RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No.

5578 Doc. No. 5578-E4-1041-PD-MX-001

Rev. 0 Page 1/24

Shop Cleaning and Painting Procedure(Tank)

AGREEMENT NO. : PROJECT NAME :

09-5578-E-4 Ruwais Refinery Expansion Project EPC-4: Tankage & Associated Interconnecting Piping Abu Dhabi Oil Refining Company (TAKREER) Mott MacDonald Ltd. Daewoo Engineering & Construction Co., Ltd.

COMPANY PMC CONTRACTOR

: : :

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 3/24

REVISION INDEX DETAILS Rev Location of Change Brief Description of Change

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 4/24

TABLE OF CONTENTS 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 SCOPE .................................................................................................................................... 5 CODES AND STANDARDS....5 SURFACE PREPARATION7 SHOP PAINTING.................................................................................................................. 8 MIXING, THINNING AND STORAGE ............................................................................. 9 SHOP TOUCH-UP REQUIREMENTS ............................................................................ 10 INSPECTION REQUIREMENTS 10 GENERAL REQUIREMENTS ..................................................................................... .11 INSPECTION CHECK LIST.11 DOCUMENTATION / RECORDS ...12 ATTACHMENT..13 ATTACHMENT 1. SHOP PRIMING INSTRUCTIONS ATTACHMENT 2. LIMA WORKSHOP FACILITIES PHOTO ATTACHMENT 3. PAINTING & TRANSPORTATION CONTROL FLOW CHART ATTACHMENT 4. TRANSPORTATION ROUTE INFORMATION BY TANK ITEMS ATTACHMENT 5. LAYDOWN AREA PAINTSHOP LOCATION ATTACHMENT 6. LAYDOWN AREA AUTO BLASTING MACHINE LAYOUT ATTACHMENT 7. PAINTING SYSTEM TABLE AND VENDOR MSDS

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 5/24

1.0 SCOPE: This procedure covers all necessary shop cleaning and painting activities to be performed at the shop to support the execution of the Tankage Work. A separate Field Painting Procedure will be developed later to all field painting activities. This procedure to comply with Company Procedure DGS-MX-001 Painting. This procedure shall comply with Project Technical Specifications and their Amendments.

2.0 CODES AND STANDARDS

It shall be the APPLICATORS responsibility to be, or to become, knowledgeable of the requirements of the referenced codes and standards. The latest edition in force shall apply. 15 January 2008 is the effective date for codes and standards i.e. the code or standard valid on that date shall be the one to be used.

NATIONAL ASSOCIATION OF CORROSION ENGINEERS (NACE) RP0178 Fabrication Details, Surface Finish Requirements, and Proper Design Considerations for Tanks and Vessels to be Lined for Immersion Service (Except Appendix B of this standard RP0178) RP0184 RP0188 RP0287 Repair of Lining Systems Discontinuity (Holiday) Testing of Protective Coatings Field Measurement of Surface Profile of Abrasive Blast Cleaned Steel Surfaces Using a Replica Tape RP0288 TM0174 Inspection of Lining on Steel and Concrete Laboratory Methods for the Evaluation of Protective Coatings and Lining Materials In Immersion Service SSPC Steel Structures Painting Council(Volumes 1 & 2)

INTERNATIONAL ORGANIZATION FOR STANDARDIZATION (ISO)

ISO 2409 ISO 2808

Paints and Varnishes Cross-cut test for adhesion Paints and Varnishes Determination of film thickness

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 ISO 4624 ISO 4628-2 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 6/24

Paints and Varnishes Pull-off test for adhesion Paints and Varnishes Evaluation of degradation of paint coatings - Designation of intensity, quantity and size of common types of defect - Part 2: Designation of degree of blistering

ISO 4628-3

Paints and Varnishes Evaluation of degradation of paint coatings Designation of intensity, quantity and size of common types of defect - Part 3: Designation of degree of rusting

ISO 4628-4

Paints and Varnishes Evaluation of degradation of paint coatings - Designation of intensity, quantity and size of common types of defect - Part 4: Designation of degree of cracking

ISO 4628-5

Paints and Varnishes Evaluation of degradation of paint coatings - Designation of intensity, quantity and size of common types of defect - Part 5: Designation of degree of flaking

ISO 4628-6

Paints and Varnishes Evaluation of degradation of paint coatings - Designation of intensity, quantity and size of common types of defect - Part 6: Rating of degree of chalking by tape method

SO 8501-1

Preparation of steel substrates before application of paints and related products -Visual assessment of surface cleanliness - Part 1: Rust grades and preparation grades of uncoated steel substrates and steel substrates after overall removal of previous coatings

ISO 8502-1

Preparation of steel substrates before application of paints and related products -Tests for the assessment of surface cleanliness - Part 1: Field test for soluble iron corrosion products

ISO 8502-2

Preparation of steel substrates before application of paints and related products -Tests for the assessment of surface cleanliness - Part 2: Laboratory determination of chloride on cleaned surfaces

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 ISO 8502-3 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 7/24

Preparation of steel substrates before application of paints and related products -Tests for the assessment of surface cleanliness - Part 3: Assessment of dust on steel surfaces prepared for painting (pressure-sensitive tape method)

ISO 8502-4

Preparation of steel substrates before application of paints and related products -Tests for the assessment of surface cleanliness - Part 4: Guidance on the estimation of the probability of condensation prior to paint application

ISO 8503-2

Preparation of steel substrates before application of paints and related productsrface roughness characteristics of blast cleaned steel substrates - Part 2: Method for the grading of surface profile of abrasive blast-cleaned steel-Comparator procedure

ISO 8504-2

Preparation of steel substrates before application of paints and related productsrface preparation methods - Part 2: Abrasive blast-cleaning

ISO 8504-3

Preparation of steel substrates before application of paints and related productsrface preparation methods - Part 3: Hand and power tool cleaning

3.0 SURFACE PREPARATION

Prior blasting cleaning, visible grease and oil shall be removed by solvent cleaning or solvent free alkaline cleaner based on emulsifiers solution, ref. SSPC SP-1. After being dried, the washed surface shall be tested for presence of residual oil and grease using water droplets.

