UJIAN FORMATIF CHEMISTRY UPPER 6 (40 MINUTES)

NAME : ___________________________________ FORM : _____________________________

Answer all questions in this section. 1

Relative abundance / %

14 16

28

44

m/e

Which of the following substance is expected to give the above mass spectrum? [Relative atomic mass: H, 1.0; C,12.0; N, 14.0; O,16.0] A B C D CO2 C3H8 N2O Mixture of N2 and O2

The diagram below represents the unit cell of a body centred cubic structure. How many lattice particles are there per unit cell?

A B C D

2 3 5 9

Which of the diagrams below represents the ground-state electron arrangement of a Nitrogen atom? A 1s 2s 2p

1s

2s

2p

1s

2s

2p

1s

2s

2p

The first ionization energies for a series of elements with increasing proton number are as follows: 632, 661, 648, 653, 718 kJmol-1 This series of elements is:A Group 1
2

B C D
5

Group 14 Group 18 d-block

Which of the following statements correctly explains the decrease in ionic radii for the elements of Period 3 from sodium to aluminium?
A B C D

Decreasing charge density of its ions. Increasing strength in the metallic bonds. Increasing polarization power for anions. Same number of electrons with increasing number of protons.

6. (a)

A container of volume 25 dm3 contains 0.50 mol of hydrogen gas, 0.10 mol of oxygen gas and an unknown amount of helium gas. The pressure of 1 mol of gas in the container at room temperature is 100kPa.
(i)

If the total pressure in the container is 88 kPa, determine the number of moles of helium gas in the container.

[2 marks]
(ii)

The mixture of gases in the container is then ignited. What is the number of moles of each gas left in the container after the ignition?

[1 mark] (iii) After ignition, the container is allowed to cool to room temperature. What is the partial pressure of helium gas in the container?

[1 mark]
(iv)

If the vapour pressure of water in the container at room temperature is 2.4 kPa, what is the total pressure in the container?
3

[1 mark]
(v)

Write a balanced equation for the reaction that has taken place.

[1 mark]

(b)

The diagram below shows four electronic transitions in the hydrogen atom.

(i) Which electronic transition emits electromagnetic radiation with the shortest

wavelength?

[1 mark]
(ii) In which region of the electromagnetic spectrum are these lines formed? What is

the name of this line series in the emission spectrum of hydrogen?

[2 marks]
(iii) Determine the maximum number of lines that can be formed in this line emission

spectrum involving the the energy levels n=2 to n=6

[1 mark] 7. (a) The boiling points of three fluorides are as follows : Fluoride SiF4 PF5 SF6 Boiling point / 0C -86 0C -75 0C -64 0C

(i) Explain in terms of structure and bonding why these compounds are all gases at room temperature and pressure

[2 marks]
(ii) Draw diagrams to show the shapes and bond angles of each of these compounds

SiF4, PF5, and SF6.

[3 marks]
(iii)Both oxygen and sulphur are in the same group in the Periodic Table. State why

compound OF6 does not exist.

[2 mark]
(iv)

Xenon reacts with fluorine to form the compound XeF4. State whether the Xe F bond is polar or non-polar and hence explain the polarity of XeF4 molecule.

[3 marks]