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INTRODUCTION
Several years ago, the use of plastic in the lighting is beyond the imagination.
But now a days it is quite possible. There are number of plastics both thermoplastic
ground as an excellent means of light control, and through its excellent electrical and
optical properties. In 1930, IG Farben, installed a plant for producing 100 tonnes of
USA was 31 million pounds which shows that the growing trend in using polystyrene
for light control. In India, where there is now a growing emphasis on scientific
The purpose of delivering this seminar to show the way towards effective use
STRUCTURE OF PS
unbranched chain.
~ CH – CH2 – CH – CH2 ~
| |
PREPARATION METHODS OF PS :
PROPERTIES OF PS
v) Low cost.
vi) Hard, rigid transparent thermoplastic which Emits a characteristic metallic ring
when dropped.
viii) Colourability.
luminaire design and performance and considered beyond the scope of the
recommendation.
compounds :
properties.
exposed to UV rays and fluorescent lamp radiation are mainly influenced by the
following.
ii) Oxygen
i) Presence of impurities :
The short chain molecules are produced due to the thermal degradation of
there is a linear relationship between the degree of yellowness and the sulphur
styrene not containing free sulphur. Through combined sulphur may be present in
the range of 0.003 – 0.006 %, it is only half harmful as free sulphur in causing
discolouration.
ultra-violet radiation.
ii) Oxygen :
rushing of iron.
precise role of oxygen and light radiation have been determined in a simple but
effective test. Identical samples of polystyrene were sealed in pyrex glass tubes
tubes containing nitrogen and other inert gases. Showed negligible discolouration
even after 6 year’s exposure. In light, with oxygen or air in the tubes, pronounced
yellowing occure. Samples stored in the dark did not yellow even though oxygen
was present. Since only samples exposed to oxygen and light yellowed, it is easy to
This exposure causes the most severe yellowing of polystyrene when exposed
i) Visible light rang : Located in the central part of the shown spectrum and includes
that portion of sunlight visible to eye as white light, extends form 400-600 m
ii) Infra-red radiation range: Located to the right of the above range and includes the
iii) Ultra-violet radiation range: Located to the left of the visible light range and
Although only 5% of the total sunlight at the earth's surface falls in to the
category of the U.V. radiation, it is the only portion subject because this is the range
Light is a radiant energy and the intensity of its energy varies inversely with
its wavelength. The shorter wavelengths, i.e. the ultraviolet, have the highest energy
to the extent of 82 K calsmole at 350 m which is more than the energy required to
atoms. This absorption of energy activates them to a stage sufficient to cause rupture
of bonds holding these atoms. The result is degradation of polystyrene and the
subsequent yellowing.
fluorescent lamps and also the causes of yellowing, it will be worthwhile to know
radiation and oxygen. This special formulation of polystyrene is called the "Light -
so modified in composition that it can resist the action of oxygen and light in causing
yellowing of polystyrene.
has to be done to keep oxygen away from the polystyrene molecules. To do this,
How does this formulation resist yellowing? The antioxidants combine with
free oxygen and then oxygen is no longer available to degrade polystyrene. That
U.V. absorbers do. These absorbers prevent the reaction and protect polystyrene by
this energy at non-destructive wavelengths before the polystyrene atoms can absorb
these radiation and re-emitting this energy at non-destructive wavelengths before the
agents, stabilisers, fillers, colouring agents, flame retardants and lubricants in to the
Compounding ingradients in the form of fine powder are blended with fine
ambient temperatures which should, however, normally be much below the softing
ANTIOXIDANTS :-
attack that may shorten the polymer's life due to discoloration, cracking, brittleness
and loss of mechanical properties. The scavenging free radical mechanism is widely
The proposed free radical mechanism involving the antioxidant Irganox 1076.
R-R 2 R*
Where,
radical.
Fast
R*+ O2 R*O2
OH
|
R* O2+ C(CH3)3 C(CH3)3
O
| ||
CH2CH2 COC18C37
Irganox 1076
O*
|
RO2H + C(CH3)3 C(CH3)3
O
| ||
CH2CH2 COC18C37
O
||
C(CH3)3 C(CH3)3
O
| ||
CH2CH2 COC18C37
Trade name - AO 68
Chemical structure
C( CH3)3
|
( CH3)3 C O P
ULTRA-VIOLET ABSORBERS :
electronically excited state A*, after which a number of process may occur. These
1) Photophysical process
A* + B Ao + B*
product.
molecules.
