CHEMISTRY points are A pair of compounds having the same boiling (A) cis but-2-ene and trans but-2-ene (B) n-hexane and neo-hexane (C) benzene and naphthalene (D) (+) butan~2~ol and (-) butan -2-ol Identify A, B and C in the sequence : cca 5S i panes c (A) CH,CH,CN, CH,CH,CH,NH, CH,CH,CH,0H (B) CH,CH,NC, CH,CH,OH, CH,CH,CH,NH, (©) CH,CH,CN, CjH,OH, C,H,N,CI (D) CH,CH,CN, CH,CH,NH,, C;H,0H Pcc CH, - CH = CH -CH,OH > CH, - CH= CH- CHO Hybridisation change involved at C-1 in the above reaction _ (A) sp? to sp (B) sp to sp? © sos (D) sp to sp diamine is progressively added in the molar ratio If a didentate ligand ethane -1, 2 ~ in the mold lowing co-ordination entities are en: Nis: 1: 1,22 1,31 to [Ni(H,0)¢)* aq solution, foll formed. 2 L [Ni(H,0),en)”*(4) —pale blue TL, [Ni(H,0),(en),F*(qq)— blue/purple Mi. [Ni (en) 3} "(aq — Violet ‘The wavelength in nm of light absorbed in case of I and III are respectively (A) 475 nm and 310. nm (B) 300 nm and 475 nm (C) 310 nm and 500 nm (D) 600 nm and 535 nm Which of the following is an organometallic compound ? : (A) CH,COONa —(B) CH,CH,MgBr_ (C) (CH,COO),Ca__(D) CH,ONa Space For Rough Work (20821K23) od @ scanned with OKEN Scanner7 a is: Dee reagent oni primary aeons siete KMnO, (A) PCC (©) Acidified K,Cr,0,, (D) C105 In the reaction : Gi) SnCl+ HCI | con.KOB COSCON Tg? XY Zz, Formation of X, formation of ¥ and Z.are known by (A) Rosenmund reduction, Cannizaro reaction. (B) Clemmensen reduction, Sandmeyer reaction. (C) Wolff-Kishner reduction, Wurtz reaction. (D) Stephen reaction, Cannizaro reaction. Compounds P and R in the following reaction arc (i) CH; MgBr. |, _cone.HySOq CHSCHO THO" heat? 2 @B Hg (i)H,0,087 (A) Position isomers (B) Functional isomers (C) Metamers (D) Identical R Aniline does not undergo (B) Sulphonation (A) Nitration (©) Friedel-Craft reaction (D) Bromination The heating of phenyl methyl ether with HI produces an aromatic compound A which on treatment with con, HNO, gives B. A and B respectively are, (A) Methanol, Ethanoic acid (B) Picric acid, Phenol (C) Iodobenzene, 1-Iodo-4-nitrobenzene (D) Phenol, Picric acid OH NaOH (i) CO) _ (i)(CH3CO),0 ) CO3 5, GXCHCO)s Y (Major product) Gon Gor Y in the above reaction is (A) Salicylaldehyde (B) Aspirin _ (©) Cumene (D) Pictic acid Space For Rough Work 6 (2C0521K23) @ scanned with OKEN Scanner15. Sucrose is dextrorotatory but after hydrolysis the mixture show Nneworottony thin because of (A) Laevorotation of glucose is more than dextrorotation of fructose: (B) Sucrose is a non-reducing sugar, (C) Recemic mixture is formed, (D) Laevorotation of fructose is more than dextrorotation of glucose: The correct order of match between column X and column ¥ is: x Y 1. Vitamin A i. Muscular weakness Tl. VitaminD i, Increased blood clotting time Mi. Vitamin E Night-blindriess IV. Vitamin iv, Osteomalacia (A) I=iv, I~ iii, I -ii, IV-i (B) I~ ii, Mi, iii, (© I-iii, Wii, IN -iv, IV-i (D) Iii, M-iv, M-i, IV-ii In the reaction : oo Aa . on ows oon" (oy P, Qand R respectively are : (A) NaNO, + dil. HCI, HBF,, Cu + NaNO, (B) NaNO, + con.HCl, Fy, Cu+NaNO, (C) NaNO, + dil, HCl, BF,, Cu+NaNO, (D) NaNO, + dil. HCl, F,, Cut NaNO, ‘Thyroxine produced in the thyroid gland is an iodinated derivative of. (A) threonine (B) lysine (© tyrosine (D) tryptophan B2 Space For Rough Work 8 (2€0521K23) € @ scanned with OKEN Scanner16. 