AIEEE FRU

Test Assessment, Analysis & Solutions

Some students are of the opinion that for AIEEE, practice is everything. At PAGE we recognize that
practice is one of the most important constituents of a good study plan. However, it is not enough to
blindly attempt tests. After every test, one needs to spend time reviewing it. The following charts will
give you a place to start your test review First check the question paper with answer keys to find out
marks scored. Religiously note down the number of questions that you obtained correct, wrong or left
unanswered in various section types. Also make a subjective self-judgment ascertaining the cause of
your performance in the various sections.

Summary performance table.

Physics Chemistry Maths Total
Total number of questions
Questions Attempted
Correct Answers
Wrong Answers
Total Scored

Analysis of wrong questions:

Reasons for wrong questions
(To be filled after you have attempted wrong questions on your own after the test) No. Questions
A. Know the solution / answer for the question but failed
to get it right in the exam: Calculation mistake

B. Know the solution / answer for the question but failed

to get it right in the exam: Applied wrong concept

C. Do not know the concept and couldn’t solve even after exam

Total Number of questions attempted wrong

If score of A &B is high then you need more practice and read questions more carefully. If C is very high you need
to revisit the topic in the textbook.
If the number of easy, average question not attempted by you is high then you need to focus on selection of
questions. In AIEEE you should select questions you can solve fast and leave lengthy and difficult questions.

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PHYSICS Analysis

Sl.No. UNITNAME Q.Nos. Correct Wrong

1. UNITSANDMEASUREMENT 35 , 44

2. DESCRIPTION OF MOTION IN ONE DIMENSION 9 , 31

3. MOTION IN TWO AND THREE DIMENSIONS 11 , 16 , 46 , 51

4. LAWS OF MOTION 30 , 36 , 58

5. WORK,ENERGY&POWER 27 , 50 , 54 ,56

6. ROTATIONAL MOTION & M.I. 12 , 21 , 42 ,57

7. GRAVITATION ---

8. SOLIDSANDFLUIDS 22 , 52

9. OSCILLATIONS 13 , 23

10. WAVES 14 , 29 ,53

11. HEATANDTHERMODYNAMICS 8 , 24 , 38 ,

12. TRANSFERENCEOFHEAT 17 , 26 , 40

13. ELECTROSTATICS 19 , 37 ,47 ,55

14. CURRENT ELECTRICITY 7, 15 , 33 43

15. THERMAL & CHEMICAL EFFECTS OF CURRENTS 28 ,39 ,49

16. MAGNETIC EFFECTS OF CURRENTS 6 , 25

17. MAGNETOSTATICS 41 , 60

18. ELECTROMAGNETIC INDUCTION & ALT. CURRENTS 5 ,20, 32, 59

19. RAYOPTICS 4 , 18 ,

20. WAVEOPTICS 48

21. ELECTROMAGNETICWAVES ----

22. ELECTRONANDPHOTONS 3

23. ATOMS, MOLECULES & NUCLEI 2 , 34

24. SOLIDS&SEMI-CONDUCTORSDEVICES 1 , 45 ,
CHEMISTRY Analysis

Sl.No. UNITNAME Q.Nos. Correct Wrong

1. SOMEBASICCONCEPTS 1 , 36 , 46
2. STATES OF MATTER 27, 39
3. ATOMIC STRUCTURE 3
4. SOLUTIONS 4, 20, 32, 47
5. CHEMICALENERGETICS&THERMODYNAMICS 26, 55
6. CHEMICALEQUILIBRIUM 18, 37, 53
7. REDOXREACTIONS&ELECTROCHEMISTRY 7, 22, 56
8. RATESOFCHEMICALREACTIONS&CHEMICALKINETICS 8, 21, 57
9. SURFACECHEMISTRY 5
10. CHEMICALFAMILIES–PERIODICPROPERTIES 2, 43
11. CHEMICALBONDING&MOLECULARSTRUCTURE 25, 41
12. CHEMISTRY OF NON-METALS – I 19
13. CHEMISTRY OF NON-METALS – II 24, 38, 60
14. CHEMISTRY OF LIGHTER METALS 9
15. HEAVYMETALS 16, 35
16. CHEMISTRYOFREPRESENTATIVEELEMENTS 34, 49
17. TRANSITIONMETALSINCLUDINGLANTHANIDES 6
18. COORDINATIONCHEMISTRY&ORGANOMETALLICS 23, 40
19. NUCLEARCHEMISTRY 30, 48
20. PURIFICATION&CHARACTERISATIONOFORGANICCOMPOUNDS 15, 58
21. SOMEBASICPRINCIPLES 17, 50
22. HYDEROCARBONS 10, 44
23. ORGANICCOMPOUNDSCONTAININGHALOGENS 14
24. ORGANICCOMPOUNDSCONTAININGOXYGEN 11, 29, 51
25. ORGANICCOMPOUNDSCONTAININGNITROGEN 12, 33, 59
26. SYNTHETIC&NATURALPOLYMERS 31, 45
27. BIOMOLECULES&BIOLOGICALPROCESSES 13, 28
28. CHEMISTRYINACTION 52
29. ENVIRONMENTALCHEMISTRY 42
MATHEMATICS Analysis

Sl.No. UNITNAME Q.Nos. Correct Wrong

1. SETS,RELATIONSANDFUNCTIONS 42, 45

2. COMPLEXNUMBERS 1

3. MATRICESANDDETERMINANTS 7, 20, 21

4. QUADRATICEQUATIONS 8, 9, 13, 24, 58

5. PERMUTATIONSANDCOMBINATIONS 10, 28

6. MATHEMATICAL INDUCTION & ITS APPLICATIONS 12

7. BINOMIALTHEOREMANDITSAPPLICATIONS 6, 20, 21

8. SEQUENCESANDSERIES 27

9. DIFFERENTIALCALCULUS 5,25,33,34,43,56,59

10. INTEGRALCALCULUS 15, 30, 31, 37, 57

11. DIFFERENTIALEQUATIONS 14

12. TWODIMENSIONALGEOMETRY 2,3,4,22,26,40,51,54

13. THREEDIMENSIONALGEOMETRY 19, 41

14. VECTORALGEBRA 36, 46, 47, 60

15. MEASURESOFCENTRALTENDENCY&DISPERSION 23, 38, 41, 53

16. PROBABILITY 11

17. TRIGONOMETRY 16, 17, 44, 50

18. STATICS 48, 49

19. DYNAMICS 29, 35, 55

SOLUTIONS CODE : FRU

1.b. Impurities cause increase in the free electrons and holes. For A' → B' → C'
2.a.
v 22 − u 2 = 2a 2 (2), and
3.d. As hv = E R + W

∴ E R = hv − w or E K = (5.0 − 2.0) eV = 3.0 eV 0 2 − v 22 = 2a1 (2)

ie. K.E of most energitic electron will be 3.0eV Adding, we get
4.b. In going from rater to denser medium, light bends to
− u 2 = 2(2a1 + 2a 2 )
wards normal.
5.a. When loops approach each other the field becomes strong. Equating (1) and (2) and solving, we get
Which should not be allowed in accordance with Lenz’s 4a 1 + a 2 = 2a 1 + 2a 2
Law. So, the current in both should be in such a way that
field decreases and hence I decreases. ⇒ a 2 = 2a 1
6.c. No emf is incuced in the parallel horizontawires. Equal 10.b. The friction force between the block M and the