Reaction d) and c) occurs much less frequently than reaction a) and c) but do
Examples :
Structure :
OH
N
N
N
CH3
Chemical structure –
O O
|| ||
HN – O – C – (CH2)8 C – O – NH
ANTISTATIS :
polymer. The low amount of water on the surface of the resin results in static
hydroscopic nature of the surface of polymer's surface. This facilitates a leak off
path.
External antistat agents are commonly quaternary amines and ammonium salts.
Examples :
Chemical structure –
O
||
Na – O – S – O – alkane
||
O
Ammonium Sulfate.
Chemical Structure :-
O C2H3
|| |
HO – S – O – CH2 – CH2 – N – CH3
|| |
O C2H5
FLAME RETARDANTS :
that serves a barrier to oxygen penetration and serves to protect the polymer from
heat. Flame retardants cool the combustion by diluting the combustion gases and
Examples :
1) Br Br Br Br
Br – – O – – Br
Br Br Br Br
Great Lakes 83
Brominated diphenyl ether.
2) Br CH3 Br
|
HO– – C – – OH
|
Br CH3 Br
Great Lakes 59
Halogenated bisphenol A
distances ranging from ½” to 3”. The results are shown in table. The change in
change after 2 years. Even in the most severe case of ½”, discoloration is negligible.
Table
Lamp to specimen
Yellowing factor
distance
Inches 12 months 24 months 36 months
½ 0.9 1.4 4.5
1 0.3 0.9 2.0
1½ 0.0 0.3 1.7
3 0.0 0.0 0.6
(Polystron600’) exposed in the fadeometer for 80, 160,320,400 and 500 hours in the
laboratory of polychem.
Table
Time in fadeometer
Yellowing factor
hours, with a rapid, almost autocatalytic range to yellowing factor of 10-71 at 500
hours. In sharp contrast, the light stabilized sample remains practically unchanged
fadeometer has continuous output of radiation in the area of the most harmful
radiation given off by a cool white fluorescent lamp. Particularly noteworthy is the
fact that fadeometer, in contrast to other testing devices, has minimum radiation in
are rotated in the central part of the equipment. The light level is very high, roughly
comparable to that of sunlight on a bright, clear day. The testing is carried out at
Where
Larger the number, greater is the yellowing and hence lower is the light stability.
STABILISED PS
Advantages :
2) Much longer service life 3-5 times long compared with unmodified PS.
Disadvantages :
2) Strength and elongation at break slightly reduced compared with unmodified PS.
most suitably employed in moulding polystyrene lighting fixtures. It has been found
that the fabrication conditions maintained during moulding play important part in the
A) INJECTION MOULDING :
2) The maximum injection pressure utilised for best overall part strength.
the material.
4) If a delay is necessary, the material from the cylinder thoroughly purged out
B) EXTRUSION :-
C) VACUUM FORMING :
This method is commonly used for moulding of luminous ceilings due to its
inherent design flexibility. Since abrupt changes in sheet thickness will show up
more vividly in lighting fixtures than in other commercial products, the forming job
WITH LIGH-STABILISED PS
1) Injection Molded Louvers for diffused lighting either singly or in continuous lengths for
luminous ceilings , 2) Injection Molder Snap-on Diffusers for Fluorescent Tube Fixtures.
used in light control is the static-dust collection or dust pickup from the atmosphere.
This problem requires our much attention , as PS is the worst in this respect.
The reason for this is that polystyrene is an excellent electrical insulator and
has very high surface resistivity. This leads to accumulation of static electric charge
on the surface of the moulding , which then attracts dust. The useful result is an
been unsuccessful the problem is not without a solution. For ordinary purpose ,
washing with a mild 10% solution of any commercial detergent does good clearing
job without affecting polystyrene. But it is necessary that the solution be allowed to
dry on the fitting by itself which leaves a film imparting antistaticity to polystyrene.
2) Louvers
5) Diffused lighting.
CONCLUSION
- Industry " for long term service life and encourages new concepts in interior
lighting decoration. Many attractive and functional lighting fixtures are made up of
is growing emphasis on proper lighting and the idea of light control is steadily
gaining ground. This has created a vast potential market for plastics in the form of
light - control media and has posed a challenge to the imagination of architects ,
contractors building engineers and the designers for economical , attractive and
BIBLIOGRAPHY
2) "Plastic Materials"
Sixth edition
By J. A. Brydson.
3) "Polymer science",
( Page No : 44 , 54 , 55 , 56 , 64 , 66 , 66 - 73 )
Wed Sites :
www.ormecon.com