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Speech from the President


Congratulations to the First Issues of APDA Magazine Desalination Industry
Dr. Masaru Kurihara President of Asia Pacific Desalination Association

Congratulations to the First Issues of APDA Magazine Desalination Industry. Although in the past, we had a big discussion on the publication of APDA Magazine in the APDA board meeting, I would like to describe the brief history and recent activity of APDA due to the publication of the first edition of APDA magazine.

1 Brief History Before the Establishment of APDA Organization


We Had the 2006 Asia Water and Membrane Forum organized by JDA on June 7, 2006 in Tokyo Japan. The representatives of 6 countries from Asia-Pacific region (Japan, China, India, Singapore, Australia and Pakistan) had participated with the former IDA president, Mr. Gassan Ejeh. As shown in Fig.1. The concept of Asia-Pacific Desalination was obtained as one of the most fruitful results of this forum. APDA was officially established on May 27, 2008. 2006 Asia Water and Membrane Forum was the motive conference to start APDA. As shown Fig.1.

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Fig.1 Asia Water and Membrane Forum, Tokyo, Japan.


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1.1 Organizational Position & Relation with IDA


The following Fig.2 was introduced at the conference on March 10th, 2010, which was held jointly by India Dessalination Asociation and APDA. As the figure indicates, various affiliates in Asia-Pacific Region based on IDA exist in the worlds water organization. IDA has many affiliates globally as shown in Table1.

IDA
R egional Affiliate Association Affiliate
Others (Future IDA affiliate members to be expected)

JDA InDA KOR E A

C DA PaKDA TAIWAN

AWA S WA

APDA
Fig.2 Organizational Position & Relation with IDA
Association affiliate (abbreviation) InDA PakDA WDEC WSTA CaribDA

Regional affiliate (abbreviation) AMTA EDS AEDyR JDA CDA AWA LDA

Affiliate Name American Membrane Technology Association European Desalination Society

Affiliate Name Indian Desalination Association Pakistan Desalination Association Water Desalination Engineering Chapter Water Science and Technology Association Caribbean Desalination Association Singapore Water Association Name Korea Desalination Association Taiwan Desalination Association

Asociacion Espanola de Desalaciony Reutilizacion


Japan Desalination Association Chinese Desalination Association Australian Water Association Levant Desalination Association

SWA Others*1 Korea Taiwan

Note *1: Others/ Future IDA affiliate members to be expected

Table1 Abbreviations and Official Names of IDA Affiliates Regional affiliates and association affiliates according to IDA constitution are categorized in 2 groups.

1.2 The Constitution of the Asia-Pacific Desalination Association


Object: The primary purpose of this Association is to make contributions to the solution of water problems in the Asia-Pacific region by exerting a synergetic effect in cooperation with each of the members of the Association which consists of Regional Affiliates, Association Affiliates, etc., under IDA and through coordination with related organizations.

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Speech from the President


Status: Association Affiliates of IDA

1.3 IDA (International Desalination Association) & APDA (Asia Pacific Desalination Association)
Fig.3 shows IDAs global affiliates and APDA. The abbreviation of each affiliate is shown in Table 1.The affiliates are composed of each country and / or each continent such as EDS. Fig.3 also shows the relationship between IDA, APDA and each affiliate of Asia-Pacific region. It also includes the others such as Korea and Taiwan for future IDA affiliate members & APDA members to be expected.
Version-2011/1/25 Fig.3 Global IDAs Affiliates and APDA.

EDS AMTA CaribDA


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WSTA LDA PakDA InDA


( 2 40 )

(KDA)
(17)

AEDyR WDEC

CDA

( 1 82 )

( 11 2 )

JDA

(TDA) SWA
(19)

( 1 20 ) (Version-2011/1/25) ( 18 8 )

AWA
( 5 00 0)

IDA

Regional affiliate Association affiliate

( T otal Mem ber: 58 7 8)

APDA

( ): Number of Affiliate Members

1.4 APDA Organization & the Related Persons Corresponding to Each Assignment
The Table 2 below shows the organizational relationship between each affiliate of APDA & the persons, corresponding to each assignment. Table 2 APDA Organization & the related persons corresponding to each assignment as of November 1, 2009 JDA
President Vice President
Mr. Iwahori, H. Dr. Kurihare,M.

CDA
Prof. Gao, Congjie
Prof. Wang, Shichang Mr. Guo, You Zhi Mr. Guo, Youzhi

AWA
Mr. Palmer, Neil

InDA

PaKDA

SWA

KOREA

TAIWAN

Mr. Mollenkopf, Dr. P. K. Tewari Tom

Mr. F. M. Mubeen Mr. Nisar Ahmed Khan Mr. M. Irfan Shaikh

Mr. Khoo Teng Mr. Ahn Hyun Sang Chye

Prof. Dr. D. J. Lee

Board Member
Mr. Fujiwara, N.

Secretary General Secretary Advisory Board Member Category


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Mr. Hirai, M.

Ms. Jan Tan Mr. S. C. Kwak Mr. K. L. Tung

Mr. Takeuchi, H. Ms. Yang, Yan Dr. Goto, T. Regional Affiliate Regional Affiliate

Dr. Diane Wiesner

Mr. K. P. Gwaiani

Mr. M. Shakaib Mr. Abdullah Mubeen

Regional Affiliate

Association Affiliate

Association Affiliate

Association Affiliate

Others

Others

2 Activities of APDA
2.1 Past Conferences Table 3 shows the past & future conferences of APDA Since the first conference in Qingdao, China, we have had 3 conferences and one APDA workshop in Taichung, Taiwan. The photos of each conference and workshop are shown below. Table 3 The Past & Future Conferences of APDA
Date 2008/5/27-30 2009/2/11-13 2010/3/10-12 2010/11/15-16 2011/7/0-0 Place Qingdao, China Sydney, Australia Chennai, India Taichung, Taiwan Singapore Theme
Organizers

2008 APDA Conference on Desalination & CDA Water Reuse AWA 2009, 2nd APDA Conference 2010, 3rd APDA Conference 2010, APDA Workshop 2011, 4th APDA Conference
InDA Taiwan SWA

As Table 3 & Fig.4 show, the first APDA conference was held between May 27th and 30th, 2008 with CDA.

Fig.4 The First APDA Conference with CDA, Qingdao, China, 2008

Fig.7 The First APDA Workshop Was Held in Taichung, Taiwan in November 2010. 2.2 Future APDA conference The 4th APDA conference with SWA will be held in Singapore on July 7, 2011.

Fig.5 The Second APDA Conference with AWA, Sydney, Australia, 2009

Fig.6 The Third APDA Conference, with InDa, Chennai, India, 2010

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Technology Development
Growth and Prospect of Seawater Desalination Technology in China
Gao Congjie Development Center of Water Treatment Technology Abstract Global economic development and ecological environment have been influenced by water resource deficiency day by day. The water resource shortage in China has been a severe impact to the development of social economy of the coastal and western regions. Desalinization technology is one of the important means to solve current water resource deficiency problems. Desalinized water output is about 70 million cubic meters per day around the whole world. The energy consumption of seawater desalinization has already dropped to 3 kWh/m3, and desalination water cost is about USD 0.5/m3. China is a great country with large water resources, the total volume of water resources is 2,810 billion cubic meters, which is in the 6th place of the world; the per capita water resource volume is 2220 cubic meters, which is only 1/4 of the world average and in the 121st place of the world. China is classified as one of the 13 countries with poorest water shortage by the United Nations. The national annual water shortage volume is up to 40 billion cubic meters, and at present, the economic losses over RMB 200 billion is caused by the lack of water, which has restricted the economic and social development seriously. Throughout the research and development of more than 50 years, China has made considerable progress in distillation technology and reverse osmosis technology on seawater desalinization. Seawater desalinization output in China is about 7.0105 m3/d. This has solved the industry and drinking water supply problem of a great deal of islands, coastal areas and western regions. The desalination water demand is expected to be increased up to 3.0 -5.0106 m3/d in the following 10-15 years. It will make desalinization become an important component of safe water supply system along coastal areas.

