Skema PAT 2011 Tingkatan 4

Paper 1 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 B C A D C A C D D B C D B D A A B C C A 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 D D B B D A B C C D D A B B A C D A D B 41 42 43 44 45 46 47 48 49 50 B B C C C B C C B B

Marking scheme paper 2 No 1 (a) (i) (ii) Haber process Hydrogen ; nitrogen Answer Mark 1 1 1 1 2 1 1 2 10

(iii) Iron / Ferum (iv) 450 0C (v) Pungent smell // dissolve in water // colourless gas // low melting point // low boiling point Choose any 2 (i) Fused glass (ii) Highly heat resistant // great purity // resistance to chemical // resistance to thermal shock (iii) Withstand high temperature // chemically inert // hard // brittle // high melting point Total

(b)

No 2 (a) (b) (c) (d) 3 Chlorine / Cl2 // Argon / Ar

Answer

Mark 1 1 1 1

Semiconductors/ to make diodes / transistors Aluminium

(e)

(i)

2. 8. 2 2. 8. 7 Magnesium atom donates two electron, (Two) chlorine atom accept one electron The number of proton increase / The charge of the nucleus increase, The attraction force between nucleus and (valence ) electron increase Total

1 1 2

(ii)

(f)

1 1 10 1 1 1 1 1 1 1

(a) (b) (c) (i) (ii)

Chemical to electrical Cu2+, H+, OH- and SO42Zinc Zinc atom releases electrons//Zinc more electropositive // Zn above in electrochemical series Brown solid deposited + 2e Cu

(d) (i) (ii) (e)

Cu2+

Blue to colourless// Blue become fade/ paler // The intensity of blue colour decreases. The number of copper(II) ions decreases //The concentration of copper(II) ions decr Cu, R, Q, P 1.5 V

1 1 1 10

(f)

(i) (ii)

4 (a)(i) (ii) (iii)

Copper(II) oxide Neutralisation Correct reactants and products Balance the equation

1 1 1 1

1 1 2

(iv) (b)(i) (ii) (iii) (c)

2HCl + CuO CuCl2 + H2O To complete the reaction Double Decomposition / Precipitation reaction Ag+ + Cl- AgCl Filtration Cation : Cu2+ Anion : Cl-

1 1 1 1 1 1 Total mark

1 1 1 1 2 10

(a) (b)

To remove the oxide layer 1 (i) Mass of magnesium = 22.30 20.50 g // 1.80 g Mass of oxygen = 23.50 22.30 g // 1.20 g 1+1 (ii) Mg 1 mol (iii) MgO 2Mg + O2 2MgO 1 1 O 1 mol 1 1

(c)

Pt 1: correct reactants and product Pt 2: balanced equation

(d)

To let the oxygen in // to prevent loss of white fumes Oxide of metal W // metal oxide Dry hydrogen

heat Pt 1 functional Pt 2 correct labeling

1+1

10 6 (a) ( i ) water ( ii ) methylbenzene// any organic solvent 1 1

b c

ions 1.X ionises in water to produce hydrogen ions, 2.Y has neutral molecules and cannot ionise ( i ) neutralization ( ii ) 2HCl + Ba( OH )2 BaCl2+ 2H2O ( iii ) 1.No. Of mole, HCl= 0.6 X 8.0 = 0.0048 ---------1000 2. No. Of mole Ba(OH)2 = 0.0048/2 = 0.0024 3. Concentration of Ba(OH )2 = 0.0024 X 1000 -------------// 8 = 0.3

1 1 1 1 1 1

1 10

Marking Scheme Paper 3 1 (a) KK0503 Measuring and using numbers EXPLANATION [Able to write both temperatures with correct to 1 decimal place] temperature reading : 82.0 C temperature reading : 97.0 C [Able to record all the volumes accurately but without decimal place] temperature reading : 82 temperature reading : 97 [Able to write at least one reading of the temperature accurately] No response given / wrong response 1 (b) KK0506 Communicating EXPLANATION [ Able to draw a graph of temperature against time of the experiment on the same axes with all the 4 items below correctly ] (i) axes labelled correctly with units (ii) suitable scale used (iii) all points plotted correctly (iv) smooth curve of graph and more than size of graph paper SCORE 1 0 2 SCORE 3

[ Able to draw a graph of temperature against time of the experiment on the same axes with all the 3 items correctly ] [ Able to manipulate two items correctly ] No response or wrong response 1 (c)KK0505 Predicting EXPLANATION [Able to state the temperature correctly and able to show the how the melting point is determined on the graph] Answer: 82 .0

1 0

SCORE 3

82oC melting point

[Able to state the temperature but without unit and did not label melting point on the graph correctly] Answer: 82
Melting point

[Able to state the temperature but without unit and did not show the melting point on the graph] Answer: 82 No response given / wrong response 1 (d) KK0508 Interpreting Data EXPLANATION [Able to interpret the data accurately] Suggested answer: The heat energy absorbed is used to overcome the forces of attraction/bonds between the molecules of acetamide [Able to give correct interpretation but less accurate] Suggested answer: The heat energy is used to overcome the forces of attraction of molecules / particles of acetamide [Able to give an idea]

SCORE 3

Suggested answer: The heat energy is used / absorbed. No response given / wrong response 1 (e) KK0505 Classifying EXPLANATION [Able to classify the ionic and covalent compounds correctly] Ionic Magnesium chloride Copper(II) nitrate Zinc sulphate Covalent Methylbenzene Tetrachloromethane Carbon dioxide

SCORE 3

[Able to state at least two pairs correctly // correct grouping but wrong heading or vice versa ] [Able to state one pair correctly in a correct grouping] No response given / wrong response 2(a) KK0510 - State the variables EXPLANATION [Able to state the three variables and action to be taken correctly] Name of variables Action to be taken (i) Manipulated variable: (i) The way to manipulate Type of group 1 metals variable: used Use lithium, sodium and potassium metal for each experiment. (ii) Responding variable: Rate of reaction//Reactivity of the reaction (ii) What to observe in the responding variable: The movement of metal on the water surface. (iii) The way to maintain the fixed variable: Use the same quantity/size of metal.