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 8/24

3.1 External carbon steel blast cleaning to Sa2 1/2 shall be followed and on the interior carbon steel components Sa3 blast cleaning shall be followed. Sa3 standard shall also be achieved on the underside surfaces of Tank bottoms. Blast media shall be Steel Shot S230(+/- 80%) & G-50(+/20%). The blasting abrasive working mix must be capable of producing a 50-75 uniform anchor profile or as specified by the coating manufacturer for the relevant paint material to be applied. The anchor profile shall be verified, in accordance with ISO 8503 using course extra course replica tape and a spring loaded micrometer. 3.2 Abrasive blasted surfaces shall be either air blown with clean, dry air, or brushed cleaned before priming. The substrate shall be inspected for the presence of visible dust or contamination, either of which is unacceptable, and re-blown or re-cleaned as necessary. 3.3 Care shall be taken to prevent rusting and/or contamination of cleaned surfaces. Cleaned surfaces shall be primed within 4 hours of blasting is done and before detrimental corrosion or recontamination occurs. If rust forms, the surface shall be re-blast cleaned before priming. Abrasive blasting shall not be performed when the ambient or the substrate temperatures are less than 3 deg. C. above the dew point. 3.4 Surface preparation shall be carried out utilizing automatic surface preparation equipment. Areas that can not be properly prepared by the automatic blast equipment shall be abrasive blasted manually utilizing conventional blasting equipment. 3.5 For shop surface preparation requirements, work this procedure in conjunction with shop Plate Sheet.

4.0 SHOP PAINTING 4.1 For SHOP painting requirements, work this procedure in conjunction with shop Prime-Sheet and Paints suppliers product data sheets.. 4.2 Prior to coating weld margins are to be masked and or protected from coating. Weld margins are to be 50 wide on either side of weld area. Weld through weldable inorganic zinc primers need not to be masked / protected.

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 9/24

4.3 Priming will be carried out in generic formats: 1) Blast Sa2.5 and 25 microns zinc primer(outer shell and fixed roof externals). 2) Blast Sa3 and 25 microns zinc primer(inner shell, floating roof externals and fixed roof internals). 3) Blast Sa2.5 with 75 microns inorganic zinc(pontoon internals). 4) Blast Sa3 and 2 200 microns Glass Flake Epoxy(underside bottom plates). 4.4 Glass Flake Epoxy on Bottom Plate Underside 1) All surfaces should be clean and free from contamination. The surface should be assessed and treated in accordance with ISO 8504. 2) Cleanliness: Power tool cleaning to min. St 2, mill scale free (ISO 8501-1:2007). Improved surface treatment (blast cleaning to Sa 2) will improve the performance. In case of hydro jetting the flash rust degree shall not exceed moderate in SSPC and NACE standards for water prepared surfaces. 3) Shopprimed steel Clean, dry and undamaged approved shopprimer. 4) Coated surfaces Clean, dry and undamaged compatible primer. Power tool cleaning to min. St 2 for rusted areas 5) Steel where blast cleaning may not be possible and on hydro jetted surfaces still being moist where gloss and color retention is of minor importance.

5.0 MIXING, THINNING AND STORAGE 5.1 All containers of coating material shall remain unopened until required for use and shall be stored under cover. 5.2 5.3 Coating material which has jelled or otherwise deteriorated during storage shall not be used. All material shall be thoroughly mixed before use to a smooth and uniform consistency. Mechanical agitation during application of inorganic zinc primers shall be sufficient to keep pigment in solution.

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 5.4 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 10/24

Coating material shall be mixed in the original container and shall not be transferred until all settled pigment is mixed in the vehicle. This does not imply that part of the vehicle may not be poured off into another container to simplify the mixing.

5.5

Material, which does not have a limited pit life, or does not deteriorate on standing, shall be mixed or re-mixed immediately before using but, if setting has occurred it shall be re-mixed before using. Coating material shall not remain in spray pots or open buckets overnight, but shall be gathered into a closed container or bucket and re-mixed before use.

5.6 5.7

Material Pot and shell lifes shall be adhered to all the times. Mixing shall be performed in a well ventilated, clean and dust-free environment. All mixing shall be performed by mechanical means. The mixing appliances shall be cleaned.

6.0 SHOP TOUCH-UP REQUIREMENTS 6.1 Abnormal or excessive runs and sags shall be abrasive paper cleaned until smooth and touched-up as per each Plate-Sheet. 6.2 For touch-up or repair of localized damaged paint or to areas of incorrectly applied paint. 6.3 When applying the initial coat of paint to corners, edges or other irregular surfaces after spray application and shall be done painting of stripe coats and touch-up paint. 6.4 Local damages during loading and unloading of tank steel plate shall be repaired as per company Job specification (DGS-MX-001).

7.0 INSPECTION REQUIREMENTS 7.1 7.2 Surface preparation shall be checked visually using pictorial standards ISO 8501-1-1998. Surface profile shall be Verified in accordance with ASTM D4417 method C or ISO 8503 using course or extra course replica tape and a spring loaded micrometer. 7.3 A calibrated Elcometer or Microtest DFT Gauge shall be used to check the DFT for each coat of paint applied, to insure the required DFT is achieved. If an area is found to be under the required thickness, additional readings shall be taken, as needed to determine the area coated surface which is under the specified thickness. The final DFT check shall be in accordance with SSPC PA-2.
Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 painting operations occur. 7.5 Wet film thickness shall be spit checked in random areas as initial indication of the required film thickness. 7.6 A sling psychrometer or whirling hygrometer in conjunction with Hydrometric Tables shall be used to measure relative humidity and dew point. Paint application shall NOT proceed unless the relative humidity and dew point are within acceptable limits set forth by the coating manufacturer. Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 11/24

7.4 A Daily Shop Blasting/Painting Inspection Report shall be completed each day that blasting and

8.0 GENERAL REQUIREMENTS 8.1 Painting of any surfaces shall not proceed when any of the following environmental conditions exist: 1) When the surface temperature is above the paint manufacturers requirements. 2) When the relative humidity in the work area is greater than 85% or otherwise specified by the coating manufacturer. 3) The surface temperature is less than 3(5) above the dew point of the air in the work area. 4) Moisture or other detrimental surface contamination is evident on the surfaces to be blasted, primed or over coated. Detrimental surface contamination does not include ingrain stains. 8.2 Paint shall be stored per the manufacturers recommendations. 8.3 Application of each coat of paint shall be per the manufacturers recommendations. 8.4 Thinning of the paints shall be per the manufacturers recommendations. 8.5 Drying times between coats shall be per the manufacturers recommendations. 8.6 Mixing of the paints shall be per the manufacturers recommendations.

