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Questions 5 and 6 refer to the following diagram.
A. nitrogen A. iron
B. oxygen B. lead
C. chlorine C. magnesium
D. iron D. zinc
C. HNO2
D. N2 15. When aqueous copper(II) sulphate is
electrolysed using copper electrodes, the
1986 equation(s) for the reaction(s) which occur(s) at
the anode is/are
9. (NH4)2Cr2O7 heat
→ N2 + 4H2O + Cr2O3 (1) Cu(s) → Cu2+(aq) + 2e-
(2) Cu2+(aq) + 2e- → Cu(s)
When ammonium dichromate is decomposed
(3) SO42-(aq) → SO2 + O2 + 2e-
according to the above equation, which of the
following correctly describes the changes in
oxidation numbers of nitrogen and chromium? A. (1) only
B. (3) only
Oxidation number Oxidation number C. (1) and (2) only
of nitrogen of chromium D. (2) and (3) only
A. increase increase
B. increase decrease
C. decrease increase 16. Which of the following metals will NOT
D. decrease decrease displace copper ions from aqueous copper(II)
sulphate?
10. In the following reaction:
A. silver
B. iron
2I + H2O2 + 2H → I2 + 2H2O
- +
C. zinc
D. aluminium
A. I- is reduced and H+ is oxidized.
B. I- is reduced and H2O2 is oxidized.
C. I- is oxidized and H2O2 is reduced.
D. I- is oxidized and H+ is reduced. 1987
11. If 0.1 M aqueous solutions of the following 17. During electrolysis, electricity passes through
compounds were electrolysed using graphite the electrolyte as a result of the movement of
electrodes, which one would give hydrogen at
the cathode and oxygen at the anode? A. cations only.
B. anions only.
A. copper(II) sulphate C. cations and anions.
B. sodium hydroxide D. mobile electrons.
C. potassium iodide
D. silver nitrate
18.
12. In which of the following reactions is sulphur
dioxide acting as an oxidizing agent?
Referring to the above diagram, which of the C. H+(aq) ions are reduced to H2O(l).
following changes would occur when a current D. the oxidation number of manganese
is passed through the solution for some time? increases from -1 to +2.
(1) is cheap.
(2) conducts electricity.
(3) is chemically inert.
(4) is a reducing agent. 1989
A. (1) and (3) only.
25. When a solution of magnesium sulphate of
B. (2) and (4) only.
known concentration is electrolysed using
C. (1), (2) and (3) only.
platinum electrodes, which of the following is a
D. (2), (3) and (4) only.
correct description of what happens?
Number of Number of
1988 moles of moles of pH value of
Mg2+(aq) SO42-(aq) the solution
21. In which of the following will a redox reaction A. decrease decrease increase
occur? remains
B. decrease decrease
unchanged
A. adding sodium to ethanol remains remains
B. bubbling sulphur dioxide into sodium C. decrease unchanged unchanged
hydroxide solution remains remains remains
C. heating copper(II) hydroxide D. unchanged unchanged unchanged
D. adding zinc oxide to concentrated nitric
acid
26. In which of the following reactions is the
underlined substance reduced?
22. In carrying out redox reactions, potassium
permanganate solution is usually acidified with A. Cu(OH)2(s) + 4NH3(aq) →
dilute sulphuric acid but not with dilute
hydrochloric acid because
[Cu(NH3)4](OH)2(aq)
A.hydrochloric acid is more expensive. B. 2H+(aq) + CO32-(aq) → CO2(g) +
B.hydrochloric acid is a stronger acid. H2O(l)
C.hydrochloric acid is an oxidizing agent. C. Cl2(g) + 2Fe2+(aq) → 2Fe3+(aq) + 2Cl-
D.hydrochloric acid reacts with potassium (aq)
permanganate solution. D. 2Ag+(aq) + Zn(s) → 2Ag(s) + Zn2+(aq)
23. Consider the reaction:
27. The anode of a dry cell is usually made of
MnO4-(aq) + 8H+(aq) + 5Fe2+(aq) →
5Fe3+(aq) + Mn2+(aq) + A. zinc.
4H2O(l) B. iron.
C. tin.
Which of the following statements concerning D. lead.
the above reaction is true?