19, Which one of the following is a non-narcotic analgesi¢ 2 (A) Heroin (B) Codeine (C) Aspirin _ () Morphine Receptors are proteins and crucial to body communication process. These receptors aye embedded in (A) Cell membrane — (B) Protein (C) Endocrine gland = (D) Chromosomes Which of the following monomers form biodegradable polymers ? (A) Ethylene glycol and pthalie acid (B) Caprolactum and 1, 3 - Butadiene (C) Phenol and formaldehyde () 3-hydroxybutanoic acid and 3-hydroxypentanoic acid Match the List-I with List-Il in the following : List-I List-II 1, Caprolactum | (a) ~(CH)-CH); | CH; 2. Vinylehloride (b)_¢cx1,-cH); Cis 3. Styrene © feny-cuy al cr ° 4. Propene ; © Cx oo _ H (A) le, 2-4, 3-a, 4-b (B) 1-a, 2-d, 3-c, 4-b (©) 1-4, 2-¢, 3-a, 4-b (D) 1-4, 2-c, 3-b, 4-a g Space For Rough Work B-2 10 (2C0821K23) C @ scanned with OKEN Scanner20. 2, 22. 24, 25. 26. 27. The correct order of first ionisation enthalpy of given elements is apes (A) Li Bond length of 0;' (B) Bond order of 03 < Bond order of O2 2 (C) Bond length of O, < Bond length of 0" (D) Bond order of O, > Bond order of O7 A gas at a pressure of 2 atm is heated from 25 °C to 323 °C and simultaneously compressed rd to} ofits original value. Then the final pressure is (A) 1.33 atm (B) 6 atm (C) 2atm (D) 4 atm 784 kJ mol"!, Enthalpy of solution Lattice enthalpy for NaCl is +788 kJ mol“! and A He of NaClis (A) +572) mol (B) +410 mol! (©) 572k mol"! (D) - 4 kJ mol" At 500 K, for a reversible reaction Azz) + Brig) > 2AByg in a closed container, Ke =2 x 10°. In the presence of catalyst, the equilibrium is attaining 10 times faster. The equilibrium constant K¢ in the presence of catalyst at the same temperature is (A) 2x 104 () 2x 10% (C) 2x 10-1 (D) 2x10 A weak acid with pK, 5.9 and weak base with pK, 5.8 are mixed in equal proportions. pH of the resulting solution is (A) 7.005 (B) 75 ©7 ° (D) 7.05 Temperature of 25 °C in Fahrenheit and Kelvin scale respectively ate (A) 77°F and 298.15 K (B) 17 °F and 298.15 K (©) 48°F and 260.15K ~ (D) 47°F and 312.15 K The number of protons, neutrons and electrons in the ion 32S" respectively are (A) 16,18, 16 (B) 16, 16, 18 © 18,16, 16 (D) 16,16, 16 ‘Space For Rough Work : x OTST sae ANAS ue oa os ad wy a aa +15 a oa (200521K23) C \ 1 @ @ scanned with OKEN Scanner28. A pair of amphoteric oxides is (A) Al,0,, Li,O. (B) BeO, BO, (C) BeO, MgO. (D) BeO, ZnO 29, The composition of water gas is +H. (A) COq+Nag 8) CH, ©) COq)+H,O ©) CO%®* Hr) 30. IUPAC name of the compound is U's ¢ 7 _ : ; ere — , \ we ay (A) 2,3~dimethylbut-2-ene (B) 2,3—dimethyl butyne (©) 1,1,2,2-tetra methylethene (D) 2,3 - dimethyl butene 31. Among the following : s I 0 m iv v The set which represents aromatic species is (A) I, Mand Il (B) II, 1VandV— (C) Hand IT (D) J, Hand IV 32. Which one of the following gases converts haemoglobin into carboxy haemoglobin ? (A) CO (B) 0, (C) NO (D) Co, 47t4. ~ 1670 33. What is the oxidation number of S in H,S,0, ? (A) +5 (B) +4 aa st (C) +7 (D) +6 Eat 34. A.30% solution of hydrogen peroxide is (A) ‘30 volume” hydrogen peroxide (C) ‘50 volume’ hydrogen peroxide (B) ‘10 volume’ hydrogen peroxide (D) ‘100 volume’ hydrogen peroxide B2 Space For Rough Work (2€0521K23) C @ scanned with OKEN Scanner:[ no? 2a ; 38. GE “a ve fia oe 36. 