Proceso: Producción de dióxido de nitrógeno (NO 2)

Reacción: N2(g) + 2O2(g) → 2NO2(g)

Sustancia Ttp (K) Ptp (bar) Tc (K) Pc (bar) Tb° (K) Tf° (K)
Informaci
ón de N2(g) 63.149 0.1260 126.200 33.530 77.350 63.150
Equilibrio O2(g)
de fases 54.360 0.0015 154.600 50.140 90.180 54.360
NO2(g) 261.800 0.2200 288.500 101.320 294.000 261.800
N2(g) + 2O2(g) → 2NO2(g)
ΔH°f (J/mol 0 0 33180 ΔHRxn 66360
ΔG°f (jJ/mol 0 0 51300 ΔGRxn 102600
C°p,m 20.79 29.38 37.3 Δ𝐶𝑃 -4.95
A (1) 30.8 32.83 32.06 Δ𝐶𝑃 (A1)= -32.34
A (2) -0.0119 -0.0363 -0.00984 Δ𝐶𝑃 (A2)= 0.06482
A (3) 0.0000237 0.000115 0.000138 Δ𝐶𝑃 (A3)= 0.0000223
A (4) -1.02E-08 -1.22E-07 -1.82E-07 Δ𝐶𝑃 (A4)= -1.098E-07
ógeno (NO 2)
(g)