28. Chlorine reacts with cold dilute aqueous sodium
A. 1 mole of electrons is transferred per mole hydroxide according to the equation:
of MnO4-(aq) ions reacted.
B. 1 mole of the reductant is required to react Cl2(g) + 2NaOH(aq) →
with 0.2 mole of the oxidant. NaClO(aq) + NaCl(aq) + H2O(l)
MC: Chemical Cells and Electrolysis Page 4
A. (1) only
B. (1) and (2) only
C. (2) and (3) only
D. (1), (2) and (3)
1990
In which of the following cases will NO
32. Which of the following elements in the third observable change occur in solution Y?
period of the Periodic Table is the strongest
reducing agent? gas X solution Y
A. sulphur dioxide bromine water
A. sodium B. sulphur dioxide calcium hydroxide
B. sulphur C. carbon dioxide bromine water
C. chlorine D. carbon dioxide calcium hydroxide
D. aluminium 1991
33. In which of the following pairs of substances is
the oxidation number of the sulphur atom and Directions:
the nitrogen atom the same? Questions 37 and 38 refer to the following
electrolysis experiment.
A. H2SO4 and HNO3
B. SO2 and HNO2
C. SCl2 and NO
D. NaHS and NH3
A. 1:1 Element W X Y Z
B. 1:2 Atomic number 9 10 14 19
C. 1:4
D. 2:1 Which of the following elements is likely to be
an oxidizing agent?
A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only
39.
A. R, P, Q, S
Which of the following combinations would
B. Q, P, R, S
produce the largest current flowing from metal
C. P, Q, S, R
X to metal Y in the external circuit?
D. P, R, S, Q
metal X metal Y
A. Fe Cu
43. Which of the two metals used as electrodes
B. Mg Ag
would give the largest cell voltage?
C. Ag Zn
D. Cu Pb
A. Q and R
40. Cl2(aq) + 2I-(aq) → I2(aq) + 2Cl-(aq) B. Q and S
C. S and R
Which of the following statements concerning D. S and P
the above reaction are correct?
44. Using 1 mole of reactant, which of the
(1) I-(aq) acts as a reducing agent. following chemical changes involves the
(2) Chlorine is a stronger oxidizing agent than highest number of electrons?
iodine.
(3) The reaction is a displacement reaction. A. CrO42-(aq) → Cr3+(aq)
A. (1) and (2) only B. Cr2O72-(aq) → Cr3+(aq)
B. (1) and (3) only C. MnO4-(aq) → Mn2+(aq)
C. (2) and (3) only D. MnO42-(aq) → MnO2(s)
D. (1), (2) and (3)
(1) KOH(aq)
(2) AgNO3(aq)
(3) MgCl2(aq)
1993 1994
48. The oxidation number of copper remains
52. When a substance X is electrolysed using
unchanged when
platinum electrodes, a gas is collected at each
electrode. X may be
A. magnesium ribbon is added to copper(II)
sulphate solution.
A. silver nitrate solution.
B. sodium carbonate solution is added to
B. potassium chloride solution.
copper(II) nitrate solution.
C. molten sodium chloride.
C. carbon is heated with copper(II) oxide.
D. molten copper(II) chloride.
D. copper foil is burnt in chlorine.
53. Both rubidium (Rb) and sodium are elements in
49. In which of the following equations does the
Group I of the Periodic Table, but rubidium is
underlined substance undergo reduction?
more reactive than sodium. When a rubidium
hydroxide solution is electrolysed using
A. 2H2O + 2K → 2KOH + H2 platinum electrodes, hydrogen gas is liberated at
B. Fe2(SO4)3 + 2KI → 2FeSO4 + K2SO4 the cathode.
+ I2
C. 2H2S + SO2 → 3S + 2H2O Which of the following statements is a correct
D. NaClO + SO2 + H2O → NaCl + explanation for the phenomenon described
H2SO4 above?
A. Electrons flow from lead electrode to the 65. In which of the following processes will lead be
magnesium electrode through the external formed?
circuit.
B. Electrons flow through the salt bridge. (1) the electrolysis of molten lead(II) bromide
C. The mass of the lead electrode remains (2) heating lead(II) oxide strongly
unchanged. (3) adding magnesium to lead(II) nitrate
D. Oxidation occurs at the magnesium solution
electrode.