9.0 INSPECTION CHECK LIST 9.1 Materials 1) Verify that shelf life of the coating has not been exceeded. 2) Verify that coating and thinning materials are as specified and from the same manufacturer. 3) Verify that blasting materials are as specified.

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 9.2 Equipment 1) Verify adequacy of coating, cleaning and blasting equipment, hoses, spray guns etc. 2) Verify all inspection equipment are properly calibrated. 9.3 Surface Preparation 1) Verify that oil and grease are removed prior to surface preparation. 2) Verify cleanliness and dryness of abrasive. 3) Verify the adequacy of cleaning and blasting equipment. 4) Verify ambient, substrate, dew point temperatures are appropriate. 5) Verify the anchor profile is as specified using appropriate instruments. Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 12/24

10.0 DOCUMENTATION / RECORDS

10.1 The APPLICATOR shall notify the CONTRACTOR of any apparent conflict between Job Specification, the application data, the codes and standards, and any other Specification noted herein. Resolution and/or interpretation precedence shall be obtained from the CONTRACTOR in writing before proceeding with surface preparation or application of coatings. 10.2 APPLICATOR shall submit the type and quantity of details and documentation for CONTRACTOR'S authorization or information as listed in the individual material requisitions and purchase orders. 10.3 Any documents for application of the paint systems in accordance with this Specification shall be followed as per Attachment 11-1 shop prime instruction.

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 13/24

11.0 ATTACHMENT ATTACHMENT 1. SHOP PRIMING INSTRUCTIONS

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 14/24

ATTACHMENT 2. LIMA WORKSHOP FACILITIES PHOTO

AUTOMATIC SPRAY AND DRYER MACHINE #1

AUTOMATIC SPRAY AND DRYER MACHINE #2

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 15/24

AUTOMATIC BLASTING MACHINE #1

AUTOMATIC BLASTING MACHINE #2

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 16/24

DUST COLLECTOR

LO2 TANK

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 17/24

LPG TANK #2

ROLLER CONVEYOR FACILITIES

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 18/24

STOCK YARD 30 TON OVERHEAD CRANE

WATER STORAGE TANK (CAPA. 226 TON)

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 19/24

WORKSHOP OVERHEAD CRANE

WORKSHOP YARD

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 20/24

ATTACHMENT 3. PAINTING & TRANSPORTATION CONTROL FLOW CHART for TANK MATERIAL

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 21/24

ATTACHMENT 4. TRANSPORTATION ROUTE INFORMATION BY TANK ITEMS

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

Shell Plate (Area 1, 2, 5) DAMMAM(CBI) To RUWAIS

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 22/24

ATTACHMENT 5. RRE EPC-4 LAYDOWN AREA PAINTSHOP LOCATION

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 23/24

ATTACHMENT 6. RRE EPC-4 LAYDOWN AREA AUTO BLASTING MACHINE LAYOUT

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

RUWAIS REFINERY EXPANSION PROJECT EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING AGREEMENT No. 09-5578-E-4 PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001
Rev. 0 Page 24/24

ATTACHMENT 7. PAINTING SYSTEM TABLE AND VENDOR MSDS

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

Jotamastic 87 GF - Comp. A

1.

Identification of the preparation and of the company

: Jotamastic 87 GF - Comp. A : 525 : Jotun Paints (Europe) Ltd. Stather Road Flixborough, Scunthorpe North Lincolnshire DN15 8RR England Tel: +44 17 24 40 00 00 Fax: +44 17 24 40 01 00 SDSJotun@jotun.no

Product name and/or code Label No. Supplier/Manufacturer

Emergency telephone number Product use

: Contact National Poison Centre via Hospital or Registered Medical Practitioner : Coatings: Solvent-borne.

2.

Hazards identification

The product is classified as dangerous according to Directive 1999/45/EC and its amendments. Flammable. Irritating to eyes and skin. May cause sensitisation by skin contact. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Irritant : Contains epoxy constituents. See information supplied by the manufacturer. This information is provided by the present Safety Data Sheet. The preparation may be a skin sensitiser. It may also be a skin irritant and repeated contact may increase this effect. Additional warning phrases

3.

Composition/information on ingredients
Notes CAS number C 6 EC number % by weight 10 - 25 2.5 - 10 2.5 - 10 201-148-0 202-859-9 202-849-4 2.5 - 10 1 - 2.5 1 - 2.5 Classification Xi; R36/38 R43 N; R51/53 R10 Xn; R20/21 Xi; R38 Xi; R36/38 R43 R10 Xi; R41, R37/38 R67 Xn; R20/22 F; R11 Xn; R20

Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances Directive 67/548/EEC. Chemical name* reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average molecular weight 700) xylene epoxy resin (MW 700-1200) 2-methylpropan-1-ol benzyl alcohol ethylbenzene See section 16 for the full text of the R-phrases declared above Occupational exposure limits, if available, are listed in section 8.

25068-38-6 500-033-5 1330-20-7 25036-25-3 78-83-1 100-51-6 100-41-4 215-535-7

Date of issue

: 29.06.2010.

Page: 1/6

Jotamastic 87 GF - Comp. A

4.

First-aid measures
: In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and seek medical advice. : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or thinners. : Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. : If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do not induce vomiting.

First-aid measures General

Inhalation

Skin contact Eye contact Ingestion

5.

Fire-fighting measures
: Recommended: alcohol-resistant foam, CO 2, powders, water spray. : Do not use water jet. : Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Appropriate breathing apparatus may be required. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses.

Extinguishing media Extinguishing media not to be used Recommendations

6.

Accidental release measures

: Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist. Refer to protective measures listed in sections 7 and 8. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13).

Personal precautions

Spill : Preferably clean with a detergent. Avoid using solvents. Note: see section 8 for personal protective equipment and section 13 for waste disposal.

7.

Handling and storage

: Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapours in air and avoid vapour concentrations higher than the occupational exposure limits. In addition, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. To dissipate static electricity during transfer, earth drum and connect to receiving container with bonding strap. Operators should wear antistatic footwear and clothing and floors should be of the conducting type. Keep container tightly closed. Keep away from heat, sparks and flame. No sparking tools should be used. Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or mist arising from the application of this preparation. Avoid inhalation of dust from sanding. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Put on appropriate personal protective equipment (see section 8). Never use pressure to empty. Container is not a pressure vessel. Always keep in containers made from the same material as the original one. Comply with the health and safety at work laws. When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.

