Chemistry

1 Which of the following are state functions?(2 correct)

energy
enthalpy
work
heat

2 Which of the following depend on the pathway? (2 correct)

energy
enthalpy
heat
work

3 When heat flows out of the system the reaction (2 correct)

is said to be exothermic
is said to be endothermic
loses as much energy as the surroundings gain
the change in heat is positive

4 When heat flows into a system the change will

depend on the pathway
not depend on the pathway

5 When a gas expands

the volume of the final state depends on the path taken
the volume of the final state does not depend on the path taken
the system does the work
the surroundings does the work

6 When heat flows into a system (2 correct)

the universe gains energy
the universe loses energy
the surroundings loses energy
the reaction within the system is endothermic
the change in heat is negative
7 In endothermic reactions (2 correct)
heat is gained by the system
heat is lost by the system
heat is gained by the surroundings
heat is lost by the surroundings
the change in heat is negative

8 The products of exothermic reactions

are at a lower energy level than the reactants
are more stable than the reactants
have stronger bonds than the reactants on average
all of the above

9 In exothermic reactions (3 correct)

heat is gained by the system
heat is lost by the system
heat is gained by the surroundings
heat is lost by the surroundings
some of the potential energy of the reactants is converted into kinetic energy in the
surroundings

10 In exothermic reactions the change in enthalpy is

negative
positive

11 The internal energy of a system is equal to the (2 correct)

sum of the kinetic and potential energies of the system
sum of the work and heat of the system
energy of the surroundings

12 When a gas expands (2 correct)

work is done to the system
work is done on the surroundings
the sign of the value of work done is positive
the sign of the value of work done is negative

13 When a gas is compressed (2correct)

work is done on the system
 work is done by the system
the sign of the value of work done is negative
the sign of the value of work done is positive

14 Consider the changing of one mole of a gas to one mole of a liquid at constant
pressure. Which of the following statements would be true?
q and w would not change
q and w would both increase
q would increase and w would decrease
q would decrease and w would increase
none of the above

15 For a reaction the value of q is 35 kJ and the value of w is -25 kJ. Which of the
following is not true? (choose 2)
work is done on the system
work is done by the surroundings
the internal energy will equal 10. kJ
the reaction is exothermic
the surroundings lose heat energy

16 For a reaction q = 36 kJ and w = -12 kJ. Which of the following are true? (choose all
correct)
The reaction is exothermic.
The reaction is endothermic.
Work is done by the system.
Work is done on the system.
The internal energy equals 24 kJ.

17 For a reaction q = -24 kJ and w = 12kJ. Which of the following are true? (choose all
correct)
The reaction is exothermic.
The reaction is endothermic.
The system does work on the surroundings.
The surroundings does work on the system.
The change in internal energy will equal 36 kJ

18 Enthalpy (2 correct)
is a state function
is not a state function
equals E + PV
equals E - PV
equals E(PV)

19 At constant pressure enthalpy equals

the energy flow as heat
 the amount of work done due to expansion only
the sum of the entropy and work changes

20 At constant pressure exothermic reactions will have a (2correct)

positive enthalpy value
negative enthalpy value
more enthalpy in the products
less enthalpy in the products

21 Ideally, in a calorimeter the heat lost by the reaction will be _________________ the
heat gained by the water in the calorimeter.
equal to
less than
more than

22 Enthalpy, or heat of reaction, is an ___________________ property.

intensive
extensive

23 Water has a specific heat capacity of 4.18 J/g x ºC. If 4.18 J of energy are added to one
gram of water, how much will the temperature rise?
4.18 ºC
10.0ºC
1.0 ºC

24 A substance has a specific heat capacity of 5.0 J/g x ºC. If a 1.0 gram mass of this
substance at 20.0 ºC has 25.0 J of energy added to it, what will its final temperature
be?
19.0 ºC
21.0 ºC
25.0ºC
30.0 ºC

25 25.0 mL of water at 25.0 ºC is added to 50.0 mL of water at 50.0 ºC and allowed to

come to a constant final temperature. Which of the following statements are true?
 The heat lost by the smaller mass of water will be greater than the heat gained by the
larger mass of water.
The heat lost by the smaller mass of water will be less than the heat gained by the larger
mass of water.
The heat lost by the smaller mass of water will be equal to the heat gained by the larger
mass of water.

26 Bomb calorimeters are used in

constant volume calorimetry
constant pressure calorimetry

27 Calorimeters have a constant-a correction value due to the heat absorbed by the
calorimeter itself. If a calorimeter is used in an exothermic reaction and the
calorimeter constant is not accounted for the final value for the change in enthalpy
will be
less negative than it should be
less positive than it should be
more negative than it should be
more positive than it should be
unaffected

28 If a reaction is reversed
the magnitude of the change in enthalpy will change
the sign of the change in enthalpy will be opposite

29 If the coefficients in a balanced chemical reaction are doubled

the magnitude of the enthalpy change will double
the magnitude of the enthalpy change will be cut in half
the sign of the enthalpy change will be reversed

30 Which of the following is not true?

The standard state of a gaseous compound is at 1 atm of pressure.
The standard concentration of a substance in solution is 1 N.
The standard state of an element is that state at which it exists at 1 atm and 25 ºC.
The standard state of a pure solid is solid.
31 The enthalpy of formation of an element in its standard state is equal to
the difference between the products' enthalpies of formation and the other elements
enthalpies of formation
the sum of the enthalpies of its component elements
zero
one

32 Petroleum is made up mostly of

minerals
hydrocarbons
ethers
gases

33 Natural gas is made up of mostly

butane
propane
ethane
methane

34 Gasoline is made up of hydrocarbons with

5-10 carbon atoms
10-18 carbon atoms
15-25 carbon atoms
greater than 25 carbon atoms

35 Which is the correct sequence of the four stages of coal formation?

bituminous - subbituminous - anthracite - lignite
lignite - bituminous - subbituminous - anthracite
lignite- subbituminous - bituminous - anthracite
anthracite -bituminous - subbituminous - lignite

36 The coal with the highest mass percent of carbon is

lignite
subbituminous
bituminous
anthracite

37 The coal with the highest energy value per gram is

lignite
subbituminous
 bituminous
anthracite

38 Which of the following can be considered greenhouse gases?(2 correct)

nitrogen
water vapor
carbon dioxide
argon

39 Syngas is
a mixture of hydrogen and carbon monoxide
formed by coal gasification
able to be converted into methanol
all of the above

40 Problems of the use of hydrogen as a fuel include (3 correct)

its lack of abundance
its ability to chemically bond to oxygen
its small size
its ability to react with metals
its relatively small energy content per unit volume

41 An advantage of ethanol as an energy source is (2 correct)

renewability
strong ability to vaporize even in cold climates
ability to be produced from sugar from many sources

42 An advantage of hydrogen as a fuel is

water is the only waste product
its low density
its ease of transport
its relatively high energy content per unit of volume