T°(K)R[=}Jmol^-1K^-1
298.15 8.314
298.15
298.15
1/T Kp In(Kp(T2)) T In(K°p) ΔH°R [=](J/mR[=]Jmol^-1 T°[=]K
-0.001 0.00130945 -6.63814717 -1000 -41.3906767 66360 8.314 298.15
-0.00105263 0.00199311 -6.21805677 -950 -41.3906767 66360 8.314 298.15
-0.00111111 0.00317868 -5.75128966 -900 -41.3906767 66360 8.314 298.15
-0.00117647 0.00535562 -5.22960878 -850 -41.3906767 66360 8.314 298.15
-0.00125 0.00963149 -4.64271778 -800 -41.3906767 66360 8.314 298.15
-0.00133333 0.01873101 -3.97757464 -750 -41.3906767 66360 8.314 298.15
-0.00142857 0.04005863 -3.21741106 -700 -41.3906767 66360 8.314 298.15
-0.00153846 0.09629882 -2.34029924 -650 -41.3906767 66360 8.314 298.15
-0.00166667 0.26793734 -1.31700212 -600 -41.3906767 66360 8.314 298.15
-0.00181818 0.89794095 -0.10765097 -550 -41.3906767 66360 8.314 298.15
-0.002 3.83270344 1.34357041 -500 -41.3906767 66360 8.314 298.15
-0.00222222 22.5849878 3.11728543 -450 -41.3906767 66360 8.314 298.15
-0.0025 207.354358 5.3344292 -400 -41.3906767 66360 8.314 298.15
-0.00285714 3586.89652 8.18504263 -350 -41.3906767 66360 8.314 298.15
-0.00333333 160469.717 11.9858605 -300 -41.3906767 66360 8.314 298.15
-0.004 32835000.1 17.3070056 -250 -41.3906767 66360 8.314 298.15
-0.005 9.6107E+10 25.2887232 -200 -41.3906767 66360 8.314 298.15
-0.00666667 5.7559E+16 38.5915858 -150 -41.3906767 66360 8.314 298.15
-0.01 2.0646E+28 65.1973111 -100 -41.3906767 66360 8.314 298.15
-0.02 9.5278E+62 145.014487 -50 -41.3906767 66360 8.314 298.15
#DIV/0! #DIV/0! #DIV/0! 0 -41.3906767 66360 8.314 298.15
0.02 2.10066E-76 -174.254216 50 -41.3906767 66360 8.314 298.15
0.01 9.69425E-42 -94.4370406 100 -41.3906767 66360 8.314 298.15
0.00666667 3.47724E-30 -67.8313153 150 -41.3906767 66360 8.314 298.15
0.005 2.08254E-24 -54.5284527 200 -41.3906767 66360 8.314 298.15
0.004 6.09551E-21 -46.5467351 250 -41.3906767 66360 8.314 298.15
0.00333333 1.24725E-18 -41.22559 300 -41.3906767 66360 8.314 298.15
0.00285714 5.57992E-17 -37.4247721 350 -41.3906767 66360 8.314 298.15
0.0025 9.65236E-16 -34.5741587 400 -41.3906767 66360 8.314 298.15
0.00222222 8.8619E-15 -32.3570149 450 -41.3906767 66360 8.314 298.15
0.002 5.22206E-14 -30.5832999 500 -41.3906767 66360 8.314 298.15
0.00181818 2.22894E-13 -29.1320785 550 -41.3906767 66360 8.314 298.15
0.00166667 7.46988E-13 -27.9227274 600 -41.3906767 66360 8.314 298.15
0.00153846 2.07838E-12 -26.8994303 650 -41.3906767 66360 8.314 298.15
0.00142857 4.99633E-12 -26.0223184 700 -41.3906767 66360 8.314 298.15
0.00133333 1.06853E-11 -25.2621549 750 -41.3906767 66360 8.314 298.15
0.00125 2.07804E-11 -24.5970117 800 -41.3906767 66360 8.314 298.15
0.00117647 3.73712E-11 -24.0101207 850 -41.3906767 66360 8.314 298.15
0.00111111 6.29651E-11 -23.4884399 900 -41.3906767 66360 8.314 298.15
0.00105263 1.00419E-10 -23.0216727 950 -41.3906767 66360 8.314 298.15
0.001 1.52847E-10 -22.6015823 1000 -41.3906767 66360 8.314 298.15
0.00095238 2.23524E-10 -22.2215006 1050 -41.3906767 66360 8.314 298.15
0.00090909 3.15781E-10 -21.8759717 1100 -41.3906767 66360 8.314 298.15
0.00086957 4.32911E-10 -21.5604887 1150 -41.3906767 66360 8.314 298.15
0.00083333 5.78087E-10 -21.2712961 1200 -41.3906767 66360 8.314 298.15
0.0008 7.54294E-10 -21.0052388 1250 -41.3906767 66360 8.314 298.15
0.00076923 9.64272E-10 -20.7596475 1300 -41.3906767 66360 8.314 298.15
0.00074074 1.21048E-09 -20.5322482 1350 -41.3906767 66360 8.314 298.15
0.00071429 1.49507E-09 -20.3210916 1400 -41.3906767 66360 8.314 298.15
0.00068966 1.81988E-09 -20.1244976 1450 -41.3906767 66360 8.314 298.15
0.00066667 2.1864E-09 -19.9410098 1500 -41.3906767 66360 8.314 298.15
0.00064516 2.59583E-09 -19.76936 1550 -41.3906767 66360 8.314 298.15
0.000625 3.04904E-09 -19.6084382 1600 -41.3906767 66360 8.314 298.15
0.00060606 3.54663E-09 -19.4572694 1650 -41.3906767 66360 8.314 298.15