Handling

Date of issue

: 29.06.2010.

Page: 2/6

Jotamastic 87 GF - Comp. A Storage : Store in accordance with local regulations. Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away from heat and direct sunlight. Keep away from sources of ignition. Keep away from: oxidising agents, strong alkalis, strong acids. No smoking. Prevent unauthorised access. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not empty into drains.

8.

Exposure controls/personal protection

: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and solvent vapours below the OEL, suitable respiratory protection must be worn. Occupational exposure limits EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbed through skin. STEL: 441 mg/m 15 minute(s). STEL: 100 ppm 15 minute(s). TWA: 220 mg/m 8 hour(s). TWA: 50 ppm 8 hour(s). EH40/2005 WELs (United Kingdom (UK), 8/2007). STEL: 231 mg/m 15 minute(s). STEL: 75 ppm 15 minute(s). TWA: 154 mg/m 8 hour(s). TWA: 50 ppm 8 hour(s). EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbed through skin. STEL: 552 mg/m 15 minute(s). STEL: 125 ppm 15 minute(s). TWA: 100 ppm 8 hour(s). TWA: 441 mg/m 8 hour(s).

Engineering measures

Ingredient name
xylene

2-methylpropan-1-ol

ethylbenzene

Personal protective equipment Respiratory system : If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use respiratory mask with charcoal and dust filter when spraying this product.(as filter combination A2-P2). In confined spaces, use compressed-air or fresh-air respiratory equipment. When use of roller or brush, consider use of charcoalfilter. Skin and body Hands : Personnel should wear antistatic clothing made of natural fibres or of hightemperature-resistant synthetic fibres. : Wear suitable gloves. Recommended, gloves(breakthrough time) > 8 hours: Viton, Responder, fluor rubber, nitrile rubber, 4H, Teflon May be used, gloves(breakthrough time) 4 - 8 hours: neoprene, butyl rubber Not recommended, gloves(breakthrough time) < 1 hour: polyvinyl alcohol (PVA), PVC For right choice of glove materials, with focus on chemical resistance and time of penetration, seek advice by the supplier of chemical resistant gloves. The user must check that the final choice of type of glove selected for handling this product is the most appropriate and takes into account the particular conditions of use, as included in the user's risk assessment. Eyes : Use safety eyewear designed to protect against splash of liquids.

9.

Physical and chemical properties

: : : : : : : Liquid. Characteristic. Various colours. Closed cup: 35C (95F) 1.5 g/cm3 1.1 - 13% Insoluble in the following materials: cold water and hot water. Page: 3/6

Physical state Odour Colour Flash point Density Explosion limits Solubility Date of issue

: 29.06.2010.

Jotamastic 87 GF - Comp. A

10. Stability and reactivity

Stable under recommended storage and handling conditions (see section 7). Hazardous decomposition products: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen. Keep away from the following materials to prevent strong exothermic reactions: oxidising agents, strong alkalis, strong acids.

11. Toxicological information

There is no data available on the preparation itself. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See sections 2 and 15 for details. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible damage. Swallowing may cause nausea, diarrhoea, vomiting, gastro-intestinal irritation and chemical pneumonia. Based on the properties of the epoxy constituent(s) and considering toxicological data on similar preparations, this preparation may be a skin sensitiser and an irritant. It contains low molecular weight epoxy constituents which are irritating to eyes, mucous membrane and skin. Repeated skin contact may lead to irritation and to sensitisation, possibly with cross-sensitisation to other epoxies. Skin contact with the preparation and exposure to spray mist and vapour should be avoided. Contains: reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average molecular weight 700), epoxy resin (MW 700-1200). May produce an allergic reaction.

12. Ecological information

There is no data available on the preparation itself. Do not allow to enter drains or watercourses. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 3 and 15 for details. Aquatic ecotoxicity Product/ingredient name reaction product: bisphenol-A(epichlorhydrin); epoxy resin (number average molecular weight 700) xylene Test Mortality Result Acute EC50 1,4 mg/l Acute LC50 3,1 mg/l Acute LC50 12000 to 16114 ug/L Fresh water Acute EC50 7,2 mg/L Acute EC50 2,93 mg/L Acute LC50 4,2 mg/L Species Daphnia Fish - fathead minnow Fish - Bluegill - Lepomis macrochirus 1,1 g Algae Daphnia Fish Exposure 48 hours 96 hours 96 hours

ethylbenzene

Population Intoxication Mortality

48 hours 48 hours 96 hours

Ecological information Biodegradability Product/ingredient name reaction product: bisphenol-A(epichlorhydrin); epoxy resin (number average molecular weight 700) xylene benzyl alcohol Bioaccumulative potential Product/ingredient name

Aquatic half-life LogKow

Photolysis BCF

Biodegradability Not readily Readily Readily Potential

Date of issue

: 29.06.2010.

Page: 4/6

Jotamastic 87 GF - Comp. A >3 reaction product: bisphenol-A(epichlorhydrin); epoxy resin (number average molecular weight 700) xylene 3,12 benzyl alcohol 1,1 <100 high high low

13. Disposal considerations

Do not allow to enter drains or watercourses. Material and/or container must be disposed of as hazardous waste. European waste catalogue : 08 01 11* waste paint and varnish containing organic solvents or other dangerous substances. If this product is mixed with other wastes, this code may no longer apply. (EWC) If mixed with other wastes, the appropriate code should be assigned. For further information, contact your local waste authority.

14. Transport information

Transport within users premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. International transport regulations Proper shipping name : Paint. UN Number : 1263 Class : 3 Packing group : III Label :

Additional information ADR / RID

: Tunnel restriction code: (D/E) Hazard identification number: 30 Special provisions: 640E ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to receptacles < 450 litre capacity). : Emergency schedules (EmS): F-E, S-E Marine pollutant: No.

IMDG

IMDG: Viscous substance. Transport in accordance with paragraph 2.3.2.5 (applicable to receptacles < 30 litre capacity). Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.