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1 Technology of seawater desalination and current situation in China


The research on seawater desalination has a long way with the initial research on electrodialysis (ED) in 1958 and research on reverse osmosis (RO) and distillation etc., in 1965. At the beginning of the 1960s, the small-scale ED device equipped with polyvinyl alcohol heterogeneous ionexchange membrane has already been put into experimentation, and was put into pilot operation in 1967 for desalting water production. Ever since the 1970s, a succession of manufactures on various homogeneous ion exchange membrane, researches on electrode dynamics and the preparation of titanium electrode coated with ruthenium, the development of the large size (8001600 mm) electrodialysis clapboard, the research on ED hydraulics parameter, the design and development of the large scale ED membrane, the technology of EDR, and the standardization of the equipment have been carried out, and abundant experience on engineering design and

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operation have been achieved. The ED seawater desalination plant of 200 m3/d located at the Xisha Islands to meet military and civil demand with the consumption of 18 kWh/m3 freshwater. By far, the annual output of ion exchange membrane is stabilized at 4.0105 m2. As for the reverse osmosis, researches were carried out in labs in 1965; between 1967 and 1969, cellulose acetate asymmetry reverse osmosis membrane was achieved in pilot scale; the development of hollow fiber and spiral RO components was made in the 1970s, and it has been industrialized and promoted into application in the 1980s; and an exploration of composite reverse osmosis was undertaken and put into pilot-scale application with great success. In 1997, a 500 m3/d seawater RO desalination demonstration plant was constructed at Shengshan Island, Zhoushan, and a 1000 m3/d seawater RO desalination plant was set up at Da Changshan Island with a freshwater consumption of 5.5 kWh/m3 in 1999. At the end of 2000, a seawater RO demonstration plant of 1000 m3/d have been built up respectively at the Long Land of Shandong and Shengsi of Zhejiang province. Later on, the Huaneng Electric Power Plants of Weihai and Dalian have established 2000 m3/d seawater RO desalination plants, and then, the Rongcheng of Shandong and Dalian Petrochemical have built up 5000 m3/d seawater RO desalination plants. In recent years, a number of large plants have been built, such as 34560 m3/d in Yuhuan Power plant, 2.0104 m3/d in Leqing Power plant, 1.0105 m3/d in Xinquan desalination plant of Tianjin, 1.0105 m3/d in Baifa desalination plant of Qingdao. Over 50 SWRO desalination plants have been established with a total freshwater output about 4.0105 m3/d. With the respect of distilling, the research and development on ship use distilling device of small-scale were the major

focus in the 1960s, and the pilot-scale research on the MSF with the capacity of a hundred ton level has acquired some design parameters and experience between 1970s and 1980s; a VC device of 30 m3/d was put into experimental use from 1980s to 1990s. In 1987, Dagang Electric Power Plant imported two sets of MSF of 3000 m3/d from the United States for boiler water supply. In 1997, a domestic designed and manufactured MSF plant of 1200 m3/d was commissioned for trial. 2 LT-MED devices of 1.0104 m3/d were imported from Sidem by Huanghua Power Plant for boiler water supply in 2002. The domestic designed and manufactured LT-MET device of 3000 m3/d was commissioned in 2004 in Qingdao Huangdao Power Plant, and another LT-MED device of 1.25104 m3/d was put in to operation in 2008 in Huanghua Power Plant. 4 LT-MED devices of 2.5104 m3/d were imported from IDE by Beijiang Power Plant for boiler water supply in 2009. With the development of nearly a half century, more than 60 seawater desalting plants have been established with a total capacity of 7.0105 m3/d, and the capacity of those under construction has exceeded 1.5106 m3/d. The cost of desalting water has been reduced from RMB 7/ton in 1980s to around RMB 4/m3 recently, and the technology and cost are equal with the advanced level in the world. As the enlargement of plant scale and the improvement of technology, reduction of cost is still possible. The main problem is that the components such as membrane, high pressure pump and energy recovery unit are all imported, and the domestic manufactured membrane components need to be tested; and the present plant is in small scale with less project experience. Nuclear power for seawater desalination process is just in preliminary stage.

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Technology Development

2 Suggestions for desalination industry development


Some suggestions for desalination industry development are listed briefly as follows: 2.1 Set up important seawater desalination demo areas to offer the seawater desalination industry a leap-forward development. 2.2 Encourage technology innovation to make the technology with independent intellectual property develop much more rapidly. 2.3 Set up a standard system of desalinization to guarantee the healthy development of desalination technology. 2.4 Expand desalination technology applications to achieve more remarkable repayments of economic, social and ecological benefits. 2.5 Set up a desalination industry chain to decrease environmental pollution and improve the comprehensive benefits. 2.6 Establish corresponding policies and regulations to make the desalination industry under standardized and legalized administration.

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years. 3.2 More than 10 key desalination technologies with independent intellectual property will be achieved, such as pretreatment, brine treatment, remineralization of desalted water and integrated desalination technologies. 3.3 More than 6 key desalination equipments with independent intellectual property will be manufactured, including RO membrane modules, high pressure pumps and boosters, energy recovery devices, CUF for seawater pretreatment, evaporator of MED, vapor sprayers and condensers. 3.4 Organize 2-3 innovative strategic alliances of seawater desalination technologies, found 10 equipment manufacturers with international competition, and establish a completed industrial chain for sea water desalination. 3.5 Set up several innovative research teams, and establish 3-5 pilot test bases. Table 1 Forecast of seawater desalination demand in China104 m3/d
Year I tem S eawater desalinatio n 2010 80-- 100 2015 150--200 2020 250--300

3 Main targets of desalination industry in China in the following 5-10 years


Through the aforesaid analysis, developing desalination industry in China should mainly rely on reverse osmosis and LT-MED. Meanwhile, attention should be paid to some innovative integrated technology and cogeneration technology. For large scale seawater desalination projects, it is recommended to consider the integration of the use of nuclear power with SWRO, MSF and LT-MED. It can even be combined with salt production industry and relative chemical industries. 3.1 More than 10 plants of SWRO or MED with the capacity larger than 2.0104m3/d will be built in next 5
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Postscript Through the efforts in next 5-10 years, China will become one of the countries with higher level of desalination technology and stronger desalination industry.

Membrane Technologies for Water Practices in Taiwan


Chihping Huang1, Kuo-Lun Tung2, 3, Duu-Jong Lee2, 4, Da-Ming Wang2, 4 and Yu-Chun Su1

1. Institute of Environmental Engineering, National Chiao Tung University, Hsinchu, Taiwan 2. R&D Center for Membrane Technology, Chung Yuan University, Chung Li, Taiwan 3. Department of Chemical Engineering, Chung Yuan University,Chung Li, Taiwan 4. Department of Chemical Engineering, National Taiwan University, Taipei, Taiwan

Abstract
Taiwans annual rainfall averages 2,510 mm, which is 3.5 times more than the average annual rainfall of the world. However, the distribution of water resources in Taiwan is uneven, both in time and space, with nearly 80 percent of precipitation falling between May and October. Due to the dramatic topographical changes in Taiwan, water resources are difficult to retain in rivers. These conditions make the management of water resources difficult, and Taiwan is categorized by the United Nations as a country with water shortage problems. To sustain the water supply in Taiwan, increasing research interest has been drawn to membrane separation technologies in recent years due to the excellent effluent quality which meets the requirements of water recycling and water reuse. In this article, we reviewed recent applications of membrane technologies in desalination, water treatment and wastewater treatment in Taiwan.
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Technology Development

1 Application of membrane technology for desalination, water treatment and wastewater treatment in Taiwan
In the past, the application of membranes in Taiwan focused on the preparation of ultrapure water for semiconductor fabrication, a major industry in Taiwan in the past two decades. Recently, membranes have been widely applied in the desalination and purification of drinking water (Lai et al., 2009). Membranes have also been widely applied in Taiwan to recycle industrial wastewater due to strict legislation. Ultrafiltration (UF) is used to treat wastewater from chemical mechanical polishing (CMP), while the membrane bioreactor (MBR) has been generally applied in treating wastewater from thin-film transistor liquid crystal display (TFT-LCD) in the past few years.
Technology Development
(1) Taoyuan (5) Kinmen (2) Hsinchu HsinTaoyuan

(4) Penghu

(3) Kaohsiung

Figure 1. Locations of RO desalination or drinking-water purification plants (Lai et al., 2009).

1.1 Desalination
Water shortage is a problem for the offshore islands, such as Penghu, Kinmen, and Matsu (Figure1). Seawater desalination seems a feasible solution to the problem. A brief description of the RO plants is given below. Ten RO units are in operation in Penghu islands. The capacity of the largest unit is 7,000 CMD. Two more units are under construction, one in 5,500 CMD and the other in 750 CMD. In Kinmen there is a RO unit with a capacity of 2,000 CMD, and in Matsu four RO units are running with a total capacity of 2,500 CMD. There is no RO unit on the main island, but two RO units, each with a capacity of 30,000 CMD, are being planned. One is to be placed in Taoyuan and the other in Hsinchu. By 2011, the total capacity of RO desalination in Taiwan will reach 21,900 CMD (Water Resource Agency, 2010). (1) Taoyuan: a RO desalination plant with a capacity of 30,000 CMD (under planning). (2) Hsinchu: a RO desalination plant

with a capacity of 30,000 CMD (under planning). (3) Kaohsiung: two plants of UF+low pressure RO (LPRO) for drinking-water purification, with a total capacity of 260,000 CMD (in operation). (4) Penghu: 10 RO plants in operation with a total capacity of about 18,000 CMD, and two more plants are under construction with the total capacity of 6,250 CMD. (5) Kinmen: a RO desalination plant with a capacity of 2,000 CMD (in operation).