0.00058824 4.08889E-09 -19.3149927 1700 -41.3906767 66360 8.314 298.15
0.00057143 4.67589E-09 -19.1808462 1750 -41.3906767 66360 8.314 298.15
0.00055556 5.30746E-09 -19.0541523 1800 -41.3906767 66360 8.314 298.15
0.00054054 5.98322E-09 -18.9343067 1850 -41.3906767 66360 8.314 298.15
0.00052632 6.70261E-09 -18.8207687 1900 -41.3906767 66360 8.314 298.15
0.00051282 7.4649E-09 -18.7130533 1950 -41.3906767 66360 8.314 298.15
0.0005 8.26924E-09 -18.6107235 2000 -41.3906767 66360 8.314 298.15
0.0004878 9.11463E-09 -18.5133855 2050 -41.3906767 66360 8.314 298.15
0.00047619 1E-08 -18.4206827 2100 -41.3906767 66360 8.314 298.15
0.00046512 1.09241E-08 -18.3322915 2150 -41.3906767 66360 8.314 298.15
0.00045455 1.18858E-08 -18.2479182 2200 -41.3906767 66360 8.314 298.15
0.00044444 1.28838E-08 -18.1672948 2250 -41.3906767 66360 8.314 298.15
0.00043478 1.39167E-08 -18.0901768 2300 -41.3906767 66360 8.314 298.15
0.00042553 1.49831E-08 -18.0163403 2350 -41.3906767 66360 8.314 298.15
0.00041667 1.60818E-08 -17.9455804 2400 -41.3906767 66360 8.314 298.15
0.00040816 1.72111E-08 -17.8777087 2450 -41.3906767 66360 8.314 298.15
0.0004 1.83699E-08 -17.8125518 2500 -41.3906767 66360 8.314 298.15
0.00039216 1.95567E-08 -17.7499501 2550 -41.3906767 66360 8.314 298.15
0.00038462 2.077E-08 -17.6897561 2600 -41.3906767 66360 8.314 298.15
0.00037736 2.20086E-08 -17.6318337 2650 -41.3906767 66360 8.314 298.15
0.00037037 2.3271E-08 -17.5760565 2700 -41.3906767 66360 8.314 298.15
0.00036364 2.45561E-08 -17.5223075 2750 -41.3906767 66360 8.314 298.15
0.00035714 2.58623E-08 -17.4704782 2800 -41.3906767 66360 8.314 298.15
0.00035088 2.71886E-08 -17.4204674 2850 -41.3906767 66360 8.314 298.15
0.00034483 2.85337E-08 -17.3721812 2900 -41.3906767 66360 8.314 298.15
0.00033898 2.98963E-08 -17.3255317 2950 -41.3906767 66360 8.314 298.15
0.00033333 3.12753E-08 -17.2804373 3000 -41.3906767 66360 8.314 298.15
0.00032787 3.26696E-08 -17.2368213 3050 -41.3906767 66360 8.314 298.15
0.00032258 3.4078E-08 -17.1946124 3100 -41.3906767 66360 8.314 298.15
0.00031746 3.54996E-08 -17.1537434 3150 -41.3906767 66360 8.314 298.15
0.0003125 3.69333E-08 -17.1141515 3200 -41.3906767 66360 8.314 298.15
0.00030769 3.83781E-08 -17.0757779 3250 -41.3906767 66360 8.314 298.15
0.00030303 3.98331E-08 -17.0385671 3300 -41.3906767 66360 8.314 298.15
0.00029851 4.12974E-08 -17.002467 3350 -41.3906767 66360 8.314 298.15
0.00029412 4.277E-08 -16.9674288 3400 -41.3906767 66360 8.314 298.15
0.00028986 4.42502E-08 -16.9334061 3450 -41.3906767 66360 8.314 298.15
0.00028571 4.57371E-08 -16.9003555 3500 -41.3906767 66360 8.314 298.15
0.00028169 4.723E-08 -16.8682359 3550 -41.3906767 66360 8.314 298.15
0.00027778 4.87282E-08 -16.8370085 3600 -41.3906767 66360 8.314 298.15
0.00027397 5.02308E-08 -16.8066367 3650 -41.3906767 66360 8.314 298.15
0.00027027 5.17374E-08 -16.7770857 3700 -41.3906767 66360 8.314 298.15
0.00026667 5.32471E-08 -16.7483228 3750 -41.3906767 66360 8.314 298.15
0.00026316 5.47594E-08 -16.7203168 3800 -41.3906767 66360 8.314 298.15
0.00025974 5.62737E-08 -16.6930382 3850 -41.3906767 66360 8.314 298.15
0.00025641 5.77895E-08 -16.666459 3900 -41.3906767 66360 8.314 298.15
0.00025316 5.93062E-08 -16.6405528 3950 -41.3906767 66360 8.314 298.15
0.00025 6.08232E-08 -16.6152942 4000 -41.3906767 66360 8.314 298.15
0.00024691 6.23402E-08 -16.5906592 4050 -41.3906767 66360 8.314 298.15
0.0002439 6.38566E-08 -16.5666251 4100 -41.3906767 66360 8.314 298.15
0.00024096 6.53721E-08 -16.5431702 4150 -41.3906767 66360 8.314 298.15
0.0002381 6.68862E-08 -16.5202737 4200 -41.3906767 66360 8.314 298.15
0.00023529 6.83984E-08 -16.497916 4250 -41.3906767 66360 8.314 298.15
0.00023256 6.99085E-08 -16.4760781 4300 -41.3906767 66360 8.314 298.15
0.00022989 7.14161E-08 -16.4547424 4350 -41.3906767 66360 8.314 298.15
0.00022727 7.29208E-08 -16.4338915 4400 -41.3906767 66360 8.314 298.15