15. Regulatory information

EU regulations Hazard symbol or symbols : The product is classified and labelled for supply in accordance with the Directive 1999/45/EC as follows: :

Irritant

Risk phrases

: R10- Flammable. R36/38- Irritating to eyes and skin. R43- May cause sensitisation by skin contact. R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. : S23- Do not breathe vapour / spray. S24- Avoid contact with skin. S37- Wear suitable gloves. S51- Use only in well-ventilated areas. : reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average molecular weight 700) epoxy resin (MW 700-1200) : 29.06.2010. Page: 5/6

Safety phrases

Contains:

Date of issue

Jotamastic 87 GF - Comp. A Additional warning phrases Industrial use : Contains epoxy constituents. See information supplied by the manufacturer. This information is provided by the present Safety Data Sheet. : The information contained in this safety data sheet does not constitute the users own assessment of workplace risks, as required by other health and safety legislation. The provisions of the national health and safety at work regulations apply to the use of this product at work.

16. Other information

CEPE Classification : 1 Full text of R-phrases : R11- Highly flammable. R10- Flammable. referred to in sections 2 and R20- Harmful by inhalation. 3 - United Kingdom (UK) R20/21- Harmful by inhalation and in contact with skin. R20/22- Harmful by inhalation and if swallowed. R41- Risk of serious damage to eyes. R38- Irritating to skin. R36/38- Irritating to eyes and skin. R37/38- Irritating to respiratory system and skin. R43- May cause sensitisation by skin contact. R67- Vapours may cause drowsiness and dizziness. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No 1907/2006. : 29.06.2010. Date of issue : 3 Version Indicates information that has changed from previously issued version. Notice to reader The information in this SDS is based on the present state of our knowledge and on current laws. The product is not to be used for purposes other than those specified under section 1 without first obtaining written handling instructions. It is always the responsibility of the user to take all necessary steps to fulfil the demands set out in the local rules and legislation. The information in this SDS is meant to be a description of the safety requirements for our product. It is not to be considered a guarantee of the product's properties.

Date of issue

: 29.06.2010.

Page: 6/6

Technical Data

Jotamastic 87 GF
Product description
Jotamastic 87 GF is a two-pack surface tolerant, glass flake reinforced, abrasion resistant, high solids epoxy mastic coating which may be applied in high film thickness. Available with different hardeners for varying substrate temperatures, Standard (Std) and Wintergrade (WG). This product is a part of a complete system which is certified not to spread flames.

Recommended use
Steel where blast cleaning may not be possible and on hydrojetted surfaces still being moist where gloss and colour retention is of minor importance. Can be used alone or in combination with various systems of primers and topcoats. Gives excellent corrosion protection both in salt and fresh water. If exposed to sunlight chalking may occur. Glass Flakes improve abrasion resistance and general wear and tear characteristics.

Film thickness and spreading rate

Std Comp. B Film thickness, dry (m) Film thickness, wet (m) Theoretical spreading rate (m/l) WG Comp. B Film thickness, dry (m) Film thickness, wet (m) Theoretical spreading rate (m/l) Minimum 200 250 4 Minimum 200 285 3,5 Maximum 350 440 2,3 Maximum 300 430 2,3 Typical 250 315 3,2 Typical 250 360 2,8

Comments
Hong Kong rules: Category of paints - Other vessel coatings; VOC 250 gms/ltr HK EPD method (Ready to use); Exempt compound - N/A; Specific gravity: 1.41 (A+B); Both VOC and Specific gravity values provided are typical values, subject to changes when different colour involved.

Jotamastic 87 GF

Page 1 of 4

Physical properties
Colour Solids (vol %)* Flash point Grey, Red, White 80 2 Std Comp.B 70 2 WG Comp.B Std Comp. B: 35C 2 (Setaflash) WG Comp. B: 31C 2 (Setaflash) 2,09 lbs/gal (250 gms/ltr) USA-EPA Method 24 170 gms/ltr UK-PG6/23(97). Appendix 3 Semigloss Fair Excellent Excellent Good Very good Good

VOC

Gloss Gloss retention Water resistance Abrasion resistance Solvent resistance Chemical resistance Flexibility

*Measured according to ISO 3233:1998 (E)

Surface preparation
All surfaces should be clean and free from contamination. The surface should be assessed and treated in accordance with ISO 8504. Bare steel Cleanliness: Power tool cleaning to min. St 2, mill scale free (ISO 8501-1:2007). Improved surface treatment (blast cleaning to Sa 2) will improve the performance. In case of hydrojetting the flash rust degree shall not exceed moderate in SSPC and NACE standards for water prepared surfaces. Shopprimed steel Clean, dry and undamaged approved shopprimer. Coated surfaces Clean, dry and undamaged compatible primer. Contact your local Jotun office for more information. For maintenance UHPWJ to WJ2 (NACE No.5/SSPC-SP 12) or Power tool cleaning to min. St 2 for rusted areas Other surfaces The coating may be used on other substrates. Please contact your local Jotun office for more information.

Condition during application

The temperature of the substrate should be minimum +10C (Std) (-5C in WG) and at least 3C above the dew point of the air, temperature and relative humidity measured in the vicinity of the substrate. Good ventilation is required in confined areas to ensure proper drying. Hydrojetting of steel surface makes a wet surface. The surrounding air must have a relative humidity not exceeding 85 %. Before painting the surface shall not be glossy with moisture, but can have a patchy appearance.

Application methods
Spray Brush Roller Use airless spray Recommended for stripe coating and small areas, care must be taken to achieve the specified dry film thickness. May be used for small areas but not recommended for first primer coat, however when using roller application care must be taken to apply sufficient material in order to achieve the specified dry film thickness.

Jotamastic 87 GF

Page 2 of 4

Application data
Mixing ratio (volume) Std Comp. B: 6:1 WG Comp. B: 4:1 6 parts Comp. A (base) to be mixed thoroughly with 1 part Jotamastic 87, Std Comp. B (curing agent). 4 parts Comp. A (base) to be mixed thoroughly with 1 part Jotamastic 87, WG Comp. B. (curing agent). 10 minutes. Std Comp. B: 10C: 4 hours, 23C: 2 hours, 40C: 1 hour WG Comp. B: 1 hour Jotun Thinner No. 17 15 MPa (150 kp/cm, 2100 psi). 0.63 - 1.09 mm (0.025-0.043") 40 - 80 Filters to be removed prior to spraying. * The temperature of the mixture of base and curing agent is recommended to be at least 15C, otherwise extra solvent may be required to obtain correct viscosity. * Too much solvent results in lower sag resistance and slower cure. * If extra solvent is necessary, this should be added after mixing of the two components.

