Nama:....................................................

SULIT 4541/1 Chemistry 2 jam 30 minit

Tingkatan :..............................

CHEMISTRY DEPARTMENT

PRA-PEPERIKSAAN AKHIR TAHUN TINGKATAN 4 TAHUN 2011 CHEMISTRY Dua jam tiga puluh minit

1 2 3 4 5

A A A A A

B B B B B

C C C C C

D D D D D

16 A 17 18 A A

B B B B B

C C C C C

D D D D D C A B

Soalan 1-30 1 2 3 4

Markah penuh 30 8 10 15 20 17

Markah

19 A 20 A

6 7 8 9 10

A A A A A

B B B B B

C C C C C

D D D D D

21 A 22 23 A A

B B B B B

C C C C C

D D D D D

Jumlah: [100]

24 A 25 A

11 12 13 14 15

A A A A A

B B B B B

C C C C C

D D D D D

26 A 27 28 A A

B B B B B

C C C C C

D D D D D

29 A 30 A

The following word equation shows a chemical reaction. X + magnesium oxide magnesium chloride + water What is acid X? A Hydrochloric acid B Sulphuric acid

C Phosphoric acid D Nitric acid

Hydrogen chloride in methylbenzene does not show any acidic property. Which of the followings explain the observation? A B C D Hydrogen choride is a covalent compound Hydrogen choride molecules ionises in the solution. This solution does not contain hydrogen ions. This solution show the electrical conductivity

Which of the following reactions does not show the role of benzoic acids as an acid? A The burning of benzoic acid to produce carbon dioxide and water B The reaction that occurs between benzoic acid and sodium hydroxide to produce salt and water C The reaction that occurs between benzoic acid and limestone to produce carbon dioxide D The reaction that occurs between benzoic acid and magnesium ribbon to produce hydrogen Which of the following statements are true for both dilute ethanoic acid and dilute hydrochloric acid of the same concentration? I II III IV They have different concentration of hydrogen ions. Their degree of ionisation in water is the same. They have different pH value. They neutralise equal amount of sodium hydroxide. C D II and IV only III and IV only

A I and II only B I and III only 5

Which of the following is a synthetic polymer? A Rubber B PVC C Protein D Starch

What is the type of glass used to make laboratory glass wares? A Lead glass B Fused glass C Borosilicate glass D Soda glass

Which of the following substances used by a farmer to neutralize an acidic soil? A Calcium oxide B Sulphuric acid C Sodium hydroxide D Ammonium hydroxide

Which of the following are insoluble salts? I II III IV Silver chloride Magnesium nitrate Barium sulphate Zinc carbonate C I, II and III only D I, III and IV only

A I and III only B II and IV only 9

If 150 cm3 of a 4 mol dm3 solution Y is added to 250 cm3 of water, what is the molarity of the diluted solution? A 1.50 mol dm3 C 2.80 mol dm3 B 2.40 mol dm3 D 3.00 mol dm3

10 Which of the following shows a precipitation reaction? A B C D K2CO3 2HCl Na2SO4 NaOH + + + + Pb(NO3)2 PbO Mg(NO3)2 K2CO3 2KNO3 + PbCO3 PbCl2 + H2O MgSO4 + 2NaNO3 Na2CO3 + 2KOH

11 The pie chart in Diagram 11 shows the composition of stainless steel.

Diagram 11 What is element X? A Tin B Copper C Iron D Aluminium

12 Which of the following statement describes the property of hydrochloric acid? A B C D It reacts with any metal to give hydrogen It liberates ammonia from ammonium salts It causes colour of litmus paper to change from red to blue It reacts with any bases to produce a salt.

13 Table 1 shows some of the steps for preparing a standard solution but they are not in order. P SQRDissolve the solute in distilled water Transfer the solution into a volumetric flask Add distilled water until the mark of the flask Weigh the mass of the solute needed

Table 3 Which of the following sequence of steps is correct? A PQRS C RPQS B RPSQ D R Q P S 14 Diagram 10 shows the industrial preparation of sulphuric acid through the Process I. I S oxygen SO2 oxygen II III SO3 H2S2O7 concentrated H2SO4 IV H2SO4 water

Diagram 10 Which stage involves the use of a catalyst? A I B II C III D IV 15 Diagram 6 shows the pH values of four different solutions.
V W X Y

pH = 1

pH = 4

pH = 8

pH = 12

Diagram 13 Which of the solutions has the highest concentration of hydrogen ions? A B C D V W X Y

