SMK DATO BENTARA LUAR BATU PAHAT 2nd CURRICULUM EVALUATION 2009 CHEMISTRY FORM 5 Answer For Section

A Question 1 2 3 4 5 6 7 8 9 10 Answer D C A C B A B B D B Question 11 12 13 14 15 16 17 18 19 20 Answer A D A C D A D D B D Question 21 22 23 24 25 Answer D B B D B

Answer Section B 1. An experiment is carried out to prepare a salt crystal. Excess copper(II) oxide powder is added to 50 cm3 hydrochloric acid 1.0 mol dm-3 in a beaker. The mixture is heated. [Relatif atomic mass: Cu, 64; Cl, 35.5; O, 16; H,1] (a) Name the salt poduced from this reaction.

Copper(II) chloride CuO + 2HCl CuCl2 + H2O

[1 mark]

(b) Explain how can you know whether copper(II) oxide was added in excess or not?

When CuO is no longger dissolve / When CuO cant dissolve any longer
[1 mark] (c) Write a chemical equation for this reaction.

2HCl + CuO CuCl2 +

H2O
[1 mark]

(d) Calculate the number of mole of hydrochloric acid used in this reaction.

No. of mole HCl = Molarity Volume 1000 = MV 1000 = 1.0 50 1000 = 0.05 mol HCl
[1 mark]

(e)

Calculate the mass of salt produced in this reaction.

FBCE;

2HCl + CuO CuCl2 +

H2O

Given in the question To Find 2HCl = CuCl2 2 mol HCl = 1 mol CuCl2 0.05 mol HCl = 1 0.05 mol CuCl2 2 = 0.025 mol CuCl2 Thus; No of mole of CuCl2 =

0.025 mol

[To find mass of copper(II) chloride] No of mole of CuCl2 = . mass . Molar mass CuCl2 Mass CuCl2 = = EASYLAH! 0.025 [64 + 2 35.5] 3.375 g

Metal X carbonate

Heated Lime water

Diagram 1

2. An experiment is carried out to investigate action of heat to metal X carbonate which is shown in Diagram 1. After a few minutes, Y gas is produced and a yellow solid when its hot, and white when is cold residue Z is formed . (a) Name (i) Metal X carbonate : :

Zinc carbonate
[1 mark]

(ii) Residue Z

Zinc oxide
[1 mark]

(iii) Gas Y

Carbon dioxide
[1 mark]

(b) (i) Based from diagram 1, state the changes in to the lime water.

Turn chalky / cloudy / milky

[1 mark] (ii) What is the conclusion from b(i)

Carbon dioxide gas is released/produced

[1 mark]

(c) Write a chemicl equation for this reaction.

ZnCO3 ZnO + CO2.

[1 mark] (d) What is the observation when residue Z is added into the water.

Colourless solution ZnO + H2O Zn(OH)2

[1 mark] 3. Diagram shows a series of reactions carried out on the solid P.

Solid P

Add ammonium hydroxide solution Blue pricipitate Q Excess ammonium hydroxide solution Dark blue solution Colourless gas S

Heat

Black solid T

Brown gas R which turns damp blue litmus paper to red

2Cu(NO3)2 2CuO + 4NO2 + O2

(a) Identify solid P.

Copper(II) nitrate
[1 mark] (b) Give the formula of the blue precipitate Q.

Cu(OH)2
[1 mark] (c) Solid P is heated strongly and decomposed to form a black solid and a mixture of gases.
(i)

Identify gas R.

Nitrogen dioxide
[1 mark] (ii) Describe a test for identify gas S.

Place/insert/put a glowing wooden splinter into the test tube. // A gas lighted up/rekindles the splinter
[2 marks]

4. (a) Based on the chemicals listed below, contructs the equation in sequences to show how zinc sulphate is produced.

1. Zinc chloride

2. Sodium carbonate

3. Sulphuric acid

(b) Describe a laboratory experiment to prepare the salt.

Answer The salt that want to be prepared: Zinc sulphate What you must do? Identify type of salt Identify the process/methode Identify the chemicals

Identify the procedure (a) ZnSO4 can be prepared through 2 reaction Preparation of insoluble salt ZnCO3 Through precipitation reaction Fisrt equation; Chemical equation; i. ZnCl2 (aq) + Na2CO3 (aq) ZnCO3 (s) + 2NaCl (aq) Ionic equation : Zn2+ + CO2- ZnCO3 Preparation of soluble salt ZnSO4 Through reaction between acid and carbonate metal Second equation; ii. H2SO4 (aq) + ZnCO3 (s) ZnSO4 + CO2 + H2O (b) Laboratory experiment to prepare the ZnCO3 through precipitation reaction
Procedure 3 -3 1. 20 cm zinc chloride 0.1 mol dm solution is measured with measuring cylinder 50 ml, and poured into a beaker.

20 cm3 sodium carbonate 0.1 mol dm-3 solution is measured with measuring cylinder 50 ml and poured into a beaker contains zinc chloride solution. 3. The mixture is stirred with a glass rod.
2.

4. The mixture is filtered to obtain the residue.

The residue is rinsed with distilled water. 6. The yellow solid is dried by pressing between two pieces of filter paper. Step 1-2: 1m Step 3-4: 1m Step 5-6: 1m [max 3 marks]
5.

Laboratory experiment to prepare the ZnSO4 through reaction between acid and carbonate metal
50 cm3 sulphuric acid 0.1 mol dm-3 is put in a beaker and is heated. 2. Using spatula zinc carbonate powder is added a little at a time to the hot sulphuric acid while stirring continuously with glass rod. 3. The addition of zinc carbonate is stopped when solids powder remain undissolved. 4. The mixture is filtered to remove the excess copper(II) oxide. 5. The filtrate/zinc sulphate solutions is transferred to an evaporating dish. 6. The filtrate/zinc sulphate solutions is slowly heated/evaporated until its saturated, or to about one-third (1/3) of the original volume. 7. The saturated solution/zinc sulphate solutions is then allowed to cool to room temperature. 8. The crystals/zinc sulphate crystals are filtered and rinsed with a little cold distilled water. 9. Salt crystals/zinc sulphate crystals are then dried by pressing it between filter papers.
1.

Step 1-3: 1m Step 4-7: 1m

Step 8-9: 1m [max 3 marks]