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Across the period, nuclear charge & negligible in shielding effect, effective nuclear charge atomic radius Formation of Cations Ionic Radius from Na+ to Si4+ as nuclear charge (each ion : Na+, Mg2+, Al3+, Si4+ have 10 e-) High m.p. due to giant metallic structure. There is strong metallic bonding. Highest m.p. due to macromolecular structure. Numerous covalent bonds between Si atoms arranged tetrahedrally in a 3Dimensional structure. Low electrical conductivity as Si is a metalloid Formation of Anions Ionic Radius from P3- to Cl- as nuclear charge (each ion : P3- , S2-, Cl- have 18 e-) Low m.p. due to simple molecular structure. Weak van der waals forces between molecules. M.p of S8 > P4 > Cl2 > Ar due to decrease in size of electron cloud as no. of electrons decreases.
High electricial conductivity, from Na to Al as no. of valence e- contributed per atom into sea of delocalised electrons Generally 1st I.E. across period as nuclear chare g and negligible increase in shielding effect, effective nuclear charge more energy required to remove the valence electron
Electronegativity Graph 6
Lower 1st I.E of Al than Mg as the 3p e- in Al is at further away from the nucleus compared to 3s e- being removed in Mg; Lower 1st I.E of S than P as a paired 3p e- in S is removed which experiences inter-electron repulsion compared to an unpaired 3p ein P. across period as nuclear charge and negligible increase in shielding effect, Effective. nuclear charge across period.
MJC 2011
Graph 1
Graph 2
first
P3S2-
Graph 5
Cl-
Proton number
Na Mg Al Na Mg Al Si P S Cl Ar Si
Cl
Proton number
Electrical conductivity
Graph 3
Graph 4
Graph 6
Na Mg Al
Si
Cl
Ar
Proton number
MJC 2011
Al Needs to be heated to 800 0C due to presence of the protective Al2O3 oxide layer
4Al (s) + 3O2 (g) 2Al2O3 (s)
S Slow Burns with a blue flame With excess O2, SO2 is oxidised to SO3
S(s) + O2 (g) SO2 (g)
Cl ---
Ar ---
Very vigorous
Na (s) + Cl2 (g) 2NaCl (s)
Vigorous
Mg(s) + Cl2 (g) MgCl2 (s)
Vigorous
2Al(s) + 3Cl2 (g) Al2Cl6 (s)
Slow
Si (s) + 2Cl2 (g) SiCl4 (l)
Slow 2 chlorides (PCl3 & PCl5) formed PCl5 formed in excess Cl2
P4(s) + 6Cl2 (g) 4 PCl3 (s) P4(s) +10Cl2 (g) 4 PCl5 (s)
---
---
No reaction
MJC 2011
Oxidation no. of oxides across period as no. of valence e- available for bond formation Giant Ionic Lattice Structure Ionic & basic Forms NaOH with water (pH 13) Forms Mg(OH)2 with boiling water (pH 9) Ionic & amphoteric No reaction (pH = 7) Giant molecular Structure Simple molecular Structure Covalent & acidic Form H3PO3, H3PO4 with water
(pH 2)
Na2O(s) + H2O(l) MgO (s) + H2O(l) Al2O3 does not dissolve in water because of P4O6(s) + 6H2O(l) 4H3PO3(aq) 2NaOH(aq) Mg2+ (aq) + its extremely high lattice energy 2OH (aq)
- Large amounts of energy are required to break the numerous strong covalent bonds, solvation cannot occur.
SiO2
Forms Al3+ (aq) Al2O3(s) + 6HCl(aq) 2AlCl3(aq) + 3 H2O(l) White ppt dissolves in excess NaOH to form colorless complex, Al(OH)4 (aq)
Al2O3(s) + 3H2O(l) + 2NaOH(aq) 2NaAl(OH)4(aq)
No reaction
No reaction
MJC 2011
Graph 7
13
Graph 8
pH of solution
Graph 9
oxides 7
chlorides
Na
Mg
Al
Si
MJC 2011
Acidic pH = 3
Acidic pH = 2
Acidic pH = 2
MJC 2011
MJC 2011