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emf of same polarity is induced in the two parallel horizontal surface decreases becuse the normal reaction
vertical wire. Hence there is not induced currentin the decreases.
loop.
7.c. When a metal is heated, the space between atoms The accelerting force becomes m (g − a o ) and the
increases due to expansion. This increases the itme to retarding force becomes µM(g − a o ) . Thus, the blocks
travel the distance between atoms. During that time the
accelerates withrespect to elevator only.
electrons suffer more collisions with other atoms, phonos
etc. This reduces the drift velocity and conductivity and When m(g − a o ) > µM(g − a o ) or m > µM .
thus increases resistivity.
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PV
The tension isthestringlies in between m(g − a o ) and
8.d. The umber of oles in bulb is given by n = µM(g − a o ) thus it decreases .
RT
Thus jarge the pressure greater the number of moles and u sinα
higher the temperature lesser the number of moles. 11.c. Tdescent = To =
g
P nR P
Since = Therefore large the value of greater
T V T u sinα 10  usinα 
T= =  
9  g 
the value of n. g
g-
9.b. Let a1 and a2 be the retardations offered to the bullet 10
by wood and iron respectively.
 10 
So, increase in time is  −1 T
a1 a2  9 

C 100
A B ⇒ % age increase = % = 11%
u v1 0 9
12.b. Restoring force = − Mg sin θ,
C' B' A'
v2 u x x
0 = − Mg
OG
= − Mg
5r − r

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Wood iron
4 cm 2 cm Mg g
That is Ma = − x or a = − x
4r 4r

For A → B → C 4r r
And T = 2 π = 4π
g g
v12 − u 2 = 2a1 (4), and

0 2 − v12 = 2a 2 (1)
Adding, we get
www.aieeepage.com 13.b. stress =
100N
10− 6 m 2
= 108 Nm − 2

− u 2 = 2(4a1 + a 2 ) 2 × 10-3
Strain = = 10-3
2

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 108 f 2 = x1 x2 or f = x 1 x2
Youg’s modulus = Nm − 2 = 1011 Nm − 2
10−3 19.b. Capacity of 1st row = 1 µf forequivalent capatiy of
1 2nd row.
Energy stored = × 100 × 2 × 10-3 J = 10-1 J = 0.1J
2 1 1 1 1
= + ∴ C1 = µf
14.c. Usig Doppler’s formul C1 1 1 2
v+u 1
f = fo   ...(1)
 v  eq. capacity of 3rd row C 2 = µf
4

v+u 1
and 0.8f = f o  v  ....(2) eq. capacity of 4th row C3 = µf
  8
Dividing (1) and (2), we get All the rows are connected in parallel across A and B
∴ The resultant capacity
1 v+u 1 - 08 u u 1
= or = ∴ =
0.8 v − u 1 + 0.8 v v 9 1 1 1 1
C = 1+ + + + + .......

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15.d. 2 4 8 16

1 1
16.c. s y = U yt + ay t2 This is a G.P.with common ratio and 1st term 1.
2 2

1 1
⇒ −70 = 50 sin 30 t − × (10) t 2 C= = 2µ f
2 i.e., 1
1−
2
50 sin30
50m/sec
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ωL=
1
20.a. Here
10° ωC
70m
1
Hence ω = = 500 rad/s
LC

⇒ −70 = 35 t − 5t 2 21.b. As 0 ω 2 − ω 02= 2 α θ

5t 2 − 25t − 70 = 0 ⇒ t 2 − 5t − 14 = 0  60 
2
00 −  2 π ×  = 2 × α × (2 π × 10)
 60 
t 2 − 7t + 2t - 14 = 0 ⇒ t = 7 sec

(220 − T ) (T − T ) − α = π /10 radian/sec2

17.a. Q = KA (2K)A 1 2
L L ω = ω0 + αt
1
= (1.5K) A (T2 −18) × 60 π 17 π
L = −2 π × − ×3 = rad/sec2
60 10 10
200 − T1 = 2 T1 − T2 = 1.5 T2 − 27 solving 22.b. Let V be volume of the load, and let its relativedensity
T1 = 116°C and T2 = 74°C be ρ then

18.d u = f + x1(f → focallength) FL Vρ gL

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Y= =
Ala Ala .........(i)
1 1 1
V = f + x2 ; ∴ + = When the load is immersed in liquid, the net weight =
V u f
weight - upthrust
1 1 1 f + x1 + f + x 2 1 FL (Vρ g - V × 1 × g)L
∴ + = ; = ∴Y = =
f + x 2 f + x1 f (f + x1 ) (f + x 2 ) f Alw Alw ......(ii)

2f + x1 + x2 1
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= ρ ρ −1
f 2 + x1f + x2f + x1x2 f Equating (1) and (2) , we get l = l
a w

2f 2 + fx1 + fx 2 = f 2 + x1f + x 2f + x1x 2

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 1a 90
which gives ρ = 1 − 1 left v′ = 90% = 220 × = 198V
a w 100
23.b. Collisions is inelastic, therefore Now the power of lam,

mv = ( M + m)V . V 2 (198)2
p '= = = 81W
R 484
m As voltage is dropped by littel amout so the value of
Hence V = v.
M +m resistance of lamp will fall by samll amount and will
Also Max PE = Max KE. become more than p ' = (81W) and shall be between
81W and 90W.
1 2 1
That is kA = ( M + m) V 2 . That is 29.b. When aeroplane is at P2 vertically above the observer
2 2
O, sound comes along P1O at 60° with the vertical.
1
M + m2 ∴ p1O = v × t, P1P2 = v p t
A=  V
 k 

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P1 (v p )t P2
1
M + m2  mv 
=  M + m
 k    Vt
60°
O
mv
= vp t vp
( M + m) k p1 p 2
sin60° = = =
v× t
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p1O v
24.b. 373 - 273
η= = 0.268 = 26.8% ∴ v p = vsin60° = v 3/2
373
25.a. The dipole is in stable equilibrium, when the torqueon it 2M 1 M 2
30.d. T= (g − F )
is zero. Since t = PE sin θ M1 + M 2
The angle θ = 0°
M1 M 2
dQ dθ =2 [ g − (− g )]
26.c. Therate of colling of a body is = ms M1 + M 2
dt dt
Shallow = Ssolid ; A hallow = Asolid M1 M 2 4W1 W2
=4 g=
M1 + M 2 W1 + W2
m hallow < msolid
31.b. Let x be increase in length of the spring. The particles
 dQ   dQ  would move ina circular path of radius. (l+x).
but  dt  =  Centripital force = force due to the spirng.
 hallow  dt solid
m ω2 l
 dθ   dθ  m (l + x) ω2 = kx;∴ x =
⇒  >  k − m ω2
  hallow  dt solid
dt
32.a. 1 1
ωL = or ω=
27.c. As area of cross section (a) is fixed, velocity (v) has to be ωC LC
raised n times to make rate of water flow n times.
1
ωL =

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d
Now P = F ∝ v = (m.v.) × v 0.5 × 8 × 10-6
dt
d 1000
= (A v P × v ) × V i.e., p ∝ v3 = = 500
dt 2

Hence P should become n 3 times. 1

33.a. Since R ∝ , therefore the resistances of the wires are
When velocitybecomes n times. A

28.c. Resistance of lamp, R =

(220) 2
100
= 484Ω www.aieeepage.com13 : 14 : 15 in the ratio
when voltage drops by 10% the voltage

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 V L
Also current I ∝ , therefore the currents in the wires
R ∴ Number of reflections =  l 
 0
are in the ratio 3 : 4 : 5.