1.2 Drinking-water purification


In the southern part of Taiwan, especially in the Kaohsiung area,the quality of drinking water was poor. The urgent need for the improvement of water quality became a political issue several years ago. Two water-purification membrane units, with UF plus low-pressure RO (LPRO), were operated for more than three years at the Kaotan (225,000 CMD) and Ongkon-yuan (36,000 CMD) water treatment plants. A Taiwanesecopany, Kintech Technology Co., is in charge of the design and operation of these membrane units. The company produces its own PVC membranes for the

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ultrafiltration units and imports RO membranes for the LPRO units. The UF membrane has a pore size of 0.1 m, a hydrophilic surface and acid tolerance (pH 2-13). The silt density index (SDI) of the UF effluent can be maintained lower than 2 and the operation pressure is set at 1.0 kg/cm2.The material of the spiral wound LPROmembranes is thin film composite polyamide (TFC-PA)

1.3 Industrial wastewater reclamation and process water production


(a) CMP wastewater reclamation: UF+RO Taiwan has become the fourth largest semiconductor manufacturer worldwide. The industry generated a gross production of US$ 53.33 billion in 2010, accounting for 12% of the gross national product. Chemical mechanical polishing (CMP) has emerged as a preferred planarization technology in the manufacture of multilevel integrated circuits (IC), and both dielectric and metal films are amenable to planarization using CMP As the IC size . grows smaller than 250 nm and the wafer size expands to 8 inch and beyond, CMP is the only polishing technique that can provide global planarization. However, CMP consumes a large amount of ultrapure water. In 2007, about 320,000 CMD of CMP wastewater was produced in Taiwan. In general, the CMP wastewater contains sub-micron particles and has high alkalinity, turbidity, total solids content and silica content. Most semiconductor manufacCMP wastewater

ers in Taiwan use coagulation flocculation to treat the CMP wastewater. However, semiconductor manufacturers inside the Science Parks in Taiwan are requested to recycle 65-75% of water from the total consumptive use and 80-85% of water in the production process. It is estimated that almost 30-40% of ultrapure water is consumed in the CMP process in the semiconductor fabrication plant (commonly called a fab). As the conventional coagulation flocculation treatment cannot meet the requirement, the membrane separation process has become more and more popular in treating the CMP wastewater (Pan et al., 2005) Figure 2 is a flowchart of the CMP wastewater treatment process in a fab of Taiwan Semiconductor Manufacturing Company, Ltd. In this CMP wastewater stream, oxideCMP and metal-CMP are mixed and the average particle size of the wastewater is around 173 nm. By using UF the conductiv, ity, turbidity, silica and TOC in the wastewater can be reduced to 80-100 S/cm, 0.03 NTU, 50 ppm and 500-700 ppm, respectively. Activated carbon and ion exchange resins are applied to polish the UF effluent before it enters the RO unit. RO, the final unit, ensures the effluent quality meets the requirements of recycling water before the effluent is recycled to the ultrapure water production system. The conductivity, turbidity, silica and TOC in the RO effluent are 5-10 S/cm, 0.003 NTU, 1.5 ppb and 20 ppb, respectively.

Pre-filter + Ultrafilter

Activated carbon

Ion exchangers

RO

UPW pretreatment

On-line Monitor Conductivity 80-100 s/cm : Turbidity : 0.03 NTU Off-line Moniotor Silica : 50 ppm TOC: 500-700 ppb

On-line Monitor Conductivity: 5-10 Silica : 1.5 ppb TOC : 20 ppb Turbidity : 0.003 NTU

Figure 2. Flowchart of the CMP wastewater treatment process s/cm


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Technology Development
(b) Ultrapure water production: UF/RO/UF To meet the requirement of recycling 80-85% of the process water and 65-75% of the total water used, electronic manufacturers are forced to recycle and reuse wastewater. However, as shown in Table 1, the requirements of ultrapure water quality in the electronic industry are very high, especially in the 12 inch IC fab. Therefore, in the final polishing step in the ultrapure production system, the UF unit is always applied to ensure the ultrapure water quality. The pore size of the UF membrane is usually around 6,000 to 10,000 Da. For example, the pore size of the final UF is 6,000 Da at an 8 inch fab and 10,000 Da at a 12 inch fab of a semiconductor manufacturer in the Hsinchu Science Park. Due to the requirement of a high recovery rate of ultrapure water in fab, two UF units are connected in series in the process to attain 100% recovery. Membrane cleaning (physical and chemical cleaning) is not usually used in the final UF unit in order to avoid contaminating the ultrapure water. UF membranes are replaced when the trans-membrane pressure (TMP) increases to 2.5 bar. The Microza OLT series produced by Asahi (Pall Corporation) are the major UF membranes used in the semiconductor industry. UF membranes are also used as a pretreatment of the RO influent whose pore size is usually around 15,000 to 50,000 Da.
Unit Specifications
12 IC fab 8 IC fab TFT LCD Color Filter 17 10 241 1/mL PDP 17 10 241 1/mL 10/mL BGA 17 10 241 PCB 1 10 241 -

Item
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Resistivity (at 25 ) Bacteria Tem perature Partic les smaller than 0.2 nm Partic les smaller than 0.1 nm Partic les smaller than 0.05 nm Dissolved oxygen TOC Chloride SiO2 Sodium Calc ium Anio ns: NH4,Br,F,NO 3 ,PO 4 Metals:Al,Ba,Cr,Cu,Fe,Li,Mg Boron

M -cm 18.2 CFU/L 1 241 100/L 100/L 200/L 1 1 0.05 1 0.03 0.05 0.02 0.02 0.05

18 5 241 9 2.5 0.2 3.5 0.2 0.2 0.2 0.2 0.2

18 10 241 1/mL

ppb
ppb ppb ppb ppb ppb ppb ppb ppb

4/mL 10/mL 10/mL


-

30 mg/L 30 mg/L 30 mg/ 30 mg/L 30 mg/L 30 mg/L 1 1 1 -

Table 1. Requirements of ultrapure water quality in the electronic industry (c) LCD wastewater reclamation Taiwan has become the second largest TFT-LCD (Thin Film Transistor Liquid Crystal Display) producer within two decades. Amount of wastewater discharged from the manufacturing TFT-LCD has substantially increased (exceeding 200,000 CMD). Organic
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solvents used in TFT-LCD manufacturing processes account for more than 33% of the total TFT-LCD wastewater. The main organic components of the TFTLCD wastewater are the stripper (ie, dimethyl sulphoxide, DMSO or monoethanolamine, MEA), the developer (tetra-methyl ammonium hydroxide,

TMAH) and chelating agents (Chen and Chen, 2004). These compounds are categorized as non- or slow-biodegradable organic compounds. Therefore, membrane bioreactors (MBR) having high MLSS and excellent organic compounds removal are considered a promising technique for the TFT-LCD wastewater treatment. In 2000, the first MBR unit using Zenon hollow fiber membranes, which has a capacity of 1,270 CMD, was built in a TFT-LCD factory. Two more MBR units using Zenon hollow fiber membranes were then installed in two TFT-LCD factories with a total capacity of 800 and 4,200 CMD in 2002 and 2003. Zenon Environmental Inc. takes most of the MBR market in Taiwan. The company has constructed MBR units in more than 12 factories with a total capacity of about 82,000 CMD in Taiwan. Some of the factories combine MBR and RO to recycle wastewater. After using MBRs, the BOD, COD and total nitrogen in the wastewater can be reduced to 6.5, 35.2 and 34.2, respectively. Moreover, SDI in the MBR effluent can be maintained at less than 2.3, which improves the RO performance in recycling wastewater.

are now carrying out these projects: the R&D Center for Membrane Technology (CMT) at Chung Yuan University, the Water Research Center at National Chaio Tung University and the Industrial Technology Research Institute (ITRI).

