Dengan Metode half-live, tentukan konstanta laju reaksi

dan orde reaksi dari data batch berikut.

t, min Ca, mol/L Half-live

0 1.0000 1.0000 0.5000
0.41 0.5000 0.5000 0.2500
1.03 0.2500 0.2500 0.1250
2 0.1250 0.1000 0.0500
2.40 0.1000 0.0144 0.0072
4 0.0500 0.0040 0.0020
9.42 0.0144
15 0.0072
20.7 0.0040
30 0.0020

CAo, mol/L CA.mol/L to,s t,s ln Cao t,1/2 ln t, 1/2

1.0000 0.5000 0 0.41 0 0.41 -0.8916
0.5000 0.2500 0.41 1.03 -0.6931 0.62 -0.4780
0.2500 0.1250 1.03 2 -1.3863 0.97 -0.0305
0.1000 0.0500 2.40 4 -2.3026 1.60 0.4700
0.0144 0.0072 9.42 15 -4.2405 5.58 1.7192
0.0040 0.0020 20.7 30 -5.5215 9.30 2.2300

1.2

0.8

0.6 Series1
Linear (Series1)
0.4

0.2

0
0 0.2 0.4 0.6 0.8 1 1.2

Slope -0.5779
Alpha 1.5779
orde 1.5779
(α-1) 0.5779
 𝟐𝜶−𝟏 −𝟏
ln (t1/2) - (1-𝜶) 𝐥𝐧 𝑪𝑨𝒐 = 𝐥𝐧 𝒌(𝜶−𝟏)

𝟐𝜶−𝟏 −𝟏
exp( ln t1/2 - (1-𝜶) 𝐥𝐧 𝑪𝑨𝒐 ) = 𝐥𝐧
𝒌(𝜶−𝟏)

𝟐𝜶−𝟏 −𝟏
k(𝜶 − 𝟏) = exp( ln t1/2 − (1−𝜶) 𝐥𝐧 𝑪 )
𝑨𝑶

(𝟐𝜶−𝟏 −𝟏)
k = exp( ln t1/2 − (1−𝜶) 𝐥𝐧 𝑪 ).(𝜶−𝟏)
𝑨𝑶

k
2.0793323
2.0524912
1.9582426
2.0159872
1.77156
2.2284061