Mixing

Induction time Pot life (23C)

Thinner/Cleaner Guiding data airless spray Pressure at nozzle Nozzle tip Spray angle Filter Note

Drying time
Drying times are generally related to air circulation, temperature, film thickness and number of coats, and will be affected correspondingly. The figures given in the table are typical with: * Good ventilation (Outdoor exposure or free circulation of air) * Typical film thickness * One coat on top of inert substrate Std Comp. B Substrate temperature Surface dry Through dry Cured Dry to recoat, minimum Dry to recoat, maximum 1 WG Comp. B Substrate temperature Surface dry Through dry Cured Dry to recoat, minimum Dry to recoat, maximum 1 1.

10C 8h 24 h 14 d 24 h -

23C 4h 10 h 7d 10 h -

40C 2h 4h 2d 4h -

-5C 24 h 48 h 21 d 48 h

0C 18 h 26 h 14 d 26 h

5C 12 h 18 h 7d 18 h

10C 6h 12 h 3d 12 h

23C 2,5 h 5h 2d 5h

Provided the surface is free from chalking and other contamination prior to application, there is normally no overcoating time limit. Best intercoat adhesion occurs, however, when the subsequent coat is applied before preceding coat has cured. If the coating has been exposed to direct sunlight for some time, special attention must be paid to surface cleaning and mattening/removal of the surface layer in order to obtain good adhesion.

Jotamastic 87 GF

Page 3 of 4

The given data must be considered as guidelines only. The actual drying time/times before recoating may be shorter or longer, depending on film thickness, ventilation, humidity, underlying paint system, requirement for early handling and mechanical strength etc. A complete system can be described on a system sheet, where all parameters and special conditions could be included.

Typical paint system

Jotamastic 87 GF Hardtop AS/XP 2 x 250 m 1 x 50 m (Dry Film Thickness) (Dry Film Thickness)

Other systems may be specified, depending on area of use

Storage
The product must be stored in accordance with national regulations. Storage conditions are to keep the containers in a dry, cool, well ventilated space and away from source of heat and ignition. Containers must be kept tightly closed.

Handling
Handle with care. Stir well before use.

Packing size
16 litres Comp. A (base) in a 20 litre container and 2.7 litres Jotamastic 87, Std Comp. B (curing agent) in a 3 litre container. 16 litres Comp. A (base) in a 20 litre container and 4 litres Jotamastic 87, WG Comp. B (curing agent) in a 5 litre container.

Health and safety

Please observe the precautionary notices displayed on the container. Use under well ventilated conditions. Do not breathe or inhale mist. Avoid skin contact. Spillage on the skin should immediately be removed with suitable cleanser, soap and water. Eyes should be well flushed with water and medical attention sought immediately. For detailed information on the health and safety hazards and precautions for use of this product, we refer to the Material Safety Data Sheet. DISCLAIMER The information in this data sheet is given to the best of our knowledge based on laboratory testing and practical experience. However, as the product is often used under conditions beyond our control, we cannot guarantee anything but the quality of the product itself. We reserve the right to change the given data without notice.
Jotun is a World Wide company with factories, sales offices and stocks in more than 50 countries. For your nearest local Jotun address please contact the nearest regional office or visit our website at www.jotun.com

ISSUED 3 APRIL 2010 BY JOTUN THIS DATA SHEET SUPERSEDES THOSE PREVIOUSLY ISSUED

Jotamastic 87 GF

Page 4 of 4

Technical Data

Resist 86
Product description
Resist 86 is a two-pack, quick curing zinc rich ethyl silicate coating that complies with the compositional requirements for SSPC Paint 20 level 1 and ISO 12944. Can also be made to order with ASTM D520 Type II zinc dust.

Recommended use
A general purpose, heavy duty, anti-corrosive primer: 1. As the first coat in a multiple layer system. 2. As a single coating for long term protection of steel exposed to moderately to severely corrosive environment. Resistant to cyclic dry temperatures up to 400C.

Film thickness and spreading rate

Film thickness, dry (m) Film thickness, wet (m) Theoretical spreading rate (m/l) Minimum 50 75 13,4 Maximum 90 135 7,4 Typical 75 115 8,9

Comments
There is a risk of mud-cracking if the film thickness exceeds 120m.

Physical properties
Colour Solids (vol %)* Flash point VOC Greenish grey, Grey 67 2 14C 2 (Setaflash) 465 gms/ltr UK-PG6/23(97). Appendix 3

Gloss Flat Water resistance Very good Abrasion resistance Excellent Solvent resistance Excellent Chemical resistance Excellent within pH-range 6-10 Flexibility Limited *Measured according to OCCA Monograph No. 4

Surface preparation
All surfaces should be clean, dry and free from contamination. The surface should be assessed and treated in accordance with ISO 8504. Bare steel Cleanliness: Blast cleaning to Sa 2 (ISO 8501-1:2007). Roughness: using abrasives suitable to achieve grade Fine to Medium G (30-85 m, Ry5) (ISO 8503-2)

Resist 86

Page 1 of 4

Other surfaces The coating may be used on other substrates. Please contact your local Jotun office for more information.

Condition during application

The temperature of the substrate should be min. 5C and at least 3C above the dew point of the air, temperature and relative humidity measured in the vicinity of the substrate. Zinc silicate paints in general requires moisture for curing. At low humidity the curing will be improved by gently sprinkling fresh water over the paint film, and/or by artificial humidification of the surrounding atmosphere. The paint must be completely cured before topcoating, otherwise the adhesion of the subsequent coat will be unsatisfactory. Use Methyl ethyl ketone (MEK) test according to ASTM D 475287 to verify the curing time before topcoating. Unweathered zinc silicate films are porous and the porosity may vary according to the weather condition during application and the application technique. When overcoating, the air in the pores will escape through the new coat of paint and may cause blisters or pinholes ("popping") in the coat just after application. To avoid this a mist coat/full coat technique is recommended: First apply a thin coat to fill the pores in the zinc silicate film and a few minutes later apply to full specified film thickness. In difficult cases it may be necessary to thin the next coat, or use Penguard Tie Coat 100 as first overcoat.