2.1 R&D Center for Membrane Technology(CMT) at Chung University

Yuan

2 Government-funded pilot projects


In Taiwan, fundamental research on membranes is versatile and has grown steadily in recent years. However, almost all the membranes and integrated systems for desalination and water treatment in Taiwan are imported except for a few microfiltration and ultrafiltration membranes. Also, the setting up of advanced membrane processes still largely relies on foreign companies. In an attempt to close the gap between academic research and industrial application, the government has funded several pilot projects with an aim to eventually transfer the technology to industries. Three prestigious research institutes in Taiwan

The Center, led by funding director Prof. Juin-Yih Lai and director Prof. Kuo-Lun Tung, is a comprehensive membrane technology center. It is a leader in several fields of fundamental membrane research in Taiwan, such as membrane formation mechanisms, morphology-control techniques, membrane modification techniques, measurement of membrane charges and measurement of free volume (e.g. Positron Annihilation Lifetime Spectroscopy (PALS) technique). The Taiwanese government has funded the Center three projects to help it extend its bench-scale expertise to pilot-scale. One of the projects is funded by he Ministry of Education, with the mission to set up a comprehensive platform for membrane research for both local membranologists and the international membrane society. The other two projects are funded by the Ministry of Economic Affairs, with a special focus on the application of membrane technology in environmental protection, such as the recovery of organic solvents, wastewater treatment and desalination techniques.

2.2 Water Research Center at National Chaio Tung University


The Center, led by Prof. Chihpin Huang, was integrated into the Disaster Prevention Center at National Chiao Tung University in 2009. The Center has 4 postdoctoral fellows, 7 research assistants, 6 PhD students, and 33 masters students dedicating to water-related research. The
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Technology Development
objective of this Center is to maintain a balance between fundamental research and applied studies. The former is principally funded by the National Science Council (NSC) and the Water Resources Agency of the Ministry of Economic Affairs. The latter is largely funded by Taiwan Water Cooperation. The Center focuses on three main research fields: membrane technologies, nano-scale catalysts and public water supply. In membrane technologies, the TiO2 composite membrane in membrane bioreactors, nano-silver surface modification of RO membranes in seawater desalination and ultrasonic time-domain reflecometry for monitoring membrane fouling have been developed to mitigate membrane fouling. In nano-scale catalysts, a novel nano TiO2/ FeO composite (NTFC), which can retard the electron-hole recombination in TiO2 and the formation of oxide layer on the surface of FeO, has been synthesized to enhance the degradation of organic contaminants in water. In public water supply, a novel supervisory control for coagulant dosing has been developed and a high-purity PACl coagulant has been prepared and applied to improve the performance of water treatment plants. Sludge from water treatment plants has also been reused in brick-making to reduce waste. In addition, operational performance evaluation and enhancement (OPEE) have been established for upgrading performance in water treatment plants. Each year the government funds many research projects at ITRI. The development of electrodialysis techniques seems to be a major interest for the Water & Environment Analysis Technology Division, currently led by Dr. ShanShan Chou. The group has helped more than 10 companies construct electrodialysis units to recover water from wastewater, with the largest unit having a capacity of 2,400 CMD. This group is also involved in the development of MBR systems for wastewater treatment. They have helped several companies to build MBR units, the largest of which has a capacity of 5,000 CMD. In addition, they are currently cooperating with a local company to develop a new membrane for MBR. A pilot unit with a capacity of 800 CMD has been built to test this new membrane.

Technology Development

Summary
Due to the limited water resources in Taiwan, the development of advanced membrane technologies is crucial to water sustainability. We believe more and more membrane units will be constructed in Taiwan for desalination, water treatment as well as wastewater treatment and reclamation in the near future.

References
Chen, T.K, Chen, J.N., 2004. Combined membrane bioreactor (MBR) and reverse osmosis (RO) system for thin-film transistor-liquid crystal display TFT-LCD, industrial wastewater recycling. Water Science and Technology 50(2), 99-106. Lai, J.Y., Tung, K.L., Liu, Y.L., Chung, T.W., Lee, K.R., Wang, D.M., 2009. Membrane researches and applications in Taiwan. Membrane 34(1), 26-33. Pan, R.J., Huang, C., Jiang, W., Chen, C., 2005. Treatment of wastewater containing nano-scale silica particles by

2.3 Industrial Technology Research Institute (ITRI)


ITRI is a national-level applied research organization which works across multiple industrial technology fields. It is devoted to R&D closely relevant to the industries and makes a great effort to improve Taiwans industrial technolo23

dead-end microfiltration: evaluation of pretreatment methods. Desalination 179, 31-40. Water Resources Agency, 2010. Statistic of Water Resources, 2341-01-03. Water Resources Agency, Ministry of Economic Affairs, Taiwan.

The National Centre for Excellence in Desalination, Australia


Neil Palmer, CEO, NCEDA David H Furukawa, Chief Scientific Officer, NCEDA

1 Introduction
The National Centre of Excellence in Desalination Australia (NCEDA) was established in 2009 from a Federal Government initiative to lead research and build national capacity and capabilities in desalination. It is a consortium of 13 partner organisations with Murdoch University as the Administering Organisation.

Table 1 Partner Organisations

CSIRO Curtin University of Technology Deakin University Edith Cowan University Flinders University Monash University Murdoch University* University of NSW University of Queensland University of South Australia University of Technology Sydney Victoria University University of Western Australia *Administering Organisation

Its establishment followed a period of consultation with universities, research organisations and the industry. A research roadmap was produced to guide the Centre to deliver on its mandate to: Optimise and adapt desalination technology for use in Australias unique circum stances Develop suitable desalination technology for use in rural and regional areas Efficiently and affordably reduce the carbon footprint of desalination facilities and technologies Five priority research themes were established: Pretreatment Reverse osmosis desalting
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Technology Development
Novel desalting Concentrate management Social, environmental and economic issues Each of the 13 partner organisations contributes a membership fee to cover the administrative costs of the Centre. This entitles them to apply for grants from a $20m Federal Government fund over a five year period which is administered by the Department of Sustainability, Environment, Water, Population and Communities. There have been two funding rounds in April and October 2009 which have committed approximately $5.9m to a total of 23 approved research projects. Finalisation of these projects is subject to completion and execution of Project Agreements with the Administering and Partner Organisation. It should be noted that the two rounds of funding so far include $5.9m of Centre funds, $13.2m of in-kind contributions from partners and $2.3m in leveraged cash from industry, a total of $21.7m of research activity. Nanostructure of diatoms: A predictive model for species sustainability: Flinders University, SARDI, SA Water Highly productive and selective bioorganic hybrid membrane water filters: The University of Queensland, Stanford University Management of brine disposal into inland ecosystems: Edith Cowan University, WA Centre of Excellence in Ecohydrology, Rio Tinto (Dampier Salt Ltd), Water Corporation, WA Department of Environment and Conservation Membrane flocculation hybrid system as pretreatment to brackish water reverse osmosis desalination system: emphasis on chemical use reduction and recovery: University of Technology Sydney, Curtin University, IFTS France, KAUST Saudi Arabia, State Water NSW, Coliban Water, Steri-flow Filtration Systems Reverse osmosis brine management by membrane distillation crystallisation: Victoria University, CSIRO, CWMWater, Siemens, Osmoflo Public perception of, and response to, desalination in Australia: Deakin University, Victoria University, Murdoch University, Edith Cowan University, Melbourne Water, Yarra Valley Water Reuse of reverse osmosis membranes: The University of New South Wales, Victoria University, Monash University, SkyJuice Foundation, Water Corporation, DOW Chemical, SA Water, Sydney Water

Technology Development

2 Round 1 Projects and Partners


Developing highly conductive graphene electrodes for capacitive desalination: University of South Australia, SA Water Development of a novel low grade heat driven desalination technology: The University of Western Australia, WA Geothermal Centre of Excellence, BHP Billiton, Worsley Alumina Evaluation of vibratory shear membrane technology for concentrate minimisation & brine recovery/recycling: Curtin University, Monash University, Orica Watercare, Water Corporation, New Logic Research Inc., UTEP High water recovery inland desalination using membrane distillation with ceramic membranes: The University of Queensland, Victoria University, Ceramipore, Tarong Energy, The Pumphouse
25

3 Round 2 Projects and Partners


Assessing and mitigating environmental impacts of SWRO outfalls on marine benthic organisms: Deakin University, University of Western Australia Tjuntjuntjara remote inland indigenous community solar/waste energy groundwater desalination project: Murdoch University, WA Deparment of Housing, Memsys Clearwater Distribution Pte Ltd