3 38. 39. 40. 1 a ims f te Av at's co) 7 anti: AC a-jr 7-8 nl eh, BA Sr 0D Ze pee ats Ata? We wae els (ba? a= a a ; ‘The ratio of radii in simple cubic, If ‘a’ stands for the edge length of the cubic systems ‘body centered cubic and face centered cubic unit cells is : 1 Mt d (A) la V3 a:V2a 9G THe 2 ay My 3 1 ae 2 - 0 © faa (Dy za:Viarrpa 4 Dimerisation of solute molecules in low dielectric constant solvent is due to : (A) Hydrogen bond : (B) Covalent bond (C) Co-ordinate bond (D) Ionic bond The swelling in feet and ankles of an aged person due to sitting continuously for long hours during travel, is reduced by soaking the feet in warm salt water. This is because of : (A) Reverse Osmosis (B) Osmosis (©) Edema (D) Diffusion w A sample of water is found to contain 5.85% @ of AB (molecular mass 58.5) and 9.50% @) XY, (molecular mass 95). Assuming 80% ionisation of AB and 60% ionisation of XY,, the freezing point of water sample is [Given : K, for water 1.86 K kg mol", Freezing point of pure water is 273 K and A, B and Y are monovalent ions) (A) 264.25 K (B) 265.56 K (©) 280.44K (D) 281.75 K Match the column A (type of crystalline solid) with the column B (example for each type) : A Molecular Solid Tonic Solid Metallic Solid S. Network Solid (A) P-iii, Qi, Roi, S-iv (©) Pri, Qiv, Rill, S-i PO” Ql, Rit, S-i Qiv, Rei, S+i A metal crystallises in.a body centered cubic lattice with the metallic radius V3 A. The volume of the unit cell in m? is (A) 64 x 10° (B) 4x 10°? (C) 6.4 x 10° (D) 4x 10-10 ~ S| For Rough Work toad A a 618) (Bx oy eee ra . ft pave 2:03 106) yo “ge awe ERIKA EM ek. OU 8F mM \ get a @ scanned with OKEN Scanner41. 42. ‘The resistance of 0.1 M weak acid HA in a conductivity cell is 2 x 10° Ohm. The cell constant of the cell is 0.78 C m-! and 2%, of acid HA is 390 S cm? mot. The pH of the solution is (a) 33 (B) 42 @s (@)3 In which one of the following reactions, rate constant has the unit mol L~! s“! 7 (A) Acid catalysed hydrolysis of CH,COOCH, (B) CHCl, + Cl, —+ CCl, + HCI, (© 2NOW* Or 92ND, : - (D) Decomposition of HI on the surface of Gold Fora reaction, the value of rate constant at 300 K is 6.0 x 105 s~1. The value of Arrhenius factor A at infinitely high temperature is : (A) 6 x 105 x @rE8300R hp) eBason. © Sy ae a - Moxie” Bis aio The, rate constants’ k, and k, for two different reactions are 106 x e207 and 1015 x e-10007T respectively. The temperature at which k; = ky is : Jee aas us = 2000 “OSs @) 2000 Ope Po) 100K * During the electrolysis of brine, by using inst eetrodca, ee (A) 0, liberates at anode (B) H, liberates at anode (© Na deposits on cathode ~'(D) Cl, liberates at anode = Consider the following 4 electrodes. eve A: Ag* (0.0001 MY/Agiy; B: Ag* (.1M)/ Age, C: Ag* (0.01 MYAgs °~ D: Agt (0.001 M)/Agiy sE, ang 4080 B2 ‘Then reduction potential in voits of the electrodes in the order * (A) B>C>D>A (B) C>D>A>B : (C) A>D>C>B ; (D) A>B>C>D Space For Rough Work 18 (20082123), @ scanned with OKEN Scanner47, When FeCl; is added to excess of hot water gives a sol *X’, When FeCl; is added to NaOH qq) Solution, gives sol 'Y’. X and ¥ formed in the above processes respectively are (A) Fe,0, + xH,0 / OH and Fe,0, « xH,0/Fe?