µ 0 2 I1 I 2  
Force between the wires is F = 1.6 × 100cm 
4π x
=  = 14
 20 cm 
µ0 2 µ 2  
Hence (3 × 4) = 0 (4 × 5) 3
4π x1 4π x 2
If first reflection is considered, then
x1 3 × 4 3 n = 14 + 1 = 15
That is = =
x2 4 × 5 5 41.d. End on position corresponds to axial line and Broadside
on position corresponds to equatorial line. Therefore,
34.b.
B1/B 2 = 2.
35.d.
42.c. Choosing the compartment as the system, the passengers
3g are external to the compartment, and can apply horizontal

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36.b. For (a) 3g − T = 3a and T = 4a ∴ a =
7 forces on it. Thus, C1 may move. For the ‘compartment
g plus passengers’ system, there are no external horizontal
For (b) 4g − T = 4a T − 3g = 3a ∴ g = forces. Thus, C 2 will not move.
7
37.d. 43.b. The arrangeents shown in (b) is more close to the actual
38.b. work done in isothermal expansion values.
44.c. F = qv × B or F = qvB sin θ
V
= nRT In B
 VA



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F MLT −2
∴ [B] =   = −1
= [A −1MT − 2 ]
= (5)(8.314) (500) (In 2)  qv  MTLT
= 14407 J
20 × 10 −3
2
v 200×200 45.a. KT = 20 × 10 −3 eV;∴ T = eV
39.a. Resistance of 40 W bulb = = k
R 40
20 × 10 −3 eV
= ; = 232K
= 1000 Ω 8.62 × 10 −5 eV
46.b. Obviously, the particle reaches the origin i the time
200 × 200
Resistance of 60 W bulb = = 666.7 Ω interval from 2s to 4s. Let t o be the instant at which the
60
particle reaches the origin.
200 × 200 Then x t = x 0 + (area of v − t grph) t = t 0
Resistance of 100 W bulb = = 400 Ω
100
1
Hence choice (3) is correct. Since the bulbs are con- or x t = −15 + (2(10) + 10(t 0 - 2) t = t 0 = -25 + 10
nected in series, the current in each is the same. Hence 2
Choice (2) is incorrect. The toral resistance = 1000 + to when the particle reaches the origin, x t = O
666.7+400 = 2066.7 Ω . Therefore, the current in the
thus O = - 25 + 10 t 0 or t 0 = 2.5s
circuit is

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47.d. Since E = O at the centre of the sphere therefore, is
200 maximum at X = O.
I= = 0.097 A
2066.7 As we move away from the centre r ≤ R, the electricfield
Hence the choice (4) is also incorrect. Since the 40 W increases linearly, therefore, the negative slope of the
bulb has the highest resistance and the current in each potential curve must increase.
bulb is the same, the potential difference across the 40 48.c. To find the intensity due to intereforence of two waves
W bulb is the highest. Hence the correct choices are (1) whose intensitites are know, first ind the amplitude of
and (3)

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40.a. From the figure given in question. each wave (∝ intensity) . Then find the mplitude due
to superposition, uising the phase difference between
l0 20 thewaves. The square ofthis amplitude gives the intensity
tan30° = ∴ I 0 = d tan 30° =
d 3 due to intereference.
49.c. As the bulb and the heater have thesame power rating,

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 they must radiate the same power. The power radiated
depends on thesurface area and the temperature of the T22 2M + M
54.b. = =3
filament. The filament ofthe heater is much longer and T12 2M − M
thicker than that ofthe bulb, and hence has greater surface
area. It can therefore raidate the same power as the bulb, ∴ T2 = T1 3 = 3 3s
at a temperature lower than that of the bulb.
50.a. Since the ball is projectedat an angle θ with horizotal, 55.a. τ max = pE sin θ and τ
therefore, its velocity has two coponents -a horizontal ∴ τ max = pE and P = (q) (2l) = (1×10−6 ) (0.02)
coponent u cos θ and a vertical component u sin θ .
The horizontal component u cos θ remains constant E = 10 5 N/C
during the flight, while the vertical component varies at τ max (1×10-6 × 0.02) ×105 ; = 2 ×10-3 N - m
the rate of g m/s 2 . 56.b To observer A, the work doen by spring force is equal to
At highest point, vertical components of velocity be the loss in kinetic energy of the block. The work done is
comes equal to zero. Therefore, at highest point the ball negative becaus sping forces and displacement are in
opposite direction
has horizontal component of velocity (u cost θ) alone.

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It implies tht at highest point kinetic energy of the ball 1 1
Ws = k f − Ki = o − mv02 = − mv02
doesnot becomes equal to zero, the kinetic energy varies 2 2
linearly with height ascended, h.
Therefore, (a) is correct.
57.d. When the sphere rolls down the plane, its acceleration is
u sinα
51.c. Tdescent = To =
g g sin θ
a= 2

www.aieeepage.com given by K
u sinα 10  usinα  1+
2
T= =  
9  g 
R
g
g-
10 Where K is the radius of gyration of the sphere about its
diameter. Now, the moment of inertia of the spehere
 10  about its diameter is
So, increase in time is  −1 T
 9  2 2
I = MR
100 5
⇒ % age increase = % = 11%
9 I 2 2
2
52.a. Rolling condition, the pont of contract should be ∴ K = = R
M 5
stationary i.e. v = ωR
Conserving angular momentum about the point of g sin θ 5
contact Therefore, a= = g sin θ
2 R2 7
Li = Lf mvo R = mvR + mR 2ω = 2mRv 1+
5 R2

vo For rolling without sliding, the frictional force f pro-

or v = vides the necessary torque τ which is given by
2
Applying the question of kinematics v-u=at τ = force × moment arm = fR
v vo But τ = Iα , where α is the angular acceleration of the
∴ o − v o = ( −µg)t or t =

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2 2µ g sphere. Thus, Iα = fR . Also, linear acceleration a

1 T a = α R. Therefore.
1
53.c. v∝ v∝
D1 π d or Iα Ia 2  2
D 2
f = = = Ma ∵ I = MR 
v' D 0.090 30 R R2 5  3 
= = =
v D' 0.093 31 Now, force of friction = µ× normal reaction = µ Mg cos θ .

 v' 
 
 30 
 
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100
Now,  v − 1 × 100 =  31 − 1 × 100 == 31 = −3.2
µ Mg cos θ =
2
Thus or a=
5
µ g cos θ
5 2
Equating (1) and (ii) we have