Control of organic membrane fouling through limitation and control of extracellular microbial product: Murdoch University, Environmental Biotechnology Co-operative Research Centre Application of capacitive deionisation in inland brackish water desalination: University of South Australia, LT Green, Power and Water Authority, SA Water Silica removal from groundwater for reverse osmosis water recovery enhancement and waste brine volume reduction: Victoria University Strategies for membrane fouling control in desalination pre-treatment: University of NSW, Curtin University of Technology; Water Corporation, Veolia, Siemens Fertilizers as draw solutes for forward osmosis desalination: a novel approach for fertigation in the Murray Darling Basin: University of Technology Sydney, Korea University, Yale University, NSW State Water Corporation, SK Energy Real time detection and management of biofouling conditioning films in seawater reverse osmosis: University of NSW, University of SA, InPhaze Pty Ltd, SA Water, Sydney Water Development of universally applicable coatings and additives for state of the art reverse osmosis and pre-treatment: Flinders University, Wind Prospects Pty Ltd, SA Water, Siemens Mitigation of biofouling using natural polysaccharide surface coating: CSIRO Non brittle ceramic hollow fibre membranes: Monash University Development of cleaning guidelines for desalination membrane users: Victoria University, Nalco, Integrated Elements

Committee, chaired by Mr Larry Lopez, access to venture capital and management support is available to assist the commercialisation process. The Chair of the NCEDA is Mr Graeme Rowley, a Director of Fortescue Metals Group. The Chair of the Research Advisory Committee is Mr Rhett Butler of Siemens Memcor. These appointments reflect underlying commercial acumen to balance the significant academic participation through the partner organisations. The Chief Scientific Officer (Mr David Furukawa), is one of the best know proponents of desalination with broad and long international experience across industry and academia. The Centres Chief Operating Officer (Sharon Humphris) and Commercialisation Manager (Dr Patty Washer) have very extensive experience in translating research to commercial outcomes. An experienced Facility Manager from the desalination industry is expected to be appointed in the near future. The focus on commercial outcomes means that we would like to see a bias toward applied research. However, the result of the current two rounds based on requests for proposals has resulted in a slight bias toward fundamental research. The Centre is considering a different approach to the next funding round so that there is more opportunity for practical design and operating issues to drive future projects.

5 Research Mandate Coverage


Analysis of the projects approved to date suggests there is a good coverage of the Centres research mandate and priority research themes. New technologies that are worthy of mention include capacitive deionisation, a technique to optimise removal of salt ions without the need to push water through a membrane being undertaken by University of SA. Membrane distillation, a technique to pass water vapour rather than liquid water through a mem26

4 Commercialisation
The Centre has a very strong commercialisation focus and promotes the development of marketable ideas. A condition of funding is that the Centre retains ownership of intellectual property developed as a result of the project, with licensing rights for participants. Through the Centres Commercialisation Advisory

Technology Development
brane is a potential to reduce energy, provided a source of heat is available. Solar energy is being considered in the Tjuntjuntjara project in outback WA. There are a number of projects looking at reducing concentrate volume and examining impact of concentrate on inland ecosystems, important issues for remote and regional Australia. One project is examining public perception of desalination amongst Australians, and another considering re-use of reverse osmosis membranes as an alternative to going to landfill. A novel approach using forward osmosis is being examined with concentrated fertilizer as the draw solute. This will increase efficiency of fertigation ie using the water supply to distribute essential nutrients to crops.
Technology Development

6 Collaboration
A significant benefit of the Centres operation has been to facilitate and encourage collaboration between Australian universities and research institutions, water utilities and private companies. There has also been significant international collaboration which exposes the Australian desalination

research community to leading thinkers and encourages interchange through fellowships and post doctoral opportunities. Eleven international companies and overseas universities are currently included in the Centres research programs. The interaction of the Centre with private industry is intended to help build up industry capability. However, this has not been developed as much as we would like and needs more focus. Activities of direct relevance include seminars and training courses (technical and commercial), provision of on site testing locations, opportunity to contribute the Centres visitor facilities, sponsorship of the Rockingham Desalination Research Facility. A sequel to the first Biofouling Seminar held in Fremantle in October 2010 is scheduled to be held in late June in Sydney. The NCEDA will contribute to the upcoming IDA World Congress to be held in Perth in September 2011, which will coincide with the Centres Grand Opening, an event expected to provide significant international exposure.

27

7 Research Facility Progress


The Rockingham Desalination Research Facility is located at the Rockingham Campus of Murdoch University. It comprises a substantial two storey solid construction building (the former Engineering school) and will include offices, laboratories, a workshop and pilot plant testing area. Design of the new facility has been undertaken by CH2MHill and a contract is about to be let for the building modifications and the pilot testing facility.

Figure 1 The Rockingham Desalination Research Facility Three bores have been drilled to tap into two underground aquifers. One is high salinity (about 80% seawater), one brackish (less than 1,000 mg/L TDS) and a recharge bore into the saline aquifer for disposal of combined permeate and concentrate. The pilot testing facility will comprise a tank farm for blending feed water, a reticulated feed supply to six tie-in points, drainage, power supply and access to an instrumentation and control system. Construction of the facilities is expected to be complete in early June, although some testing work is expected to commence before this to meet project deadlines.

8 Conclusion
The NCEDA is now into its second year with a strong sense of achievement in terms of establishment, appointment of key people, research projects and progress on the Rockingham Facility. 2011 will be big year in terms of activity with the end of the year seeing completion and full operation of the Rockingham Desalination Research Facility with pilot scale projects, research laboratories, office facilities for partner organisations, a multimedia conference and visitor centre and a hands on Edulab for practical demonstration of water science and desalination technologies. Our ultimate objective is to establish a sustainable centre for research and industry capability development of international renown which reflects the can do attitude underpinning Australian know-how.

28

Technology Development

Water Desalination in the Indian Context


Saly T. Panicker & P K. Tewari Desalination Division, Bhabha Atomic Research Centre, .

1 Introduction
Population and economic growth are causing pressure on freshwater resources around the world. India has a highly seasonal pattern of rainfall with 50% of rain falling in 15 days and most of the river flows occurring in just four months. There are areas such as the coastal regions of Tamil Nadu, Saurashtra and Kutch, Western Rajasthan, etc., which face perennial water shortage. In several parts of the country, the ground water has total dissolved solids ranging from 1000 to 3000 ppm. In some other parts, people are known to be suffering from excess fluoride, nitrate, iron, arsenic and microbial contaminations in the water. Hence, a holistic approach is required to cope with the freshwater needs of the country. It includes, water purification brackish water desalination seawater desalination in coastal areas recovery of water from effluents for reuse conventional water supply schemes including rainwater harvesting

while contribution of Council of Scientific & Industrial Research (CSIR) is in the field of RO and Electrodialysis (ED). Defence Research Laboratory, Jodhpur has also developed ED system. National Institute of Ocean Technology (NIOT) is engaged in development of desalination systems using ocean thermal energy. Some of the Indian Institutes of Technology (IIT) and universities are also engaged in developmental activities on desalination/water purification technologies.

2.1 Membrane Desalination

Technology Development

The developmental efforts of the national laboratories and public & private sectors have led to the installation and operation of RO plants of capacities ranging from Kilo-Litres per Day (KLD) to Million Litres per Day (MLD), in water scarce coastal areas of India to provide potable water from seawater.

2 Status of Desalination in India


In India, desalination has potential as a possible means to augment water supply for meeting the growing demand of clean water. Requirement exists for all sizes of desalination plants, ranging from small and community size to large capacities. The growth of industry has encompassed the entire spectrum ranging from small to large capacity plants utilizing both the thermal and membrane routes. Bhabha Atomic Research Centre (BARC), Mumbai is engaged in developing advanced Reverse Osmosis (RO) and Thermal Desalination technologies,
29

Fig.1 SWRO Plant at NDDP Kalpakkam ,

BARC has developed design methodology of seawater Reverse Osmosis (SWRO) system and based on the experience gained from the 100 KLD SWRO plant at Trombay, it has setup a 1.8 MLD SWRO system (Fig.1) as a part of Nuclear Desalination Demonstration Plant (NDDP) at Kalpakkam. The product water is supplied to the drinking water reservoir. Apart from this, desalination plants (5 KLD capacity each) for disaster management were designed and installed in the tsunami affected areas in the south east coast. The design features of these units are such that, they could operate under wide range of feed water quality in terms of physical, chemical and biological contaminants with minimal pretreatment. Fig.2 shows pictures of the trailer mounted desalination unit.