A. (1) only
B. (2) only
C. (1) and (3) only
Directions: The two questions below refer to the D. (2) and (3) only
following experiment.
66. Which of the following substances are
commonly found in the waste water produced
by electroplating factories?
(1) acids
(2) alkalis
(3) cyanides
A. C(s) → CO2(g)
B. NO3-(aq) → NO2(g)
C. SO32-(aq) → SO42-(aq)
D. MnO4-(aq) → Mn2+(aq)
Which of the following metals would produce
the smallest voltage in the above set-up?
70.
A. iron
B. aluminium
C. copper
D. magnesium
MC: Chemical Cells and Electrolysis Page 9
A zinc-carbon cell is connected to a voltmeter A. Permanganate ions migrate into the salt
as shown in the above diagram. Which of the bridge.
following statements concerning the set-up is B. Electrons flow from electrode X to
INCORRECT? electrode Y in the external circuit.
C. Carbon electrodes are used because they are
A. Electrons flow from the zinc case to the chemically inert.
carbon rod in the external circuit. D. The half equation for the change occurring
B. The zinc case gradually becomes thinner as at electrode Y is Fe2+ + 2e- → Fe.
the cell discharges.
C. Manganese(IV) oxide acts as an oxidizing
agent.
D. Ammonium chloride acts as a reducing 74. Consider the following chemical equation:
agent.
Zn + pMnO2 + qNH4+ →
Zn2+ + xMn2O3 + yNH3 + zH2O
1998
Which of the following combinations is correct?
V
c o p p e r( II) s u lp h a te
c a rb o n s a lt b rid g e c a rb o n s o lu tio n
e le c tro d e X e le c tro d e Y
a c id ifie d
Which of the following statements concerning
iro n (II) this experiment is correct?
p o ta s iu m
s u lp h a te
p e rm a n g a n a te
s o lu tio n
s o lu tio n A. The mass of the impure copper rod
decreases.
B. The blue colour of the copper(II) sulphate
Which of the following statements concerning
solution gradually fades off.
the above experiment is correct?
C. Oxidation takes place at the pure copper
rod.
MC: Chemical Cells and Electrolysis Page 10
D. The electrolysis process can enhance the (1) Potassium hydroxide acts as a reducing
corrosion resistance of copper. agent.
(2) The oxidation number of chlorine changes
from 0 to –1.
(3) The oxidation number of chlorine changes
77. Potassium permanganate solution acidified with from 0 to +5.
dilute sulphuric acid is a commonly used
oxidizing agent. Dilute nitric acid is not used to A. (1) only
acidify potassium permanganate solution B. (2) only
because C. (1) and (3) only
D. (2) and (3) only
A. nitric acid is more expensive than sulphuric
acid.
B. dilute nitric acid is an oxidizing agent and 81. Which of the following reagents is/are
would react with the reducing agent. commonly stored in brown bottles?
C. nitric acid decomposes more readily than (1) potassium permanganate solution
sulphuric acid. (2) concentrated sulphuric acid
D. dilute nitric acid would react with (3) concentrated nitric acid
potassium permanganate solution.
A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only
82. Consider the following chemical cell:
V
78. Consider the following chemical reaction:
z in c copper
2HNO3 + xFeSO4 + yH2SO4 → e le c tro d e e le c tro d e
zFe2(SO4)3 + 4H2O + 2NO
2000
80. The equation below represents the reaction of
chlorine with hot concentrated potassium 83. Which of the following gases are the major
hydroxide solution: products liberated in the electrolysis of
concentrated sodium chloride solution using
3Cl2(g) + 6KOH(aq) → carbon electrodes?
5KCl(aq) + KClO3(aq) + 3H2O()
Cathode Anode
Which of the following statements concerning A. hydrogen chlorine
this reaction is/are correct? B. chlorine hydrogen
C. hydrogen oxygen
D. oxygen hydrogen
MC: Chemical Cells and Electrolysis Page 11
A. NH3
B. NO
C. N2O
D. N2
1 M m a g n e s iu m 1 M c o p p e r(II)
s u lp h a te s u lp h a te
s o lu tio n s o lu tio n
B eaker X B eaker Y