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 When the magnet is brought near and parallel to it, the
5 5 2
g sin θ = µg cos θ or µ = tan θ time period reduces to 1 sec, i.e., time period decreases.
7 2 7 Hence the field is not (H+F). Hence
58.b. The system consists of three identical balls marked 1, 2 12
and 3. Let m be the mass of each ball. Before the colli-  1 
T =1= 2 π  
sion.  M(+ F) 
1
KE of the system = KE of 1 + KE of 2 + KE of 3 = 12
2 2 H + F 4  H+F
∴ = or | = 
1  H  1  H 
1
mυ 2 + 0 + 0 = mυ 2
2 F F
or, 4 = 1 + or | 3 =
Case(a): After the collision, H H
KE of the system = KE of 1+KE of 2+KE of 3 61.b. 0.0018 ml = 0.0018 g = 0.0001 mole of water
2 ∴ number of water molecules
1 υ 1 υ 1 = 6.023 x 1023 x 10-4 = 6.023 x 1019
= 0+ m   + m  = mυ 2
2 2 2 2 4

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62.d. Let bond energy of A 2 be x then bond energy of AB
case (b): KE of the sytem = KE of 1 + KE of 2 + KE
of 3 is also x and bond energy of B 2 is x/2.
Enthalpy of formation of AB is - 100 KJ/mole:
1 1
0+0+ mυ 2 = mυ 2 A 2 + B 2 → 2AB
2 2
Case (c) : KE of the system = KE of 1 +KE of 2 +KE 1 1
of 3 A 2 + B 2 → AB : ∆ = -100KJ
www.aieeepage.com 1x
2 2
2 2 2
1 υ 1 v 1 υ
= m  + m  + m  x
2 3 2 3 2 3 or − 100 =  + − x
 2 4
1
= mυ 2 2x + x − 4x
6 ∴ −100 = ∴ x = 400 KJ
4
Case(d) : KE of the system = 0 63.d. Rutherford used doubly charged helium particle ( α -
Now, in an elastic collision, the kinetic energy of the particle)
system remains unchanged. Hence choice (b) is the only 64.b. More than theoretical weight since impurity will not
possible result of the collsion. contribute.
59.b. Magnetic flux at the centre of soleniod 65.b. When temperature increases, the absorbed molecules get
B1 = µ 0 (N1 /L)i1 energy and desorption starts increasing, therefore
absorption decreases with increase in temperature.
Magnetic flux through each turn of the coil of area A
µ 0 N1i1
φ1 = B1A = ×A
L 66.a. Mn (II) [ Ar ] 3d 5
Magnetic flux, linked witht he coil of turns N 2
CN − being strong ligand cause pairing of unpaired elec-
µ 0 N1i1A trons so only one unpaired electron is present
φ 2 = φ1 × N 2 =
L

PAGE
According to thedefinition of mutual inductance
0 RT [Fe 2 + ]2
φ 2 = Mi1 67.c. Nernst equation E Cell = E cell −
nF [Fe 3+ ]2
µ 0 N1 N 2 i1 µ NN iA
∴ Mi1 = A or M = 0 1 2 1 increassing [Fe 2+ ] well decrease the E Cell
L L
68.b. Since the nature of reaciton (i.e. exothermic or
 1  endothermic) not given therefore Ea for reverse reaction
60.a. We know that T = 2π   can be more or less.
 MB H
12
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
BaCO + 2CH COOH → 69.c. 3 3

 1  Ba(CH 3COO) 2 + CO 2 + H 2 O
Here T = 2 = 2 π Where | B H = H
 MH 
  Ba(CH 3COO) 2 + K 2 CrO 4 →

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 BaCrO 4 + 2KOOCCH 3
Yellow ppt CH 3 CH 3
| |
BaCO 3 + H 2SO 4 → BaSO 4 + CO 2 + H 2 O CH 3 − C − −C − CH 2 − Cl
White ppt | |
CH 3 CH 3
Liq. NH
70.b. CH 3CH 2 CHCl 2 + 2NaNH 3  7 → 1 − chloro 2, 2, 3,
196 K
3 − tetramethyl
CH 3C ≡ CH + 2NaCl + 2NH 3 bu tan e
71.b. Alkaline hydrolysis of polyvinyl acetate 75.a % of C = 40%
% of H = 6.67%
72.c. NH 2 NH 2
Br Br % of O = 100 - ( 40+ 6.67 )
3 Br2 /H 2 O NaNO2 = 100 - 46.67
-3 HBr = 53.33.
HCl
Element Percentage Atomic Relative simple

PAGE
Br of amount weight number of ratio
atom
N 2Cl N 2 BF4 40 3.33
Br Br Br Carbon 40 12 = 3.33 =1
Br
HBF4
12 3.33

-HCl 6.67 6.67

Hydrogen 6.67 1 = 6.67 =2
Br Br 1 3.33

Br
F
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Br
Oxygen 53.3 16
53.33
14
= 3.33
3.33
3.33
=1

∆
− N 2, − BF3 The ratio of C, H and O in the molecule in 1 : 2 : 1 and
hence the empirical formula of compound is CH2O.
Br
76.a. [Cu(NH3)4]2+ reacts with HNO3 in excess of water to
2, 4, 6 - tribromofluorobenzene
give cupric nitrate, [Cu(NO3)2]
H O
73.a. Methnal (formaldehyde). [ Cu( NH3 ) 4 ]Cl 2 + HNO3 
2
→[Cu (NO3 ) 2 ]
74.a. Cupric nitrate
CH 3
| 77.d. Such question can be solved by considering the relative
2CH 3 − C − −Cl + 2 Na diethyl
 ether
→ basic character of their conjugated bases which for
| − 2 Nacl H 2 O, C 2 H 2 , H 2 CO 3 and C 6 H 5 OH are
CH 3
-
OH, HC ≡ C − :, HCO3− , C 6 H 5O − More the
CH 3 CH 3 possibility for the dispersal of the negative charge,
| | weaker will be the base. Thus the relative basic character
CH 3 − C − −C − CH 3 of the four bases is
| |
CH 3 CH 3 HCO3− < C 6 H 5 O − < − OH < HC ≡ C −
Eqivalent Non - equivalent Oxygen can accommodate
resonating structures -charge easily

PAGE
CH 3 CH 3
| | Due to resonance
hv
CH 3 − C − −C − CH 3 + Cl 2 →
| | − HCl Thus the acidic character of the four corresponding acids
CH 3 CH 3 will be
H 2 CO 3 > C 6 H 5 OH > H 2 O > HC ≡ CH

78.c. A+B C+D

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At eqm.
0.9 0.9
0.3 0.3
0 0
0.6 0.6

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 0.6 × 0.6 2.0 M × 32 × 150
Kc = =4 =
0.3 × 0.3 1000
79.c. Glas contains silica. It dissoves in HF forming
9600
H 2 [SiF6 ] (hydrofluorosilicic acid) = = 9.6 gm
1000
80.b. ∆p ∆p X 2 10 0.5 −α 224
−β 238
= X2; = ; = 90.b. 238
92 X → 90 Y → 91 Z
p0 ∆p' X 2 20 X 2
Atom Z has 91 protons hence the number of neutrons
∴ X 2 = 0.4, X1 = 1 − 0.4 = 0.6 in its nuclei is :
81.c. A → B Atomic mass - atomic number
t=0 0.8 0 = 234 - 91 = 143
t = 1| 0.8-0.6 0.06 91.d.
t=0 0.9 0|
t=? 0.9 -0.675 0.675 92.d. ∆Tf = K f × w × i Vant Hoff factor i = 5 for

2.303 Al 2 (SO 4 ) 3 hence lowest freezing point.

PAGE
1sr order t =
K
NH 2 N = NCI
2.303 0.8 2.303
I= log K= log4
K 0.2 1 93.b. + NaNO 2 + 2HCI → +
K = 2.303 × 0.6020
2.303 0.9 2.303 × 0.124 NaCI
t= log = = 0.2 hr
2.303 × 0.6020

a 0.8
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0.675 2.303 × 0.602
S O ,S − S 94.d. In 2 7
2−
bond is absent.