Fig.3 Indigenous Membranes Developed in BARC a 100 MLD seawater desalination plant at Chennai on DBOOT basis set up by IVRCL, Hyderabad along with BEFESA, Spain. BARC has provided technical advice for the plant. Another 100 MLD seawater desalination plant is under construction at Chennai on Engineering Procurment Construction (EPC) basis. In Gujarat, seawater reverse osmosis plants have been put up for industrial use by several industries.Recently, Ion Exchange India has commissioned a 26 MLD Seawater RO Desalination Plant at Chennai Petroleum Corporation Ltd., Chennai. ROCHEM Separations (I) Ltd. has supplied several small and medium size RO plants for seawater desalination on-board ships and land based applications With time, the design of membrane based desalination system may undergo significant changes. Conventional pretreatment systems may be replaced by membrane based pretreatment (ultrafiltration (UF), nanofiltration (NF) etc.,), providing better operating environment for the RO membrane, thus
30

Fig.2 Trailer Mounted RO Plant A 3.8 MLD sea water RO desalination plant is installed by Bharat Heavy Electricals Limited (BHEL) at Ramanathapuram for state government to provide drinking water for people. Chennai Metro Water Supply and Sewerage Board (CMWSSB) has recently commissioned

Technology Development
helping to extend its life. Energy Recovery systems evolved over the years which are capable of recovering a major part of the energy from the reject stream, may be improved further. Next generation better quality RO membrane may be introduced changing the present scenario to a great extent. National research laboratories such as BARC and CSIR are also involved in the development of membrane. Cellulose acetate and cellulose acetate blend membranes were developed in the early eighties and the technologies were transferred to several parties. These first generation membranes suffered due to relatively poor solute rejection, higher operating pressure and less membrane life owing to chemical & biological deterioration. At present, the laboratories in the country are successful in developing TFCP brackish water membranes in spiral configuration (Fig.3). Efforts are being made to further improve the flux and solute rejection, suitable for seawater desalination. Efforts are also directed towards the development of tailor made membranes for effluent treatment and removal of specific contaminants. The work on development of nano-composite membrane for water treatment and purification applications has been recently taken up by BARC. Ion Exchange (I) Ltd., Goa and Permionics (I) Ltd, Vadodara are the private parties in the country, who have facilities to make spiral elements. National Chemical Laboratory (NCL) Pune is involved in the development of UF membranes. Central Glass & Ceramics Research Institute (CGCRI), Kolkata is working on the development of microfiltration systems in collaboration with BARC. 2.2 Thermal Desalination Development of thermal desalination technologies using low grade and waste heat for seawater desalination was initiated by BARC. Technology was evolved through pilot plant studies. The experience was utilized in the design of a 4.5 MLD capacity Multi-Stage Flash (MSF) system installed as a part of NDDP . The design was aimed at saving energy by designing the plant with a high performance ratio (PR) and less capital cost using long tubes and more number of flash stages with better thermodynamic efficiency. In Lakshadweep islands, a desalination plant was set up for producing 10 KLD of distilled quality water using waste heat of the engine cooling water of a Diesel Generator set. Development of thermal desalination technologies with value addition such as Multi-Effect Distillation (MED), Vapor Compression (VC) and Low Temperature Evaporation (LTE) with cooling tower has also been demonstrated by BARC at Trombay. A 100 KLD desalination system utilizing the ocean thermal energy for seawater desalination was set up and commissioned by NIOT at Kavaratti, Union Territory of Lakshadweep. BARC had provided consultancy on design review to NIOT for this plant, which is based on low temperature flashing process. IDE Technologies (Israel) has installed quite a few MED and MVC plants in the western and southern parts of India. 2.3 Nuclear Desalination Nuclear desalination is defined as the production of potable water from seawater in a facility in which a nuclear reactor is used as the source of energy for the desalination process. Interest in using nuclear energy for producing pure water has been growing worldwide in the past decade. This has been motivated by a variety of reasons from economic competitiveness of nuclear energy to energy supply diversification, from conservation of limited fossil fuel

Technology Development

31

resources to environmental protection and spin-off effect of nuclear technology in the industrial development. It involves three technologies; nuclear, desalination and coupling system. In this, both the reactor and the desalination system are located at a common site and energy is produced for the desalination system. It involves some degree of common or shared facilities, services, man-power and sea water intake & outfall structures.

Fig.4 Nuclear Desalination Demonstration Plant, Kalpakkam BARC has set up and commissioned a first-of-its-kind, the largest nuclear desalination plant based on hybrid technology at Kalpakkam (Fig.4). The hybrid technology has several advantages (Fig.5). It has provision for redundancy, utilization of streams from one to another and production of two qualities of water for the best utilization. The desalinated water produced from MSF is of distilled quality which is good for high end industrial use. The desalinated water produced from RO is of potable quality, which is supplied to nearby areas. The two products can also be blended for either human or industrial consumption. NDDP consists of a 4.5 MLD MSF system and a 1.8 MLD RO system, coupled to Madras Atomic Power Station (MAPS). The requirements of seawater, steam and electrical power for the desalination plant are met from MAPS. The RO unit incorporates necessary pretreatment and an energy recovery system. As many of the water scarce urban areas are lying in the coastal regions, there is a great potential for seawater desalination. These areas are also witnessing rapid industrialization requiring distilled quality water for high end applications. The hybrid technology is thus highly promising in urban areas of coastal regions.

Fig.5 Features of Hybrid Desalination System Another nuclear desalination plant of 30 KLD capacity based on low temperature evaporation is coupled to the CIRUS reactor at Trombay, for utilizing a part of the waste heat from the Primary Coolant Water (PCW) system and produces desalted water to meet the make-up water requirement of the reactor (Fig.6).
32

Technology Development

Fig.6 Desalination Plant Using Waste Heat of CIRUS, Trombay India now leads the world in nuclear desalination. BARC (India) is active as a member of the Technical Working Group on Nuclear Desalination (TWG-ND) of International Atomic Energy Agency (IAEA) for providing advice and guidance for activities on nuclear desalination. BARC has been participating in Coordinated Research Projects (CRPs) of IAEA, sharing the expertise on nuclear desalination with other Member States such as Argentina, China, Egypt, France, Indonesia, Israel, Russian Federation, Saudi Arabia and UAE. Technocrats from different countries have visited the nuclear desalination facilities in India for undergoing training under IAEA Technical Cooperation and bi-lateral programs.

Technology Development

3 Conclusion
Cost of desalination is one of the challenges involved in setting up more number of plants in India. For arid or coastal areas, locally produced water through desalination may be cheaper than transporting it from far away places. Affordability, acceptability and accessibility are the key concerns being addressed by the desalination community in the country. The on-going R&D efforts towards improving the efficiency & life of the systems and usage of cheaper materials are expected to help growth of the desalination industry.

4 References
1. P K. Tewari, The Potential of Desalination in India, Int. J. Nuclear Desalination, Vol2, . No. 4 (2007) pp 303-310 2. P K. Tewari, Nuclear Energy for Water Security, Atom for Peace : An International Jour. nal, Vol 1, Nos. 2/3 (2008) pp 199-205
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The Study of Chinese Desalination Development 2010-2011

Kun Yang, Youzhi Guo, Yan Yang

1National strategies of desalination


China is a developing country with the huge pressure of energies and resources incomparable with any other countries in the world due to the huge population, and the development of blue territories is much more significant to future development of China. Therefore, the level of Chinese desalination development will influence developing status and economic decision-making of China. Some experts predict that by 2030 the population of China will reach 1.516 billion, and the crisis of water shortage may be much more serious than that of energy. Developing the technology of seawater utilization including seawater desalination and direct utilization of seawater to industry and living will not only support realization of the next economic goal, but also directly determine survival and development of the Chinese nation. As the Ministry of Land and Resources surveyed, among over 660 cities in China, there are over 400 cities lack in water, 114 of which suffer severe water shortage, 71 in north China and 43 in south China.

