.
Na2CO3(aq) + Ca2+(aq) → CaCO3(s) + 2Na+(aq)
Ans. : A
Ans. : A
14. A : correct.
B : correct. NaOH acts as a catalyst to speed up the rate of hydrolysis of tri-ester (found in
vegetable oils / animal fats) to give glycerol and soap.
C : correct. It can help precipitation of soap from soap solution.
D : wrong. It is used in for preparation of soapless detergents.
Ans. : D
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PLASTICS AND DETERGENTS Textbook (Book 3) : p.199 – 224
15. statement (1) : correct. Since soaps are manufactured from vegetable oils or animal fats which
can be decomposed easily by the bacterial action. Soaps are biodegradable.
statement (2) : wrong. Soaps do not work well in hard water as they can form insoluble scum
with Mg2+ or Ca2+ ion found in hard water.
2RCOONa(aq) + Mg2+(aq) → (RCOO)2Mg(s) + 2Na+(aq)
2RCOONa(aq) + Ca2+(aq) → (RCOO)2Ca(s) + 2Na+(aq)
statement (3) : correct. The hydrophilic part is an ionic head and the hydrophobic part is a
hydrocarbon chain.
Ans. : B
16.
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