In first case = =4
a - x 0.2 O O
O O -
S2 O 52- O -S -S - O
-

a
=
0.9
=4 S2 O 24− ;
In second case O -S -S - O
-
O
a - x 0.225
Since the ratio is the same, hece time will be same
Therefore 0.2 hr
WA WB 27 Wca O O O
82.d. = ; = ;∴ Wca = 7.95g
EA E E 108 31.8 S2 O 32- O- -S - O- ; S2 O 72- O- -S - O -S O-
83.c. Since the complex with AgNo 3 solution given two S O O
moles of AgCl it must have two ionisable Cl atoms. 95.b. 21.6 carat gold contains 21.6 parts of gold in 24 parts by
Hence the complex is [Co(NH 3 ) 5 NO 2 ] 2 Cl 2 . On weight of alloy % age gold in 21.6 carat gold =
ionisation it will give three moles of ion viz. 21.6
× 100 = 90%
[Co(NH3 )NO 2 ]2 + 2Cl− 24
84.b. 96.c. OH
85.b. Equivalent structures make the resonance very impor-
tant is a false statement.

PAGE
-H O
86.b. Adding the given two reactions gives the required 
2
→
reaction.
87.c d = PM/RT or d1/d 2 = T2 /T1 or d/0.75 d = T2 /300 100 mg 82g

300 × 4 Since yield is 75%. Therefore wt. of cyclohexene

Thus T2 = = 400 K
3
75
88.b. produced = 82 × = 61.5
100
89.a. W = NEV/1000
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Solubility = Solubility product = 4.9 × 10 −5

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 = 7 × 10 −3 106.d.
X
98.a. SO 2 and H 2S both being reducing agents, can turn Nal + NaCl → Na 2SO4

acidified dichromate solution green. SO 2 can be 1g 1g

obtained by the action of acid upon sulphite while H 2S is X 1 − x 2 ×1

+ = X = 28.28%
evolved by the action of acid upon sulphide. However, 150 58.5 142
SO 2 has a burning sulphur smell which is irritating. 107.a.
6.3 1000
× × 10 = 0/x ⇒ x = 40
H 2S has rotten egg like smell. 6.3 250
99.b.
3RT U T1 1200 1
U= ⇒ 1 = = = 2; 108.b. n = 40
M U2 T2 300 24

1 −
∴ U2 = U1 109.b. Pb +2 stable and ionic due to inert pair effect and Br
2

PAGE
and I − are good readucing agent to large size and low
100.b. Ni in [ Ni(CN)4 ]2- is dsp 2 hybridized and the comlex EM.
is square planar and diamegnetic. 110.c. 2,4,6, - tribroophenol

101.d. H H H 111.d. CH3OH + HOCH3 

ConH2SO4
→CH3 − O − CH3
−H2O

112.b. It is aspirin and used as analgesic.

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H C C C H
113.d. The pH of H 2S is calculated by considering the first
step of dissociation of H 2S
C≡N C≡N C≡N
σ − bonds = 13, π − bonds = 6 [H + ] [HS− ] [H + ]2
K1 = = {∵ [H + ] [HS− ]}
[H 2S] [H 2S]

102.b. CO 2 is necessary for photosynthesisbutits excess [H +2 ]

10 −7 = ⇒ [H + ]2 = 10 −8 ; ⇒ pH = 4
causes global warining. 0.1
103.d. A sudden jump between thevalues ofsecond and third 114.b DE = E1 - E3
ionoisation energies of an element shows that element is
alkaline earth metsl. This jump occurs when valence shell 2.179 × 10 −11
= 2.179 × 10 −11 −
charges during removal of electron. 9
104.c. NBS brings aboutallylic bromination, i.e.,
8
= × 2.179 × 10 −11
CH 3 CH 2Br 9
= 1.91 x 10-11 = 0.191 x 10-11 erg.
NBS
→ Since electr4on is going from n = 1 to n = 3, hence energy
is absorbed.
Phenylbeomo
Toluens
methane 115.c. ∆H° = ∑ ∆H° f ( product ) − ∑ ∆H° f ( reac tan t )
∴ from the given data :

PAGE
105.b. The monomer unit ofsilicones is R 2SiO as shown
− Y = 2 × ∆H° f (CO 2 )
below:
R R −[ 2 × ∆H° f (CO) + ∆H° f (CO 2 )]

−o − Si − o − Si − or − Y = 2( − X ) − 2 × ∆H ° f (CO 2 ),

[∵ ∆H ° f (O 2 ) = 0 ]
R
www.aieeepage.com2 × ∆H°
R
or f (CO 2 ) = Y − 2K

Y − 2X
or ∆H° f (CO 2 ) =
2

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116.c. Cu 2 + + e − → Cu + ; E10 = 0.15V ....(i) a + ex1 and a − ex1
Sum = a + fx1 + a − ex1
Cu 2 + + 2e − → Cu; E10 = 0.34V .... (ii)
= 2a = 8
Multiplying eq. (i) by (ii) we get 125.d. Since a strictly monotone and continuous functions is
always one-one and hence has inverse.
2Cu 2+ + 2e − → 2Cu + ; E 30 = 0.30V ...(iii)
126.c. From Pascal’s triangle it can be easily observed that
Substracting eq. (ii) from eq. (iii) 7
C1, 7 C2 , 7C3 = 7, 21,35 are in A.P. ∴n = 7
2+ −
2Cu + 2e → 2Cu
127.a. x + ω 2 1 ω
2+ −
− Cu + 2e → Cu ω ω 2
1+ x = 0 ....(i)
2+ + 1 x + ω ω2
Cu → 2Cu − Cu

since, x = 0 is satisfying (i), therefore, x = 0
2Cu + →
or
Cu + Cu 2 +
2
128.b. 7 log 7 ( x − 4 x + 5)
= x −1
∴ E° = 2( E 02 − E10 )

PAGE
⇒ x − 4 x + 5 = x −1 ⇒ x 2 − 5x + 6 = 0
2
= 2 ( 0.34 - 0.15) = 0.38 V
⇒ ( x − 2) ( x − 3) = 0 ⇒ x = 2 or x = 3
117.b. 2N2O5 → 4NO2 + O2, this reaction is of first order and
the rate expression for this reaction is : 129.b. | (5 − x)a |2 <| 2a |2
dx ⇒ (5 − x)2 < 4
= K[ N 2 O 5 ]
dt
⇒−2<5− x < 2

or [N 2O5 ] =
dx 1
×
dt K
www.aieeepage.com 130.c.
⇒ x ⇒ 3<x< 7
The four digits 3, 3, 5, 5 can be arranged at four even