1 0

SCORE 6

(iii) Fixed variable: Quantity/size of metal used.

[Able to state any five items correctly] [Able to state any four items correctly] [Able to state any three items correctly] [Able to state any two items correctly]

5 4 3 2

[Able to state any one item correctly] No response given / wrong response 2 (b) KK0512 Stating hypothesis EXPLANATION [Able to state the relationship between manipulated variable and responding variable correctly] Suggested answer: The metal which is below in Group 1 is more reactive in the reaction with water//The lower the metal in Group 1 the more reactive is the reaction with water. [Able to state the relationship between manipulated variable and responding variable but in the opposite direction] Suggested answer:
The more reactive the reaction, the lower the position of the metal in Group 1

1 0

SCORE 3

[Able to state an idea of the hypothesis] Suggested answer: Metals in Group 1 can react with water No response given / wrong response 2(c) KK 0508 Interpreting Data EXPLANATION [Able to arrange the metals in descending order based on their reactivity] Suggested answer: K, Na, Li [Able to arrange the metals in ascending order based on their reactivity] Answer: Li, Na, K, [Able to arrange the position of at least two metals in descending/ascending] Suggested answer: Na, Li, K// Li, K, Na// Na, K, Li No response given / wrong response

SCORE 3

2(d) KK0507- Making relationship EXPLANATION [Able to state the relationship accurately] Suggested answer: The lower the position of the metal in Group 1, the higher the reactivity of the metal. [Able to state the relationship correctly but less accurate] Suggested answer: The reactivity of the metals is inversely proportional to their position in the group. [Able to state an idea of a relationship] SCORE 3

Suggested answer: Position of metals affect the reactivity No response given / wrong response c2(e) KK 0508 Predicting EXPLANATION [Able to predict the reactivity of rubidium correctly] Suggested answer: The reaction of Rubidium is most reactive among lithium, sodium and potassium when react with water [Able to predict the arrangement of the metals based on their reactivity] Suggested answer: The reaction of Rubidium is most reactive. [Able to give an idea Suggested answer: Rubidium is a reactive metal No response given / wrong response 3.(a) KK051021 Statement of the problem EXPLANATION [Able to make a correct statement of problem] Suggested answer: Does the distance between two/ pair of metals in the electrochemical series give different voltage values? [Able to make a statement of the problem or suitable aim] Suggested answer: Does the distance between two /pair of metals give different voltage values?// Distance between two/pair of metals in the electrochemical series gives different voltage values. [Able to state an idea of statement of problem or aim] Metals influence the voltage values No response given / wrong response 3 (b) KK051202 Stating variables EXPLANATION [Able to state all the three variables correctly] Suggested answer: Manipulated variable : types of pairs of metals Responding variable: voltage values//potential difference Constant variable : electrolyte used such as copper(II) sulphate solution. [Able to state any two of the variables correctly] [Able to state one of the variables correctly or state idea regarding variable] No response given / wrong response

SCORE 3

SCORE 3

1 0

SCORE 3

2 1 0

3(c) KK051202 Stating hypothesis EXPLANATION [Able to state the relationship between manipulated variable and responding variable correctly] Suggested answer: The further the distance/position between two metals in the electrochemical series, the bigger the voltage value. [If the responding variable comes first, the score is 2] [Able to state the relationship between manipulated variable and responding variable] Suggested answer: The further the distance /position between two metals, the bigger the voltage value//vice versa [Able to state an idea of the hypothesis] Suggested answer: Metals influence the voltage value No response given / wrong response 3(d) KK051205 List of materials and apparatus EXPLANATION [Able to state the list of materialss and apparatus correctly and completely] Suggested answer: Beaker, connecting wires, crocodile clips, voltmeter, sand paper, [magnesium ribbon, zinc strip,lead strip, copper strip], [copper(II) sulphate solution] [Able to state the list of substances and apparatus correctly but not completely] Suggested answer: Beaker, connecting wires, voltmeter, [magnesium ribbon, zinc, copper],[copper(II) sulphate solution] [Able to state an idea about the list of substances and apparatus] Suggested answer: Beaker, metals, voltmeter, electrolyte, wire. No response given / wrong response 3(e) KK051204 Procedure EXPLANATION [Able to state a complete experimental procedure] Suggested answer: [30 -200] cm3 of copper(II) sulphate solution is poured into a beaker. Magnesium ribbon and copper strip are cleaned with the sand paper. Magnesium and copper are dipped into the copper(II) sulphate solution. Both metals are connected to a voltmeter. The voltmeter reading is recorded. The circuit is completed. Steps 1 to 6 are repeated by using different of metals to pair with copper. SCORE 3 SCORE 3 SCORE 3

1. 2. 3. 4. 5. 6. 7.

[Able to state the procedure which include the following steps] Answer: Steps 1,3,4,5,6 [Able to state an idea of procedure] Answer: Steps 3,5 No response given / wrong response 3(f) Tabulation of data EXPLANATION [Able to exhibit the tabulation of data correctly ] Pairs of metals Voltage/V Negative terminal

1 0

SCORE

3 [Able to exhibit the tabulation of data less accurately ] Pairs of metals Voltage 2

[Able state an idea about the tabulation of data] Metals Voltage

No response given / wrong response