Application methods
Spray Brush Use airless spray or conventional spray Recommended for stripe coating and small areas, care must be taken to achieve the specified dry film thickness. In order to avoid settling of heavy zinc, continuous mechanical stirring during application is recommended.

Application data
Mixing ratio (volume) Mixing 8:2,6 Comp. A is a liquid and Comp. B is dry zinc dust. Consists of 8 litres Comp. A and 18.5 kg/2,6L Jotun Zinc 100, Comp B or 18.5 kg/2,6L Jotun Zinc 100 ASTM D520 Type II, Comp B. Pour the zinc dust slowly into the liquid during mechanical mixing. The Comp. A must be well shaken before use. Stir until lump free and pass through a 60 mesh sieve. 8-12 hours. (Reduced at higher temp.) Jotun Thinner No. 4/25 Adjusting spray pattern and drying may sometimes become necessary*. Use max 5% Jotun Thinner No. 4 (fast evaporation) when temperature is low and Jotun Thinner No. 25 (slow evaporation) when temperature is high. Thinner should be added after mixing of components 10 MPa (100 kg/cm, 1400 psi) 0.46-0.58 mm (0.018-0.023") 30-80 Check to ensure that filters are clean. *Thinner should be added after mixing components.

Pot life (23C) Thinner/Cleaner

Guiding data airless spray Pressure at nozzle Nozzle tip Spray angle Filter Note

Drying time
Drying times are generally related to air circulation, temperature, film thickness and number of coats, and will be affected correspondingly. The figures given in the table are typical with: * Good ventilation (Outdoor exposure or free circulation of air) * Typical film thickness * One coat on top of inert substrate * Relative humidity of 70%

Resist 86

Page 2 of 4

Substrate temperature Surface dry Through dry Cured 1 Dry to recoat, minimum 2 Dry to recoat, maximum 3

5C 60 min 90 min 18 h 18 h

10C 30 min 45 min 13 h 13 h

23C 15 min 30 min 4h 4h

40C 13 min 25 min 1,5 h 1,5 h

1. 2. 3.

Curing time to be verified by MEK test (ASTM D 4752-87). Recommended data given for recoating with coatings normally specified on top of zinc ethyl silicate coatings. The surface should be free of zinc salts and other contamination prior to application.

The given data must be considered as guidelines only. The actual drying time/times before recoating may be shorter or longer, depending on film thickness, ventilation, humidity, underlying paint system, requirement for early handling and mechanical strength etc. A complete system can be described on a system sheet, where all parameters and special conditions could be included.

Typical paint system

Resist 86 1 x 75 m Normally overcoated with an epoxy system. (Dry Film Thickness)

Other systems may be specified, depending on area of use

Storage
The product must be stored in accordance with national regulations. Storage conditions are to keep the containers in a dry, cool, well ventilated space and away from source of heat and ignition. Containers must be kept tightly closed. The component A must be stored below 25C. The product component B is zinc dust and has no strict limitation's for storage. SHELF LIFE: 6 months at 23C for Comp. A. , 4 years for comp. B, subject to re-inspection thereafter. Higher temperatures during storage may reduce the shelf life and may lead to gelling in the tin.

Handling
Handle with care. Stir well before use. Continuous stirring during application will prevent the heavy zinc pigment from settling.

Packing size
10,6 litres unit: 8 litres Resist 86 Comp A in a 10 litre container and 18,5 kg/2,6 litres Jotun Zinc 100, Comp B (previously named Resist 78/86, Comp B) in a 20 litre container or 10,6 litres unit: 8 litres Resist 86 Comp A in a 10 litre container and 18,5 kg/2,6 litres Jotun Zinc 100 ASTM D520 Type II, Comp B (previously named Resist 86 ASTM D520 Type II, Comp B) in a 20 litre container.

Health and safety

Please observe the precautionary notices displayed on the container. Use under well ventilated conditions. Do not breathe or inhale mist. Avoid skin contact. Spillage on the skin should immediately be removed with suitable cleanser, soap and water. Eyes should be well flushed with water and medical attention sought immediately. For detailed information on the health and safety hazards and precautions for use of this product, we refer to the Material Safety Data Sheet. DISCLAIMER The information in this data sheet is given to the best of our knowledge based on laboratory testing and practical experience. However, as the product is often used under conditions beyond our control, we cannot guarantee anything but the quality of the product itself. We reserve the right to change the given data without notice.
Jotun is a World Wide company with factories, sales offices and stocks in more than 50 countries. For your nearest local Jotun address please contact the nearest regional office or visit our website at www.jotun.com

Resist 86

Page 3 of 4

ISSUED 18 SEPTEMBER 2009 BY JOTUN THIS DATA SHEET SUPERSEDES THOSE PREVIOUSLY ISSUED

Resist 86

Page 4 of 4

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

Resist 86 - Comp. A

1.

Identification of the preparation and of the company

: Resist 86 - Comp. A : 684 : Jotun Paints (Europe) Ltd. Stather Road Flixborough, Scunthorpe North Lincolnshire DN15 8RR England Tel: +44 17 24 40 00 00 Fax: +44 17 24 40 01 00 SDSJotun@jotun.no

Product name and/or code Label No. Supplier/Manufacturer

Emergency telephone number Product use

: Contact National Poison Centre via Hospital or Registered Medical Practitioner : Coatings: Solvent-borne.

2.

Hazards identification

The product is classified as dangerous according to Directive 1999/45/EC and its amendments. Highly flammable.

Highly flammable

3.

Composition/information on ingredients
Notes CAS number 64-17-5 107-98-2 111-76-2 78-10-4 EC number 200-578-6 203-539-1 203-905-0 201-083-8 % by weight 25 - 50 10 - 25 2.5 - 10 2.5 - 10 Classification F; R11 R10 R67 Xn; R20/21/22 Xi; R36/38 R10 Xn; R20 Xi; R36/37

Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances Directive 67/548/EEC. Chemical name* ethanol 1-methoxy-2-propanol 2-butoxyethanol tetraethyl silicate

See section 16 for the full text of the R-phrases declared above Occupational exposure limits, if available, are listed in section 8.

4.

First-aid measures
: In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and seek medical advice. : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or thinners. : 29.06.2010. Page: 1/5

First-aid measures General

Inhalation

Skin contact Date of issue

Resist 86 - Comp. A Eye contact Ingestion : Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. : If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do not induce vomiting.

5.