1.02 × 10 −4 4!
= =3 places in = 6 ways and the remaining digits viz.,
3.4 × 10 − 5 2!2!
2, 2, 8, 8, 8 can be arranged at the five odd places in
118.b. Recall definition of Perkin reaction.
119.c. 5!
= 10 wyas. Thus the number of possible
120.b. SnCl4 is colourless volatile liquid and SnCl2 is colourless 2! 3!
solid Sn conducts electricity and it belongs to 14 group. arrangements is (6) (10) = 60
 2i 
2
4i 2
−4 − 2 131.d. We have P (head on exactly 50 coins)
121.b.   = = = = 2i = P (head on exactly 51 coins)
1+ i  1 + i 2 + 2i 2i i
100
122.a. Out of given choices, only for the pair of straight lines ⇒ C50 × p 50 (1 − p) 50 =100C51 × p 51 (1 − p) 49

2 x 2 = y ( x + 2 y) 51
⇒ p=
101
i.e., 2 x 2 − 2 y 2 − xy = 0, we have
a + b = 2 + (-2) = 0 132.c. iz 3 + z 2 − z + i = 0 ⇒ i 2 z 3 + iz 2 − iz + i 2 = 0
So, these pair of straight lines intersect at right angle
123.c. Let the coordinates of P be (x, y) then ⇒ − z 3 + iz 2 − iz + i 2 = 0 (i 2 = −1)
∆POA = 2∆ POB
Either z = i ⇒| z |= 1 or

PAGE
x y 1 x y 1
z 2 = −i ⇒| z 2 |= 1 ⇒ | z |= 1
⇒ 0 0 1 =±0 0 1
0 4 1 6 0 1 Hence, |z| = 1, implies that z lies on unit circle.
133.a. Let α and â be the roots, then
⇒ 4 x = ±12 y ⇒ x = ±3 y ⇒ x + 3 y = 0 or
(α − β) 2 = (α + β) 2 − 4 ∝ β
x − 3y = 0 i.e., x 2 − 9 y 2 = 0

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124.d. Equation of ellipse can be written as 4b 2
c
2
2 2 ⇒ − 4d = 2
−4
x y a a
+ =1
(4) 2 (3) 2
⇒ ac = b 2 + a 2 d 2
The focal distances are

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134.c. Rewrite the given differential equation as follows:
56
dy 2x 1 ∴15th term of H.P. =
15
+ 2 y= 2 , which is a linear form
dx x − 1 x −1 137.b. We know OM = length of the ⊥ from (0, 0) on
The integrating factor I.F.
1
2x y = 2x + 1 =
∫ 2 dx n(x 2 −1) 5
= e x −1 =e = x2 −1
and OP = radius of the given circle = 2;
Thus multiplying given equation by (x 2 − 1), we
1 6
dy ∴ PQ = 2.PM = 2 OP 2 − OM 2 = 2 2 − =
get (x 2 − 1) + 2xy = 1 5 5
dx
138.c. Exhaustive number of cases = 6 3 = 216.
d
⇒ [y(x 2 − 1)] = 1 On integrating we get Favourable number of cases = Coeff. of x15in
dx

y(x 2 − 1) = x + c ( x1 + x 2 + x 3 + ... + x 6 )

PAGE
3
The first curve y = x 2 is the parabola with vertex 3 1 − x 
6
135.c.
=Coeff.. of x15in x   = Coeff. of x12 in
(0, 0) concavity upwards and the axis as y-axis.  1 − x 
The second curve y = 2|x| represents a pair of
straight (1 − x 6 ) 3 (1 − x) −3 = Coeff. of
lines y = -2x and y= 2x The required area is shown
as the shaded region in the figure below. The x12 in(1- 3x 6 + 3x12 − x18 )

(2 , 4) and ( - 2 , 4 ) . www.aieeepage.com
points of intersection A and B are respectively

= 1 + 3x + 6 x 2 + ..... +
( r + 1)( r + 2) r
1 .2

x + ....
By symmerty the required are  
= 94 - 84 = 10
Y
10 5
∴ Probability = =
y=

2x

A(2, 4)
216 108
-2

y=
x

sinA sinB 3/4 sinB 21

139.d. = ⇒ = ⇒ sinB = > 1,
x a b 5 7 20
O
Which is impossible. Thus no triangle is possible.

a×b
2
140.c. = Required unit vector = η̂
 x3   8 8 | a×b |
2 ∫02 (2x − x 2 )dx = 2 x 2 −  = 24 −  =
 3  0  3 3
i j k
136.d. 7th term of H.P. is 8. a×b = 1 −2 3
1 1 3 1 2
∴ 7th term of A.P. is and 8th term of A.P. is
8 7
= (−4 − 3)i − (2 − 9)j + (1 + 6)k = −7 î + 7ĵ + 7k̂
1 1
∴ = a+ 6d = a + 7d ⇒| a × b |= 7 3
8 7

PAGE
1 1
− = −d ∴ Unit cector η̂ = - 7 î + 7ĵ + 7k̂ = − i + j + k
8 7 7 3 3
141.b. Equation of a plane through the point (0, 4, 3) is
1 1
− = −d ⇒ d = a (x -0) + b (y - 4) + c (z - 3) = 0 ...(1)
56 56 It passes through (-2, -2, 1) and (1, 1, -1)
1 6 7−6 1 If a + 3b + c = 0 and a - 3b - 4c = 0
a= −
8 56
=
56
=
56 www.aieeepage.com
⇒
a b
= =
−9 5 −6
c
1 14 15
⇒ 15th term of A.P. = a + 14d = + = ∴ From (1), equation of plane is
56 56 56
−9( x − 0) + 5( y + 4) − 6( z − 3) = 0 or

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 It is satisfied by ( −1, − 5, − 3) 1
1−
142.b. i(a × i) = (i. i)a − (i. a)i = a − (i. a)i x 2n − 1 x 2n 1− 0
Lt = Lt = =1
n →∞ x 2n + 1 n →∞ 1 + 1 1+ 0
so i(a × i) + j × (a × j) + k × (a × k)
x 2n
= a - (i.a)i + a - (j.a)j + a - (k.a)k
x 2n − 1
= 3a − [(i. a)i + (j . a)j + (k . a)k] When | x |= 1, Lt =0
n →∞ x 2n + 1
= 3a − a = 2a
146.b. Let the two given circles be
143.a. The given equation is
6x 2 + 2hxy + 12y 2 + 22x + 31y + 20 = 0
S1 : x 2 + y 2 + 2g1x + 2f1 y + c1 = 0 ...(1)

The general equation of the second degree is S2 : x 2 + y 2 + 2g 2 x + 2f 2 y + c 2 = 0 ....(2)

2 2
ax + 2hxy + by + 2gx + 2fy + c = 0 Let the third circle be
Equating the coefficients of (1) and (2), we get a = 6,
S : x 2 + y 2 + 2gx + 2fy + c = 0
31