Even in the drainage area of the Changjiang River, there are still 59 cities and 155 counties with water shortage. In terms of the global orientation of water resources in China, the reserves of water resources is 2800 billion m3, which is in the sixth place in the world, but the reserves per capita of fresh water resources is only 2125 m3, which is only 1/4 of global level, China is therefore classified as one of the 13 water-poor countries by the United Nations. Especially in coastal areas covering 2/3 of Chinese economic aggregate with developed economy and dense population, the per capita water resources is mostly below 500 m3. By the end of 2009, the population in Beijing had increased sharply to 19.70 million, and the per capita water resources is 126.6 m3, which had replaced Tianjin (per capita water resources of 126.8 m3 ) as the largest city with water shortage in China. (Refer to the General Plan of Social and Economic Development of Beijing in 2010). Besides energy, water shortage has become the primary bottleneck restricting social and economic development in China.
34

Technology Development
For some time, groundwater exploitation and water transfer are both vital methods to solve water shortage in China. However, these meth ods can only solve the problem of uneven spatial and temporal distribution of water other than increasing the overall reserves of fresh water resources. In long views, the reserves of fresh water in China is relatively stable, but the need for fresh water in economic and social development is rigidly increasing. Hence, besides saving the limited reserves, new increment must be achieved. Industrialization of seawater utilization in coastal areas may save much more fresh water for the inland, which means that the reserves of fresh water is increased successively. In this sense, industrialization of desalination not only can resolve the conflicts of fresh water supply in coastal areas, but also has strategic significance to generally solve the problem of water shortage in China. The National Development & Reform Committee plans that about 1/3 of water consumption in coastal areas can be supplied through desalination before 2020. 2 Rapid expansion of desalination capacity By Oct. 2010, 65 sets of desalination facilities have been established, and the daily desalination capacity has nearly reached 612.6 thousand m3, which has surpassed the last year by 52%. The capacity of the largest desalination project under construction is 100 thousand m3 per day. Generally, desalination market of China is quickly growing to a regional market with certain global influence and great improvement on component supply, equipment manufacture, assistant equipments, engineering design and installation. The desalination in China is under quick industrialization promoted by market demand, however, the core elements of desalination are still dispersed, and there is still no core enterprises driving the development of desalination. Besides, the bottleneck and problems blocking development of desalination in China are not solved. Therefore, such condition offers multinationals an opportunity to enter the Chinese market. At present, corporations such as IDE of Israel, BEFESA of Spain, HYFLUX of Singapore have occupied larger market shares. With the continuous development of desalination in China, the average capacity of single facility is successively increasing from 2500 m3 per day in 2005 to over 6550 m3 per day nowadays. The average capacity can reflect the economic level of Chinese projects and the investment capability under a relatively poor status, thus we should realize that we still have a long way to compare with the world level.

Technology Development

35

3 Policy and tendency of desalination In 2006, the National Development & Reform Committee initiated the issuance of Special Plans for Seawater Utilization in China with relevant departments, and the daily capacity of 800-1000 thousand m3 will be reached in 2010. As things go, there is still a big gap between current scale and the goal. According to the analysis, many places in China intend to construct desalination projects, and the most important reason for the gap is the low water price policy of the government, inversion of the cost and price restrains the enthusiasm of coastal areas on constructing desalination projects, and the government does not reach an agreement on the policies of investment and price subsidies. Besides, the problems of ineffective implementation and incompatibility of the policies supporting desalination development are not solved perfectly, for example, desalinated water is still not a part of municipal water supply system, desalination projects have difficulty in investment and financing and can hardly enjoy the national preferential policy on infrastructure projects. Even so, there are still some enterprises and investment corporations exploring positive elements of desalination; they are mostly aiming at long-term development in the future to influence the future structure of Chinese market. For example, the nuclear-power enterprises plan to deal with desalination industry, integrate market factors and attempt to form the management structure of water and power integration. The capacity of desalination coordinated by coastal power enterprises is 70-80% of the gross

capacity in China; it seems feasible for thermal power plants to develop desalination, however, the 5 larger power enterprises are much more interested in investing maritime solar and wind plants than seawater desalination projects; some steel and equipment manufacturers plan to engage in seawater desalination; in addition, chlor-alkali and soda enterprises are researching the coupling technique of chlor-alkali and desalination, and if the process can be optimized, it will be a new choice for the new coastal chlor-alkali projects. Though Chinese desalination has owned basic conditions of industrialization, it still has a long way to go in aspects such as research level, innovation capability, development and manufacture of equipments, design and integration of systems prominently reflected in the facts that the ability of scientific and technical innovation is relatively weak and the core technology and equipments still depend on foreign suppliers. Moreover, the uneven development of Chinese desalination and the unreasonable industrial chain reflect that the market mechanism needs to be further improved. In terms of technology and products, it is crucial to cut down the cost of desalination, and the long-term targets of desalination are promoting the localization of core parts such as membrane, materials of membrane and key facilities, intensifying R&D for new technologies, procedures, facilities and products of desalination with independent intellectual property, and enhancing the capability of constructing largescale desalination projects by ourselves.

Table 1 Statistics of construction of desalination devices in China during the recent five years (quantity & scale)
Category Time 2010Capacity of already established devices Quantity (set) 65 Total capacity 10 m /d 61.26
4 3

Capacity of the devices under construction Quantity (set) 2 Total capacity


3 104 m /d

15

* The total capacity contains the non-operated parts of the already established devices * Source of data: China Desalination Database
36

Technology Development
Table 2 Desalination projects completed and put into operation in 2010
Project name Desalination pro ject of Tian jin Technical type MED Capacity (104 m 3 /d) 100000 Industry Area

Northern Border Po wer Plant Desalination Quzhou Island Desalination project Alkali Factory Laizhou Power Plant Desalination project of Guangzhou Huilai Power Plant Desalination pro ject of Guangdong Huizhou Pinghai Power Plant Desalination pro ject of Fu jian Ningde Nuclear Power Plant Desalination
Technology Development

Power

Binhai District Tianjin

pro ject

of of

Zhejiang Qingdao

SWRO SWRO SWRO SWRO SWRO SWRO

2500 7000 7000 17000 17000 11 000

Municipal Chemical Industry Power Power Power Nuclear power

Daishan Zhejiang Qingdao Shandong Laizhou Shandong Huilai Guangdong Pinghai Guangdong Ningde Fujian

Desalination pro ject of Shandong

pro ject

of

Dalian

Hongyanhe Nuclear Power Plant

SWRO

15 000

Nuclear power

Dalian Liaoning

As the above tables show that, the total capacity of desalination has been increased. After 2005, construction of desalination projects has been quickened with averagely 4 or 5 projects finished every year, and the rate of newly-increased capacity of desalination in China is between 35% and 50% for consecutive years.

4 Stably increased market demand


With decades of development, the Chinese market of desalination has formed a certain structure. A lot of coastal industrial enterprises have adopted desalination because of the advantages of surplus heat utilization and co-generation and water and power, and desalination is therefore applied to more and more industrial fields, especially in power industry. However, new changes have happened to desalination in recent years. The industrial transfer of steel and chemical industries to coastal areas promotes the construction of desalination projects as infrastructures of coastal industrial parks, and the rapid growth of nuclear power in the last few years has expanded the new market of desalination. Besides, in the field of municipal water supply, seawater desalination adopted in coastal country37

level islands is another important direction of the development. Seawater desalination has promoted the development of overall markets of equipment manufacture, project design and installation, anti-rot materials and technical services, etc. At present, the domestic market scale has been up to thousands of billion RMB per year. Desalination is mainly applied in the following fields: 1.Boiler water used in power industry. The rapid growth of this market is mainly oriented by the national industrial policy stipulating that the newly established coastal projects must adopt desalination as the water source, therefore, desalination has been widely applied due to the competitive advantages of renewable resources and low cost. Consequently, the purpose of optimizing the structure of industrial water consumption is achieved; the market space of seawater desalination is expanded more quickly, and

s p b c w w a w m u w I w 2 s t a e p s c t h b p 3 r a T m r a t i c l s s

such condition is same for the boiler water market of power and metallurgy industries. It is estimated that, before 2010, the newly increased power in the coastal areas of China will be at least 35000 MW, which needs over 180 thousand tons of boiler water with high quality. At present, the procedures of adopting desalinated seawater to supply boiler water in coastal power plants have been relatively mature, e.g. the North China Power Bureau plans to universally adopt desalinated seawater as boiler water while establishing new coastal power plants. In coastal areas, desalinating seawater as boiler water will be the mainstream of the power industry. 2.More desalinated seawater is used as the water supply for coastal steel and petrochemical industries, ports and boilers because of the integrative advantages of the large quantity of low pressure exhaust gas and residual heat generated during production. In order to opti mize the water supply structure, realize heat balance, reduce production cost and guarantee reliability of water for production, more and more coastal industrial enterprises have adopted seawater desalination facilities and become the new customers of desalination projects. 3.Due to the unreasonable distribution of water resources, most coastal areas suffer water shortage, which is much more serious in many islands. The water supply only depends on rainwater accumulation and shipment from the land, the cost may reach RMB50/ton, and the water supply is not guaranteed upon bad weathers. Seawater desalination may guarantee the water supply for the islands. The coastline of China is over 18000km, the coastal areas have developed economy and large demand of fresh water, and there are thousands of inhabited islands. Therefore, such market space is huge.