T ΔGrxn (J/mol)
-1000 -55189.5556
-950 -49112.0778
ΔGrxn (J/mol)
-900 -43034.6
700000
-850 -36957.1223
-800 -30879.6445
600000
-750 -24802.1667
500000
-700 -18724.6889
-650 -12647.2111
400000
-600 -6569.73336
300000
-550 -492.255576
-500 5585.2222
200000
-450 11662.7
100000
-400 17740.1778
-350 23817.6555
0
0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000
 200000

100000

0
0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000
-300 29895.1333
-250 35972.6111
-200 42050.0889
-150 48127.5667
-100 54205.0444
-50 60282.5222
0 #DIV/0!
50 72437.4778
100 78514.9556
150 84592.4333
200 90669.9111
250 96747.3889
300 102824.867
350 108902.344
400 114979.822
450 121057.3
500 127134.778
550 133212.256
600 139289.733
650 145367.211
700 151444.689
750 157522.167
800 163599.644
850 169677.122
900 175754.6
950 181832.078
1000 187909.556
1050 193987.033
1100 200064.511
1150 206141.989
1200 212219.467
1250 218296.944
1300 224374.422
1350 230451.9
1400 236529.378
1450 242606.856
1500 248684.333
1550 254761.811
1600 260839.289
1650 266916.767
1700 272994.245
1750 279071.722
1800 285149.2
1850 291226.678
1900 297304.156
1950 303381.633
2000 309459.111
2050 315536.589
2100 321614.067
2150 327691.545
2200 333769.022
2250 339846.5
2300 345923.978
2350 352001.456
2400 358078.933
2450 364156.411
2500 370233.889
2550 376311.367
2600 382388.845
2650 388466.322
2700 394543.8
2750 400621.278
2800 406698.756
2850 412776.233
2900 418853.711
2950 424931.189
3000 431008.667
3050 437086.145
3100 443163.622
3150 449241.1
3200 455318.578
3250 461396.056
3300 467473.533
3350 473551.011
3400 479628.489
3450 485705.967
3500 491783.445
3550 497860.922
3600 503938.4
3650 510015.878
3700 516093.356
3750 522170.833
3800 528248.311
3850 534325.789
3900 540403.267
3950 546480.745
4000 552558.222
4050 558635.7
4100 564713.178
4150 570790.656
4200 576868.133
4250 582945.611
4300 589023.089
4350 595100.567
4400 601178.045
ΔGrxn (J/mol)
80000
-55189.5556
-49112.0778 60000
-43034.6
40000
-36957.1223
-30879.6445 20000
ΔGrxn (J/mol)
-24802.1667 0
-18724.6889 -1200 -1000 -800 -600 -400 -200 0
-12647.2111 -20000
-6569.73336 -40000
-492.255576
5585.2222 -60000

11662.7 -80000
17740.1778
23817.6555 T
29895.1333
35972.6111
42050.0889
48127.5667
54205.0444 In(Kp(T2)) 1/T Pol. ΔCp
60282.5222 -6.63814717 -0.001
#DIV/0! -6.21805677 -0.00105263
72437.4778 -5.75128966 -0.00111111
78514.9556 -5.22960878 -0.00117647
0
84592.4333 -4.64271778 -0.00125 -20 0 20 40
90669.9111 -3.97757464 -0.00133333
96747.3889 -3.21741106 -0.00142857 -0.005
102824.867 -2.34029924 -0.00153846
108902.344 -1.31700212 -0.00166667
114979.822 -0.10765097 -0.00181818 -0.01
121057.3 1.34357041 -0.002
1/T