PAGE
h = h, b =12, g = 11, f = , c = 20
2 It intersects S1 and S 2 orthogonally, thus we have
The equation (1) will represent two straight lines if
2gg1 + 2ff1 = c + c1 ....(4)
abc + 2fgh - af 2 − bg 2 − ch 2 = 0
2gg 2 + 2ff 2 = c + c 2 ....(5)
31 312 Subtracting (4) & (5), we get
⇒ 6.12.20 + 2. .11.h − 6. − 12.112 − 20.h 2 = 0
2 4 2g (g1 − g 2 ) + 2f(f1 − f 2 ) = c1 − c 2 ....(6)

⇒ 1440 + 341h -
2883
2
− 1452 − 20.h 2 = 0 www.aieeepage.com
S S
Now, the equation of the common chord of the circles
and is S1 − S2 = 0
1 2
2
⇒ 40h − 682h + 2907 = 0 ⇒ 2(g1 − g 2 )x + 2(f1 − f 2 )y + c1 − c2 = 0
682 ± 465124 - 465120 682 ± 2 684 ⇒ 2(g1 − g 2 )x + 2(f1 − f 2 )y + 2g(g1 − g 2 ) + 2f(f1 − f 2 ) = 0
⇒h= = =
80 80 80 [from (6)]
680 171 17 2(x + g)(g 1 − g 2 ) + 2(y + f)(f1 − f 2 ) = 0
or = or
80 20 2 Clearly the centre of the circle S, i.e. (-g, -f) satisfies (7)
Thus the common chord passes through the centre of
q r the third circle.
144.c. We have α + β = − , αβ =
p p 147.b. The numbers between 100 and 500, divisible by 7 are
105, 112, 119,.........483, 490, which is an A.P. with
Now the given equation α( x - β) 2 + β(x − α) 2 = 0 common difference 7.
If such number be n, then
⇒ (α + β)x 2 − 4αβx + αβ(α + β) = 0
497 = x n = 105 + (n − 1) × 7 ⇒ n = 57
 q r r  q The numbers between 100 and 500, divisible by 21 are
⇒  −  x 2 − 4 x +  −  = 0
 p p p p 105, 126, 147,.....483, which is an A.P. with common
difference 21.
⇒ pqx 2 + 4prx + rq = 0 ------(i)
If such numbers be m, then

PAGE
Since α and β have opposite signs, therefore p and r 483 = x m = 105 + (m − 1) × 21 ⇒ m = 19
must have opposite sings. Hence, the required number = 57 - 19 = 38
⇒ pq and rq must have opposite signs ⇒ roots of 148.b. Given, n points, the numbr of triangles that cen be
equation (i) have opposite sings drawn by joining any three non-collinear points=
n m
x 2n − 1 −1 C 3 , out of this C 3 is to be subtracted as m points
145.c. When |x|<1, Lt = = −1 as x 2n → 0
2n
+1 1 are collinear and no triangle is possible within these m

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n →∞ x
point.
When |x|>1,
Hence required number of triangles = n C 3 − m C 3
149.d. Let the train meet after time t and let s be the
distance of the meeting point from A, then

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= 50t
1
AIEEE
+ .18.tat the
2
National
......(1)
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2

16
 1 P Q C R
and 100-s = 50t - .18.t 2
2 A B
1 1 1 1
Adding 100 = 100t
11
∴t =1 2 3
∴ s = 59 from (1) 4 5
100 km
A
C
B
X=
∑m X 1 1
=
2.1 + 3.2 + 15.3 + 5.4 73
=
∑m 2 + 3 + 15 + 5 25
150.c. Let φ( x) = {f(x) + f(-x)} {g(x) - g(-x)} 155.b. The length of the chord intercepted by the circle

φ( − x) = {f(-x) + f(x)} {g(-x) - g(x)} x 2 + y 2 = a 2 on the straight line y = mx + c is

= −{f ( x) + f(-x)}{g(x) - g(-x)} = -φ(x) a 2 (1 + m 2 ) − c 2

2
π 1+ m2

PAGE
∴ φ( x) is an odd function ∫ −2 π φ( x)dx = 0 Here a = 5 and y = mx + c passes through (2, 3), there-
2
fore 3 = 2m + c i.e. c = 3 - 2m

151.b. The probability of hitting the target 5th time at the a 2 (1 + m 2 ) − c 2

10th throw = P (the probability of hitting the target 4 By hypothesis, 2 =8
times in the first 9 throws) × (the probability of 1+ m2
hitting the target at the 10th throw),
25(1 + m 2 ) − (3 − 2m) 2
⇒2 =8

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4 5 10
 1   1   1  9!  1  63 1+ m2
=  9 C 4       = ×  = 9
  2   2   2  4!5!  2  2 (on putting he values if a and c)
152.c. Let h feet be the height of the house and t the total 12
1 2 ⇒ 5m 2 + 12m = 0 ⇒ m = 0, − 5
time. Then h = gt ....(1)
2 39
⇒ c = 3 or (using c = 3 - 2 m)
2 5
1 2 1  1
and 20 = gt − g  t −  ....(2)
2 2  4 1 1+ x2 + x
156.d [ 1 + x 2 − x]−1 = =
1 1 1+ x2 − x ( 1+ x 2 )2 − x 2
From (2) 20 = gt − g = 8t - 1[∵ g = 32]
4 32
= 1+ x2 + x
21
∴t = Then (1) gives ∴ Coefficient of x = 1
8
2 1− x
1  21  441 157.d. Putting = y2
h= .32.  = ft = 110.25 ft 1+ x
2  8  4
153.c LetP.V of B be r . Therefore P.V of point dividing Ab 1− y2 −4y
in the ratio 2 : 3 is a We get x = and dx = dy
1+ y 2
(1 + y 2 ) 2

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2 r + 3(a + 2b) 2 r − 3(a + 2b)
∴a = or ∴ a = y(1 + y 2 )y
2+3 2−3 ∴1 = −4 dy
∴ r = a − 3b, which is given in ( c ) or
(1 + y ) (1 − y )
2 2 2

r = a + 3b, which is not given . y 2 dy  1 1 

Hence correct answer is (c)
= −4 ∫ (1 + y )(1 − y )
2 2
= −2  ∫ 2
+ 2
 1− y 1+ y 
dy

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154.c
1− y −1
= log + 2tan y+c
1+ y

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 1+ x − 1− x 1− x y = ex
= log + 2tan −1 +c Y
1+ x + 1− x 1+ x y x

1− x
∴ f(x) = tan −1
1+ x O

158.b. Let the number of boys be n 1 and that of girls be

We see that these graph do not intersect at any point
n 2 then i.e. there is not any common point on two curve . Thus
A∩B = φ
80n1 + 50n 2 166.c. a 2 + b2 + c 2 + 2
60 = ⇒ 60n 1 + 60n 2 = 80n 1 + 50n 2
n1 + n 2 (a . b + b . c + c . a) = 1+ 16 + 64 + 0 = 8

⇒ 10n 2 = 20n 1 ⇒ n 1 : n 2 :: 1 : 2 [∴ a(b + c) + b.(c + a) + c.(a + b) = 0]