Fire-fighting measures
: Recommended: alcohol-resistant foam, CO 2, powders, water spray. : Do not use water jet. : Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Appropriate breathing apparatus may be required. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses.

Extinguishing media Extinguishing media not to be used Recommendations

6.

Accidental release measures

: Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist. Refer to protective measures listed in sections 7 and 8. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13).

Personal precautions

Spill : Preferably clean with a detergent. Avoid using solvents. Note: see section 8 for personal protective equipment and section 13 for waste disposal.

7.

Handling and storage

: Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapours in air and avoid vapour concentrations higher than the occupational exposure limits. In addition, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. To dissipate static electricity during transfer, earth drum and connect to receiving container with bonding strap. Operators should wear antistatic footwear and clothing and floors should be of the conducting type. Keep container tightly closed. Keep away from heat, sparks and flame. No sparking tools should be used. Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or mist arising from the application of this preparation. Avoid inhalation of dust from sanding. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Put on appropriate personal protective equipment (see section 8). Never use pressure to empty. Container is not a pressure vessel. Always keep in containers made from the same material as the original one. Comply with the health and safety at work laws. When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.

Handling

Storage

: Store in accordance with local regulations. Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away from heat and direct sunlight. Keep away from sources of ignition. Keep away from: oxidising agents, strong alkalis, strong acids. No smoking. Prevent unauthorised access. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not empty into drains.

Date of issue

: 29.06.2010.

Page: 2/5

Resist 86 - Comp. A

8.

Exposure controls/personal protection

: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and solvent vapours below the OEL, suitable respiratory protection must be worn. Occupational exposure limits EH40/2005 WELs (United Kingdom (UK), 8/2007). TWA: 1920 mg/m 8 hour(s). TWA: 1000 ppm 8 hour(s). EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbed through skin. STEL: 560 mg/m 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 375 mg/m 8 hour(s). TWA: 100 ppm 8 hour(s). EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbed through skin. STEL: 50 ppm 15 minute(s). TWA: 25 ppm 8 hour(s).

Engineering measures

Ingredient name
ethanol

1-methoxy-2-propanol

2-butoxyethanol

Personal protective equipment Respiratory system : If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use respiratory mask with charcoal and dust filter when spraying this product.(as filter combination A2-P2). In confined spaces, use compressed-air or fresh-air respiratory equipment. When use of roller or brush, consider use of charcoalfilter. Skin and body Hands : Personnel should wear antistatic clothing made of natural fibres or of hightemperature-resistant synthetic fibres. : Wear suitable gloves. May be used, gloves(breakthrough time) 4 - 8 hours: Teflon, PE, nitrile rubber, neoprene Not recommended, gloves(breakthrough time) < 1 hour: polyvinyl alcohol (PVA), PVC Recommended, gloves(breakthrough time) > 8 hours: butyl rubber, Viton, Saranex, 4H For right choice of glove materials, with focus on chemical resistance and time of penetration, seek advice by the supplier of chemical resistant gloves. The user must check that the final choice of type of glove selected for handling this product is the most appropriate and takes into account the particular conditions of use, as included in the user's risk assessment. : Use safety eyewear designed to protect against splash of liquids.

Eyes

9.

Physical and chemical properties

: : : : : : : Liquid. Characteristic. Various colours. Closed cup: 14C (57,2F) 1.09 g/cm3 1.1 - 19% Insoluble in the following materials: cold water and hot water.

Physical state Odour Colour Flash point Density Explosion limits Solubility

10. Stability and reactivity

Stable under recommended storage and handling conditions (see section 7). Hazardous decomposition products: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen. Keep away from the following materials to prevent strong exothermic reactions: oxidising agents, strong alkalis, strong acids.

Date of issue

: 29.06.2010.

Page: 3/5

Resist 86 - Comp. A

11. Toxicological information

There is no data available on the preparation itself. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See sections 2 and 15 for details. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible damage. Swallowing may cause nausea, diarrhoea, vomiting, gastro-intestinal irritation and chemical pneumonia.

12. Ecological information

There is no data available on the preparation itself. Do not allow to enter drains or watercourses. The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is not classified as dangerous for the environment.

13. Disposal considerations

Do not allow to enter drains or watercourses. Material and/or container must be disposed of as hazardous waste. European waste catalogue : 08 01 11* waste paint and varnish containing organic solvents or other dangerous substances. If this product is mixed with other wastes, this code may no longer apply. (EWC) If mixed with other wastes, the appropriate code should be assigned. For further information, contact your local waste authority.

14. Transport information

Transport within users premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. International transport regulations Proper shipping name : Paint UN Number : 1263 Class : 3 Packing group : II Label :

Additional information ADR / RID

IMDG

: Tunnel restriction code: (D/E) Hazard identification number: 33 Special provisions: 640D : Emergency schedules (EmS): F-E, S-E Marine pollutant: No.

Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.

15. Regulatory information

EU regulations Hazard symbol or symbols : The product is classified and labelled for supply in accordance with the Directive 1999/45/EC as follows: :

Highly flammable

Date of issue

: 29.06.2010.

Page: 4/5

Resist 86 - Comp. A Risk phrases Safety phrases Industrial use : R11- Highly flammable. : S23- Do not breathe vapour / spray. : The information contained in this safety data sheet does not constitute the users own assessment of workplace risks, as required by other health and safety legislation. The provisions of the national health and safety at work regulations apply to the use of this product at work.

16. Other information

CEPE Classification : 1 Full text of R-phrases : R11- Highly flammable. R10- Flammable. referred to in sections 2 and R20- Harmful by inhalation. 3 - United Kingdom (UK) R20/21/22- Harmful by inhalation, in contact with skin and if swallowed. R36/37- Irritating to eyes and respiratory system. R36/38- Irritating to eyes and skin. R67- Vapours may cause drowsiness and dizziness. This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No 1907/2006. : 29.06.2010. Date of issue : 1.02 Version Indicates information that has changed from previously issued version. Notice to reader The information in this SDS is based on the present state of our knowledge and on current laws. The product is not to be used for purposes other than those specified under section 1 without first obtaining written handling instructions. It is always the responsibility of the user to take all necessary steps to fulfil the demands set out in the local rules and legislation. The information in this SDS is meant to be a description of the safety requirements for our product. It is not to be considered a guarantee of the product's properties.

Date of issue

: 29.06.2010.

Page: 5/5