127134.778 3.11728543 -0.00222222

133212.256 5.3344292 -0.0025 -0.015
139289.733 8.18504263 -0.00285714
145367.211 11.9858605 -0.00333333
151444.689 17.3070056 -0.004 -0.02
157522.167 25.2887232 -0.005
163599.644 38.5915858 -0.00666667
-0.025
169677.122 65.1973111 -0.01
175754.6 145.014487 -0.02
181832.078
187909.556
193987.033
200064.511
206141.989
212219.467 T(K) 4.76% de errPol. ΔCp 2.82% de erroΔHcons. Cp const.
218296.944 50 66360 71605.8189 67588.3425 0.07325967 0.05610545
224374.422 100 66360 71605.8189 67340.8425 0.07325967 0.05956187
230451.9 150 66360 69030.4522 67093.3425 0.03868513 0.02806167
236529.378 200 66360 67984.983 66845.8425 0.02390209 0.01675577
242606.856 250 66360 67090.5806 66598.3425 0.01088947 0.00733692
248684.333 300 66360 66334.2913 66350.8425 -0.00038756 -0.00024951
254761.811 350 66360 65699.0439 66103.3425 -0.01006036 -0.0061538
260839.289 400 66360 65163.6496 65855.8425 -0.01835917 -0.01062238
266916.767 450 66360 64702.8022 65608.3425 -0.02561246 -0.01399538
272994.245 500 66360 64287.078 65360.8425 -0.03224477 -0.01670265
279071.722 550 66360 63882.9356 65113.3425 -0.03877506 -0.01926034
285149.2 600 66360 63452.7163 64865.8425 -0.04581811 -0.02227054
291226.678 650 66360 62954.6439 64618.3425 -0.05409221 -0.02642694
297304.156 700 66360 62342.8246 64370.8425 -0.06443685 -0.03253009
303381.633 750 66360 61567.2472 64123.3425 -0.07784582 -0.04151713
309459.111 800 66360 60573.783 63875.8425 -0.09552346 -0.05451302
315536.589 850 66360 59304.1856 63628.3425 -0.11897667 -0.07291487
321614.067 900 66360 57696.0913 63380.8425 -0.15016457 -0.09852923
327691.545 950 66360 55683.0189 63133.3425 -0.19174573 -0.13379884
333769.022 1000 66360 53194.3696 62885.8425 -0.24750045 -0.18218982
339846.5 promedio -0.04757736 -0.02819264
345923.978 % de error 4.75773608 2.81926434
352001.456
358078.933
364156.411
370233.889
376311.367
382388.845
388466.322
394543.8
400621.278
406698.756
412776.233
418853.711
424931.189
431008.667 N2(g) + 2O2(g) →
437086.145 ΔH°f (J/mol) 0 0
443163.622 ΔG°f (jJ/mol) 0 0
449241.1 C°p,m 20.79 29.38
455318.578 A (1) 30.8 32.83
461396.056 A (2) -0.0119 -0.0363
467473.533 A (3) 0.0000237 0.000115
473551.011 A (4) -1.02E-08 -1.22E-07
 479628.489 A (4) -1.02E-08 -1.22E-07
485705.967
491783.445
497860.922
503938.4
510015.878
516093.356
522170.833
528248.311
534325.789
540403.267
546480.745
552558.222
558635.7
564713.178
570790.656
576868.133
582945.611
589023.089
595100.567
601178.045