∴| a + b + c |= 9

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x2 y2
159.c. Y = mx +c touches − =1 167.d. Let P(x1, y1), Q(x2 , y 2 ) be two points on the curve
a2 b2
1
If c2 = a 2m 2 − b2 y=x+
x
Here m = 4, a 2 = 1, b2 = 1 Let j be a unit vector along y - axis
Then OP = x1 i + y1 j, OQ = x 2i + y2 j
∴ C 2 = 16 − 1 = 15 ⇒ c = ± 15
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160.b. General equation of plane parallel z - x plane is
by + d = 0. If it passes through (0, 2, 0) equation
Since OP . i = 1 and OQ . i = -1
∴ x1 = 1 and x 2 = −1 ⇒ y1 = 2 and
becomes y = 2
y2 = −2
161.c.
∴ OP = i + 2j ; OQ = -i - 2j
1 x
162.c. f(x) = , f(f(x)) = and f(f(f(x))) = x ∴ 2 OP + 3 OQ = 2i + 4j - 3i - 6j = -i - 2j
1− x x −1
Hence |2 OP + 3OQ| = 1+ 4 = 5
163.b. f' (x) = 4(x 2 − 1)So, for 0 ≤ x ≤ 1, we get
168.a. Rcos θ = 2P cos0 + 3P cos120° + P cos 240°
f' (x) < 0, i.e., f(x) is m.d. and for 1 < x ≤ 2
3P P
we get f' (x) > 0, i.e., f(x) is m. i = 2P − − =0
2 2
4 8 R sin θ = 2P sin0 + 3P sin 120° + P sin 240°
∴ minf(x) = f(1) = −4 = −
3 3
3 3 2P 3
164. c. Let a =11, b =13 and = 3P. − P. = = 3P
2 2 2
c= 290 + 143 3 = 112 + 132 + 11.13 3

⇒ c > a, c > b and a + b > c, so that a triangle with a, π

R = 3 P and θ =
b, c as sides exists, the greatest angle is C opposite to 2
the greatest side C. 169.d. R = mg cos θ : F cos θ = mg sin θ
a 2 + b 2 − c 2 112 + 132 − 132 − 11.13 3 − 112

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∴ cosC =
2ab
=
2(11)(13) ∴ F = mg tanθ

3 5π 5π 170.a. Let x = sin(2 tan −1 2) = sin 2θ where tan θ = 2

=− = cos ⇒C=
2 6 6
2tanθ 2(2) 4 4
sin 2θ = = = ∴x =
165.c. y = e x represents to the exponetial curve and y = x 2
1 + tan θ 1+ 4 5 5
represents the straight line. Their graphs are shown in
1 4 φ 4
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below figure . y = sin  tan −1  = sin where tan φ =
2 3 2 3

3 φ 3
∴ cos φ = ∴1 − 2 sin 2 =
5 2 5

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 φ 2 φ 1 φ 1 ∴ (c) is not continuous on (0, π) . Similarly (d) is not
⇒ 2sin 2 = ⇒ sin 2 = ⇒ sin = ±
2 5 2 5 2 5 π
continuous at x = and hence on (0, π)
2
1
∴y = ± ∴ x > y and y 2 = 1 − x 1 dx
5 177. a Let I=∫ dx = ∫
x
1 + sinx 2tan
171.c. 1+ 2
3 4 2 3 4 2 x
1 + tan 2
2
5 8 2= 2 4 0
x y 2 x−5 y −8 0  2 x x
1 + tan dx sec 2
 2 2
= 2 (2y - 16 - 4x + 20) = 2 (2y - 4x + 4) ∫ = ∫
x x x x
1 + tan 2 + 2 tan 1 + tan 2 + 2 tan
∴ given determinant = 0 2 2 2 2
⇒ 2y - 4x + 4 = 0 ⇒ 2x - y - 2 = 0
x 1 x x
which represents st. line. Substitute tan = t ⇒ sec 2 dx = dt ⇒ sec 2 dx = 2dt.
2 2 2 2
172.d. For X = 0, the given determinant is a skew - symmetric

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2dt dt −1 −2
determinant of odd order Then I=∫ = 2∫ =2 +c = +c
1 + t 2 + 2t (1 + t) 2 (1 + t) x
1 + tan
∴ its value = 0 2

1.12 + 2.22 + .... + n.n 2 x

−1 tan
173.b. Weighted mean = 2 2 2 2 2
1 + 2 + ... + n = 1− + (c − 1) = + b,
x x Where b = c - 1, a new
1 + tan tan + 1
2 2
n 2 (n + 1)2 constant
3
Σn 3n(n + 1)
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= 2 = 4 =
n(n + 1) (2n + 1) 2(2n + 1) x
Σn 1 − tan
=− 2 + b = − tan( π − x ) + b = tan x − π  + b.
6 x 4 2
1 + tan 2 4
174.b. With y the mutually perpendicular lines as axes, we get 2

| x | + | y |= 1 . So, the locus consists of four lines, each π

enclosing the Clearly a = − and b ∈ R
4
1 ALTERNATE:
same area .3.3 with the axes.
2 1 1
I=∫ dx = ∫ dx
1 + sinx π 
1 + cos − x 
 2u sinα  2 
175.b. Time of flight =  sec

 g 
dx 1 π x π x x π
=∫ = ∫ sec 2  − dx = − tan −  + b = tan −  + b
2 × 49 sin60° π x 2 4 2 4 2  2 4
= sec 2cos 2  − 
4 2
9.8
1 178.a. Given equation is x + 1 − x − 1 = 4x − 1
176.b. Since t sin is continuous on (0, π) squaring
t
x 1 ( x + 1) + ( x − 1) − 2 x 2 − 1 = 4 x − 1
∴ F ( x) =
∫0
t sin dt is continuous on (0, π) Since
t
⇒ 1 − 2 x = 2 x 2 − 1, Again squaring
π

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tan x is not defined at x = , therefore tan x is
2 1 + 4x2 − 4 x = 4x2 − 4
π 5
discontinuous at x = ⇒ 4x = 5 ⇒ x =
2 4
For (c), lim f ( x ) = 1 which does not satisfy the given equation.
Hence no solution is possible.
3π x π 179.d. Let f(x) = sin (| x |) - | x |
x→ and lim f(x) = lim 2 sin = 2 sin = 2
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4 3 4
f ( 0 − h ) − f ( 0) sin h − h − 0
Lf ' (0) = lim = lim ,h > 0
3π +
3π + h→0 −h h→0 −h
x→ x→
4 4

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 sin h
= − lim + 1 = −1 + 1 = 0
h →0 h
f ( 0 + h ) − f ( 0) sin h − h
Rf ' (0) = lim = lim = 1−1 = 0
h→ 0 h h →0 h
So, (d) is the answer
180.b. Displacement vector d = QP = 2iˆ − 2 ˆj + 10kˆ

Force vector F = 3iˆ + 2 ˆj + 5 ˆj + 2iˆ + ˆj − 3kˆ

= 5iˆ + 3 ˆj + 2kˆ

∴W .D = F .d = (5iˆ + 3 ˆj + 2kˆ).(2iˆ − 2 ˆj + 10kˆ)

= 10 - 6 + 20 = 24

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