16 Which pairs of substances are suitable to prepare copper(II) sulphate in the laboratory? I II III IV Copper and dilute suphuric acid Copper(II) carbonate and dilute sulphuric acid Aqueous copper(II) nitrate solution and dilute sulphuric acid Copper(II) hydroxide and sulphuric acid C D II and IV only I, II and III only

A I and II only B I and III only

17 Lead (II) Iodide can be prepared through A B C D Precipitation Reaction Neutralization Reaction Crystallization Recrystallization

18 Diagram 15 shows the setup of apparatus for the titration of potassium hydroxide solution with sulphuric acid.

Sulphuric acid 1.0 mol dm-3 25 cm3 of potassium hydroxide solution 1.0 mol dm-3 and phenolphthalein as an indicator

Diagram 15 What is the volume of sulphuric acid at the end point of the titration? A 12.5 cm3 B 25 cm3 19 Sulphuric acid is a diprotic acid because A B C D sulphuric acid has the properties of acid and also a dehydrating agent. one mole of sulphuric acid can neutralise two moles of bases. one molecule of sulphuric acid contains two moles OH- ions. one molecule of sulphuric acid produces two H+ ions in water. C 50 cm3 D 100 cm3

20 Process II can be represented by the following equation: N2 (g) + 3H2 (g) 2NH3 (g) What is the catalyst, temperature and pressure used in this process? Catalyst Iron Platinum Platinum Iron Temperature(C) 450 900 800 200 Pressure (atm) 200 150 10 1050

A B C D 21

Table 2 shows the pairs of polymer and monomer. Polymer Carbohydrate Polyvinyl chloride Protein Natural rubber Monomer Glucose Chloroethene Amino acid Neoprene

I II III IV

Table 2 Which of the following pairs of polymer and monomer are correct ? A I and II only B I, II and III only C D II, III and IV only I, II, III and IV

22 Neutralization reaction between nitric acid and calcium hydroxide is shown in the chemical equation below. 2HNO3 + Ca(OH)2 Ca(NO3)2 + 2H2O What is the minimum volume of nitric acid of 0.2 mol dm-3 needed to completely neutralise 50 cm3 calcium hydroxide solution 0.05 mol dm-3. A B C D 12.5 cm3 25.0 cm3 37.5 cm3 50.0 cm3

23 When sodium hydroxide is added dropwise until in excess to a solution, a white precipitate which is soluble in excess is formed. The ions that could be present in the solution are I II III IV A B C D Al3+ Zn2+ Mg2+ Pb2+ I and II only III and IV only I, II, and IV only I, II, III and IV

24 A green solid is heated up strongly and the residue is black in colour. The solid is A B C D Sodium carbonate Lead(II) nitrate Iron(II) carbonate Copper(II) carbonate

25 The table below shows the results of qualitative analysis of a salt. Qualitative analysis Sodium hydroxide solution added until excess into salt solution 2 cm3 of dilute nitric acid is added and followed by 2 cm3 silver nitrate solution. Observation White precipitate formed and dissolve in excess. White precipitate is formed.

Among the following ions, which may be present in the salt? A B C D Zn2+ and ClMg2+ and ClZn2+ and SO42Mg2+ and SO42-

26 The table below shows the observation of the reaction between calcium carbonate and ethanoic acid in two different solvents. Beaker X Y Reaction calcium carbonate + ethanoic acid in distilled water. calcium carbonate + ethanoic acid in benzene Observation Effervescence occurs No visible change

Which of the following statements are true about the observation in beaker X and beaker Y? I II III IV A B C D Water ionizes ethanoic acid in beaker X Benzene ionizes ethanoic acid in beaker Water reacts with calcium carbonate in beaker X. Ethanoic acid remains as molecule in beaker Y.

I and II only I and IV only II and III only III and IV only

27 The body of the car shown in the diagram below is made of alloy T.

Alloy T

What is alloy T? A B C D Steel Brass Bronze Duralumin

28 Ammonium nitrate fertilizer is obtained through the reaction between ammonia solutions with A B C D sodium nitrate solution nitrogen dioxide gas dilute sulphuric acid dilute nitric acid

29 Ammonium sulphate, (NH4)2SO4 is an example of a fertilizer. Calculate the percentage of nitrogen in 1 mole of ammonium sulphate. [Relative atomic mass: N=14, H=1, S=,32, O=16] A B C D 12.12 % 21.21 % 23.23 % 31.31 %

30 Which salt solution is colourless? A Iron(III) sulphate B Aluminium nitrate C Copper(II) chloride D Potassium dichromate(VI)

1. Diagram 4 shows three test tubes contain dry glacial ethanoic acid, aqueous solution of ethanoic acid and dilute hydrochloric acid.
Aqueous solution of ethanoic acid -3 0.1 moldm Blue litmus paper Dilute hydrochloric acid 0.1 moldm Blue litmus paper
-3