According to different water quality, temperatures and geographical conditions, some characteristics are reflected in technical development and market of seawater desalination in China. The south parts such as Zhejiang and Guangdong have better water quality and lower annual temperature difference, and the water shortage is mainly on islands and large industrial enterprises. Therefore, the water supply scale is small, and the requirement to cost is high. According to statistics, except several projects adopting the combination of reverse osmosis membrane and thermal method, the reverse osmosis is mainly adopted. The capacity of a single set of facility is usually below 2000 tons. Electrical energy is the main cost for smaller reverse osmosis devices, and the price of power supply may greatly influence profits of the projects. The main consumers are island water supply and enterprises, especially the power plants. At present, other projects with better prospects are Caofeidian Industrial Park Seawater Desalination Project, Baosteel Zhanjiang Iron Base Project and the nuclear power projects under planning and construction. The seawater desalination through thermal method assisted by membrane method under low temperature and multi-effect mode is applicable to the areas with worse water quality and larger temperature difference in northern China. At present, the desalination plants with the largest scales and most advanced technology adopting the advanced imported equipments and constructed by foreign contractors, such as Tianjin North Border Power Plant constructed by IDE, Shougang Tangshan Steel Project constructed by SIDEM and Tianjin Dagang HYFLUX Desalination Plant constructed by Singapore HYFLUX, are gathered here. The thermal method applies residual heat exhaust systems or cooling systems of steel plants, thermal power plants and nuclear power stations to provide steam for water production. The main projects with prospects in the future are large-scale industrial enterprises in Tianjin, Shandong and Hebei, some of which are planned with municipal water supply functions.

5 Characteristics of seawater utilization environment

38

Technology Development
China with the annual capacity of 1.2 million m2 and over 2000 pieces of composite membranes and solving the crucial technology of membrane and component production, and there are almost a hundred of water treatment corporations and associated product enterprises with the annual production value up to over RMB 2 billion. In recent years, two production lines of RO composite membrane with the annual production capacity of 2 million m2 have been established in Hangzhou and Guiyang through importing advanced technologies and equipments. The components of composite membrane for seawater desalination have been developed, the localization of membrane pressure vessels for seawater desalination have been basically realized, and the designing capability for complete set of desalination project has been possessed. In 2008, China Blue Star Group and Japan Toray Industries Inc. jointly established a plant of RO modules in China with the annual productivity of 6.17 million m2. Besides technical problems, seawater desalination is also influenced by project management and financing, etc. Therefore, full support of government is essential to development of desalination. In this respect, China still needs careful research and scientific development compared with foreign countries. In recent years, more and more foreign corporations have entered into Chinese market and occupied larger market shares with mature technology and powerful capital advantages, while Chinese enterprises seems to be inadequate on financing. The process of multiplied investment in Chinese desalination is still under the beginning stage, so the sustained support of government on policy, investment and infrastructures, etc. is most crucial. The domestic demand for desalination at present as well as in the future will create opportunities for enterprises in the forms of BOO and BOT.

6 Engineering-oriented capability and associated industries


Through R&D and demonstration of almost 40 years, the seawater desalination in China has formed the tendency of industrialization and laid solid foundations for large-scale application. Among the already established seawater desalination facilities, reverse osmosis (RO) and multieffect distillation (MED) are the most popular methods, whose capacity covers 95% of the total capacity, that of multi-stage flash (MSF) covers about 5%, and that of electro-dialysis (ED) & vapor compression (VC) covers less than 1%. According to the development trends, no other methods than RO can meet with the situation of China. As for the condition of practical applications, RO has greater advantages in municipal water supply, and MED also has certain competitive advantages to produce boiler water and fresh water in power plants as well as petrochemical enterprises with low-grade steam or residual heat. The research and development of key materials, components and equipments such as the energy recycling and variable-frequency control are under active development to largely reduce the energy consumption of RO desalination. In the recent 10 years, the technology of RO in China has a rapid growth and has become the major desalination method. At present, there are over 40 divisions dealing with desalination research and over 600 enterprises producing associated devices. Hangzhou Water Treatment Technology R&D Center is the biggest desalination engineering corporation in

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Currently, restricted by regional factors and market demand, the Chinese desalination market is mainly for industrial water supply in coastal developed cities. With appreciation of tap water and application of the latest seawater desalination technologies, there will be greater breakthroughs in the development of Chinese seawater desalination industry.

7 Large-scale projects newly established in 2010


1. The first stage of Northern Border Power Plant has a total investment of RMB 12.1 billion, and two generating-sets of 1000MW as well as a desalination device with daily capacity of 200 thousand tons will be constructed. The MED desalination device of Israel IDE Corporation can produce 65.70 million tons of fresh water, and it is the largest desalination device in China up to now. 2.The desalination project of Shougang Jingtang Iron and Steel Base adopts two sets of MED devices with the daily capacity of 12500 tons imported from SIDEM Corporation. The base is the biggest domestic steel enterprise associating desalination devices, and it can balance the economic benefits through residual heat application.

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Technology Development
3.Zhejiang Liuheng Seawater Desalination Project has a designed daily capacity of 100 thousand tons and the total investment of RMB 540 million. The daily capacity of the first stage is 22.5 thousand tons. The project was completed in Sep. 2009, and the desalination system was put into operation in the beginning of 2010 after being examined by experts. After the whole project is completed, it will become the largest desalination project in China at present. 4.Tianjin HYFLUX Desalination Project Tianjin Dagang Xinquan Desalination Project is constructed by Singapore HYFLUX Group with the investment of RMB 1.059 billion. The daily capacity of the first stage is 100 thousand tons, and after the whole project is finished, the daily capacity will be up to 150 thousand tons. The successful test water supply marks that most industrial water is supplied by the Dagang Xinquan Desalination Project.
Technology Development

5.Caofeidian New District Aqualyng Desalination Project was started in Jan. 2011 with the investment of RMB 350 million. It is planned to be put into production in October this year, and 10 million m3 of water can be saved after completion of the project.

8 The anticipation for combination of nuclear power and seawater desalination is worthy of expect.
As experts predicted, the combination of nuclear power and desalination in China will have deep significance in the future, and nuclear power enterprises will grasp the energy and water resources necessary for economic development if they can simultaneously provide power as well as large quantity of desalinated water, which depends on the extent of coupling of two technologies and integration of industrial development. During the period of the Eleventh Five-Year Plan, China reformulates the new Medium and Long-term Nuclear Power Development Plan (2005-2020), which has greatly accelerated the process of nuclear power development. Lead by nuclear power development, the desalination industry faces a new opportunity for development. Nuclear power plants have both the price advantage of energy and the resource advantage of integrated development of water and power. Two major Chinese nuclear power corporations have respectively started to discuss the commercial prospects of associating coastal nuclear power plants with large-scale desalination in the future. Though the coupled technologies of nuclear power and desalination have the encouraging prospect, the industrial integration of them has had

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certain commercial significance. In terms of large-scale nuclear power enterprises, the intensivism of nuclear power projects can reduce the cost because of ready-made utilities such as water-taking facilities as well as water transfer conditions, the new industries can drive development of localized integration capability and manufacturing, and state-owned enterprises are capable of and willing to undertaking social responsibility. Therefore, we can anticipate that the integration of nuclear power and desalination will face opportunities in the future, and enterprises with the above conditions will bring new spaces for development of Chinese desalination if they can seize the opportunities.

nation device in Dalian Hongyanhe Nuclear Power Plant with daily capacity of 20 thousand tons has been formally put into operation. At present, 4 or 5 of the 13 nuclear power plants under planning and construction have planned and designed associate desalination devices, however, it still takes time to plan large-scale water supplying facilities of desalination. The desalination industry has become the industrial component of the blue economy in China, and is bringing infinite opportunities as a new industry. The industrialization of desalination technology can not only resolve the problem of water shortage in China, but also be a new growth point for Chinas economy. In 2010, the Chinese Government decided to support the development of seven new industries to build the future High-tech development structure, and as a vital component of blue economy, desalination has attracted wide attention from the investment field, and during period of the Twelfth Five-Year plan, Chinese desalination industry will have a rapid growth. With the quickened process of marketization of Chinese water resources, desalination will become a new economic growth point and form a gigantic industrial economic scale. According to the National Development Planning, the daily capacity of desalination will be up to 2 million m3 in 2015, and the sales value of desalination equipments will be RMB 48 billion. Hence, the Chinese desalination development has a broad prospect and demonstrates a trend of rapid growth, and there is a huge potential and a rapid growth in desalination demand. As predicted in the future 20 years, the international seawater desalination market will grows most rapidly in the Middle East, and then in China, India and USA.

The first large-scale desalination project of nuclear power enterprise has been completed and put into operation in 2010, and the desali-

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