Caso 1.
A B
X 0.19381746 0.40823619 -0.81647238

Caso 2.
P,bar X mol prod. A B
1 0.01845158 0.03690317 3.9947622 -11.9842866
3.5 0.04598144 0.09196288 3.9720964 -11.9162892
6 0.072176 0.14435201 3.92371171 -11.7711351
8.5 0.106103 0.21220601 3.81790892 -11.4537267
11 0.15109423 0.30218847 3.57621462 -10.7286439
13.5 0.21102354 0.42204707 2.98852526 -8.96557579
16 0.2906067 0.5812134 1.43624747 -4.3087424
18.5 0.39191033 0.78382066 -3.12611248 9.37833743
21 0.51227417 1.02454833 -18.5067369 55.5202107
23.5 0.64166711 1.28333421 -80.4064496 241.219349
26 0.76424003 1.52848006 -394.601157 1183.80347
28.5 0.86463507 1.72927014 -2570.68861 7712.06584
31 0.9345294 1.8690588 -25707.9404 77123.8212
33.5 0.97479362 1.94958725 -480640.133 1441920.4
36 0.99300286 1.98600572 -23107635 69322905.8
3500 4000 4500 5000
3500 4000 4500 5000
38.5 0.99883545 1.9976709-5056590017 1.517E+10
 ΔGrxn (J/mol) T
-55189.55559 -1000
-49112.07781 -950
-43034.60003 -900
-36957.12225 -850
-30879.6445 -800 Caso 1.
-24802.16669 -750
-18724.68891 -700 X 0.19381746
-12647.21114 -650
-6569.733356 -600
-492.2555761 -550 Caso 2.
5585.2222036 -500
11662.699983 -450 X 0.64722312
17740.177763 -400
23817.655543 -350
29895.133322 -300
35972.611102 -250
42050.088881 -200
48127.566661 -150
54205.044441 -100
60282.52222 -50

0
-20 0 20 40 60 80 100 120 140 160

-0.005

-0.01

-0.015

-0.02

-0.025
In(Kp)
 80000

70000

60000

50000

40000

30000

20000
4.76% de error con ΔHRxn cons. Pol. ΔCp
10000

0 2.82% de error con ΔCp const.

0 200 400 600 800 1000 1200

2NO2(g)
33180 ΔHRxn 66360
51300 ΔGRxn 102600
37.3 Δ𝐶𝑃 -4.95
32.06 Δ𝐶𝑃 (A1)= -32.34
-0.00984 Δ𝐶𝑃 (A2)= 0.06482
0.000138 Δ𝐶𝑃 (A3)= 0.0000223
-0.000000182 Δ𝐶𝑃 (A4)= -1.098E-07
 -0.000000182 Δ𝐶𝑃 (A4)= -1.098E-07

C D Kp T(k)
-4.4897047646 0.8979409529 5.910626E-05 0.89794095 -550

C D Kp T(K)
-0.0157134142 0.0052378047 0.000892781 0.00130945
-0.0837108103 0.0279036034 -0.0007539 0.00199311 0
-0.2288648684 0.0762882895 -7.52431E-05 0.00317868 0
-0.5462732547 0.1820910849 -0.000254 0.00535562 0
-1.2713561256 0.4237853752 -0.00090263 0.00963149 0
-3.0344242132 1.0114747377 -2.22549E-05 0.01873101 0
-7.6912576001 2.5637525334 -1.25205E-05 0.04005863 0
-21.378337427 7.1261124757 -1.39554E-06 0.09629882 0
-67.520210742 22.506736914 -0.00016598 0.26793734 0
-253.21934872 84.406449574 -0.00043811 0.89794095 0
-1195.8034721 398.60115737 4.861372E-05 3.83270344 0
-7724.0658441 2574.6886147 0.000667739 22.5849878 0
-77135.821218 25711.940406 0.000148199 207.354358 0
-1441932.4 480644.13333 3.87145E-06 3586.89652 0
-69322917.79 23107639.263 0.000173017 160469.717 0
-15169770064 5056590021 0 32835000.1 0
0
 A B C D Kp T(k)
0.4082361883 -0.816472377 -4.4897047646 0.89794095 5.91063E-05 0.89794095 -550

A B C D Kp T(K)
-8.58E+01 2.57E+02 -2.69E+02 8.98E+01 -5.91E-06 8.98E-01 -550
Pol. ΔCp

1000 1200
 Tc(K) 318.7 R(cm^3 * bar/molK)
Pc(Bar) 37.6
V(cm^3/mol)
T(K) 348.16
P(Bar) 15 Z

Formas basicas

a 7877349.4634
b 88.087493351

H 15
Y -17.63302366
O 2.6330236983

0 4.015125E-08
 83.14

1729.66769

0.89632403

H Y O