Dry glacial ethanoic acid

Blue litmus paper

P Diagram 4

(a) (i) State the colour change of the litmus paper in test tubes R. ...................................................................................................................................... [1 mark] (ii) Write the formula of ion which caused the colour change of the litmus paper. .......................................................................................................................................[1 mark] (b) Is there any changes of colour of the litmus paper in test tube P? Explain why. ..................................................................................................................................... .....................................................................................................................................[2 marks] (c) Table 4 shows the pH value of aqueous solution of ethanoic acid and dilute hydrochloric acid of the same molarity. Type of acid aqueous solution of dilute hydrochloric ethanoic acid acid -3 Molarity 0.1 moldm 0.1 moldm-3 pH value 2.9 1.0 Table 4 Explain the difference in the pH value of aqueous solution of ethanoic acid and dilute hydrochloric acid. .................................................................................................................................... .................................................................................................................................... ....................................................................................................................................[3 marks] Calcium carbonate powder is added into test tube R. State one observation in test tube R. ..................................................................................................................................[1 mark]

(i)

2(a) Diagram 2 shows an industrial preparation of Ammonium sulphate from the product(s) of Process I and Process II.
Process I

Sulphuric acid

Reaction Y

Ammonium sulphate

Process II

Compound X Diagram 2

(i) State the names of compound X. .[1 mark] (ii) State the name of Process I and Process II. Process I: .. Process II: ......[1 mark] (iii) State the reaction Y: ... [1 mark] (iii) Write the balanced chemical equation for reaction Y to produce ammonium sulphate. ..[2 marks] (b) (i) Qualitative analysis can be used to determine the presence of cations and anions in solutions. Describe chemical tests that can be used to verify the sulphate ion, SO42- . ... [3 marks] (ii) In table 3, state the observation made when confirmatory test is carried out for ammonium ion, NH4+. Confirmatory Test Observation Added small amount of sodium hydroxide solutions to ammonium ion, NH4+ solution. Followed by heat the mixture of sodium hydroxide solutions and ammonium ion, NH4+ solution. [2 marks]

3.

An experiment is carried out to determine the concentration of nitric acid. 25 cm3 0.10 mol dm-3 potassium hydroxide solution is titrated with nitric acid from a burette. Phenolphthalein is used as an indicator. Figure 1 shows the initial and final readings of the three titrations carried out.

(a)

Record the readings for each titration in the spaces provided in Figure 1. [3 marks]

(b) (i)

A change in the colour of phenolphthalein indicator is observed at the end point. State the colour change. . [3 marks] State the operational definition for end point in this titration. . [3 marks]

(ii)

(c)

Construct a table to show all the data in each of these titrations.

[3 marks] (d) Calculate the concentration of nitric acid that is used in this experiment.

[3 marks]

The flow chart in the diagram shows a series of chemical changes of solid Q .

Substance Q Heated + Dilute sulphuric acid

Solid U + Gas R Solid U is black + Dilute nitric acid Solution Z

(a)

Solution V + Gas R + Metal M Solution W + Solid X

Draw a labelled diagram of the set-up of apparatus for the chemical reaction of converting substance Q to solid U and gas R. In your diagram show how gas R is tested. [4 marks] Solution Z and V are the products from reaction in flow chart. (i)Name the possible metal cation in solution Z (ii)Describe the confirmatory test for a cation mention in b(i) [3 marks]

(b)

(c)

Describe how to obtain crystal salt V from their solution V [4 marks]

(d)

Metal M is more electropositive than the metal in solution V. When metal M is added into solution V , chemical reaction occured. Name the metal M and give an observations for the reaction that produces solution W and solid X. [2 marks] The chemicals supplied are Zinc oxide Sodium carbonate solution Dilute nitric acid Describe briefly how you can prepare a sample of dry zinc carbonate in the laboratory. Include in your answer all chemical equations involved. [7 marks]

(e)

5.

Diagram 3 shows two beakers containing colourless solution labelled A and B.

Beaker A

Beaker B

Diagram 3

You are told that the two colourless solutions are calcium nitrate and magnesium nitrate. You are required to label correctly the name of each solution in the containers. Design an experiment to identify which is calcium nitrate and which is magnesium nitrate solution by using aqueous of ammonia solution as a reagent.

Your answer should include the following:

(a) Problem statement (b) Hypothesis (c) All variables (d) List of materials and apparatus (e) Procedure (f) Tabulation of data [17 marks]

END OF QUESTION PAPER