* (B) Fe,0, + xH,0/H" and Fe,0, + xH,0/Nat (C) Fe,0, + xH,0/ Clr and Fe,0, « xH,0/OH™ (D) Fe,0, » xH,0/ Fe** and Fe,0, xH,O/OH- 48. The reducing agent in the given equations : ot x th - 4 AB + 8 ONG) # 2H 0 uy + 5, —> AABN) Tay * 40H 2AB(CN) hg) * 2%) —> [Zn(CN), Igy + AKG,” 4:0 (A) Zn @) 0, (© H,0 (D) CN" 49. For the formation of which compound in Ellingham diagram’AG° becomes more and more negative with increase in temperature ? (A) CO , 8) Feo (©) Zn0 (D) Cu,0 50. Which of the following compound does not give dinitrogen on heating ? (A) BaN,), (B) NH,NO,, (© NH,NO, ©) (NH), Cr,0, 51. Aqueous solution of raw sugar when passed over beds of animal charcoal, it becomes colourless. Pick the correct set of terminologies that can be used for the above example. Adsorbent Adsorbate Process (A) [Solution of Sugar [Animal Charcoal__| Sorption (B) [Animal Charcoal | Solution of Sugar__| Absorption (© [Animal Charcoal —_ | Colouring substance | Adsorption (D) [Colouring Substance [Animal Charcoal | Adsorption 52. For Freundlich adsorption isotherm, a graph of log (x/m) Vs. log (P) gives a straight line. The slope of line and its Y-axis intercept respectively are ») 1 (A) log (, K (B) t log K (C) log ( log K (D) ak B Space For Rough Work B2 20 (2€0521K23) C @ scanned with OKEN Scanner2 Si. 58. 59, 60. In solid state, PCI, is a/an (A) Octahedral structure (B) Ionic solid with [PCI,]* and [PCI] (C) Tonic solid with (PC1,]* and [PCI,]- (D) Covalent solid present in the form of P,Clig In which one of the following pairs, both the elements does not have (n-1)d"°ns? configuration in its elementary state ? (A) Zn, Cd (B) Cd, Hg (C) Hg, Cn (D) Cu, Zn Which of the following is CORRECT with respect to melting point of a transition element ? (A) V>Cr (B) Cr> Mn. (C) Mn> Fe (D) Ti>V 4 “ aMn0j + bS,0;" + H,0—> xMnO, + ySO,? + z0H- aand y respectively are.” (A) 83 (B) &6 36 (D) 88 Which formula and name combination is INCORRECT ? (A) K,[AI(C,0,)3] — Potassium trioxalatoaluminate (III) (B) [PQNH,), CI(NO,)] - Diamminechloridonitrito - N — platinum (11) (©) [CoCI,(en),]CI — Dichloridodiethylenediammine cobalt (II) chloride (©) [Co(NH,), (HO)CIICI, - Tetraammineaquachloridocobalt (III) chloride Which of the following system in an octahedral complex has maximum unpaired electrons ? (A).d? (high spin) —_(B) d® (low spin) (C) d¥ (low spin) (D) d” (high spin) ‘The correct decreasing order of basicity of hydrides of Group-15 elements is (A) SbH, > AsH, > PH, > NH; (B) PH, > AsH, > SbH; > NH, (C) AsH, > SbH, > NH, > PH, (D) NH, > PH, > AsH, > SbH, Which one of the following oxoacids of phosphorus can reduce AgNO, to metallic silver ? (A) HPO. (B) H,P,0, (C) H,P,0, (D) H;PO, Space For Rough Work 2 (200521K23) C @ scanned with OKEN Scanner